2020 Rui Melt Conv
2020 Rui Melt Conv
2020 Rui Melt Conv
Ziliang Rui, Juan Li, Jie Ma, Han Cai, Binjian Nie, Hao Peng
PII: S2211-3797(20)31741-1
DOI: https://doi.org/10.1016/j.rinp.2020.103274
Reference: RINP 103274
Please cite this article as: Rui, Z., Li, J., Ma, J., Cai, H., Nie, B., Peng, H., Comparative study on natural
convection melting in square cavity using lattice Boltzmann method, Results in Physics (2020), doi: https://
doi.org/10.1016/j.rinp.2020.103274
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Engineering, Nanjing Tech University, No. 30 Pu Zhu South Road, Nanjing 211816, P. R. China
b School of Mechanical and Electrical Engineering, Nanjing Forestry University, No. 159 Long Pan Road, Nanjing 210037,
P. R. China
c School of Chemical Engineering, University of Birmingham, Birmingham B15 2TT, UK
Abstract:
The phase change process is of significant importance in the application of phase change material (PCM). In
this paper, the natural convection melting in a square cavity was investigated and the enthalpy-based lattice
Boltzmann model (TLBM) combined with the pseudo-potential LB model was developed to trace the solid-liquid
interface. Four cases with different boundary conditions were calculated and the corresponding temperature
contours, velocity vectors and average liquid fraction at various time were compared.
Results show that TLBM has good accuracy in simulating the solid-liquid phase transition process. Variation
in boundary conditions has appreciable impact on the natural convection process and melting behavior. Comparing
model.1 (single heating wall) with model.2 (double adjacent heating walls with cold wall), the maximum liquid
fraction is increased 16.7% in model.2 and the additional top heating wall acts to accelerate the average melting
rate by 16.7%. The comparison between model.3 (double opposite heating walls) and model.4 (double adjacent
heating walls without cold wall) shows that the natural convection heat transfer is intensive in model.3 and
resulting in a 280% faster melting rate than that in model.4. Comparing the melting rate between the model.5 (all
heating walls) and model.3, the increase of 54% due to the more heating walls in model.5 is observed.
Key words: Natural convection, phase change material, Lattice Boltzmann, liquid fraction, melting behavior
1
Nomenclature
total enthalpy corresponding to the solid dimensionless relaxation time for density
Hs τf
temperature [kJ∙kg-1] distribution function
2
1. Introduction
The phase change materials (PCM) are receiving significant attention for thermal energy storage in recent
years [1]. A small volume of PCMs can store massive energy during solid-liquid phase-change process[2]. With
the ability to absorb and release latent heat when undergoing solid-liquid phase change process, PCM have been
recommended to apply in waste heat recovery[3], liquid-air energy storage system(microchannel[4], tank[5],
packed bed units[6] ), thermochemical energy storage system[7], cryogenic thermal energy storage system[8] and
other thermal management systems [9]. Furthermore, Microencapsulated Phase Change Material (MPCM) based
thermal energy storage technology has the potential to reduce the energy consumption of the buildings[10], by
improving the indoor thermal comfort, when integrated directly into the building materials[11]. The solid–liquid
phase transition is the key issue in analyzing PCM thermal energy storage system [12] especially the latent heat
thermal system [13]. The moving boundary of solid–liquid interface[14] and the complicated heat transfer
mechanisms of multiphase is one of the main obstacles to solving the problem [15]. Consequently, many numerical
models are established to investigate phase transition process and obtain accurate results. Among a series of 2D
and 3D models such as T-shaped enclosure[16], triangular chamber[17], and porous enclosure[18] or chamber[19],
the 2D square cavity is one of the most used classic models. Due to its high computing efficiency and intuitive
results, the model has been applied to solve many complicated thermal systems.
The Lattice Boltzmann method, as a relatively new numerical model, is reliable in solving solid-liquid phase
change problem. Compared with traditional numerical models, its obvious advantages such as the mesoscopic
kinetic background, easy boundary treatment and inherently parallelizable computation property make it an
Three types of models have been applied in phase transition simulation: phase field LB method, interfacial
tracking method and enthalpy based LB method. In the phase field LB model, a governing equation for the order
parameter is introduced to capture the phase interface. Based on the phase field lattice Boltzmann, Abadi and
Rahimian [20]applied a hybrid lattice Boltzmann finite difference model to simulate the phase transition in a
ternary system. The model was validated against available results. In the interfacial tracking model, the movement
of phase interface was explicitly tracked by the Stefan condition. Huang and Wu [21]proposed an Immersed
Boundary-LBM for the simulation of solid-liquid phase change problem. The momentum force term and energy
force term were introduced to treat the solid-liquid interface. The simulation results were satisfactorily consistent
with analytical solutions. Li and Wu [22]established the LBM with interfacial tracking method to investigate the
melting and solidification of thin gold film and compared the results with those of Two-Temperature Model (TTM).
3
The results of the two models agreed well with the experimental data. The phase field model and interfacial
tracking model can basically solve the phase transition problem, however, the treatments of velocity and
temperature boundary conditions on the phase interface were quite complex in these two models.
The enthalpy-based LB model was introduced to simplify the phase interface treatment. Jiaung et al.
[23]proposed the first enthalpy-based LB model for the phase transition problem with heat conduction. In this
model, the total enthalpy was divided into two different variables: latent heat and sensible enthalpy. The latent
heat term was calculated as a heat source term in temperature field governing equation and an iteration procedure
was introduced to solve the implicit lattice Boltzmann equation. The phase interface and total enthalpy were
updated simultaneously. Several phase change simulations of different dimensions were established to validate
this model and the results were convincing. Xu et al. [24]extended the two-dimensional enthalpy-based lattice
Boltzmann model to treat the axisymmetric solid-liquid phase change problems and obtained highly accurate
results. Based on the enthalpy-based LBM, Lu et al. [25]proposed an optimal two-relaxation-time (OTRT) Lattice
Boltzmann Equation (LBE) and studied five cases including one-dimensional to three-dimensional solid-liquid
phase change process. Results showed that the OTRT LBE has a smaller numerical error than other LBE in a large
range of relaxation time. Ren et al. [26]used the enthalpy-based multiple-relaxation-time LBM to study the phase
change process of PCM in a latent heat thermal energy storage system and found that replacing rectangle fins with
triangle fins improved the charging rate of PCM. Eshraghi and Felicelli [27]proposed an implicit LB model in
order to simplify the calculating procedure. They employed their model to simulate two-dimensional solidification
of a binary alloy and compared computational performance with FEM. The results of implicit LBM agreed well
with those of FEM. Huang and Wu [28]proposed the total enthalpy-based LB model, and the latent heat term was
combined with the time derivative term in this model in order to improve the stability and computational efficiency.
The temperature field equilibrium distribution function was modified to recover the correct governing equation.
Hu et al. [29]incorporated this model with D3Q19 lattice and simulated several three-dimensional solid-liquid
phase change problems. The model was validated under the condition that the solid phase is unfixed. Huang and
Wu [30]investigated the phase interface effects for this LB model and then improved the total enthalpy-based
model by introducing the multiple-relaxation-time (MRT) collision term to solve the velocity equation [31]. Luo
et al. [32] used the total enthalpy-based LB model to investigate the influence of various numbers and arrangements
of tubes on the melting dynamics of shell and tube models under different Rayleigh and Stefan numbers. The
improved model was demonstrated to be accurate and efficient by studying a few melting cases.
Although the above LB models have been used widely for phase change problem, it can be found that those
4
simulation cases for the 2D phase transition in square cavity were based on simple boundary condition which
includes top adiabatic wall, bottom adiabatic wall and heating wall with opposite cold wall. The influences of the
number and position of heating wall on melting behavior were still insufficient and the physical principles that led
to those effects were not specifically explained. In addition, the effect of cold wall was usually ignored, further
investigations were needed. Therefore, in present work, the cases of natural convection melting process in a square
cavity with four different numbers and positions of heating walls were studied. The difference in the numbers and
positions of cold walls was also considered in these models. The enthalpy-based TLBM model combined with the
pseudo-potential LB model was developed to trace the solid-liquid interface and the BGK approximation with
D2Q9 Lattice was applied to simulate the temperature and the velocity fields. The temperature contours, velocity
vectors and average liquid fraction at various times in these different cases were discussed and analyzed. The
physical principles behind the effect of different boundary conditions were clearly revealed.
5
2. Lattice Boltzmann model
Adiabatic
Liquid
T=Th
T=Tc
Solid
Model.1
Adiabatic
The basic model (model.1) is shown in Fig.1, the cavity is filled by solid pure substance. The melting
temperature of the pure substance is Tm. The initial temperature of the cavity is Tc, the temperature of left boundary
is Th, and the top and the bottom walls are adiabatic.
(2) physical properties such as density, specific heat and thermal conductivity of both liquid and solid phase
For the comparative study, four models(model.2-5) with different boundary conditions were established, as
shown in Fig.2
T=Th Adiabatic
T=Th
T=Th
T=Tc
Solid
Solid
Model.2 Model.3
Adiabatic Adiabatic
(a)Double adjacent heating walls (with cold wall) (b) Double opposite heating walls
6
T=Th T=Th
Liquid Liquid
Adiabatic
T=Th
T=Th
T=Th
Solid
Solid
Model.4 Model.5
Adiabatic T=Th
(c) Double adjacent heating walls (no cold wall) (d) All heating walls
c pT Lf l
c pTu T Lf l u (1)
t t
For a pure substance, the third term on the right side of Eq (1) is usually ignored, Eq (1) can be simplified to:
H
c pTu T (2)
t
H c pT Lf l (3)
In present study, 2D Lattice Boltzmann model with 9 velocity vectors was used(D2Q9). The corresponding
(0, 0) i =0
k k
ci (cos( ),sin( ) i =1-4 (4)
2 2 2 2
k 9 k
2(cos( 2 4 ),sin( 2 4 )) i =5-9
4 / 9 i0
i 1/ 9 i 1-4 (5)
1/ 36 i 5-9
The Enthalpy-based lattice Boltzmann methods ‘TLBM’ is used for solid-liquid phase transitions. TLBM
uses temperature T as basic evolution variable in the LB equation, and the phase transition term is considered as
7
the sink term in collision step.
For the TLBM, the evolution equation for the temperature distribution function is expressed as [28]:
1 L
gi ( x ci t , t t ) gi ( x, t ) gi ( x, t ) gieq ( x, t ) twi f l ( x, t ) f l ( x, t t )
(6)
g cp
3 1
g (7)
c t 2
2
ci u (ci u ) 2 u 2
gieq wiT (1 2) (8)
c2 2c 4 2c
9
1
T
cp
g
i 0
i (9)
H c pT f l t t L (10)
0 H H s c pTc
H Hs
f l x, t H s H Hl H s L (11)
Hl H s
1 H Hl
Natural convection is considered and the Lattice Boltzmann equation for the natural convection source term
1
f i ( x ci t , t t ) f i ( x, t ) ( f i eq ( x, t ) f i ( x, t ))+tFi ci (12)
f
3 1
f (13)
c 2 t 2
ci u (ci u ) 2 u 2
f i eq ( x, t ) wi (1 2) (14)
c2 2c 4 2c
8
Th Tc
Fi 3wi G (T ) (15)
2 2
The Prandtl number (Pr), Rayleigh number (Ra) Stefan number (Ste) and Fourier number (Fo) are the four
key dimensionless parameters to characterize the melting behavior in the present work, as listed below [33]:
Pr / (16)
Fo t / l 2 (19)
To be noticed, in TLBM, the temperature can locally decrease below the initial solid temperature when the
sink term dominates at low Stefan number (St), which is in contradiction with the phase change associated with
pure substance melting. To avoid this situation, the value of St needs to be controlled at suitable level. Furthermore,
the pseudo-potential LB model was combined with TLBM model so the boundary treatment on the phase interface
was not required. To validate the present LB model, the results obtained in the present work was compared with
that in Mencinger’s work[34]. In his work, the Ra, Pr, and Ste number were 25000, 0.02, and 0.01 respectively,
and the dimensionless parameters in present model were set to the same values. Comparison of the average liquid
fraction(fl) between present LB model and Mencinger’s results is shown in Fig.3. The maximum error of fl is
1.96% and the average error is around 1.54% which proves that the present LB model is acceptable.
1.0
Mencinger's work[27]
0.8 Present model
0.6
fl
0.4
0.2
0.0
0 2 4 Fo 6 8 10
Fig.3 Comparison of the average fl between present LB model and previous work
For all the following models, the dimensionless parameters were set to be Ra=25000, Pr =0.02 and Ste=0.5.
9
All the results are obtained on the 50×50 square grid. The Fourier number (Fo) is used to represent the time step.
The LBM codes of this paper were solved in Visual Basic. Fig.4(a) shows the temperature contours and velocity
vector graphs (the black lines) of model.1. As shown in this figure, at Fo=0.4, the phase interface is nearly vertical
and the distribution of the velocity vector is generally regular. The reason may be attributed to the following. The
conduction effect plays the main role and the natural convection term can be neglected at the initial stage of the
melting process. While Fo=1, the phase interface is crooked and the solid material in the upper part of the cavity
melts faster than that in the lower part. It can also be noticed that a whirlpool caused by the natural convection
appears in the upper part of the flow field. While Fo increases to 2 and 4, the difference of the melting rate in the
upper and the lower part becomes pyramidally obvious, and the whirlpool in the flow field increases sharply. It
can be concluded that as the melting process goes on, the effect of natural convection becomes significant. Fig.4(b)
shows the average liquid fraction in single heating wall melting process. It can be found that the melting rate slows
down with the increase of the distance between solid-liquid interface and heating wall. Moreover, since the
temperature of cold wall is lower than the melting temperature, the solid materials in the cavity cannot melt
completely and the maximum value of average liquid fraction is about 0.6.
Temperature
1. 0
0.9
0.8
0.7
Fo=0.4 Fo=1
0.6
0.5
0.4
0.3
0.2
0.1
0.0
Fo=2 Fo=4
0.8
model.1
0.6
fl
0.4
0.2
0.0
0 1 Fo 2 3 4
In this section, the effect of double heating walls (model.2, model.3 and model.4) on the melting behaviors
(temperature contour, velocity vector and average liquid fraction) was investigated. The corresponding boundary
In Fig.2(a), the top and the left wall were both heating walls (model.2). Fig.5 shows the simulation results of
the temperature and velocity distribution. When Fo=0.4, the melting process in the upper area of the cavity is
significantly accelerated compared with Fig.4(a). The natural convection phenomenon in the velocity field is
clearly observed at Fo=1. As illustrated in figures of Fo=1, 2 and 4, the temperature contours and velocity vectors
in the lower region are almost the same with those in Fig.4(a), which indicates that the melting behavior in the
lower area in model.2 is similar with that in model.1. It can be concluded that the top heating wall accelerates the
melting rate of the upper solid phase but it has little influence on the phase transition in the lower area.
Temperature
1. 0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
Fo=0.4 Fo=1 0.0
11
Fo=2 Fo=4
In Fig.2(b), the right cold wall was replaced by a heating wall. As seen from the simulation results in Fig.6,
the temperature contours and velocity vector graph are vertically symmetrical. While Fo=0.4, the temperature
contour and velocity vector in the left half region of model.3 are almost the same as those of model.1. Isotherms
in central area are in shapes of peak curve when Fo=0.6. Two whirlpools can be seen at this moment too, which
means the convection term acts on both left and right sides. While Fo=0.8, the left and right liquid phase of the
upper region gets in contact with each other and the solid-liquid interface is in shape of peak curve. While Fo=1
the cavity is nearly filled with liquid which means the phase changing process is almost complete.
Temperature
1. 0
0.9
0.8
0.7
0.6
Fo=0.4 Fo=0.6
0.5
0.4
0.3
0.2
0.1
0.0
12
Fo=0.8 Fo=1
In Fig.2(c), the right cold wall is replaced by an adiabatic wall. The top and right walls are heating walls.
From the results in Fig.7, while Fo≤2, the temperature contour, velocity vector and phase interface are diagonally
symmetric and the shapes of both phase interface and isotherms are getting closer to quarter circle. However, the
symmetry does not exist anymore at Fo=3, and the cavity is almost filled with liquid. This is because that the
gravity force only has little effect on liquid phase while the solid phase exists. With the melting process pushing
on, the area of solid phase decreases and the effect of gravity increases. Furthermore, the whirlpool in this model
is obviously larger than other models due to the influence of top heating wall and right adiabatic wall.
Temperature
1. 0
0.9
0.8
0.7
Fo=0.4 Fo=1
0.6
0.5
0.4
0.3
0.2
0.1
0.0
Fo=2 Fo=3
In order to quantitatively analyze the melting behaviors, the comparison of average liquid fraction fl for
The comparison between mode.1 and model.2 proves that the top heating wall has little effect on the variation
rate of the melting speed. It can also be noticed that the maximum fl of model.2 increases to 0.7 which means the
action of top heating wall increases the average melting rate by 16.7%. Comparing model.4 to model.2, when
13
Fo=3.1, the fl of model.4 and model.2 are 1 and 0.68 respectively. In other words, the average melting rate of
model.4 increases by 84.33% compared with that of model.2. That is because the cold wall seriously hinders the
melting behavior. According to the comparison between model.3 and model.4, the melting end time of model.3
and model.4 are Fo =3.1 and Fo=1.1 respectively. It can be observed that the average melting rate of opposite
heating walls melting is 280% faster than that of adjacent heating walls melting. The explanation can be given for
this phenomenon. The difference in temperature caused by left or right heating wall induce an extra driving force
in upward direction. The upward driving force accelerates the movement of liquid phase in the cavity and enhance
the natural convection heat transfer. However, the driving force arisen from the top heating wall only acts on the
liquid phase near the top wall because of gravity force. The conclusion can be drawn that the natural convection
heat transfer is intensive under the action of right heating wall. Moreover, the trends of average liquid fraction
show that the melting rate in model.3 accelerates during Fo=0.6 to 0.8 which is obviously different from those of
the other three models. The reason can be attributed to the natural convection phenomenon caused by left and right
heating wall becomes especially obvious when the left and right phase interface get in contact with each other.
1.0
model.4
0.8 model.3
0.6
model.2
fl
0.4 model.1
Fo=3.1
0.2
Fo=1.1
0.0
0 1 2 3 4
Fo
Fig.8 Average fl comparison of model.1: single heating wall melting, model.2: double adjacent heating walls
melting (with cold wall), model.3: double opposite heating walls melting and model.4: double adjacent heating
walls melting (no cold wall)
while Fo=0.4, the isotherms near the center point and the solid-liquid interface are almost circular. As the Fo
increases to 0.6, the circular phase interface becomes elliptic because of the faster melting rate in the upper area
and the gravity force. In addition, from the comparison of average liquid fraction in Fig.9(b), the sudden change
in melting rate does not exist in all heating walls melting process. The finish time of model.5 and model.3 are 0.68
14
and 1.05 respectively which means the additional heating walls in model.5 increase the melting rate by 54%.
Temperature
1. 0
0.9
0.8
0.7
Fo=0.4 Fo=0.6
0.6
0.5
0.4
0.3
0.2
0.1
0.0
Fo=0.64 Fo=0.68
0.8
0.6 model.5
model.3
fl
0.4
Fo=1.1
0.2
Fo=0.68
0.0
0.0 0.5 1.0 1.5 2.0 2.5
Fo
Fig.9(b) Comparison of average fl between model.3: double opposite heating walls melting and model.5: all
4.Conclusion
In this paper, the enthalpy-based TLBM model has been developed to simulate the 2D natural convection
15
melting process in square cavity. For all examples with mixed boundary conditions, good accuracy is demonstrated.
(1) In model.2 (double adjacent heating walls with cold wall), the top heating wall accelerates the melting
rate of the upper solid phase but has little influence on the phase transition in the lower area. The maximum liquid
fraction in model.2 has a 16.7% augment and the additional top heating wall expedites the average melting rate by
16.7%.
(2) The comparison between model.3 (double opposite heating walls) and model.4 (double adjacent heating
walls without cold wall) shows that the difference in diving forces arisen form different heating walls causes the
enhancement in natural convection heat transfer and a 280% faster melting rate in model.3. Moreover, when the
left and right phase interface get in contact with each other, the enhancement in heat transfer caused by left and
(3) Comparing model.2 with model.4, the average melting rate of model.4 is 84.33% faster than that of
model.2 because the cold wall seriously hinders the melting behavior.
(4) The comparison between model.5 (all heating walls) and model.3 demonstrates that the additional heating
Acknowledgement
The authors acknowledge the financial support provided by National Natural Science Foundation of China
(Grant No. 51776095) and Young Science Leaders Project of Jiangsu Province.
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Credit author statement
Rui Ziliang: Conceptualization, Methodology, Software, Data Curation, Writing - Original
Draft.
Li Juan: Data curation, Formal analysis.
Ma Jie: Writing- Reviewing and Editing.
Han Cai: Writing- Reviewing and Editing.
Nie Binjian: Writing- Reviewing and Editing, Supervision, Validation.
Peng Hao: Writing- Reviewing and Editing, Resources, Project administration, Funding
acquisition
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Highlights
The TLBM model was developed to simulate the 2D natural convection melting.
Four cases with various numbers and positions of heating walls were calculated.
For all cases with mixed boundary conditions, good accuracy is demonstrated.
21