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    Poster Pozzolan

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    ayoubdrai2022
    This document summarizes a study examining the use of Algerian pozzolan as an adsorbent for removing malachite green dye from aqueous solutions. Characterization of the pozzolan found it contains minerals like quartz, hematite, and anorthite. Adsorption tests showed the pozzolan has an optimal adsorption capacity of 64.02 mg/g under initial pH of 8-8.5, 75 minutes of contact time, and 1g/L adsorbent dose. Both Langmuir and Freundlich isotherm models fit the adsorption data well, indicating the pozzolan is an effective and low-cost adsorbent for removing malachite green

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    Poster Pozzolan

    Uploaded by

    ayoubdrai2022
    12 views1 page
    This document summarizes a study examining the use of Algerian pozzolan as an adsorbent for removing malachite green dye from aqueous solutions. Characterization of the pozzolan found it contains minerals like quartz, hematite, and anorthite. Adsorption tests showed the pozzolan has an optimal adsorption capacity of 64.02 mg/g under initial pH of 8-8.5, 75 minutes of contact time, and 1g/L adsorbent dose. Both Langmuir and Freundlich isotherm models fit the adsorption data well, indicating the pozzolan is an effective and low-cost adsorbent for removing malachite green

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    This document summarizes a study examining the use of Algerian pozzolan as an adsorbent for removing malachite green dye from aqueous solutions. Characterization of the pozzolan found it contains minerals like quartz, hematite, and anorthite. Adsorption tests showed the pozzolan has an optimal adsorption capacity of 64.02 mg/g under initial pH of 8-8.5, 75 minutes of contact time, and 1g/L adsorbent dose. Both Langmuir and Freundlich isotherm models fit the adsorption data well, indicating the pozzolan is an effective and low-cost adsorbent for removing malachite green

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    © All Rights Reserved
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    12 views1 page

    Poster Pozzolan

    Uploaded by

    ayoubdrai2022
    This document summarizes a study examining the use of Algerian pozzolan as an adsorbent for removing malachite green dye from aqueous solutions. Characterization of the pozzolan found it contains minerals like quartz, hematite, and anorthite. Adsorption tests showed the pozzolan has an optimal adsorption capacity of 64.02 mg/g under initial pH of 8-8.5, 75 minutes of contact time, and 1g/L adsorbent dose. Both Langmuir and Freundlich isotherm models fit the adsorption data well, indicating the pozzolan is an effective and low-cost adsorbent for removing malachite green

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    1st International Congress on Analytical Chemistry, Electrochemistry and Separation Techniques

    October 15th-16th, 2022

    STRUCTURAL/TEXTURAL CHARACTERIZATION AND ADSORPTION PROPERTIES OF


    ALGERIAN POZZOLAN FOR REMOVAL OF MALACHITE GREEN FROM AQUEOUS SOLUTION

    DRAI Ikram1*, DAR Kebira Fatima2, STEUDEL Annett3, G. Weidler Peter 3, BENGUEDDACH Abdelkader4, HAMACHA Rachida4, CHERIFA Bachir1,4
    1 Laboratoire de Chimie Appliquée LAC, C.U. Aïn-Témouchent, Route Sidi Bel Abbes BP 284, 46000 Aïn Témouchent, Algeria
    2 Laboratoire de Chimie Inorganique et Environnement (LCIE), Université Aboubekr Belkaid Tlemcen BP-119, 13000, Tlemcen, Algeria.

    3 Institute of Functional Interfaces, Karlsruher Institut für Technologie KIT, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

    4 Laboratoire de Chimie des Matériaux L.C.M., Université d’Oran 1 Ahmed Ben Bella, BP-1524 El-Mnaouer, 31000 Oran, Algeria.

    Email*: Draiikram1997@gmail.com

    INTRODUCTION

    The water resource is currently threatened by pollution because all human activities lead to the production of synthetic organic chemical compounds
    in the environment. One of the main pollutants is synthetic dyes used in the textile industry, as well as food dyes such as rhodamine B, metanil
    yellow, and malachite green. To remove dyes and other colored contaminants from wastewater, we need green chemistry. i.e., processes that lead to
    the use of more environmentally friendly adsorbents that are both cheap and renewable. So, in this study, pozzolan, a natural Algerian siliceous
    volcanic filler from the Ain-Temouchent region (Beni-saf), was used as a renewable, available, and inexpensive adsorbent for the removal of the
    textile dye malachite green from aqueous solutions.

    MATERIALS RESULTS AND DISCUSSION


    Table 1: Chemical composition by X-ray fluorescence (XRF)
    Oxyde SiO2 Al2O3 Fe2O3 MnO CaO Na2O K2O TiO2 P2O5 SO3 LOI

    PM (%) 44 ,31 16,01 8,12 0,14 4,29 9,78 1,45 1,91 0,66 0,04 9,72

    (a) (b)
    (c)

    Figure 1: Pozzolan (AP)- Absorbent

    MG ADSORPTION
    Figure 3: (a) X-ray diffraction, (b) FT-IR, (c) TG/DSC of Pozzolan.

    MG solutions Table 2: Textural properties and CEC of Pozzolan.


    SSAa Vtb DPDFTc CECd
    AP (m2/g) (cm3/g) (nm) (meq/100g)
    Pozzolan
    0.071 1.7 25
    68
    a:
    Specific surface area, b: Total pore volume, c: Pore diameter determined by DFT, d: Sum of exchanged cations
    Stirring
    measured by ICP-OES.

    Sampling at
    different times
    ➢ From the XRD analyses , the PA contains crystalline minerals. according to the most
    intense peaks the AP is composed of: quartz, hematite, anorthite and augite, which
    confirms the results of XRF (high content of SiO2, Fe2O3 and Al2O3 oxides).
    Figure 2: Malachite green dye (MG) Filtration
    ➢ The FT-IR spectrum of the AP shows a broad peak at wavenumbers [1007-1050 cm-1]
    -1
    which is attributed to the Si-O and Al-O vibration. The band displayed at 3456 cm is
    UV-Vis analysis attributed to the stretching vibration of the -OH bond.
    ➢ high thermal stability up to 600 °C.
    ➢ A specific surface of 68 m2/g and a slight porosity, low CEC (25 meq/100g).
    Adsorption

    Table 4:Langmuir and Freundlich isotherm parameters of MG


    adsorption on pozzolan
    Paramètres de Langmuir Paramètres de Freundlich

    Qm KL KF(mg/g) 1/n (L/g)


    (mg/g) (L/mg)
    (a) (b) (c)
    64,02 0,59 0,88 22,45 0,71 0,93
    Figure 4: Effect of experimental parameters in MG adsorption onto pozzolan material: (a) CONCLUSION
    Initial pH , (b) Contact time , (c) Absorbent dose ,
    ➢ Optimal experimental conditions: Algerian pozzolan a natural product used has a bleaching
    -Initial solution pH= 8-8,5 -Contact time = 75min -Adsorbent dose = 1g/L power on the green of malachite with a percentage of
    ➢ The adsorption isotherms: giving a value of R2< 1. This means that the adsorption efficiency of adsorption and bleaching of VM of 99%.
    is more important for low concentrations and a progressive saturation of the solid.

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