TAV COLLEGE

Remedial Sec V Chemistry

Fall 2020

Assignment
(To be handed in at the entry to the Final Exam)

Question #1:

Name the following compounds:

Copper(III)Bromide
a) NO2 Nitriate e) NaBr Sodium Bromide i) CuBr3

b) N2O Nitrous Oxide f) CaO Calcium oxide j) Cu3P

Copper(I) Phosphide
g) Li2S Lithium Sulfide
c) ZnF2 Zinc Froride k) Fe(SO4)2
h) Fe(NO3)3 Iron(III) Nitrate Iron(IV) Sulfate
d) CCl4 Carbon Tetrachloride

Question #2:

Write formulas for each of the following:

NaNO3
a) nitrogen trichloride NCl3 j) sodium nitrate

b) dinitrogen trioxide N2O3 k) calcium carbonate CaCO

c) phosphorus pentafluoride PF5 l) lithium sulfate Li2SO4

d) tetraphosphorus tetraoxide P4O4 m) sodium phosphate Na3PO4

e) sulfur dibromide SBr2 n) calcium chloride CaCl2

f) oxygen difluoride OF2 o) Copper (II) nitrite Cu(NO2)2

g) carbon disulfide CS2 p) Iron (III) oxide Fe2O3

h) potassium iodide KI q) Zinc (V) bromide ZnBr5

i) aluminum chloride AlCl

记得查看balance！！
Question #3

If 15.0 g of C4H9OH react with 22.4 g of NaBr and 32.7 g of H2SO4 according to the reaction
C4H9OH + NaBr + H2SO4 C4H9Br + NaHSO4 + H2O
Which reactant is the limiting reagent and which are the excess?

Question #4

When sucrose (C6H12O6) reacts with oxygen, water and carbon dioxide are formed.

a) Write the balanced equation for the reaction given:

C6H12O6 + O2 → CO2 + H2O

b) What mass of carbon dioxide forms in the reaction of 25 grams of glucose with 40 grams of
oxygen?

Question #5

Balance these equations (even if the value is one put it in the blank) and identify the type of
reaction. (Synthesis, Decomposition, Single Replacement, Double Replacement or Combustion)

Type of reaction

1. __HgO __Hg + __O2 ____________

2. __ NaCl + __ AgNO3 __NaNO3 + __AgCl ____________

3. __ Cl2 + __ Ca __ CaCl2 ____________

4. __ C2H6 + __ O2 __CO2 + __H2O ____________

5. __ H2O + __ Fe __ Fe2O3 + __ H2 ____________

6. __ Al2S3 + __Ca(OH)2 __ Al(OH)3 + __ CaS ____________

7. __ S8 + __ Fe __ FeS ____________

8. __ N2 + __ H2 __ NH3 ____________

9. __ KClO3 __ KCl + __ O2 ____________

10. __ Al2(SO4)3 + __Ca(OH)2 __ Al(OH)3 + __ CaSO4 ____________

Question #6

How many moles of oxygen gas (O2) would occupy a volume of 41.5 L at a pressure of 760 torrs and a
temperature of 232.4 C? After determining the number of moles, calculate the number of grams of
oxygen gas contained in this container?

Question #7

If I initially have a gas at a pressure of 10.0 atm, a volume of 24.0 liters, and a temperature of 200 K, and
then I raise the pressure to 14.0 atm and increase the temperature to 300 K, what is the new volume of
the gas?

Question #8

A gas takes up a volume of 15 liters, has a pressure of 3.3 atm, and a temperature of 299 K. If I raise the
temperature to 350 K and lower the pressure to 1050 mmHg, what is the new volume of the gas?

Question #9

A gas that has a volume of 28 liters, a temperature of 65 °C, and an unknown pressure has its volume
increased to 36 liters and its temperature decreased to 35 °C. If I measure the pressure after the change
to be 2.0 atm, what was the original pressure of the gas?

Question #10

A gas has a temperature of 14 °C, and a volume of 5.5 liters. If the temperature is raised to 29 °C and
the pressure is not changed, what is the new volume of the gas?

Question #11

If I have 20 liters of gas at a temperature of 67 °C and a pressure of 88.89 atm, what will be the pressure
of the gas if I raise the temperature to 94 °C and decrease the volume to 12 liters?

Question #12

I have an unknown volume of gas at a pressure of 0.50 atm and a temperature of 325 K. If I raise the
pressure to 900 torr, decrease the temperature to 320 K, and measure the final volume to be 48 liters,
what was the initial volume of the gas?

Question #13

If I have 21 liters of gas held at a pressure of 78 atm and a temperature of 800 K, what will be the
volume of the gas if I decrease the pressure to 45 atm and decrease the temperature to 750 K?

Question #14

If I have 3.9 L of gas at a pressure of 5.0 atm and a temperature of 50.0 °C, what will be the temperature
of the gas if I decrease the volume of the gas to 2.4 L and decrease the pressure to 303.0 kPa?
Question #15

A total of 54.0 joules of heat are absorbed as 58.3 g of lead is heated from 12.0°C to 42.0°C.
From these data, what is the specific heat of lead?

Question #16

The specific heat of wood is 2.03 J/g∙°C. How much heat is needed to convert 550 g of wood
at -15.0°C to 10.0°C?

Question #17

What is the total amount of heat needed to change 2.25 kg of silver at 0.0°C to 200.0°C?
The specific heat of silver is 0.129 J/g∙°C

Question #18

Granite has a specific heat of 800 J/g∙°C. What mass of granite is needed to store 150,000 J
of heat if the temperature of the granite is to be increased by 15.5°C?

Question #19

A 55 kg block of metal has an original temperature of 15.0°C and 0.45 J/g∙°C. What will be
the final temperature of this metal if 450 J of heat energy are added?

Question #20

Determine the H for each of the following reactions. Classify each reaction as either
exothermic or endothermic.

a. C3H8(g) + 5O2(g)  3CO2(g) + 4H2O(g)

b. H2 (g) + Cl2(g)  2HCl(g)

c. CH4(g) + 2O2(g)  CO2(g) + 2H2O(g)

d. 2F2(g) + 2H2O(l)  4HF(g) + O2(g)

Question #21

Calculate the enthalpy change for the reaction in which methane and oxygen combine to form ketene,
CH2CO, and water.

2CH4(g) + 2O2(g)  CH2CO(g) + 3H2O(g)

Provided with the following;

CH2CO(g) + 2O2(g)  2CO2(g) + H2O(g) H = 981.1 kJ

CH4(g) + 2O2(g)  CO2(g) + 2H2O(g) H = 802.3 kJ

Question #22

Calculate H for the reaction of calcium oxide and sulfur trioxide. Is this reaction exothermic
or endothermic?
CaO(s) + SO3(g)  CaSO4(s)

Use the following equations and data.

H2O(l) + SO3(g)  H2SO4(l) H = 132.5 kJ/mol
H2SO4(l) + Ca(s)  CaSO4(s) + H2(g) H = 602.5 kJ/mol
Ca(s) + ½ O2(g)  CaO(s) H = 634.9 kJ/mol
H2(g) + ½ O2(g)  H2O(l) H = 285.8 kJ/mol

Question #23

Find the enthalpy of the reaction of magnesium oxide with hydrogen chloride.
MgO(s) + 2HCl(g)  MgCl2(s) + H2O(l)

Use the following equations and data.

Mg(s) + 2HCl(g)  MgCl2(s) + H2(g) H = 456.9 kJ/mol
Mg(s) + ½ O2(g)  MgO(s) H = 601.6 kJ/mol
H2O(l)  H2(g) + ½ O2(g) H = +285.8 kJ/mol
Question #24

What mass of solute will dissolve in 100mL of water at the following temperatures?

i. KNO3 at 60°C

ii. NaCl at 10°C

iii. NH4Cl at 50°C

iv. NaNO3 at 30 °C

v. KClO3 at 30 °C
Question #25

For the following table or mixtures, please write the products of the double displacement
reaction and state if they are solid (s) or aqueous (aq).

AgNO3 BaOH NaCl KOH

AgNO3

Pb(NO3)2

CaSO4

KI
Question #26

Consider the production of ammonia following the below reaction;

N2(g) + 3H2(g) 2NH3(g)

If initially we start with 8 mol of each chemical (products and reactants) in a 3.2L contgainer and at
equilibrium we have 0.50 mol/L of NH3 (g). What is the equilibrium constant of this reaction

Question #27

Write the equilibrium constant expression for each of the following reactions.

a. 2 H2O2 (g) ⇌ 2 H2O (g) + O2 (g)

b. 6 H2O2 (g) ⇌ 6 H2O (l) + 3 O2 (g)

c. 2 PbS (s) + 3 O2 (g) ⇌ 2 PbO (s) + 2 SO2 (g)

d. MgCl2(s) ⇌ Mg2+ (aq) + 2 Cl- (aq)

Question #28

Calculate the equilibrium constant for this reaction:

2 PO2Br (aq)  2 PO2 (aq) + Br2 (aq)

Given: [PO2Br] = 0.0255M, [PO2] = 0.155M, and [Br2] = 0.00351M at equilibrium.

Question #29

Calculate the equilibrium constant K for this unbalanced reaction:

SO3 (g)  SO2 (g) + O2 (g)

Given: [SO3] = 0.0255M, [SO2] = 1.08M, and [O2] = 1.45M at equilibrium.

Question #30

Consider the equilibrium: 2N2O(g) + O2(g) 4NO(g)

3.00 moles of NO(g) are introduced into a 2.00-Liter flask. When the system comes to
equilibrium, 1.00 mole of N2O(g) has formed. Determine the equilibrium concentrations of
each substance. Calculate the Keq for the reaction based on these data.

Question #31

A 0.0240 mol sample of N2O4(g) is allowed to reach equilibrium with NO2(g) in a 0.372 L flask at 25.0oC.
Calculate the concentration of N2O4(g) at equilibrium given the following;

N2O4(g)  2 NO2(g) Keq = 4.61 x 10-3

Question #32

Predict the effect (left or right direction) of decreasing the pressure of the container for each
equilibrium.

i. 2H2O(g) + N2(g) ↔ 2H2(g) + 2NO(g) ________________

ii. SiO2(s) + 4HF(g) ↔ SiF4(g) + 2H2O(g) ________________

iii. CO(g) + H2(g) ↔ C(s) + H2O(g) ________________

Question #33

Predict the effect (left or right direction) of decreasing the [H2O(g) ] of the container for each equilibrium.
我理解你的问题，这是一个很好的问题。让我们具体分析一下：
i. 2H2O(g) + N2(g) ↔ 2H2(g) + 2NO(g)
i. 2H2O(g) + N2(g) ↔ 2H2(g) + 2NO(g) ________________
-减少水的浓度：根据勒夏特列原理，减少水的浓度会导致平衡向右移动
，生成更多的水，即 2H2O(g) + N2(g) ↔ 2H2(g) + 2NO(g)。
ii. SiO2(s) + 4HF(g) ↔ SiF4(g) + 2H2O(g) ________________ -减少总的气体压力：当水的浓度减少时，影响的是水的浓度，而水的参
与并不影响气体的总压力。因此，这里减少总的气体压力不会导致平衡
方向的改变。
iii. CO(g) + H2(g) ↔ C(s) + H2O(g) ________________
在这两种情况下，水的浓度和总的气体压力对平衡位置的影响并不一定
相同。勒夏特列原理是一种根据系统受到的干扰来调整平衡位置的原理
Question #34 ，其响应可能取决于具体的平衡方程和条件。

What would happen to the position of the equilibrium (left or right) when the following changes are
made to the equilibrium system below?
2SO3(g) ↔ 2SO2(g) + O2(g)
i. Sulfur dioxide is added to the system. __________________

ii. Sulfur trioxide is removed from the system. __________________

iii. Oxygen is added to the system. __________________

Question #35
Calculate the pH for the following solutions:

a) [OH-] = 0.0410M c) [H+] = 5.54x 10-7

b) [H+] = 0.005M d) [H+] = 0.0345M

Question #36

Calculate the [H+] for the following solutions:

a) pOH = 6.34 c) pOH = 12.34

b) pH = 4.56 d) [OH-] = 0.0337M

Question #37

Complete the following reaction and make sure to;

a. Balance chemical and reaction

b. Identify ;
i. Acid (A)
ii. Base (B)
iii. Conjugate Acid (C.A.)
iv. Conjugate Base (C.B.)

a) Ca(OH)2 + H2CO3 
b) HF + Mg(OH)2 
c) HNO3 + Al(OH)3 
d) HCl + KOH 
e) HPO3 + LiOH 
Question #38

Fill in the table

ACID or
pH [ H3O+ ] or [H+] pOH [ OH– ]
BASE?

1
3.45

2 3.22 x 10–2 M

3 8.4

4 1.67 x 10–9 M

5 1

Question #39

Consider the rate of the following reaction (UNBALANCED):

NaOCl(aq) NaCl(aq) + O2(g)

a) Write a balanced formula equation for this reaction.

b) If the rate of consumption of NaOCl is 4.3x 10-4 mol/s, find the rate of
production of Oxygen in moles/s.

c) If the rate of consumption of NaOCl is 2.1 x 10-5 mol/s, find the rate of production
of NaCl in g/s.

d) If the rate of consumption of NaOCl is 5.0 x 10-9 mol/s, find the rate of production
of O2 in L/s (28 C and 1.4atm).

e) If the rate of production of Oxygen is 3.9 x 10-9 mol/s, find the mass of NaOCl
consumed in 5.0 minutes.