Transtar Ghs Sds 4063F

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SAFETY DATA SHEET.

Issuing date 10-Jan-2017 Revision Date 11-Mar-2022 Version 1.02

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier
Product name Super Stick Trim Adhesive
Product number 4063-F, 60-4063-F

Product Type Extremely flammable aerosol


Synonyms None
Supplier's details

Recommended Use Trim Adhesive. For Professional and Industrial Use Only.
Uses advised against Not for sale to the general public.

Manufacturer/Supplier: Transtar Autobody Technologies


2040 Heiserman Drive
Brighton, MI 48116
810-360-1600

CHEMTREC 24hr Emergency +1-703-741-5970 (INTERNATIONAL)


Telephone Number(s) 1-800-424-9300 (USA & Canada)

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2. HAZARDS IDENTIFICATION
Classification

Skin corrosion/irritation Category 2


Serious eye damage/eye irritation Category 2A
Reproductive Toxicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Aspiration toxicity Category 1
Flammable Aerosols Category 1
Gases under pressure Compressed Gas

GHS Label elements, including


precautionary statements

Emergency Overview
DANGER

Hazard Statements
Causes skin irritation.
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child
May cause respiratory irritation. May cause drowsiness or dizziness.
May cause damage to organs (Eyes, Skin, Respiratory System, Central Nervous System, and Peripheral Nervous System )
through prolonged and repeated exposure.
May be fatal if swallowed and enters airways.
Extremely Flammable Aerosol
Contains gas under pressure; may explode if heated

Appearance Cloudy Physical state Aerosol Odor Solvent Solvent

Precautionary Statements - Prevention


Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves, protective clothing,eye protection,face protection.
Wash face, hands and any exposed skin thoroughly after handling.
Do not breathe dust, fume, gas, mist, vapors, spray.
Use only outdoors or in a well-ventilated area.
Keep away from heat, sparks, open flames, hot surfaces - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.

Precautionary Statements - Response


If exposed or concerned: Get medical advice, attention.
Specific treatment (see first aid on this label)
IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice, attention
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice, attention.
Take off contaminated clothing and wash it before reuse.

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IF INHALED : Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor, physician if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER, doctor, physician.
Do NOT induce vomiting.

Precautionary Statements - Storage


Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F

Precautionary Statements - Disposal


Dispose of contents, container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC)

None

Other information

0% of the mixture consists of ingredient(s) of unknown toxicity.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight %*


PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 20-30
ACETONE 67-64-1 20-30
HEXANE 110-54-3 10-20
POLYTERPENE RESIN PROPRIETARY 10-20
CHLOROBENZOTRIFLUORIDE 98-56-6 10-20

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES


First aid measures for different exposure routes

General advice Avoid contact with eyes, skin, and clothing. Avoid breathing vapors, mist, or gas.

Eye contact Immediately flush with plenty of water for at least 15 minutes. After initial flushing, remove
any contact lenses and continue flushing. If eye irritation persists, consult a doctor.

Skin contact Wash off with soap and plenty of water. Remove and wash contaminated clothing before
re-use. If skin irritation persists, call a physician.

Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped,
contact emergency medical services immediately.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or Poison Control Center immediately. Risk of product entering the lungs on
vomiting after ingestion.

Most important symptoms/effects, acute and delayed

Main Symptoms Causes skin and serious eye irritation. May cause respiratory irritation. May cause
drowsiness or dizziness. May be fatal if swallowed and enters airways.

Indication of immediate medical attention and special treatment needed, if necessary

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Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Water fog.Dry chemical. Foam.Carbon dioxide (CO2). Cool containers/tanks with water spray.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical


Extremely Flammable / Flammable. Keep product and empty container away from heat and sources of ignition.

Explosion Data
Sensitivity to Mechanical Impact none.
Sensitivity to Static Discharge Yes.

Protective Equipment and Precautions for Firefighters


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Use shielding to protect fire-fighters from bursting containers. In the event of fire and/or explosion do not breathe
fumes.

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures

Personal precautions Use with adequate ventiliation to keep the exposure levels below the OELS.

Environmental precautions

Environmental precautions Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do
not allow material to contaminate ground water system. Prevent product from entering
drains. Report spills as required by local and federal regulations.

Methods and materials for containment and cleaning up

Methods for Containment Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material. Contain liquid and collect with an inter,
non-combustible material. Pick up and transfer to properly labeled containers. Clean
contaminated surface thoroughly . After cleaning, flush away traces with water. Prevent
product from entering drains. Take precautionary measures against static discharges.

7. HANDLING AND STORAGE


Precautions for safe handling

Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not
puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top
of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat,
flames, and all other sources of ignition. Keep can away from all sources of electricity such
as electric motors and batteries. Do not spray on hot surfaces.

Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep container tightly closed in a dry and well-ventilated place. Keep away from open
conditions flames, hot surfaces, and sources of ignition. Keep in properly labeled containers. Keep out
of the reach of children. Store locked up.

Incompatible products Strong acids, alkalis, oxidizing agents.

Aerosol Level 2

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
PROPANE/ISOBUTANE/N-BUTANE 74-98-6: TWA: 1000 ppm 74-98-6:TWA: 1000 ppm 74-98-6:IDLH: 2100 ppm
68476-86-8 106-97-8: STEL: 1000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm
75-28-5: STEL: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1800 mg/m3
(vacated) TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm
106-97-8: (vacated) TWA: 800 TWA: 1900 mg/m3
ppm 75-28-5:TWA: 800 ppm
(vacated) TWA: 1900 mg/m3 TWA: 1900 mg/m3

ACETONE STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm
67-64-1 TWA: 250 ppm TWA: 2400 mg/m3 TWA: 250 ppm
(vacated) TWA: 750 ppm TWA: 590 mg/m3
(vacated) TWA: 1800 mg/m3
(vacated) STEL: 2400 mg/m3
The acetone STEL does not
apply to the cellulose acetate
fiber industry. It is in effect for all
other sectors.
(vacated) STEL: 1000 ppm
HEXANE TWA: 50 ppm TWA: 500 ppm IDLH: 1100 ppm
110-54-3 Skin - potential significant TWA: 1800 mg/m3 TWA: 50 ppm
contribution to overall exposure (vacated) TWA: 50 ppm TWA: 180 mg/m3
by the cutaneous route (vacated) TWA: 180 mg/m3
CHLOROBENZOTRIFLUORIDE TWA: 2.5 mg/m3 F TWA: 2.5 mg/m3 F IDLH: 250 mg/m3 F
98-56-6 (vacated) TWA: 2.5 mg/m3
ACGIH: (American Conference of Governmental Industrial Hygienists)
OSHA: (Occupational Safety & Health Administration)
NIOSH IDLH: Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Exposure controls

Engineering Measures Showers, eyewash stations, and ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses with side-shields.

Skin and body protection Chemical resistant apron. Protective gloves.

Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.

Hygiene measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical and chemical properties

Physical state Aerosol


Appearance Cloudy Odor Solvent Solvent
Color Light Amber Odor Threshold

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Property Values Remar
ks •Met
hods
pH No information available
Melting/freezing point No information available
Boiling point/boiling range
Flash Point -96.4 °C / -141 °F Based on propellant
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limits in Air
upper flammability limit
lower flammability limit
Vapor pressure
Vapor density
Specific Gravity 0.806
Water solubility Practically insoluble
Partition coefficient: n-octanol/water
Autoignition temperature No information available Not applicable
Decomposition temperature
Viscosity No information available
Explosive properties

Other information

VOC Content(%) 42.10

10. STABILITY AND REACTIVITY


Reactivity
Stable under recommended storage
conditions

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions


None under normal processing.

Conditions to Avoid
Extremes of temperature and direct sunlight.

Incompatible Materials
Strong acids, alkalis, oxidizing agents.

Hazardous Decomposition Products


Carbon oxides , Hydrocarbons, Fumes.

11. TOXICOLOGICAL INFORMATION


Information on likely routes of exposure

Product Information

Inhalation Avoid inhaling vapors or mists. Harmful if inhaled. May cause irritation to respiratory
system.

Eye contact Causes serious eye irritation.

Skin contact Causes skin irritation.

Ingestion May be fatal if swallowed and enters airways.

Component Information

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Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
ACETONE = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h
67-64-1
HEXANE = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h
110-54-3
CHLOROBENZOTRIFLUORIDE = 13 g/kg ( Rat ) > 2 mL/kg ( Rabbit ) = 33 mg/L ( Rat ) 4 h
98-56-6

Information on toxicological effects

Symptoms Causes skin and serious eye irritation. May cause drowsiness or dizziness. May cause
respiratory irritation. May be fatal if swallowed and enters airways.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Irritating to skin.


Eye damage/irritation Irritating to eyes.
Irritation Causes eye and skin irritation . May cause respiratory irritation.
Sensitization No information available.
Germ cell mutagenicity Not a germ cell mutagen.
Carcinogenicity There are no carcinogenic chemicals in this product.
ACGIH: (American Conference of Governmental Industrial Hygienists)
A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
IARC: (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Group 1 - Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans
OSHA: (Occupational Safety & Health Administration)
X - Present
Reproductive toxicity This product contains a chemical(s) which is a known or suspected reproductive hazard .
Specific target organ systemic May cause respiratory irritation. May cause drowsiness or dizziness.
toxicity (single exposure)
Specific target organ systemic May cause damage to target organs listed below through prolonged and repeated
toxicity (repeated exposure) exposure.
Chronic toxicity Intentional misuse by deliberately concentrating and inhaling contents may be harmful or
fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and
potential cardiac arrest.
Target Organ Effects Eyes, Skin, Respiratory System, Central Nervous System , Gastrointestinal Tract, Liver,
and Kidney, Eyes, Skin, Respiratory System, Central Nervous System, and Peripheral
Nervous System.
Aspiration hazard May be fatal if swallowed and enters airways. No information available. May be fatal if
swallowed and enters airways.

Numerical measures of toxicity - Product Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity.


The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 26068 mg/kg
ATEmix (dermal) 23833 mg/kg
ATEmix (inhalation-dust/mist) 668 mg/l
ATEmix (inhalation-vapor) 102564 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Toxicity to algae Toxicity to fish Toxicity to Toxicity to daphnia and
microorganisms other aquatic invertebrates
PROPANE/ISOBUTANE/N- - - - -
BUTANE
68476-86-8
ACETONE - 4.74 - 6.33 mL/L LC50 - 10294 - 17704 mg/L EC50
67-64-1 Oncorhynchus mykiss 96h Daphnia magna 48h Static

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6210 - 8120 mg/L LC50 12600 - 12700 mg/L EC50
Pimephales promelas 96h Daphnia magna 48h
static 8300 mg/L LC50
Lepomis macrochirus 96h
HEXANE - 2.1 - 2.98 mg/L LC50 - -
110-54-3 Pimephales promelas 96h
flow-through
CHLOROBENZOTRIFLUOR - - - 3.68 mg/L EC50 Daphnia
IDE magna 48h
98-56-6

Persistence and degradability


.

Bioaccumulation

Chemical Name log Pow


PROPANE/ISOBUTANE/N-BUTANE 2.8
68476-86-8
ACETONE -0.24
67-64-1
CHLOROBENZOTRIFLUORIDE 3.7
98-56-6

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment

Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261). Dispose of in accordance with federal, state, and local regulations.

Contaminated packaging Do not re-use empty containers.

14. TRANSPORT INFORMATION

DOT Ground CONSUMER COMMODITY ORM-D


or
LIMITED QUANTITY

IATA UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD.QTY.

IMDG UN1950, AEROSOLS, 2.1, LTD. QTY.

15. REGULATORY INFORMATION


International Inventories

Chemical Name TSCA DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS
NCS
PROPANE/ISOBUTA X X X x X X X X
NE/N-BUTANE

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ACETONE X X X X X X X X
HEXANE X X X X X X X X
CHLOROBENZOTRIF X X X X X X X X
LUORIDE

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
CHINA - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

U.S. Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain a
chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,
Part 372:

Chemical Name CAS-No Weight %* SARA 313 - Threshold


Values %
HEXANE - 110-54-3 110-54-3 10-20 1.0

SARA 311/312 Hazard Categories


Acute Health Hazard Yes
Chronic Health Star Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard Yes
Reactive Hazard No

Clean Water Act


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).

CERCLA
This material, as supplied, does contain substances regulated as a hazardous substance under the Comprehensive Environmental
Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ


RQs
ACETONE 5000 lb RQ 5000 lb final RQ
67-64-1 RQ 2270 kg final RQ
HEXANE 5000 lb RQ 5000 lb final RQ
110-54-3 RQ 2270 kg final RQ
U.S. State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals:

This product can expose you to chemicals including those listed below, which is [are] known to the State of California to cause cancer, birth defects
or other reproductive harm. For more information go to www.P65Warnings.ca.gov

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Chemical Name California Prop. 65
HEXANE - 110-54-3 Developmental , Reproductive (Male) 10-20%

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania


ACETONE X X X
67-64-1
HEXANE X X X
110-54-3
CHLOROBENZOTRIFLUORIDE X
98-56-6
EPA Pesticide Registration Number Not applicable

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the SDS contains all the information required by the CPR.

16. OTHER INFORMATION


NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical
hazards -
HMIS Health Hazard 2* Flammability 4 Physical Hazard 1 Personal protection B
Chronic Hazard Star Legend Chronic Health Star Hazard Repeated or prolonged exposure may cause central nervous system
damage

Prepared By Transtar Autobody Technologies

Issuing date 10-Jan-2017


Revision Date 11-Mar-2022
Revision Note
15
Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.

End of Safety Data Sheet

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