Acetic acid 50-80% - Version 3 Page 1 of 12

SAFETY DATA SHEET

Acetic acid 50-80%

The safety data sheet is in accordance with Commission Regulation (EU) 2020/878 of 18 June 2020 amending
Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH)

SECTION 1: Identification of the substance / mixture and of the company /

undertaking
Date issued 13.07.2021
Revision date 18.08.2021

1.1. Product identifier

Product name Acetic acid 50-80%
Synonyms Acetic acid
Article no. 385, 435

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance / mixture Laboratory chemical.

1.3. Details of the supplier of the safety data sheet

Company name Acinor AS
Office address Titangt. 13, NO-1630 Gamle Fredrikstad
Postal address Titangaten 13
Postcode 1630
City Gamle Fredrikstad
Country Norway
Telephone number 69384082
Fax 69384084
Email post@acinor.no
Website www.acinor.no
Enterprise No. NO 984 648 324 MVA

1.4. Emergency telephone number

Emergency telephone Telephone number: +47 22 59 13 00
Description: Norwegian Poison Information Center

SECTION 2: Hazards identification

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2.1. Classification of the substance or mixture

Classification according to Skin Corr. 1B; H314
Regulation (EC) No 1272/2008
[CLP / GHS] Eye Dam. 1; H318
Substance / mixture hazardous Causes severe burns and eye damage.
properties

2.2. Label elements

Hazard pictograms (CLP)

Composition on the label Acetic acid ...%

Signal word Danger
Hazard statements H314 Causes severe skin burns and eye damage.
Precautionary statements P260 Do not breathe gas/mist/vapours/spray.
P280 Wear protective gloves / protective clothing / eye protection / face
protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water / shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor / physician.
P501 Dispose of contents / container to an approved waste facility.

2.3. Other hazards

PBT / vPvB PBT/vPvB assessment has not been performed.
Physicochemical effects Can form explosive gas-air mixtures.
Other hazards None of the components are listed on ECHAs Endocrine disruptor assessment
list.

SECTION 3: Composition / information on ingredients

3.2. Mixtures
Substance Identification Classification Contents Notes
Acetic acid ...% CAS No.: 64-19-7 Flam. Liq. 3; H226; 50 - 80 %
EC No.: 200-580-7 Skin Corr. 1A; H314;
Index No.: 607-002-00-6
REACH Reg. No.:
01-2119475328-30
Description of the mixture Aqueous solution.
Remarks, substance CAS No 64-19-7 has specific concentration limits:
Skin Corr. 1A; H314: C ≥ 90 %
Skin Corr. 1B; H314: 25 % ≤ C < 90 %
Skin Irrit. 2; H315: 10 % ≤ C < 25 %

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Eye Irrit. 2; H319: 10 % ≤ C < 25 %

Substance comments See section 16 for explanation of hazard statements (H) listed above.

SECTION 4: First aid measures

4.1. Description of first aid measures
General Emergency telephone number: see section 1.4. In case of unconsciousness or
severe accidents, call 112.
Inhalation Fresh air and rest. Serious cases: If not breathing, give artificial respiration. Get
medical attention.
Skin contact Remove contaminated clothing. Flush skin thoroughly with water. Chemical burns
must be treated by a physician. Get medical attention immediately!
Eye contact Promptly rinse eyes with plenty of water (tempered at 20-30°C) for at least 30
minutes. Remove contact lenses and open eyes wide apart. Transport to
physician. Keep on flushing during transport. Get medical attention immediately!
Ingestion Rins the mouth. Drink 1-2 glasses of water in small sips. Do NOT induce
vomiting. If vomiting occurs, keep head low so that stomach content doesn't get
into the lungs. Get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Acute symptoms and effects Skin contact: Corrosive. Forms blisters and can cause ulceration.
Eye contact: The chemical is corrosive to the eyes and may cause permanent
damage. Symptoms such as strong burning, tearing/watering, redness and
blurred vision may occur. In severe cases, there is a risk of visual damage/
blindness.
Ingestion: May have a corrosive effect on the digestive canal.
Delayed symptoms and effects Repeated or prolonged inhalation of dust increases the risk of developing lung
diseases.

4.3. Indication of any immediate medical attention and special treatment needed
Other information Treat symptomatically. No specific information from the manufacturer.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media Dry-powder, carbon dioxide (CO2), water mist, foam.
Improper extinguishing media Do not use water jet.

5.2. Special hazards arising from the substance or mixture

Fire and explosion hazards The chemical is not classified as flammable. Can form explosive gas-air
mixtures.
Hazardous combustion products May include, but is not limited to: Carbon dioxide (CO2). Carbon monoxide (CO).

5.3. Advice for firefighters

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Personal protective equipment Use compressed air equipment when the chemical is involved in fire. In case of
evacuation, an approved protection mask should be used. See also section 8.
Other information Containers close to fire should be removed immediately or cooled with water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures Keep away from sources of ignition - No smoking.
Personal protection measures Provide adequate ventilation. Use protective equipment as referred to in section
8. Avoid contact with skin and eyes. Avoid inhalation of vapours and aerosol
spray. Beware! The product is corrosive.

6.2. Environmental precautions

Environmental precautionary Do not allow to enter into sewer, water system or soil.
measures

6.3. Methods and material for containment and cleaning up

Clean up Absorb in vermiculite, dry sand or earth and place into containers. Do not use
sawdust or other combustible material. Collect in a suitable container and
dispose as hazardous waste according to section 13.

6.4. Reference to other sections

Other instructions See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Handling Provide adequate ventilation. Use protective equipment as referred to in section
8. Avoid inhalation of vapours and aerosol spray. Avoid contact with skin and
eyes. Beware! The product is corrosive.

Protective safety measures

Safety measures to prevent fire Keep away from heat / sparks / open flames / hot surfaces. — No smoking.
Vapours can form explosive mixtures with air.
Advice on general occupational Do not eat, drink or smoke during work. Wash hands at the end of each work shift
hygiene and before eating, smoking and using the toilet. Wash contaminated clothing
before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage Store in tightly closed original container in a dry, cool and well-ventilated place.
Keep upright.
Conditions to avoid Avoid heat, flames and other sources of ignition. Water, moisture.

Conditions for safe storage

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Advice on storage compatability Keep away from: Alcohols. Alkalies. Oxidizing agents. Water. Food and feed.

7.3. Specific end use(s)

Specific use(s) See section 1.2.

SECTION 8: Exposure controls / personal protection

8.1. Control parameters
Control parameters comments References (laws/regulations): Norwegian regulation on exposure limits:
"FOR-2011-12-06-1358 Forskrift om tiltaksverdier og grenseverdier for fysiske og
kjemiske faktorer i arbeidsmiljøet samt smitterisikogrupper for biologiske
faktorer (forskrift om tiltaks- og grenseverdier)".

DNEL / PNEC
DNEL Group: Professional
Route of exposure: Acute inhalation (local)
Value: 25 mg/m³
Comments: Applies to CAS-nr.: 64-19-7.

Group: Professional
Route of exposure: Long-term inhalation (local)
Value: 25 mg/m³
Comments: Applies to CAS-nr.: 64-19-7.
PNEC Route of exposure: Freshwater
Value: 3,0508 mg/l
Comments: Applies to CAS-nr.: 64-19-7.

Route of exposure: Saltwater

Value: 305.8 µg/l
Comments: Applies to CAS-nr.: 64-19-7.

Route of exposure: Sewage treatment plant STP

Value: 85 mg/l
Comments: Applies to CAS-nr.: 64-19-7.

Route of exposure: Freshwater sediments

Value: 11.36 mg/kg dw
Comments: Applies to CAS-nr.: 64-19-7.

Route of exposure: Saltwater sediments

Value: 1.136 mg/kg dw
Comments: Applies to CAS-nr.: 64-19-7.

8.2. Exposure controls

Precautionary measures to prevent exposure

Technical measures to prevent Provide adequate ventilation. The personal protective equipment must be
exposure CE-marked and the latest version of the standards shall be used. The protective
equipment and the specified standards recommended below are only
suggestions, and should be selected on advice from the supplier of such

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equipment.
A risk assessment of the work place/work activities (the actual risk) may lead to
other control measures. The protection equipment's suitability and durability will
depend on application.

Eye / face protection

Eye protection equipment Description: Wear tight-fitting goggles or face shield.
Reference to relevant standard: EN 166 (Personal eye-protection. Specifications).
Additional eye protection Eye wash facilities shall be available at the work place. Either a fixed eye wash
measures facility connected to the drinking water (preferably warm water) or a portable
disposable unit.

Hand protection
Suitable gloves type Butyl rubber. Polyvinyl chloride (PVC).
Breakthrough time Value: > 8 hour(s)
Thickness of glove material Value: 0.5 mm
Hand protection equipment Description: Use protective gloves that are suitable for the application. The
gloves abilities may vary among the different glove manufacturers.
Reference to relevant standard: EN ISO 374 (Protective gloves against chemicals
and micro-organisms). EN 420 (Protective gloves - General requirements and test
methods).
Additional hand protection Replace gloves if signs of wear and tear.
measures

Skin protection
Recommended protective clothing Description: Wear appropriate protective clothing to protect against possible skin
contact. Wear an apron. og gummistøvler.
Additional skin protection Emergency shower should be available at the workplace.
measures

Respiratory protection
Recommended respiratory Description: In case of inadequate ventilation or risk of inhalation of vapours, use
protection suitable respiratory equipment with combination filter (type E/P2).
Reference to relevant standard: EN 14387 (Respiratory protective devices. Gas
filter(s) and combined filter(s). Requirements, testing, marking). EN 143
(Respiratory protective devices - Particle filters - Requirements, testing, marking).

Appropriate environmental exposure control

Environmental exposure controls Do not allow to enter into sewer, water system or soil.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state Clear Liquid.
Colour Colourless.

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Odour Characteristic.
Odour limit Comments: Not determined.
pH Status: In aqueous solution
Value: ~ 2,5
Concentration: 20 g/l
Melting point / melting range Comments: Not relevant.
Freezing point Value: -27 - -7 °C
Boiling point / boiling range Value: 102 - 118 °C
Flash point Value: > 60 °C
Evaporation rate Value: 1,34
Test reference: Highest known value.
Flammability Not relevant.
Explosion limit Value: 4 - 19,9 vol%
Vapour pressure Value: ~ 0,2020 kPa
Vapour density Value: ~ 2,10
Relative density Value: 1,06 - 1,07
Density Value: ~ 1,0490 g/cm³
Temperature: 20 °C
Solubility Medium: Water
Comments: Soluble.
Partition coefficient: n-octanol/ Comments: Not relevant for a mixture.
water
Auto-ignition temperature Value: ~ 463 °C
Decomposition temperature Comments: Not determined.
Viscosity Value: ~ 1,17 mm2/s
Temperature: 20 °C
Type: Kinematic
Explosive properties Not determined.
Oxidising properties Not determined.

9.2. Other information

Other physical and chemical properties

Physical and chemical properties No further information is available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The chemical is water reactive. Reactive with the materials listed in Section 10.5.

10.2. Chemical stability

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Stability The chemical is stable under normal conditions of storage and use.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions Arise in contact with incompatible materials (see section 10.5) and/or under
inappropriate conditions (see section 10.4).

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Water, moisture.

10.5. Incompatible materials

Materials to avoid Alcohols. Alkalies. Oxidizing agents. Water.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal conditions. See also section 5.2.
products

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity Effect tested: LD50
Route of exposure: Oral
Duration: 6 day(s)
Value: 4960
Species: Mouse
Comments: Applies to CAS-nr.: 64-19-7.

Effect tested: LD50

Route of exposure: Oral
Duration: 6 day(s)
Value: 3310
Species: Rat
Comments: Applies to CAS-nr.: 64-19-7.

Effect tested: LC50

Route of exposure: Inhalation.
Duration: 14 day(s)
Value: > 16000
Species: Rat
Comments: Applies to CAS-nr.: 64-19-7.

Effect tested: LC50

Route of exposure: Inhalation.
Duration: 1 hour(s)
Value: 5620
Species: Mouse
Comments: Applies to CAS-nr.: 64-19-7.

Other information regarding health hazards

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Assessment of acute toxicity, Based on available data, the classification criteria are not met.
classification
Assessment of skin corrosion / Causes severe burns to the skin.
irritation, classification
Assessment of eye damage or Causes chemical burns to the eyes.
irritation, classification
Assessment of respiratory Based on available data, the classification criteria are not met.
sensitisation, classification
Assessment of skin sensitisation, Based on available data, the classification criteria are not met.
classification
Assessment of germ cell Based on available data, the classification criteria are not met.
mutagenicity, classification
Assessment of carcinogenicity, Based on available data, the classification criteria are not met.
classification
Assessment of reproductive Based on available data, the classification criteria are not met.
toxicity, classification
Assessment of specific target Based on available data, the classification criteria are not met.
organ toxicity - single exposure,
classification
Assessment of specific target Based on available data the classification criteria are not met.
organ toxicity - repeated exposure,
classification
Assessment of aspiration hazard, Based on available data, the classification criteria are not met.
classification

Symptoms of exposure
In case of ingestion May have a corrosive effect on the digestive canal.
In case of skin contact Corrosive. Forms blisters and can cause ulceration.
In case of inhalation Prolonged inhalation of high concentrations may damage respiratory system.
In case of eye contact The chemical is corrosive to the eyes and may cause permanent damage.
Symptoms such as strong burning, tearing/watering, redness and blurred vision
may occur. In severe cases, there is a risk of visual damage/blindness.

11.2 Other information

Other information None of the components are listed on ECHAs Endocrine disruptor assessment
list.

SECTION 12: Ecological information

12.1. Toxicity
Aquatic toxicity, fish Toxicity type: Acute
Value: > 300,82 mg/l
Effect dose concentration: LC50
Test duration: 96 hour(s)
Species: Oncorhynchus mykiss
Method: OECD 203
Comments: Applies to CAS-nr.: 64-19-7.

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Aquatic toxicity, algae Toxicity type: Acute

Value: > 300,82 mg/l
Test duration: 72 hour(s)
Species: Skeletonema costatum
Comments: Applies to CAS-nr.: 64-19-7.
Ecotoxicity The chemical is not classified as environmentally hazardous. However, this does
not exclude the possibility that large or frequent spills may be potentially
hazardous.

12.2. Persistence and degradability

Persistence and degradability Readily biodegradable.
description/evaluation

12.3. Bioaccumulative potential

Bioaccumulation, comments Not expected to bioaccumulate.

12.4. Mobility in soil

Mobility Soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB The chemical contains no PBT or vPvB substances.
assessment

12.6. Endocrine disrupting properties

Endocrine disrupting properties None of the components are listed on ECHAs Endocrine disruptor assessment
list.

12.7. Other adverse effects

Additional ecological information Do not allow to enter into sewer, water system or soil. Large spills can negatively
impact the aquatic environment locally due to an decrease in the pH-value.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Appropriate methods of disposal Disposed of as hazardous waste by approved contractor. The waste code
for the chemical (EWC-Code) is intented as a guide. The code must be chosen by the user, if the
use differs from the one mentioned below.
EWC waste code EWC waste code: 060106 other acids
Classified as hazardous waste: Yes

EWC waste code: 070101 aqueous washing liquids and mother liquors
Classified as hazardous waste: Yes
NORSAS 7134 Organic acids
Other information Do not empty into drains.

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SECTION 14: Transport information

Dangerous goods Yes

14.1. UN number
ADR/RID/ADN 2790
IMDG 2790
ICAO/IATA 2790

14.2. UN proper shipping name

Proper shipping name English ACETIC ACID SOLUTION
ADR/RID/ADN
ADR/RID/ADN ACETIC ACID SOLUTION
IMDG ACETIC ACID SOLUTION
ICAO/IATA ACETIC ACID SOLUTION

14.3. Transport hazard class(es)

ADR/RID/ADN 8
Classificaton code ADR/RID/ADN C3

14.4. Packing group

ADR/RID/ADN II
IMDG II
ICAO/IATA II

14.5. Environmental hazards

IMDG Marine pollutant No

14.6. Special precautions for user

Special safety precautions for user Not relevant.

14.7. Maritime transport in bulk according to IMO instruments

Product name ACETIC ACID SOLUTION
Ship type required Data lacking.

Additional information
Hazard label ADR/RID/ADN 8
Hazard label IMDG 8
Hazard label ICAO/IATA 8

ADR/RID Other information

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Tunnel restriction code E

Transport category 2
Hazard No. 80

IMDG Other information

EmS F-A, S-B

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance
or mixture
References (laws/regulations) Regulation (EC) No 1272/2008 on classification, labelling and packaging of
substances and mixtures (CLP-regulation) with later amendments. Regulation
(EC) No 1907/2006 on the registration, evaluation, authorization and restriction
of chemicals (REACH Regulation), with later amendments. The Carriage of
Dangerous Goods and Use of Transportable Pressure Equipment Regulations
2009. The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No.
895).

15.2. Chemical safety assessment

Chemical safety assessment Yes
performed

SECTION 16: Other information

Supplier's notes The information contained in this SDS must be made available to all those who
handle the product.
List of relevant H-phrases (Section H226 Flammable liquid and vapour.
2 and 3) H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
CLP classification, comments Calculation method.
Key literature references and Suppliers Safety data sheet dated: 07.03.2018.
sources for data
Abbreviations and acronyms used ADR: The European Agreement concerning the International Carriage of
Dangerous Goods by Road DNEL: Derived No Effect Level EWC: European Waste
Code (a code from the EU's common classification system for waste) IATA: The
International Air Transport Association ICAO: The International Civil Aviation
Organisation IMDG: The International Maritime Dangerous Goods Code LC50:
Median concentration lethal to 50% of a test population. LD50: Lethal dose, is the
amount of a substance given to a group of test animals, which causes the death
of 50%. PBT: Persistent, Bioaccumulative and Toxic PNEC: Predicted No Effect
Concentration RID: The Regulations concerning the International Carriage of
Dangerous Goods by Rail vPvB: very Persistent and very Bioaccumulative
Information added, deleted or Sections being revised since previous version: 1,16
revised
Version 3

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