0801232020piw27 Qp. Aod

0801232020PIW27
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. A sphere and a cube of same material, surface finish and same total surface area are
placed in the same evacuated space turn by turn after they are heated to the same
temperature. Find the ratio of their initial rates of cooling in the enclosure.
 
A) :1 B) :1 C)  : 1 D)  : 1
6 3 6 3
2. A rod of length  and cross section area A has a variable thermal conductivity given by
K  T, where  is a positive constant and T is temperature in Kelvin scale. The two
ends of the rod are maintained at temperatures T1 and T2  T1  T2  . Heat current (rate of
heat flow) flowing through the rod in the steady state will be
A)

A T1  T22
2
 B)

A T1  T22
2
 C)

A T1  T22
2
 D)

A T1  T22
2

  3 2
3. A potato at initial temperature T0 is placed inside a hot convection oven maintained at a

constant temperature T1(>T0). Assume that the potato receives heat only because of
convection phenomenon and the rate at which it receives heat is given as hA (T1 –T)
where h is a constant, A is surface area of the potato and T is instantaneous temperature
of the potato. Mass and specific heat capacity of the potato are m and s respectively. In
T0  T1
how much time the potato will be at a temperature T2  ? Assume no change in
2
volume of the potato.
2ms ms ms 3ms
A) log e 2 B) log e 2 C) log e 2 D) log e 2
hA hA 2hA 2hA
4. Consider a composite cylinder shown in the figure. The conductivity of the material the
cylinder from radius a to 2a is K1 and that for the cylinder from radius 2a to 4a is K2.
The temperature of inner most wall is maintained at temperature T1 and the outermost
wall is maintained at temperature T2. Find the temperature T of the intermediate
cylindrical wall of radius 2a.
K1T1  K 2T2 K1T2  K 2T1 K1 K2

A) B) C) T1  T2  D) T1  T2 
K1  K 2 K1  K 2 2K2 2 K1
5. The earth is getting energy from the sun whose surface temperature is Ts and radius R.
Let the radius of the earth be r and the distance from the sun be d. Assume the earth
and the sun both to behave as perfect black bodies and the earth is thermal equilibrium
at a constant temperature Te . If the temperature Ts of the sun is xTe where x is
2d 2R 4d d
A) B) C) D)
R r r r
6. If a body takes 6 minutes to cool from 800C to 700C, how long will it take to cool from
600C to 500C, if the surrounding temperature is 250C?(Assume Newton’s Law of
Cooling is valid)
A) 8 min B) 10 min C) 12 min D) 6 min

SECTION - 2 (Maximum Marks : 24)
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
7. One mole of an ideal gas goes through a cycle consisting of alternate isothermal and
adiabatic curves. AB, CD, EF are isothermal and BC, DE, FA are adiabatic curves.
Temperature of each isothermal curve is given in the graph. The volume changes two
fold in every isothermal expansion. Choose the correct options(s)
A) Work done by the gas in the cycle is R T1  T2  2T3  log e 2
B) Work done by the gas in the cycle is R  2T3  T1  T2  log e 2
C) Heat absorbed by the gas is R T1  T2  log e 2
2T3
D) Efficiency of cycle is 1 
T1  T2
8. An amount Q of heat is added to a mono atomic ideal gas in a process in which the gas
Q
performs a work on its surrounding. Choose correct option (s) (Symbols have usual
2
meaning)
A) Equation of the process is PV 1/3  Constant
B) Equation of the process is PV 4/3  Constant
C) Molar heat capacity for the process is 3R
D) Molar heat capacity for the process is 3R / 2
9. A composite block is made of slabs A,B,C,D and E of different thermal conductivities

(given in terms of a constant K) and sizes (given in terms of length, L) as shown in the
figure. All slabs are of same width. Heat ‘Q’ flows only from left to right through the
blocks. Then in steady state.Choose the correct options(s)
A) heat flow through A and E slabs are same

B) heat flow through slab E in maximum
C) temperature difference across slab E is smallest
D) Heat flow through C = Heat flow through B + Heat flow through D
10. A heat conductor of length L has its surface A and B at temperature 2T and T
respectively (in steady state) Its thermal conductivity is k. Choose correct options :
L
A) Thermal resistance will be
k ab
B) Temperature gradient decreases along its length (left to right)
C) Temperature gradient increases along its length (left to right)
D) If the above conductor replace with another rod of same material same length with
uniform area of cross-section for the same rate of heat flow the radius of the rod is
ab
2
11. A metal cylinder of 5kg is heated electrically by a 20W heater in a room at 200C. The
cylinder temperature rises unoiformly to 300C in 5 minute and finally becomes constant
at 450C. Assuming that the rate of heat loss is proportional to the excess
temperaturteover the surroundings.Choose the correct options(s)
A)The rate of loss of heat of cylinder to surrouding at 250C is 4W
B) The rate of loss of heat of cylinder to surrouding at 450C is 20W
C) The rate of loss of heat of cylinder to surrouding at 100C is 8W
D) The specific heat capacity of metal is 120J/Kg k
12. Two stars A and B of same size, have thermal emissivities of 0.2 and 0.64 respectively.
Both stars emit total radiant power at same rate. If the temperature of A is 5000K and
the wavelength B corresponding to maximum spectral radiancy in the radiation from
B is shifted from the wavelength corresponding to maximum spectral radiancy in
radiations from A by 2.0  m , then find the temperature of star B and wavelength B
.Choose the correct options(s).(Take 51/4  1.495 )
A) The temperature of star B is 3738K
B) The temperature of star B is 2890K
C) B  7.92  m
D) B  5.21 m
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. One mole of an ideal mono atomic gas is taken around a cyclic process shown in
figure. The processes AB,BC,CD and DA are isobaric, adiabatic, isochoric and
 
isothermal respectively. It is given TA  4TB and VA  8 2 VD . Find the efficiency of
the cyclic process. (Round off to two decimal places) (Take log e 2  0.693 )
14 A thin spherical shell of radius R made up of highly conducting material contains
water at 00C. The thermal conductivity of ice is K and the latent heat of fusion of ice is
L. The density of water is  . If the time required to freeze the whole mass of wateris
 LR 2
. Find the value of X.
XK
(Neglect the expansion during freezing, Take temperature of atmosphere  0C )
15 An adiabatic chamber has frictionless insulated piston of mass m. Mss of the remaining
chamber is 4m. An ideal monoatomic gas is present inside the chamber in very small
quantity i.e. the mass of gas is very small compared to the system (Take n mole) at
atmospheric temperature and pressure. Piston is in relaxed state and confined to move
horizontally along the length of chamber. A block of mass m moving horizontally with
speed v, strikes elastically with the piston. The change in temperature of the gas is T ,
when the compression of the piston is maximum. The change in temperature of gas is
Kmv 2
, then the value of K is ……… ( R is gas constant)
15nR
16. Two containers A and B are connected by a conducting solid cylindrical rod of length
242
cm and radius 8.3 cm. Thermal conductivity of the rod is 693 watt/m–K. The
7
container A contains two mole of oxygen gas and the container B contains four mole of
helium gas. At time t = 0 temperature difference of the containers is 50ºC, after what
time (in seconds) temperature difference between them will be 25ºC. Transfer of heat
takes place through the rod only. Neglect radiation loss.
22
(Take R = 8.3 J/mole–K and   , log e 2  0.693 )
7
A B
O2 He
17. A rod of length l = 0.693 m with thermally insulated lateral surface consists of material
2
whose heat conductivity coefficient varies with temperature as K  , where T is the
T
temperature in Kelvin.The ends of the rod are kept at temperature
T1  400 2 K and T2  200 2 K .The temperature in kelvin at the mid point of the rodis
100  p  K . Then find the value of p.

[ Given ln 2 = 0.693 ]
18. All the rods in given arrangement are made up of same material and have same cross-
section. Find the temperature of junction O (in 0C). (Neglect the transfer of heat
through radiations and convection)
0801232020PIW27
CHEMISTRY MAX.MARKS: 66
19. Which compound would give 5-oxo-2-methyl hexanal upon ozonolysis?
A) B) C) D)
20. Select the major organic product for the given reaction from the following options.
Br
CH 3 CH 3 Alc. KOH (Excess)
Δ
Ph
Br
CH 3
CH3
CH 3 CH 3 CH 3 CH 3
CH 3
A) B) Ph C) Ph
D) Ph CH3
Ph
21. Which of the following reaction is not correctly matched with its major organic product
OH
H2C CH3 H3C CH3
(i) Hg(OAc)2/H2O
A) CH3 CH3
H3C (ii) NaBH4 H3C
HO
D CH3
1. B2H6/THF D
CH3
B) H3C
H3C D 2. H2O2/NaOH D
H
CH3 CH3
MCPBA (1 Equiv.)
C) O
CH3 CH3
CH3
CH3 OH
Alkaline KMnO4
D) OH
cold
H
22. A hydrocarbon X of formula C8H14 is reduced by Na in liq.NH3 to a single product Y
(C8H16). Bothof these compounds (X and Y) undergo hydrogenation over Pt catalyst to
give 2,5–dimethyl hexane.Ozonolysis of Y with an oxidative work up produces a single
carboxylic acid (C4H8O2). Reaction of Ywith perbenzoic acid (C6H5CO3H) gives a
chiral product (C8H14O), but reaction with bromine givesan achiral product (C8H14Br2).
What are X and Y?
A) X is 2, 5–dimethyl hex –3– yne; Y is cis–2, 5–dimethyl hex–3–ene
B) X is 2, 5–dimethyl hex–3–yne; Y is trans–2,5–dimethyl hex–3–ene
C) X is 2,5–dimethyl hexa–1,5–diene; Y is 2,5–dimethyl hex–3–yne
D) X is 2,5–dimethyl hexa–2,4–diene; Y is cis–2,5–dimethyl hex–3–ene
23. Identify ‘[Z]’ in the following reaction sequence,

H3C (i) B2H6/THF Cl2/H2O
Al2O3/Δ
CH2 [X] [Y] [Z]
(ii) H2O2/OH-
Note – Consider major organic product in each step

Cl OH OH
Equimolar mixture of H3C and H3C H3C

A) B)
Cl Cl Cl
Cl Cl
H3C H3C
C) D)
HO Cl
24. The correct stability order of the following species is
(x) (y) (z) (w)
A) x> y > w > z B) y > x > w > z C) x > w > z > y D) z > x > y > w
correct options.
option.
25. Which of the following statements are true about the following reaction.
H3C CH3
O
B2 H 6 Et OD
Borane Deuterated
THF intermediate product
CH2
A) Resultant product is Bicycloduterio-alkane
B) Borane approaches reactant from top face
C) Borane approaches reactant from bottom face
D) Reaction of Borane to above alkene follow Markownikov addition
26. An alkyl bromide [X] produces single alkene[Y] when it reacts with alcoholic EtONa.
[Y] upon hydrogenation produces 2-methylbutane. Choose the correct statement(s)

among the following.
A) [X] is a tertiary alky bromide
B) [X] is a primary alky bromide
C) [X] may or may not show stereoisomerism
D) [Y] can exhibit geometrical isomerism

27. The product (s) in the above reaction that can be formed is/are
Br2, H 2O
Product(s)
NaCl
Br Br Cl Br
A) B) C) D)
Cl Br Cl OH
28. Identify the correct statement(s) about the product “A and B” formed in the following
reactions. (Consider only major products for both reactions and assume carbocations do
not rearrange)
H2C
(i) CH2 + HCl Product [A]

(Excess)
H2C
H2C
(ii) CH2 + HCl Product [B]

(Excess)
A) In reaction (i), two geometrical isomers of (A) are possible.
B) In reaction (i), two optical isomers of (A) are possible.
C) In reaction (ii), two geometrical isomers of (B) are possible.
D) In reaction (ii), three stereoisomers of (B) are possible.
29. Which of the following statements is/are correct?
A) Trans 2-phenyl cyclohexyl acetate on pyrolysis gives 1-phenyl cyclohexene as

major product.
B) Cis 2-phenyl cyclohexyl acetate on pyrolysis gives 1-phenyl cyclohexene as major

product.
CH3
OCOR
C) on pyrolysis gives 1-methyl cyclohexene as major product.

O O
CH3
H
Δ
A (Major product)
D) Major product A is
30. Correct statement(s) regarding addition of Br2 to the following compound is/are.
Me
H
Et
H
H Me
A) Br2 serve as electrophile in the first step of reaction.

B) Total two (major) products are formed.
C) Cyclic bromonium ion is formed as the intermediate.
D) If this addition proceeds in H2O, bromohydrin forms as product.
31. CH3
Br Alc.KOH (Excess)
Br
[Y]; Major elimination product
H3C
Δ
Br
CH3
[X]
If number of stereoisomers possible for [X] are Mand number of stereoisomers of

organic elimination products [Y] (by assuming completedehydrohalogenation)
obtained in the above reaction are N.
Find the value of M + N.

32. How many of the following reaction sequences are correctly matched with their major
organicProduct(s)?
HO O O
OH
KOH/Δ
I.
Ph Ph Ph Ph
CH3
H3C KOH/EtOH CH3
II. + H3C
S Δ
H3C CH3
Ph H3C
H3C Br
III. 
KOCH 2 CH3
HOCH 2 CH3
H Ph Ph
H Ph
Cl
IV. Alc.KOH/Δ
V.
VI.
VII.
33. An alkene [X] on ozonolysis gives acetone as the only organic product. The number
ofcyclic structural isomers (containing four and five membered rings only) of the
alkene [X] is_______
34. Identify the magnitude of X-Y
H
 B  
Ni 
2
 A 
HOT KMnO 4
 diethyl Ketone + CO 2 
 Alkene 
Cl 2
hν
 X 
Fractional
distillation
 Y fractions
 number of isomeric 
monochloro products
35. Consider following reactions.
Ifp = number of ( – H) in compound X;
q = number of ( – H) in compound Y;
Then value of (q – p) is
36. Analyse the following reaction sequence

CH3
1. Alc.KOH/Δ
Br [X]; Major organic product
2. HBr/CH2Cl2
3. t -BuOK/Δ
Find the total number of C – H bonds taking part in hyperconjugation in the major
organic product [X]
Note – Consider major organic product in each step to proceed further

0801232020PIW27
MATHEMATICS MAX.MARKS: 66
37. A horse runs along a circle with a speed of 20km/h. A lantern is at the centre of the
circle. A fence is there along the tangent to the circle at the point at which the horse
start. The speed with which the shadow of the horse moves along the fence at the
moment when it covers 1/8 of the circle in km/h is__.
A) 20 B) 40 C) 30 D) 60
k
38. The function f  x   2 x  x  2  x  2  2 x has a local maximum at x  k then 
2
A) 0.66 B) 0.33 C) 0.25 D) 0.87
39. Let f  x   30  2 x  x3 , then find the number of positive integral values of x which
satisfies f  f  f  x     f  f   x  
A) 5 B) 4 C) 2 D) 1
40. A point P moves on the curve y  2 x 2 and its velocity at P  x, y  is 4 feet per second.
Then rate at which inclination of tangent to the curve at P changing when P 1, 2  is
16 16 16
A) rad / sec B) rad / sec C) rad / sec D) 2 rad / sec
17 17 17 17
41. The number of parallel tangents to f1  x   x 2  x  1 and f 2  x   x3  x 2  2 x  1 is___.
A) 0 B) 1 C) 2 D) Infinite
b 2c 3
42. If ax 2   c for all positive x where a  0, b  0 then maximum value of
x ab 2
27 27
A) 27 B) C) D) 1
2 4
correct options.
option.
1
43. For the function f  x   x cos , x  1 , Which of the following is correct?
x
A) For atleast one x in 1,   , f  x  2   f  x   2
B) Lt f '  x   1 C) x in 1,   , f  x  2   f  x   2
x 
D) f '  x  strictly decreases in [1, )
44. Let f  x  and g  x  be derivable functions satisfying the following equations
 f '  x   f  x   g  x   g  x   g '  x  and

2
 g '  x   g  x   f  x   f  x   f '  x  ; x  R
2
if f  0   1  2; g  0   1  2 , then
A) f  x  is increasing function B) g  x  is increasing function
C) f  x   0x  R ` D) g  x   0x  R
 x   x 1
45. Let f  x    x 1  x  , where  x   greatest integer function and  x 
1  x   x
fractional part of x . Then which of the following is/are Correct?
A) f  x   0 for x   , 1
B) f  x  has no real root for x   0,1

C) for x   0,1 , range of f  x  is (2, 1]
D) for x  [1, 2), f  x  has exactly one local minima
Let f  x    x 2  1  x 2  x  1 , n  N then f  x  has local extremum at x  1 , when

n
46.
A) n  2 B) n  3 C) n  4 D) n  6
  
47. Let the function g :  ,      ,  be given by g  u   2 tan 1  eu   . Then which of

2 2  2
the following statements is/are TRUE?
A) g  u   g  u  u  R B) g  u    g  u  u  R
C) g  u  is strictly increasing in  ,   D) g  u  is strictly decreasing in  ,  
48. Which of the following pairs of curves intersect orthogonally?
x2 y 2 x2 y 2 x2 y 2 x2 y 2
A)   1 and  1 B)   1 and  1
31 41 91 19 71 17 31 23
x2 y 2 x2 y 2 x2 y 2 x2 y 2
C)   1 and  1 D)   1 and  1
37 41 47 31 13 17 19 23

49. Let P  x0 , y0  be a point on the curve C :  x 2  11  y  1  4  0 , x0 , y0  N . If area of the
triangle formed by the normal drawn to the curve ' C ' at P and the co-ordinate axes is
a
  , a, b  N then the least value of  a  6b  is___.
b
50. Let A 1, 1 , B  4, 2  and c  9,3 be the vertices of the triangle ABC . A parallelogram
AFDE is drawn with the vertices D , E and F on the line segment BC , CA and AB
respectively, then the maximum area of the parallelogram AFDE is_____.

51. ABCD is a rectangular sheet with AB  L & BC  1 unit (Where L  1) , The corner B of
the rectangular sheet is folded over so as to reach the opposite edge CD of the sheet,
then the value of

 minimum length of crease formed 
3 3
52. Let f be a differentiable function upto fourth degree (i.e fourth derivative for f  x 
exists x  R ) such that f  a   1, f  b   2, f  c   3, f  d   1 and f  e   0 where
a  b  c  d  e g  x    f '  x   f "  x   f  x   f "  x    f  x  f '  x  f '"  x  ,

2 2
If x   a, e then g '  x   f "'  x    g  x  f iv   x  can have atleast ‘k’ roots, then k is ……
53. Tangent at any point P1 (other than (0,0) on the curve y  x3 meets the curve again at P2
16 area of P1 P2 P3
. Tangent at P2 meets curve again at P3 and so on. Then the value of is
Area of P2 P3 P4
equal to_____.
54. If the function f  x    a  2  x3  3ax 2  9ax  1 decreases for all real values of x then least
integral value of a is___.

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3. A potato at initial temperature T0 is placed inside a hot convection oven maintained at a

K1T1  K 2T2 K1T2  K 2T1 K1 K2

A) 8 min B) 10 min C) 12 min D) 6 min

A) Work done by the gas in the cycle is R T1  T2  2T3  log e 2

B) Work done by the gas in the cycle is R  2T3  T1  T2  log e 2

C) Heat absorbed by the gas is R T1  T2  log e 2

B) Equation of the process is PV 4/3  Constant

C) Molar heat capacity for the process is 3R

D) Molar heat capacity for the process is 3R / 2

9. A composite block is made of slabs A,B,C,D and E of different thermal conductivities

A) heat flow through A and E slabs are same

(Neglect the expansion during freezing, Take temperature of atmosphere  0C )

100  p  K . Then find the value of p.

A) X is 2, 5–dimethyl hex –3– yne; Y is cis–2, 5–dimethyl hex–3–ene

B) X is 2, 5–dimethyl hex–3–yne; Y is trans–2,5–dimethyl hex–3–ene

C) X is 2,5–dimethyl hexa–1,5–diene; Y is 2,5–dimethyl hex–3–yne

D) X is 2,5–dimethyl hexa–2,4–diene; Y is cis–2,5–dimethyl hex–3–ene

23. Identify ‘[Z]’ in the following reaction sequence,

Note – Consider major organic product in each step

Equimolar mixture of H3C and H3C H3C

24. The correct stability order of the following species is

(x) (y) (z) (w)

A) Resultant product is Bicycloduterio-alkane

B) Borane approaches reactant from top face

C) Borane approaches reactant from bottom face

D) Reaction of Borane to above alkene follow Markownikov addition

[Y] upon hydrogenation produces 2-methylbutane. Choose the correct statement(s)

A) [X] is a tertiary alky bromide

B) [X] is a primary alky bromide

C) [X] may or may not show stereoisomerism

D) [Y] can exhibit geometrical isomerism

(i) CH2 + HCl Product [A]

(ii) CH2 + HCl Product [B]

A) In reaction (i), two geometrical isomers of (A) are possible.

B) In reaction (i), two optical isomers of (A) are possible.

C) In reaction (ii), two geometrical isomers of (B) are possible.

D) In reaction (ii), three stereoisomers of (B) are possible.

29. Which of the following statements is/are correct?

A) Trans 2-phenyl cyclohexyl acetate on pyrolysis gives 1-phenyl cyclohexene as

B) Cis 2-phenyl cyclohexyl acetate on pyrolysis gives 1-phenyl cyclohexene as major

C) on pyrolysis gives 1-methyl cyclohexene as major product.

A) Br2 serve as electrophile in the first step of reaction.

If number of stereoisomers possible for [X] are Mand number of stereoisomers of

Find the value of M + N.

35. Consider following reactions.

Ifp = number of ( – H) in compound X;

36. Analyse the following reaction sequence

Note – Consider major organic product in each step to proceed further

A) 0.66 B) 0.33 C) 0.25 D) 0.87

41. The number of parallel tangents to f1  x   x 2  x  1 and f 2  x   x3  x 2  2 x  1 is___.

A) For atleast one x in 1,   , f  x  2   f  x   2

D) f '  x  strictly decreases in [1, )

44. Let f  x  and g  x  be derivable functions satisfying the following equations

 f '  x   f  x   g  x   g  x   g '  x  and

A) f  x  is increasing function B) g  x  is increasing function

fractional part of x . Then which of the following is/are Correct?

A) f  x   0 for x   , 1

B) f  x  has no real root for x   0,1