R&T SESSION: 2023-24

Name. ______________________ Roll#____________

CHEMSITRY SSC-II

SECTION-A (5-MARKS)
Time allowed: 5 minutes 15-1-2024
NOTE: - Section-A is compulsory. All parts of this section are to be answered on question paper itself. It should be
completed in first 5 minutes. Deleting/Overwriting is not allowed. Do not use lead pencil.
Q.1 Circle the correct option i.e. A/B/C/D. Each part carry 1 mark.
Sr.No Question A B C D A B C D
1. Reaction of alkynes with Dehydration Hydroxylation Combustion Oxidation O O O O
KMnO4 is an example of?
2. Dehydrohalogenation is best Zn/HCl Alc.KOH Aq.KOH Ni O O O O
carried out by:

3. When ethene is allowed to Vicinal Discharging of Appearance of Presence of O O O O

react with bromine water then dihaldies are the color of oily layer gaseous bubbles
choose the appropriate formed bromine
observation that confirms the
presence of unsaturation?
4. Which one of the following is Ethane Methane Ethene Ethyne O O O O
most reactive hydrocarbon?
5. Which of the following is Alcohols Aldehydes Ketones Vicinal dihalides O O O O
used to prepare alkynes?

--------------------------------------------------------------------------------------------------------------------------------------------------------
Time allowed: 30 minutes Total Marks Sections B and C: 15
NOTE: - Answer all three parts from Section ‘B’ and any one question from Section ‘C’ on the separately provided answer
book. Write your answers neatly and legibly.
_________________________________________________________________________________________________________
SECTION-B (Marks 09)
Q.2 Answer all THREE parts. The answer should not exceed five to six lines. (3 × 3 = 09 )
1. Give the chemical reactions to predict the products of the reaction between Propene:
a. H2O/H2SO4,1000C b. KMnO4 c. Cl2
Ans:
H2SO4
a. CH3-CH=CH2 + H2O → CH3-CH-CH3
1000C OH
b. 3CH3-CH=CH2 + 2KMnO4 + 4H2O →CH3-CH-CH2 + 2MnO2 + 2KOH
OH OH
c. CH3-CH=CH2 + Cl2 →CH3-CH-CH2
Cl Cl

2. A student adds Hydrobromic acid in an ethyne to make it vinyl bromide. Propose a scheme to recover ethyne
from vinyl bromide with appropriate chemical reactions.
Ans:
CH=CH + HBr → CH2=CH-Br
Alcohol
CH2=CH-Br + KOH → CH=CH + KBr + H2O

TEACHER: M.HARIS HASHMI Session:2023-24

Test#5: CH#12(2) CLASS: 10th-AB
 R&T SESSION: 2023-24

Name. ______________________ Roll#____________

CHEMSITRY SSC-II

3. Chemically prove that ethene is more reactive than ethyne.

Ans:
When an ethene is treated with dilute alkaline solution of KMnO 4(1%),the pink colour of KMnO4 solution is
discharged during the reaction. This reaction is used as a test for the presence of an alkene and is known as
Baeyer’s test.

3CH2=CH2 + 2KMnO4 + 4H2O 3CH2-CH2+2MnO2+ 2KOH

Ethene OH OH
Ethylene Glycol
Alkynes do not react with dilute alkaline solution of KMnO 4. However, they are oxidized by strong solution
of KMnO4 to give oxalic acid. First the four –OH groups add across triple bond.
4KMnO4 + 4KOH 4K2MnO4 + 4[O]

OH OH
CH CH + 2[O] + 2H2O CH-CH
Ethyne OH OH
Tetrahydroxy ethane
Tetrahydroxyethane is unstable compound; it loses two water molecules to form glyoxal which oxidizes to
oxalic acid.
OH OH -2H2O O O 2[O] OO
CH-CH H-C-C-H OH-C-C-OH
OH OH Glyoxal Oxalic acid
SECTION-C (Marks 06)
Note: Attempt the ONE question. This question carries six marks. ( 1 × 06 )
Q.3 Convert 2,3-Dichlorobutane into 1,2-Dichlorobutane

Ans:
Heat
CH3-CH-CH-CH3 + Zn CH3-CH=CH-CH3 + ZnCl2
Cl Cl
Ni
CH3-CH=CH-CH3 + H2 CH3-CH2-CH2-CH3
200-3000C

CH3-CH2-CH2-CH3 + Cl2 CH3-CH2-CH2-CH2-Cl + HCl

Alcohol
CH3-CH2-CH2-CH2-Cl + KOH CH3-CH2-CH=CH2 + KCl + H2O

CH3-CH2-CH=CH2 + Cl2 CH3-CH2-CH-CH2

Cl Cl

TEACHER: M.HARIS HASHMI Session:2023-24

Test#5: CH#12(2) CLASS: 10th-AB