Trimethylolpropane

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Product Safety Assessment

Trimethylolpropane

This document provides a brief description of trimethylolpropane, its uses, and the potential hazards
associated with short and long term exposure. Environmental impact information for accidental releases
is included. This information is general in nature and is not intended as a replacement for the safety
data sheet (SDS), product label and other safe handling literature. For additional information consult the
LANXESS safety data sheet.

Identification
Product Name: Trimethylolpropane
Chemical Name: 2,2-Dihydroxymethylbutanol-1
Synonym(s): 1,1,1-Trimethylolpropane
1,1,1-Tris(hydroxymethyl)propane
2,2-Bis(hydroxymethyl)-1-butanol
Hexaglycerol
CAS Number: 77-99-6

Description
Overview: Trimethylolpropane is a white solid in flake or powder form at ambient
temperatures. The chemical is shipped and used in a liquid (hot melt)
form. Liquid form trimethylolpropane is colorless and has a mild odor.
Uses: Trimethylolpropane is used as an additive or intermediate in the
manufacture of alkyd and polyester resins, synthetic lubricants,
polyurethane foams, lacquers, glues, adhesives, dyes, pigments, paints
and silicone products.
Properties: Melting Point: 138.2°F (58°C) Approx.
Boiling Point: 579°F (304°C)
Flash Point: 372°F (189°C) Soluble
Solubility in Water:

Last Revised: August 2015 Page 1 of 3


Product Safety Assessment: Trimethylolpropane

Potential Human Health Effects


Occupational Exposure
Potential for occupational exposure to trimethylolpropane exists during manufacture, at
transloading, storage and staging areas and in mixing or sampling operations. A much lower
potential for exposure exists in facilities using the chemical in closed manufacturing processes by
trained personnel.
Employee Training
Workers handling trimethylolpropane are trained to implement proper handling procedures and to
understand the potential health and physical hazards of this product. A NIOSH approved air-
purifying particulate respirator may be required in work environments with insufficient ventilation. In
addition, LANXESS recommends that goggles, permeation resistant clothing, gloves and foot
protection be worn when handling trimethylolpropane.
Consumer Exposure
LANXESS does not sell trimethylolpropane to the general public. Consumers may be exposed to
trace amounts of the chemical from the handling of products manufactured using the chemical as
an ingredient.
Short-Term Health Effects
Inhalation or ingestion of trimethylolpropane dust may induce a cough. Contact with heated (liquid)
trimethylolpropane may cause thermal burns. Mechanical irritation may occur when in contact with
the eyes.
Long-Term Health Effects
No applicable information was found concerning any adverse chronic health effects from
overexposure to this product.

Physical Hazards
Trimethylolpropane is stable under normal conditions of use. Avoid contact with moisture in storage.
Avoid contact with phosphorus compounds, nitric acid, hydrogen peroxide and strong oxidizing
agents. Heating to decomposition may release carbon monoxide, carbon dioxide and other
potentially toxic fumes.

Last Revised: August 2015 Page 2 of 3


Product Safety Assessment: Trimethylolpropane

Potential Environmental Impact


Trimethylolpropane is readily biodegradable. An accidental release to water may pose a danger to
fish (low toxicity), invertebrates (low toxicity) and other aquatic organisms (low toxicity) prior to
degradation. Bioaccumulation is not expected.

Conclusion
Under normal conditions of anticipated use as described in this Product Safety Assessment, and if
the recommended safe use and handling procedures are followed, trimethylolpropane is not
expected to pose a significant risk to human health or the environment.

References
International Chemical Safety Card, International Programme on Chemical Safety (IPCS)
IUCLID Dataset - CAS 77-99-6, European Chemicals Bureau, European Commission
Safety Data Sheet (SDS), TRIMETHYLOLPROPANE PURE LIQUID, LANXESS
Corporation
MedlinePlus Medical Encyclopedia, U.S. National Library of Medicine and the National
Institutes of Health
ToxNet Hazardous Substances Data Bank, U.S. National Library of Medicine, National
Institutes of Health and the U.S. Department of Health and Human Services

Contact Information
LANXESS Corporation, Product Safety & Regulatory Affairs, 111 RIDC Park West Drive, Pittsburgh, PA
15275-1112, USA, Phone 1-800-526-9377 [1-800-LANXESS]

Notices
Use and Application Information
The conditions of your use and application of our products, technical assistance and information
(whether verbal, written or by way of production evaluation(s)), including any suggested
formulations and recommendations, are beyond our control. Therefore, it is imperative that you test
our products, technical assistance and information to determine to your own satisfaction whether
they are suitable for your intended uses and applications. This application-specific analysis at least
must include testing to determine suitability from a technical as well as health, safety, and
environmental standpoint. Such testing has not necessarily been done by LANXESS. All
information is given without warranty or guarantee. It is expressly understood and agreed that
customer assumes and hereby expressly releases LANXESS from all liability, in tort, contract or
otherwise, incurred in connection with the use of our products and information. Any statement or
recommendation not contained herein is unauthorized and shall not bind LANXESS Corporation.
Nothing herein shall be construed as a recommendation to use any product in violation of any
patent covering any material or its use. No permission or license to use any patent is implied or in
fact granted by this publication.

Last Revised: August 2015 Page 3 of 3

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