Organic
Organic
Organic
ketone
64 Zn-He/HCl carbonyl compound into alkane
65 HzN-NHz /KOH carbonyl compound into alkane
66 KMn0,/OH/ KxC1r,0, Ketones into mixture of carboxylic acids
/H,SO, or HNO; on prolonged oxidation
67 (Ag(NH3),)}NOz+NaOH Tollen s test
68 Cu(OH)> _ Fehiling s test
69 NaOH+L; Iodoform
70 | NaOH or Ba(OH), aldal condenzation
Tl Conc KOH or NaOH Cannizaro s reaction
72 KMnO, /KOH Toluene/alkyl Benzene into Benzoic Acid
73 H,0/H* Cyanides into carboxylic acids, amides
into carboxylic acids, esters into
carboxylic acis and alcohols, acid
chlorides or anhydrides into carboxylic
acids
74 NaOH Saponificaiton of ester, acid into salt of
acid
75 NazCO; or NaHCO; Carboxylic acid test
76 P01 or Ps Dehydration of acids into anhydride,
amides into nitriles
T7 ROH/conc HaSO, Caroxylic acids into esters
T8 PCh, SoCl, PCI; Carboxylic acids into acid chlorides
79 NH; heating Carboxylic acids into amides
a0) NaQH/Cad Decarboxylation (acids into alkanes)
al LiAlHy Carboxylic acids into alcohols, amides
into amines
82 Cl: /red Ps HYZ reaction
83 Sn /HCl or Fe /HCI, HyPd | Reduction of nitro compounds into
amines
84 NH, Alkyl halides into amines
85 Hz/ Ni or Hy/Pd LiAIH, Amides into cyanindes
86 KOH/R-X Phthalamide into amine
8&7 NaOH /Brz Hoffman bromamide, amide into amine
with one C less
88g KOH,CHC1; Amines into Carbyl amines
89 NaNO;/HCI ° aliphatic amines into alcohols
90 NaNOvVHC] O Aniline into diazonium chloride
91 | C.HsS0,C1 Distinguishing 1",2” & 3” amines
92 Bro/HO Aneline into tri bromo aniline
93 Br2/ CH-CO-Cl Aniline into Bromo Aniline
(ACHCO},O
ORGANIC REAGENTS
S+ 4% $I*
NAME REACTIONS
H
4. | Friedel-Crafts Fg CH ,COCI
- i
Boylan Anhydrous AICI
cl
7. | Wurtz-Fitti : zNa
BIE rine (> + dH, —— é Hz + Nati
| Dry ether
OH ON OH
Ma OH CO,
8. | Kolbe (> ——_— _ _
ii}H
OH
CH Cl + Na OH
5, | Reimer-Tiemann (> h—_— — ENG H*
ce
H,0*
11.] Stephen HIE—N+ SnCl ,+HO —— HE —HESIH — C—O
CHO
CHO
13.| Gatterman
= Koch (> £o7H0 m1 R
| Anhydrous AK ,
14.] Rogenmund i ue ~ i
reduction Hac cl Pd / BaSO , Hat” —“H
on
15.) Che mmensen | Zn- Hg
C. = HE —Hyh;
reduction ag CH Conc, HC
i |, aH
19.) fodaform c = CHI afr CH ,COO Na
H.C” “CH OR, NaDQl
dil
I Md NaOH I
20] Aſda) 2 hc CHO = H,C-DH TH 2—ECHO —2> CH = HHO
condensotion
. Cone, NaOH
21.] Cannizzoro HCHO 4 HOO ——— —- Hoon + HL —oh
i) Cl . / Red Phosphorus
22.| Hellvolhard: | wgc—coon ens
zt
Zelingky (HVT) i}H ,0 ,
a d
iO
23.] Hoffmonn | fir,
bromomide HC C NH 3 a nn HH;
degradation Naſh
= —_— A
Sh) SHONE R-NH; + CHCl; + 3 KOH —= R-NC + 3K + 3H,0
"a a
35, l I NaMO , + da HCI —
= 273-276 Kk ! at
NyCi
* = 1
28,] Covpting & oO + H ‘>
10. For esters (ROOOR) : Hydrolyses first. Then see the products ( acid & alcohol) and give a test
to identify them.
11. All alkenes (C=C) and alkynes (C=C) decolorizes Br, -— water from red to colourless
12. Lucas Test to distinguish primary, secondary and tertiary alcohols
Lucas reagent: ZnCl,/HCl
3".alcohol + Lucas reagent —= Immediate turbidity