Safety data sheet

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

MasterGlenium ACE 499 also GLENIUM ACE 499

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Product for construction chemicals

1.3. Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Construction Chemicals

Telephone: +49 621 60-74354

E-mail address: info.construction-chemicals@basf.com

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

No need for classification according to GHS criteria for this product.

 Page: 2/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
According to Directive 67/548/EEC or 1999/45/EC

Possible Hazards:
No specific dangers known, if the regulations/notes for storage and handling are considered.

2.2. Label elements

Globally Harmonized System, EU (GHS)

The product does not require a hazard warning label in accordance with GHS criteria.

According to Directive 67/548/EEC or 1999/45/EC

Directive 1999/45/EC ('Preparation Directive')

The product does not require a hazard warning label in accordance with EC Directives.

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Chemical nature

Aqueous solution based on: polycarboxylate ether

Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008

No particular hazards known.

Hazardous ingredients
according to Directive 1999/45/EC

Does not contain any hazardous ingredients.

 Page: 3/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. Immediately remove contaminated
clothing.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.

On skin contact:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances
should organic solvent be used. If irritation develops, seek medical attention.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: No significant symptoms are expected due to the non-classification of the product.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
foam, water spray, dry powder, carbon dioxide

Unsuitable extinguishing media for safety reasons:

water jet

5.2. Special hazards arising from the substance or mixture

Carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black

5.3. Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
 Page: 4/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire,
keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do
not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed
of in accordance with official regulations.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Do not breathe vapour/aerosol/spray mists. Wear eye/face protection. If exposed to high vapour
concentration, leave area immediately. Use personal protective clothing. Handle in accordance with
good building materials hygiene and safety practice.

6.2. Environmental precautions

Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

6.3. Methods and material for containment and cleaning up

For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of
contaminated material as prescribed.
For large amounts: Pump off product.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures
necessary provided product is used correctly.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect from direct sunlight.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

 Page: 5/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
111-42-2: 2,2'-iminodiethanol; diethanolamine

8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of
organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).

Hand protection:
impermeable gloves
Synthetic rubber gloves
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
light protective clothing

General safety and hygiene measures

Do not inhale gases/vapours/aerosols. Avoid contact with the skin, eyes and clothing. Avoid
exposure - obtain special instructions before use. Handle in accordance with good building materials
hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not
eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be
inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: liquid
Colour: yellow to amber
Odour: characteristic
Odour threshold:
No applicable information available.
pH value: approx. 7
(20 °C)
Melting temperature: approx. 0 °C
boiling temperature: approx. 100 °C
Flash point:
Non-flammable.
Evaporation rate:
not determined
Vapour pressure:
The product has not been tested.
Density: approx. 1.07 g/cm3
(20 °C)
 Page: 6/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
Relative vapour density (air):
not determined
Solubility in water: miscible
(20 °C)
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
Viscosity, dynamic:
not determined
Explosion hazard: not explosive

9.2. Other information

Miscibility with water:

(20 °C)
soluble
Hygroscopy: Non-hygroscopic
Solids content: approx. 31.5 %
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: No corrosive effect on metal.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

The product is stable if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:
strong acids, strong bases, strong oxidizing agents, strong reducing agents

10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually
nontoxic by inhalation. Based on available Data, the classification criteria are not met. The product
has not been tested. The statement has been derived from the properties of the individual
components.

Irritation

Assessment of irritating effects:

Not irritating to eyes and skin. The product has not been tested. The statement has been derived
from substances/products of a similar structure or composition.

Respiratory/Skin sensitization

Assessment of sensitization:
There is no evidence of a skin-sensitizing potential. Based on available Data, the classification
criteria are not met. The product has not been tested. The statement has been derived from the
properties of the individual components.

Germ cell mutagenicity

Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect.

Experimental/calculated data:
Ames-test
Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity

Assessment of carcinogenicity:
The chemical structure does not suggest a specific alert for such an effect.

Reproductive toxicity

Assessment of reproduction toxicity:

The chemical structure does not suggest a specific alert for such an effect.

Developmental toxicity

Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

No reliable data was available concerning repeated dose toxicity.
 Page: 8/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015

Other relevant toxicity information

On the basis of the product's composition, no acute general toxic effects are to be expected. The
product has not been tested. The statement has been derived from substances/products of a similar
structure or composition.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

There is a high probability that the product is not acutely harmful to aquatic organisms.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

Not readily biodegradable (by OECD criteria).

12.3. Bioaccumulative potential

Bioaccumulation potential:
No data available.

12.4. Mobility in soil

Assessment transport between environmental compartments:

Adsorption in soil: No data available.

12.5. Results of PBT and vPvB assessment

The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).

12.6. Other adverse effects

The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.

12.7. Additional information

Other ecotoxicological advice:

There is a high probability that the product is not acutely harmful to aquatic organisms. Do not
discharge product into the environment without control. The product has not been tested. The
statement has been derived from substances/products of a similar structure or composition.

SECTION 13: Disposal Considerations

 Page: 9/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
13.1. Waste treatment methods

Observe national and local legal requirements.

Residues should be disposed of in the same manner as the substance/product.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.

SECTION 14: Transport Information

Land transport

ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Inland waterway transport

ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Transport in inland Not evaluated
waterway vessel:
 Page: 10/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015

Sea transport

IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport

IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

14.6. Special precautions for user

 Page: 11/11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.11.2014 Version: 2.0
Product: MasterGlenium ACE 499 also GLENIUM ACE 499
(ID no. 30609759/SDS_GEN_EU/EN)
Date of print 18.09.2015
See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

15.2. Chemical Safety Assessment

Chemical Safety Assessment not required

SECTION 16: Other Information

In addition to the information given in the safety data sheet we refer to the product specific 'Technical
Information'.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.