Safety Manual B2

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Safety Manual

Operational Information and Safety


Precautions for General Equipment

Issue B2

Date of Issue: July 2019

Sonardyne International Limited T. +44 (0) 1252 872288


Blackbushe Business Park F. +44 (0) 1252 876100
Yateley, Hampshire E. support@sonardyne.com
GU46 6GD, United Kingdom www.sonardyne.com
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

© 2012–2019 Sonardyne International Limited. All rights reserved.


This Safety Manual is the copyright and intellectual property right of Sonardyne International Limited
(“Sonardyne”) and is provided solely for the customer’s use of the Sonardyne equipment as described
in this user manual and in accordance with Sonardyne’s then prevailing terms and conditions of sale.
This user manual has been compiled to the best of Sonardyne’s knowledge and belief, but no
representation, warranty (whether express or implied) or guarantee is made to any persons or legal
entities as to the accuracy, reliability or completeness of the information contained in this user manual.
This user manual contains the proprietary, confidential information of Sonardyne and other third parties
and as such may not be used, disclosed or placed in the public domain (by whatever means) by the
customer except expressly in accordance with and subject to the above referenced terms and
conditions of sale.
The copyright and any and all intellectual property rights of any and all third parties which may be
referenced in this user manual or which may have provided proprietary products and/or software
and/or documentation (in whatever format) to Sonardyne in respect of the Sonardyne equipment as
described in this user manual are hereby duly acknowledged. The provision of any and all such
products and/or software and/or documentation by Sonardyne shall be subject to and in accordance
with the relevant third parties’ terms and conditions or the Sonardyne then prevailing conditions of sale,
as appropriate.
The Sonardyne equipment described in this user manual is protected by various UK and US Patents
and other patents internationally and registered trademarks of Sonardyne International Limited.

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Contacting the Sonardyne Support Team


24-hour Emergency Telephone Helpline: +44 (0) 1252 877600

The Sonardyne 24-hour helpline is answered at the UK Headquarters during normal office hours
(08:00 to 17:00). Outside these hours, your call is automatically transferred to an agency, which logs
the details of your emergency and alerts the appropriate Sonardyne personnel.
Our aim is to make sure emergency requests are dealt with immediately during office hours, and are
responded to within 30 minutes at all other times.
Please note the helpline is for emergency use only.
If you require non-emergency product support, please contact your nearest Sonardyne office.
Alternatively, contact the Sonardyne Head Office:
Sonardyne International Ltd
Blackbushe Business Park
Yateley
Hampshire
GU46 6GD
United Kingdom
Telephone: +44 (0) 1252 872288
Fax: +44 (0) 1252 876100
Email: support@sonardyne.com
Note
Email and telephone support is available during normal UK office hours (08:00 to 17:00).

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Precautions for General Equipment Issue B2

Contents
Contacting the Sonardyne Support Team 3
Amendment History 6
Section 1 – Introduction 7
1.1 General Operational Safety Precautions 7
1.2 General Safety Precautions 7
1.2.1 Hazard Appreciation 7
1.3 General Handling of Equipment 8
Section 2 – Pressure Housings 9
2.1 Introduction 9
2.2 Instruments fitted with a Pressure Relief Vent Valve 9
2.3 Instruments not fitted with a Pressure Relief Vent Valve 10
2.4 Dismantling Precautions (Instrument fully functioning) 10
2.5 Dismantling Precautions (instrument known or suspected to be pressurised) 10
Section 3 – Electronic Hazards 12
3.1 High Voltages 12
3.1.1 High Voltage Awareness 12
3.1.2 Storage Capacitors 12
3.1.3 Handling of Electronic Components 12
Section 4 – Batteries 13
4.1 Use of Appropriate Battery Types 13
4.2 Primary Lithium (Li) Batteries 14
4.2.1 Lithium Battery Types 14
4.2.2 Safety Precautions for Primary Lithium (Li) Batteries 14
4.2.3 Fault Procedures 14
4.2.4 Primary Lithium Batteries Storage Instructions 15
4.2.5 Transporting Primary Lithium Batteries 15
4.2.6 Disposal of Primary Lithium Batteries 16
4.3 Lithium Ion (Li+) Batteries 16
4.3.1 Safety Precautions for Lithium Ion (Li+) Batteries 16
4.3.2 Fault Procedures 16
4.3.3 Lithium Ion Batteries Storage Instructions 16
4.3.4 Transporting Lithium Ion Batteries 17
4.3.5 Disposal of Lithium Ion Batteries 17
4.4 Alkaline and Nickel Metal Hydride (NiMH) Batteries 17
4.4.1 Alkaline Batteries 17
4.4.2 Nickel Metal Hydride (NiMH) Batteries 17
4.5 Charging Batteries in Sealed Containers 17
4.6 Reconnecting a Partially Used Battery 18
4.7 Batteries – End of Life 18
4.8 Fitting a New Battery 18
4.9 Battery Pack Fuses 18
4.10 WEEE Directive 18

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4.11 Additional Battery Manufacturer Information 19


Section 5 – Equipment Environmental Limitations 20
5.1 Storage Temperature Limits 20
5.2 Instrument Load Bearing Capability 20
5.3 Floatation Equipment 20
5.3.1 Introduction 20
5.3.2 Float Inspection 20
5.3.3 Minimum Nett Buoyancy of Floats 20
5.3.4 Float Inserts 21
Appendix A – Safety Datasheets/Battery Information Sheets 22
A.1 Lithium Cells and Batteries 22
SAFT Lithium Safety 2019 23
A.2 Lithium-ion Cells and Batteries 31
SAFT Lithium-ion Safety 2019 32
Appendix B – Cell Specifications 38
B.1 Lithium Cells 38
B.2 Lithium-ion Cells 38
B.2.1 MGL28321 Safety Information 39
270-0610 - Allbatteries MGL28321 - Safety 40
B.2.2 MGL28321 Datasheet 46
270-0610 - Allbatteries MGL28321 - Datasheet 47
Definitions 59
Definitions of Loads, Loading and General Terms 59
Abbreviations 59

Figures
Figure 4–1 Example of a Lithium Battery Identification Label 13
Figure 4–2 Example of a Lithium-ion (Li-ion) Battery Identification Label 13
Figure 4–3 Example of an Alkaline Battery Identification Label 13

Tables
Table 4–1 WEEE Directive 2002/96/EC Logo Definitions 18
Table B–1 Lithium Cells 38
Table B–2 Lithium-ion Cells 38

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Amendment History
The amendment history records all amendments and additions made to this manual.
Issue Revision Date Comments Section Page
A 0 11/04/2012 Initial Issue All All
B 0 21/05/2012 Complete review of manual; datasheets and All All
MCDS certificates Appendices added
B 1 05/07/2016 Battery datasheets updated and general update All All
B 2 22/07/2019 Battery datasheets updated and general update All All

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Section 1 – Introduction
1.1 General Operational Safety Precautions
This Safety Manual provides information and safety precautions for operating and servicing
Sonardyne products. Sonardyne products can contain hazardous energy and must only be opened by
qualified service personnel.
Operators and Service personnel must be familiar with the information detailed in this manual before
using or servicing Sonardyne equipment.
Additional information including warnings and cautions (if applicable) is included in the relevant
product user, operating or maintenance manual for the specific equipment and must be read and fully
understood before operating the equipment.

Documentation must be consulted whenever the warning symbol is found on the equipment, in
order to find out the nature of the potential hazard and any precautions which have to be taken.
Sonardyne equipment should not be used outside of the manufacturer’s specifications as the
equipment could be damaged or its operation impaired.
The safety of any system incorporating any Sonardyne equipment is the responsibility of the
assembler of the system.
It is the operator’s responsibility to conduct Hazard Identification and Risk Analysis for all conditions.

1.2 General Safety Precautions


The general safety precautions that follow are not equipment or installation specific.
Before the installation or use of equipment the facilities local Health and Safety legislation, regulations,
Safe Working Procedures and Practices must be understood and followed.
All procedures and practices contained in this Safety Manual must be read and fully understood.
It is the RESPONSIBILITY OF ALL PERSONS working on or near an installation to make sure they:
l Work with and obey all persons that have responsibilities for the safe operation of the
applicable installation.
l Report any defect of any equipment that can cause danger to the health, safety or welfare of
persons that work on or may be affected by the installation or equipment.
l Use equipment only for the purpose for which it is intended.
l Do not act in a way on or near the installation, that could cause a danger to you or other
persons that work on or near the installation.
l Do not cause any equipment used on or near an installation to be unsafe.
l Do not remove any WARNING signs without permissions.
l Do not remove or alter any safety equipment without permissions.
l Do not disconnect or connect any power source without permissions.

1.2.1 Hazard Appreciation


Subsea equipment remains safe in use when operated and handled within standard operating
procedures and written guidelines, therefore in normal operation little threat is posed to the safety of
personnel or instruments. However, all subsea units are capable of posing a threat to personal safety,
particularly when pressure housings become internally pressurised. Great care must be taken when

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this happens, or is suspected to have happened, since the pressures present within the instrument are
likely to be extremely high. Internal pressure problems may also be aggravated by unknown chemical
hazards if battery breakdown has occurred.
l The following non-exhaustive list gives examples of typical hazardous situations:
l All deteriorated/failed batteries (not just lithium batteries)
l High voltages being present when the equipment is transmitting, particularly on the transmitter
PCB and transducer.
l A pressure housing becoming internally pressurised by water pressure due to a leak
l A pressure housing becoming internally pressurised due to battery failure
l Charging of non-rechargeable battery packs/cells
l Using equipment or instrumentation outside the design parameters
l Using equipment or instrumentation beyond the load bearing limits
l Failing to maintain equipment reducing its load bearing capability
l Using unauthorised components or inferior parts in critical assemblies, e.g. release systems,
battery packs etc.

1.3 General Handling of Equipment


Do not allow instruments to be dropped or exposed to shock damage which can cause sensitive
internal components to fail. Note that minor damage to metal finishes often creates burrs which can
present a hazard to unprotected hands, other parts of the body and to components such as O-rings.
Control the local working environment with good house-keeping practices to prevent slips, trips or
falls, and make sure ropes or cables which are attached to equipment are positioned safely to prevent
entanglement.
Do not allow any tools or equipment to block any access routes or impede normal traffic flows in a
gangway or on a stairway.
Water tightness of instruments depends on fine surface finishes, accurate dimensional tolerances and
cleanliness of components. When dismantling equipment care should always be taken to protect
surface finishes. The disassembly process should be carried out in a well-ventilated area with as few
personnel in the vicinity as possible.
Servicing must always be carried out by suitably qualified and experienced personnel.
.

Section 1 – Introduction 8
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Section 2 – Pressure Housings


2.1 Introduction
Subsea equipment fitted with a pressure housing is subject to a vast range of externally applied
pressures and is susceptible to internal pressure build up, for example, if a leak occurs or the
instrument’s battery malfunctions/fails, resulting in venting. Internal pressure presents a potentially
dangerous situation and all appropriate safety measures must be enforced.
WARNINGS

Fumes given off by malfunctioning/failed batteries, particularly lithium based, pose a health
hazard. Make sure the area is well ventilated and the appropriate personal protective equipment, such
as gloves, aprons and goggles, are worn.

When an instrument has leaked it often behaves like a valve, i.e. water pressure causes a rise in
internal pressure which cannot then escape because the point of leakage becomes sealed. When this
happens the instrument is potentially dangerous and all precautions described in this section must be
followed.

Any instrument recovered that is not operable should be suspected of leaking and being flooded.
There may be no prior indication of the presence of a build-up of internal pressure. First indications
may be the endcap(s) of the instrument being forced out of the housing under pressure during the
dismantling process.
Complete removal of an endcap’s retaining mechanism means it becomes unconstrained and
therefore free to be discharged from its housing under high internal pressure; an uncontrolled and
potentially dangerous situation.
Symptoms that indicate a higher risk of internal pressure include:
l Equipment that failed when deployed, in transit or storage.
l Equipment stored for a long time with batteries connected.
l Equipment having suffered physical damage.

WARNING

Do not transport equipment that is internally pressurised.

2.2 Instruments fitted with a Pressure Relief Vent Valve


Pressure relief vent valves are fitted into all subsea equipment housings containing batteries. They
comprise a valve with dual O-rings and a vent hole behind the second O-ring. The pressure relief vent
valve is designed so it can operate automatically to release any internal pressure, or it can be manually
withdrawn, using a screw, to the point where the relief hole becomes open to the atmosphere and
allows internal pressure to dissipate. The valve is normally retained to the instrument by means of a
retaining spring preventing it from being completely extracted.
A normal functioning instrument may emit a short audible rush of air when the pressure relief vent
valve is operated. A longer rush of air/gas indicates a pressurised instrument, in which case the work
area must be ventilated while the air/gas is discharged. Internal pressure dissipates to atmosphere in
a very short time and may be accompanied by water, debris, fumes, noise etc.

Section 2 – Pressure Housings 9


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WARNING

Risk of Toxic Gases. When operating the pressure release vent valve, ensure the work
environment is well ventilated and only necessary authorised personnel are present as toxic gases
may be released. Ensure personal protective equipment, such as gloves and eye protection are worn.

2.3 Instruments not fitted with a Pressure Relief Vent Valve


Some older Sonardyne instruments are not fitted with a pressure relief vent valve.
If an instrument indicates, or is suspected of being pressurised and does not have a pressure relief
vent valve fitted, contact the Sonardyne Emergency Support Line (+44 (0) 1252 877600) in the first
instance for advice on the correct course of action to follow.

2.4 Dismantling Precautions (Instrument fully functioning)


The techniques for retaining endcaps in the pressure housings differ for instrument types; refer to the
instrument's user manual for the dismantling procedure.
The normal procedure before opening any underwater instrument is to wash the instrument in clean
fresh water to remove any salt, sand/silt and marine growth and then dry it with a lint free cloth. The
instrument should only be opened in a clean, well-ventilated, dry area.
To ease dismantling and release any slight internal pressure that may have built up during normal
operation, the pressure relief vent valve should be operated as described in Instruments fitted with a
Pressure Relief Vent Valve on the previous page and in the instrument’s user manual.
WARNING

Do not stand directly in front of the end cap during removal. There is potential for the endcap to
be ejected forcibly without notice due to internal pressure.

2.5 Dismantling Precautions (instrument known or suspected to be


pressurised)
The techniques for retaining endcaps in the pressure housings differ for instrument types; refer to the
instrument's user manual for the dismantling procedure.
The normal procedure before opening any underwater instrument is to wash the instrument in clean
fresh water to remove any salt, sand/silt and marine growth and then dry it with a lint free cloth. The
instrument should only be opened in a clean, well-ventilated, dry area.
If an instrument is known, or suspected to be internally pressurised through water ingress or battery
failure, additional precautions must be taken.
Remove the instrument to a well-ventilated location away from other working personnel.
WARNING

Do not attempt to dismantle or perform any maintenance activity on an instrument that has a hot
housing. The instrument must be cooled before proceeding.

If the instrument housing is hot, this indicates recent or current active internal chemical action and it
must not be dismantled. Wear the appropriate personal protective equipment such as gloves and
lower the instrument overboard into the water for several hours or until it has cooled. Refer to the
battery manufacturer’s SDS/BIS (see Safety Datasheets/Battery Information Sheets on page 22).

Section 2 – Pressure Housings 10


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To release internal pressure operate the pressure relief vent valve as described in Instruments fitted
with a Pressure Relief Vent Valve on page 9. If there is no significant pressure dissipation and no
fumes indicating a battery failure, the instrument can be dismantled; refer to the instrument's user
manual for the dismantling procedure. If a pressure relief vent valve is not fitted follow the precautions
described in Instruments not fitted with a Pressure Relief Vent Valve on the previous page.
If chemical fumes are present when the pressure relief vent valve is released, or there are deposits
around the vent exterior, these are signs that the battery has vented due to water ingress or battery
failure. In these circumstances the battery pack and internal electronics may have been severely
damaged.
Take extreme care when removing the endcap. There may be a possibility of some internal pressure
remaining, due to the pressure relief vent valve being blocked with products of the internal chemical
reaction.
If a removed battery is found to be leaking, it must be placed in a sealable plastic bag and covered with
a mixture of neutralizing agent (soda ash or baking soda) and absorbent material (vermiculite) and
then placed in a secondary bag for additional containment. The battery should be classified as
hazardous waste and disposed of in accordance with local health and safety, and environmental
regulations.
Any spilled electrolyte must be absorbed/neutralized using absorbent material and neutralizing agent.
The contaminated absorbent must be placed into a sealable bag and then placed in a secondary bag
for additional containment, and disposed as hazardous waste. The contaminated area can be cleaned
with water or an ammonia-based cleaner.
The electronics, end caps and pressure housings should be thoroughly cleaned with fresh water.

Section 2 – Pressure Housings 11


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Section 3 – Electronic Hazards


3.1 High Voltages
3.1.1 High Voltage Awareness
Operation of Sonardyne equipment does not present any danger to users in normal use. Where
permitted, if the internal electronics chassis is removed from its housing for maintenance, high
voltages are present when transmitting, particularly on the transmitter PCB and transducer. The
following warning symbol , when found on the equipment, indicates high voltage awareness is
required.

3.1.2 Storage Capacitors


Subsea equipment incorporates capacitors which are capable of storing large quantities of electrical
energy. Avoid contact or inadvertent discharge during dismantling.

3.1.3 Handling of Electronic Components


Most of the circuits in subsea equipment use CMOS logic, which is easily damaged by static discharge
or excessive supply voltage. The best action for electronics is no handling.
CAUTION

Electrostatic Discharge (ESD) precautions (grounded wrist strap) must be taken before handling
circuit boards or modules.

Field servicing cannot compare in efficiency and accuracy with the original factory calibration and
therefore field servicing should be limited to checking correct calibration/operation (within the limits of
the test gear available) and repair by exchange of PCBs or modules.

Section 3 – Electronic Hazards 12


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Section 4 – Batteries
4.1 Use of Appropriate Battery Types
WARNING

Do not fit unauthorised battery pack types into equipment.

Battery packs must not be reconfigured from one type to another, e.g. NiMH to alkaline or lithium
as this may lead to alkaline or lithium cells being inadvertently charged.

Sonardyne equipment uses a variety of battery types including: rechargeable, alkaline and lithium
based packs. Instruments must not be fitted with alternative battery pack types unless they are
specifically designed to use them.
Note
Damage caused by using unauthorised battery packs will invalidate any warranty.

To identify the type of battery installed, a label is attached on the outside of the equipment. Examples
of the labels used are shown below:
Figure 4–1 Example of a Lithium Battery Identification Label

Figure 4–2 Example of a Lithium-ion (Li-ion) Battery Identification Label

Figure 4–3 Example of an Alkaline Battery Identification Label

Section 4 – Batteries 13
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4.2 Primary Lithium (Li) Batteries


4.2.1 Lithium Battery Types
Primary (non-rechargeable) lithium batteries are often referred to as lithium metal batteries.
Two types of primary lithium cells (LS and LSH) are used throughout Sonardyne products depending
on the application requirements. The LS cell types used are: LS26500 (Size C), LS33600 (Size D)
and LS14500 (Size AA).
The LSH cells are designed for applications requiring higher continuous currents. The LSH cell types
used are: LSH14 (Size C) and LSH20 (Size D).

4.2.2 Safety Precautions for Primary Lithium (Li) Batteries


WARNINGS

Fire, explosion and burn hazard. Do not recharge, short circuit, crush, disassemble, heat above
100°C, incinerate or expose battery contents to water.

Lithium based batteries become hazardous (fire and corrosion) if exposed to air and water and if
damaged may emit fumes. Consult the battery manufacturer's Safety Datasheet/Battery Information
Sheet prior to operating lithium based battery products.

Special precautions and regulations apply to the transport, handling and disposal of primary Lithium
products; see Transporting Primary Lithium Batteries on the next page.
Lithium batteries are powerful sources of electrical energy and should be handled with care to avoid
short-circuiting.
When a battery powered underwater instrument is suspected of flooding, extreme caution must be
exercised when opening the instrument in case it is internally pressurised; see Dismantling
Precautions (Instrument fully functioning) on page 10 and Dismantling Precautions (instrument known
or suspected to be pressurised) on page 10.
Safety Datasheets/Battery Information Sheets for primary lithium cells and batteries are shown in
Lithium Cells and Batteries on page 22.
Primary lithium cell specifications are shown in Lithium Cells on page 38.

4.2.3 Fault Procedures


WARNINGS

If a cell is ruptured, potentially flammable materials may be exposed.

For primary lithium battery packs, CO2 extinguishers or, even preferably, copious quantities of
water or water based foam, can be used to cool down burning LI-SOCI2 cells and batteries, as long as
the extent of the fire has not progressed to the point that the lithium metal they contain is exposed
(marked by deep red flames). Do not use for this purpose sand, dry powder or soda ash, graphite
powder or fire blankets. Use only metal (Class D) extinguishers on raw lithium.

There is a risk of burns and injury when handling hot batteries; suitable personal protective
equipment, such as gloves, aprons and goggles, must be worn.

If a cell or battery is shorted or starts to heat up, it should be disconnected from the transponder
immediately and removed to the outdoors or to a well-ventilated area to cool down. Tongs, or a shovel,
are recommended for this purpose. Should the battery overheat significantly or catch fire, use the fire-
fighting media as described in in the above Warning, or the cell manufacturer’s safety datasheet. Once

Section 4 – Batteries 14
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the temperature has dropped and it is deemed safe to do so, the cell or battery can be disposed of as
described in Disposal of Primary Lithium Batteries on the next page.
Charging of Non-Rechargeable Battery Packs
WARNING

Do not attempt to charge non-rechargeable batteries or battery packs.

Non-rechargeable cells exhibit a range of unpredictable characteristics if any attempt is made to


charge them. Very high pressures and temperatures can occur in an instrument often some-time after
the attempt to charge them has terminated.
Attempts to charge a primary battery may lead to an imbalance within the cell potentially leading to gas
generation and in extreme cases explosion.

4.2.4 Primary Lithium Batteries Storage Instructions


Primary Lithium batteries should be stored in their original containers, in a clean, dry, cool, ventilated
area, where the temperature should be as cool as possible to maximise shelf life and not exceed 30°C.
CAUTION

Battery life may be reduced if exposed to temperatures in excess of 30°C.

Instruments with batteries installed should not be left on deck in strong sunlight such that they become
hot to the touch.
Observe the manufacturers minimum and maximum storage temperatures.
Store all primary lithium battery packs in an isolated area, away from combustible materials. Store
depleted cells in an area separate from fresh cells. Allow space for complete encapsulation with Lith-X
in the event of a fire.
Any primary lithium battery storage area should have immediate access to both a class D and an ABC
fire extinguisher. Refer to the battery manufacturer’s specifications for extinguishing fires containing
this battery type.
Instruments should be cooled to normal room temperature or lower before being opened for battery
replacement.

4.2.5 Transporting Primary Lithium Batteries


The current regulations and the information below is provided for guidance only. Note that datasheets
concerning quantities of lithium per cell are available from cell manufacturers and these may change
without prior notice, therefore the quantities of lithium per battery pack cannot be verified by
Sonardyne Ltd.
When transporting lithium based products it is the operator’s responsibility to comply with local,
national and international regulations in force at the time of transport.
l By Road: ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road Regulations (http://www.unece.org)
l By Sea: International Maritime Dangerous Goods Code (http://www.imo.org)
l By Air: IATA Dangerous Goods Regulations (http://www.iata.org)
Transportation Certificates for cells are shown in . The certificates detail nominal voltage, capacity,
energy and the equivalent Lithium Metal content. Transportation certificates for battery packs used in
Sonardyne equipment are available on request from Sonardyne Support.

Section 4 – Batteries 15
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The IATA Dangerous Goods Regulations Section II, Packing Instructions 967, Note A154 states that
lithium batteries identified by the manufacturer as being defective for safety reasons, or that have been
damaged, that have the potential of producing a dangerous evolution of heat, fire or short circuit are
forbidden for transport.

4.2.6 Disposal of Primary Lithium Batteries


WARNING

Do not dispose of primary Lithium batteries in a fire as there is a potential risk of battery
explosion.

Cells and batteries must be disposed of in accordance with local health and safety, and environmental
regulations regarding hazardous substances. Packaging suitable for the storage and transport of
Lithium cells/batteries must be used at all times when not installed in an instrument.
Suitable personal protective equipment, such as gloves, apron and goggles, should be worn when
handling suspect cells/batteries. If the skin has come into contact with the electrolyte, it should be
washed thoroughly with clean water.

4.3 Lithium Ion (Li+) Batteries


In a lithium ion (li-ion) cell, the negative electrode (anode) is graphite and the positive electrode
(cathode) is a lithium-bearing metal compound. Li-ion cells have an exceptional cycling aptitude owing
to the stable electrode structure. Charging and discharging involves exchange of lithium ions between
the electrodes via the electrolyte. Because of the high output voltage (up to 4.2 V), a non-aqueous
electrolyte is used, mainly comprising a mixture of organic carbonates.
Safety Information for li-ion cells and batteries are shown in Lithium-ion Cells and Batteries on
page 31.
Li-ion cell specifications are shown in Lithium-ion Cells on page 38.

4.3.1 Safety Precautions for Lithium Ion (Li+) Batteries


Refer to Safety Precautions for Primary Lithium (Li) Batteries on page 14.
WARNINGS

Only charge li-ion batteries using the charging equipment supplied; do not attempt to charge
li-ion batteries using any other type of charging equipment.

4.3.2 Fault Procedures


Refer to Fault Procedures on page 14.
WARNING

Dry chemical type or CO2 extinguishers, Halon, or copious quantities of water or water-based
foam can be used to cool down burning li-ion cells and batteries. During water application, caution
should be exercised as burning pieces of flammable particles may be ejected from the fire. In case of
fire, it is recommended to wear self-contained breathing apparatus to avoid contact with irritant
fumes. Evacuate all persons from immediate area of fire. Do not re-enter the area until it has been
adequately purged of the fire vapour and extinguishing agent.

4.3.3 Lithium Ion Batteries Storage Instructions


Refer to Primary Lithium Batteries Storage Instructions on the previous page

Section 4 – Batteries 16
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When charging li-ion batteries for the first time after long-term storage, deactivation of reactants may
lead to increased battery voltage and decreased battery capacity. It is possible to restore batteries to
their original performance by repeating several cycles of charging and discharging.
For long-term storage of more than one year, li-ion batteries should be charged at least once a year to
prevent leakage and deterioration in performance due to self-discharging. Batteries stored whilst
connected to equipment and batteries containing sophisticated battery management electronics may
need to be monitored and charged several times a year to avoid technical and performance difficulties.

4.3.4 Transporting Lithium Ion Batteries


Transporting Lithium Ion Batteries above
The IATA Dangerous Goods Regulations Section II, Packing Instructions 967, Note A164 states that
li-ion batteries and cells contained in equipment, must have the battery electrically disconnected and
exposed terminals protected before transportation.

4.3.5 Disposal of Lithium Ion Batteries


Refer to Disposal of Primary Lithium Batteries on the previous page.

4.4 Alkaline and Nickel Metal Hydride (NiMH) Batteries


Other battery types installed in Sonardyne equipment are Alkaline and Nickel Metal Hydride (NiMH).

4.4.1 Alkaline Batteries


WARNING

Do not attempt to charge alkaline batteries.

Alkaline batteries are non-rechargeable. They must be disposed of as hazardous waste, in


accordance with local health and safety, and environmental regulations.

4.4.2 Nickel Metal Hydride (NiMH) Batteries


WARNING

Only charge NiMH batteries using the charging equipment supplied; do not attempt to charge
NiMH batteries using any other type of charging equipment.

Nickel Metal Hydride (NiMH) batteries are rechargeable. Sonardyne supplies the correct charging
equipment with any euipment containing NiMH batteries.
NiMH batteries should be replaced when they fail to hold their charge. They must be disposed of as
hazardous waste, in accordance with local health and safety, and environmental regulations.

4.5 Charging Batteries in Sealed Containers


Batteries may give off gases when charged. As a general rule, sealed containers must be allowed to
vent to atmosphere during the charging process.
Some equipment may be fitted with safety features which prevent the possibility of problems caused
by gases vented by batteries. Refer to the equipment user manual for the correct charging procedure.
Equipment fitted with a pressure relief vent valve must be checked to make sure the vent valve is
seated properly following recharging of the batteries.

Section 4 – Batteries 17
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

4.6 Reconnecting a Partially Used Battery


When reconnecting a partially used battery, calculate if the remaining battery life will allow the next
mission to be safely accomplished. If so, note the date of reconnection, both on the battery label and in
written records, against the serial number of the instrument.

4.7 Batteries – End of Life


Discharging batteries below their end point voltage can lead to internal corrosion and leakage of
electrolyte in certain types of cells. Although there is very little gas to cause a pressure rise under these
conditions, the electrolyte leakage will cause severe corrosion.
After recovering an instrument, the battery voltage(s) should be checked while still connected to see if
it is above the end point voltage for that type of cell. Disconnect and mark as usable or not with date of
disconnection noted both on the pack and in written records. Check the instrument, including solder
joints for signs of corrosion.
The remaining life of a battery depends on both time and, for a transponder, the number of times it has
been interrogated. Some transponders keep their own record of battery usage, but a separate record
should be maintained consisting of time elapsed whilst battery is installed and connected, plus
estimates of the number of interrogations .

4.8 Fitting a New Battery


Refer to the equipment user manual for the instructions on how to fit a new battery.
Make a note of the date when a new battery is connected. Write this date on the battery label and also
in your written records.

4.9 Battery Pack Fuses


A number of Sonardyne battery packs have carefully selected, highly-reliabile fuses soldered onto the
diode-board of the pack. The fuses can be either resettable “Polyfuse” devices, or "Littelfuse" devices.
If a fuse has blown due to mishandling, it may be replaced by an identicaly specified fuse type; the
rating must not on any account be increased.

4.10 WEEE Directive


A number of Sonardyne battery packs may have the WEEE (Waste from Electrical and Electronic
Equipment Directive 2002/96/EC) ‘crossed out wheelie bin logo’ marked on them.
This logo indicates that the batteries must not be disposed of in a landfill. If the logo has a black solid
line under it, this indicates that the equipment was manufactured after 13 August 2005, after the
directive came into force and that the equipment must not be disposed of in a landfill.
Table 4–1 WEEE Directive 2002/96/EC Logo Definitions

Symbol Definition
The WEEE Directive (Waste from Electrical and Electronic Equipment Directive)
2002/96/EC used on equipment to show the product must not be disposed of in landfill. The
logo is defined in detail in the European Standard EN50419

Section 4 – Batteries 18
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Table 4–1 WEEE Directive 2002/96/EC Logo Definitions (continued)

Symbol Definition
The same as the WEEE Directive (detailed above) but the bottom bar is added to indicate
equipment that has been manufactured after 13 August 2005, after the Directive came into
force. This must not be disposed of in landfill.

4.11 Additional Battery Manufacturer Information


Additional information applicable to lithium and lithium-ion cells is available from:
Saft Headquarters
12, rue Sadi Carnot
93170 Bagnolet
France
Tel: +33 (0)1 49 93 19 18
Fax: +33 (0)1 49 93 19 50
http://www.saftbatteries.com

Panasonic Batteries
Panasonic Industrial Company
A Division of Panasonic Corporation of North America
5201 TollView Drive, 1F-3
Rolling Meadows, IL-60008
Toll Free: 877-726-2228
Fax: 847-468-5750
e-mail: oembatteries@us.panasonic.com
http://www.panasonic.com/batteries

E-One Moli Energy Corp.


10 Dali 2nd Rd., Shan-Hwa
Tainan County
Taiwan, R.O.C,
Tel: 886-6-505-0666
Fax: 886-6-505-0777
http://www.molicel.com/

allbatteries/Enix Energies
Unit 20, Monkspath Business Park
Highlands Road
West Midlands
B90 4NZ
Tel: +44 121 5068619
http://www.allbatteries.com

Section 4 – Batteries 19
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Section 5 – Equipment Environmental Limitations


5.1 Storage Temperature Limits
Equipment must be stored according to the specifications quoted in the equipment manual/datasheet.
It should be noted however that lines connecting pressure transducers to a transponder may become
partly filled with seawater during service. This cannot easily be expelled and may therefore freeze if
transponders are stored at sub-zero temperatures after recovery from the sea.
Batteries should be stored in their original containers, in a clean, dry, cool, ventilated area, where the
temperature should be as cool as possible to maximise shelf life and not exceed 30°C. Refer to the
battery manufacturers specifications for battery storage.

5.2 Instrument Load Bearing Capability


Navigational Transponders are not normally designed to take in-line loads greater than the maximum
upthrust applied by the floatation equipment. The carrying straps, if fitted, are for ease of manual
handling and the range of transducer guards selected for their acoustic properties.
WARNING

Do not exceed the Working Load Limit capabilities of release mechanisms, or additional lifting
equipment.

The Working Load Limit (WLL) capability of the release mechanism built into many instruments, can
only be used for in-line lifting operations if a suitably-rated, approved, lifting strap, transducer guard,
buoyancy collar eyes or other safe method is selected.
It is the responsibility of the Responsible Body at the worksite to make sure the condition of the
equipment is acceptable and that a safe lifting method has been devised for any particular operation.
Sonardyne’s range of Oceanographic Release Transponders have been designed specifically for in-
line lifting operations.
Appropriate shackles must be used in release systems to ensure freedom from corrosion. It is
important to note that instruments, their release mechanisms and shackles form part of an integrated
and complete system.

5.3 Floatation Equipment


5.3.1 Introduction
Floatation equipment is fitted to subsea transponders in order to aid their recovery once a deployment
is complete. A nett up-thrust requirement is given in manuals and technical data for any particular
instrument. The following guidelines are given to assist operators in their understanding of the general
requirements.

5.3.2 Float Inspection


The float lifting eyes and attachment bolts can be susceptible to corrosion. To guarantee safe
operation, the float lifting eyes and attachment bolts must be inspected prior to use, any indication of
corrosion and the lifting eyes and bolts must be replaced.

5.3.3 Minimum Nett Buoyancy of Floats


Floats are described as having a minimum nett buoyancy in seawater and this is the figure quoted in
Sonardyne float technical data and by the float manufacturer. Total up-thrust can be calculated by

Section 5 – Equipment Environmental Limitations 20


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

knowing this figure, e.g., a float with 30 kilogram nett buoyancy in sea water supporting a load with
weight in sea water of 30 kilogram would result in neutral buoyancy, i.e. no nett up-thrust.

5.3.4 Float Inserts


Float collar Inserts are used to allow floats of larger internal bore to be used with housings of nominal
six inches diameter. The weight in water of an insert is usually slightly positive and this will be
additional to the weight of the instrument being supported by the float. Two inserts will result in
approximately 0.5 kilogram reduction in nett up-thrust.
Nett Upthrust
The difference between the nett buoyancy of the float and the total weight of an object, or objects, in
water that it is supporting, e.g.
Nett Upthrust = (minimum nett buoyancy of the float) - (the weight of the instrument + the float inserts
in water)
e.g. 30 kg - (11.2+ 0.5) kg = 17.3 kg nett upthrust
Float Storage Conditions
Floats should be stored within the temperature range -6 to +65°C. Floats are not hygroscopic and
should not therefore be affected by moisture in air.
CAUTION

Do not stack the floats on top of each other or store in direct sunlight.

Float Over-Pressure
The maximum water depth quoted for a float must not be exceeded. Over-pressured floats are forced
to absorb water and their weight in air thus increases. All floats should be weighed prior to use to
check that they are maintaining their original manufactured weight.

Section 5 – Equipment Environmental Limitations 21


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Appendix A – Safety Datasheets/Battery Information Sheets

A.1 Lithium Cells and Batteries

Appendix A – Safety Datasheets/Battery Information Sheets 22


Battery Information Sheet
Primary Li-SOCl2 single cells and multi-cell battery packs

According to REACH regulation (EC 1907/2006, Art 31) and to OSHA regulation (29 CFR 1910.1200),
batteries are ARTICLES with no intended release. As such, they are not covered by legal requirements
to generate and supply an SDS or an MSDS.

This Battery Information Sheet is provided solely as information


document for the purpose of assisting our customers.

1. IDENTIFICATION
1.1 Product
Lithium-thionyl dichloride primary unit cells and multi-cell battery systems composed of these cells

1.2 Supplier
Headquarters Saft S.A.S.
Address 26 quai Charles Pasqua, 92300 LEVALLOIS-PERRET – France
Phone/Fax Phone / Fax : +33 1 58 63 16 00/+33 1 58 63 16 18
Factory Saft Poitiers
Address Rue Georges Leclanché, BP 1039, 86060 POITIERS Cedex 9 – France
Phone/Fax +33 (0)5 49 55 48 48 /+33 (0)5 49 55 48 50
Factory Saft Ltd.
Address River Drive, Tyne & Wear, SOUTH SHIELDS, NE33 2TR – United Kingdom
Phone/Fax +1 44 191 456 1451/+1 44 191 456 6383
Factory Saft America Inc.
Address 313 Crescent Street, VALDESE, NC 28690 – USA
Phone/Fax +1 828 874 4111/+1 828 874 2431
Factory Saft Batteries Co., Ltd.
Address Zhuhai Free Trade Zone, Lianfeng Road, ZHUHAI 519030, Guangdong Province – China
Phone/Fax +86 756 881 9318/+86 756 881 9328
Factory Tadiran Batteries Ltd.
Address 34 Y. Rabin Avenue – KIRYAT EKRON 76950 - Israel
Phone/Fax +972 894 44374/+972 894 13066
Factory Tadiran Batteries GmbH
Address Industriestrasse 22, D-63654 BÜDINGEN – Germany
Phone/Fax +49 (0)6 042 954 599/+49 (0)6 042 954 190

1.3 Emergency contact For chemical emergency ONLY (in case of spill, leak, fire, exposure or accident) call CHEMTREC at:
International: +1-703-527-3887 for English
Within the USA: +1-800-424-9300

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 1
2. HAZARD IDENTIFICATION

The Li-SOCl2 batteries described in this Battery Information Sheet are sealed units which are not hazardous under normal
operating conditions in accordance with manufacturer’s recommendations, as stated in the user’s manual or other similar
documentation. Under normal use, the battery integrity is maintained and the active components it contains are isolated
from the outside.
In particular, the battery should not be submitted to any mechanical (opening, puncture, immersion), thermal (burning,
heating to temperatures above the normal temperature range of the product) or electrical abuse (short-circuit, recharge,
forced discharge), which will lead to the activation of safety valves and/or the rupture of the battery container.
Any accidental release of the inner components of the cell, or their combustion products could be highly hazardous. Battery
content exposition to air humidity/liquid water may be followed by severe battery vent/explosion/fire, depending on the
hazard causes and circumstances.

Protection from charging:


Whenever lithium batteries are not the single power source in a circuit, the following measures recommended by
Underwriters Laboratories are relevant. The cells should not be connected with an electrical power source that would
increase the load through the cells. The electronic circuit shall include one of the following:

A. Two suitable diodes or the equivalent in series with the cells to prevent any reverse (charging) current. The second
diode is used to provide protection in the event that one would fail. Quality control, or equivalent procedures,
shall be established by the device manufacturer to check that the diode polarity is correct for each unit.

Or

B. A blocking diode or the equivalent to prevent any reverse (charging) current and a resistor to limit current in case
of diode failure. The resistor should be sized to limit the reverse (charging) current to the maximum value
according to the data sheet of the cell.

3. COMPOSITION, INFORMATION OR INGREDIENTS

Each unit cell consists of a hermetically sealed metallic can containing a number of chemicals and materials of construction
of which the following are potentially hazardous upon release to air.

Component CAS Number EINECS/ELINCS Content (wt. %)*


Lithium metal 7439-93-2 231-102-5 2-6
Thionyl dichloride 7719-09-7 231-748-8 18-47
Aluminium chloride 7446-70-0 231-208-1 1-5
Gallium chloride 13450-90-3 236-610-0 0-2
Lithium chloride 7447-41-8 231-212-3 1-2
Carbon 1333-86-4 215-609-9 2-5
PTFE 9002-84-0 N/A 0-1
Stainless steel, Nickel and inert material N/A N/A remainder
* Quantities may vary with cell model

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 2
4. FIRST AID MEASURES (not anticipated under normal use)

4.1 Electrolyte contact

EYE CONTACT: Immediately flush with plenty of water for at least 15 minutes and get medical attention.

SKIN CONTACT: Remove contaminated clothing and immediately flush with plenty of water for at least 15 minutes. In
severe cases, get medical attention.

INHALATION: Contents of an opened cell may cause respiratory tract and mucus membrane irritation. Remove from
exposure, rest and keep warm. Immediately inhale Cortisone spray. In severe cases, track medical surveillance for 48 hours.

INGESTION: Wash out mouth thoroughly with water and give plenty of water to drink. Get medical attention.

FURTHER TREATMENT: All cases of eye contamination, persistent skin irritation and casualties who have swallowed this
substance or have breathed its vapours should be seen by a Doctor.

4.2 Lithium metal contact


EYE CONTACT: Immediately flush with large quantities of water for at least 15 minutes, with open eyelids, and get medical
attention.

SKIN CONTACT: Remove particles of lithium from skin as quick as possible. Immediately flush with plenty of water for at
least 15 minutes and get medical attention.

INHALATION/INGESTION: Contents of an opened cell may cause respiratory tract and mucus membrane irritation. Remove
from exposure, rest and keep warm. Immediately inhale Cortisone spray. In severe cases, track medical surveillance for 48
hours.

5. FIRE FIGHTING MEASURES (not anticipated under normal use)

ESTINGUISHING MEDIA:
 During a fire with lithium batteries, using large amounts of cold water or water-based foam has some cooling
effect and is effective to prevent fire expansion as long as the extent of the fire has not progressed to the point
that the lithium metal they contain is exposed (as marked by appearance of deep red flames). Do not use warm or
hot water.
 Lith-X Class D extinguishers are effective on fires involving only a few lithium batteries.
 Do not use CO2 or Halon-type extinguishers.
 Do not use sand, dry powder or soda ash, graphite powder or fire blankets.
 Use only class D metal extinguishers on raw lithium metal.

SPECIAL FIRE FIGHTING PROCEDURES:


 Fire fighters should wear approved/certified positive pressure self-contained breathing apparatus.
 Full protective clothing is necessary to prevent potential body contact with electrolyte solution.
 During water spraying, caution is advised as burning pieces of lithium may be ejected from the fire.

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 3
 It is permissible to use any class of extinguishing medium, specified above, on these batteries or their packing
material. Cool exterior of batteries if exposed to fire to prevent rupture.
 If the cells or batteries are not located at the center of the fire, copious amounts of water may be supplied using a
diffuser type nozzle so that the cells remain cool during the fire containment and extinction. A sprinkler system
should be suitable for this purpose, the critical factor being that the lithium cells do not experience temperatures
above the melting point of lithium (180°C).
 Small amounts of water should never be used such as the volumes contained within portable fire extinguishers.
Standard dry powder extinguishers are ineffective. It should be kept in mind that a hazard of hydrogen formation
exists whenever hot lithium metal comes into contact with water.

6. ACCIDENTAL RELEASE MEASURES (not anticipated under normal use)

INDIVIDUAL PRECAUTIONS: Evacuate the employees from area until fumes dissipate. In case of electrolyte leakage from a
cell or battery, do not inhale vapors or touch liquid with bare hands. In case of skin or eye contact, inhalation or ingestion,
follow the measured described in section 12.

ENVIRONMENTAL PRECAUTION: Avoid sewage, surface water and underground water contamination. Avoid ground and
atmosphere contamination.

WAYS OF CLEANING: With protective glasses and gloves, use absorbent material (sand, earth, chalk (CaCO3) or lime (CaO)
powder or Vermiculite) to absorb any exuded material. Seal leaking battery (unless hot) and contaminated absorbent
material tight in plastic bag, and dispose of as hazardous waste in accordance with local regulations. Electrolyte traces may
be wiped off dryly using household paper. Rinse with water afterwards.

7. HANDLING AND STORAGE

IMPORTANT NOTICE: Lithium-thionyle chloride batteries are not rechargeable and should not be tentatively charged or
recharged. Manufacturer’s recommendations should be followed regarding maximum current and operating

temperature range. Applying pressure or deforming the battery may lead to disassembly and cause eye, skin and throat
irritation.

STORAGE: Store in a cool, regulated (preferably below 21°C and in any case below 30°C), dry and ventilated area, away
from possible sources of heat, open flames, food and drink. Avoid exposure to direct sunlight for long periods.
Temperatures above 100°C (or higher for High Temperatures cells and batteries such as the LSH20-150 cell- refer to
individual data sheets for maximum temperatures) may cause leakage and rupture, and result in shortened battery service
life. Keep proper clearance space between batteries and walls. Since short circuit can cause burn hazard, leakage or
explosion hazard, keep batteries in original packaging until use and do not mix them.

HANDLING:
 Do not open the battery system.
 Do not crush or pierce the cells.
 Do not short (+) or (-) terminal with conductors.
 Do not reverse the polarity.
 Do not submit to excessive mechanical stress.
 Do not mix batteries of different types or mix new and old ones together.
 Do not use the unit without its electronic management system.

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 4
 Do not expose the unit to water or condensation.
 Do not directly heat, solder or throw into fire. Such unsuitable use can cause leakage or spout vaporized electrolyte
fumes and may cause fire or explosion.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION* (not anticipated under normal use)

Respiratory
In all fire situations, use self-contained breathing apparatus
protection
Hand
In case of leakage wear protective gloves
protection
Eye
Safety glasses are mandatory during handling
protection

Other In the event of leakage or ruptured cells, wear a rubber apron and protective clothes.

*AFNOR pictograms
Occupational exposure standard:
Compound 8 hour TWA 15 min TWA SK
Sulfur Dioxide 1 ppm 1 ppm -
Hydrogen chloride 1 ppm 5 ppm -

9. PHYSICAL AND CHEMICAL PROPERTIES

The lithium-thionyl chloride cell or battery described by this Battery Information Sheet is a sealed unit when offered for
sale. It is a manufactured “article” and does not expose the user to hazardous chemicals when used in accordance with
manufacturer specifications.

Appearance – Cylindrical shape


Odour – If leaking, gives off a pungent corrosive odour
Flash point – Not applicable Flammability – Not applicable
Boiling Point – Not applicable Melting Point – Not applicable
Vapor Pressure – Not applicable Vapor Density – Not applicable
pH – Not applicable Specific Gravity – Not applicable
Solubility (in water) – Not applicable Solubility (other) – Not applicable

10. STABILITY AND REACTIVITY

The battery system is stable when handled and stored according to section 4.

MATERIALS TO AVOID: Oxidizing agents, bases, water. Avoid electrolyte contact with aluminium or zinc.

CONDITIONS TO AVOID: Do not heat above 100°C (or higher (150°C) for High Temperatures cells and batteries such as the
LSH20-150 cell- refer to individual data sheets for maximum temperatures) or incinerate. Do not disassemble, crush, pierce,
short, charge or recharge. Avoid mechanical or electrical abuse.

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 5
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen (H2) as well as lithium oxide (Li2O) and lithium hydroxide (LiOH) dust
are produced in case of reaction of lithium metal with water (hydrolysis).
Chlorine (Cl2), sulfur dioxide (SO2) and disulfur dichloride (S2Cl2) are produced in case of thermal decomposition of thionyl
dichloride above 100°C. Hydrochloric acid (HCl) and sulfur dioxide (SO2) are produced in case of reaction of thionyl
dichloride with water at room temperature.
Hydrochloric acid (HCl) fumes, lithium oxide (Li 2O), lithium hydroxide (LiOH) and aluminium hydroxide (Al(OH) 3) dust are
produced in case of reaction of lithium tetrachloroaluminate (LiAlCl4) with water.

11. TOXICOLOGICAL INFORMATION

There is no risk, unless the battery ruptures. In the event of accidental exposure to internal contents, corrosive fumes will
cause severe skin, eye and mucous membrane irritation. Medical conditions are generally aggravated by exposure to
battery internal contents: eczema, skin allergies, lung injuries, asthma and other respiratory disorders may occur.
Overexposure may cause symptoms of non-fibrotic lung injury and ingestion can cause tissue damage to throat and gastro-
respiratory tract.

12. ECOLOGICAL INFORMATION

The batteries do not contain mercury, cadmium or other heavy metals.


Eco-toxicity None known if used/disposed of correctly.
Mammalian affects None known if used/disposed of correctly.
Bioaccumulation potential None known if used/disposed of correctly.
Environmental fate None known if used/disposed of correctly.

13. DISPOSAL CONSIDERATIONS

Batteries do not contain hazardous materials according to EC Directives 91/157/EEC, 93/86/EEC, and 2002/95/EC (RoHS)
Directive). Battery recycling is either mandatory or recommended: The European Directive 2006/66/EC has been
implemented by most EC member states.
Dispose of in accordance with local laws and regulations. Store material for disposal as indicated in Section 4. A disposal
service is offered upon request by Tadiran Batteries.
Do not incinerate, or subject cells to temperatures in excess of 100°C (or 150°C for LSH20-150 cells and the battery packs
assembled from them). Such abuse can result in loss of seal, electrolyte leakage and/or violent disassembly with risk of
material projections.
For additional information a Technical Notice is available upon request.
See the section on “Sustainability & Environment” on https://www.saftbatteries.com/about-us/environmental-responsibility

The recycling of batteries must only be conducted by fully trained personnel of licensed recyclers. Attempting to dismantle
batteries or modules into individual cells may lead to serious injuries or death due to high electrical voltage and/or energy.

14. TRANSPORTATION INFORMATION

Note: when manufacturing a new battery pack, one must assure that it has fulfilled the tests according to the UN Model
Regulations, Manuel of Tests and Criteria, Part III, subsection 38.3.

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 6
14.1 United Nations Class

For the single cell batteries and multi-cell battery packs that are non-restricted to transport (non-assigned to the
Miscellaneous Class 9), use lithium batteries inside label.
For the single cell batteries and multi-cell battery packs which are restricted to transport (assigned to Class 9), use Class 9
Miscellaneous Dangerous Goods and UN Identification Number Labels.
In all cases, refer to the product transport certificate issued by the manufacturer.
UN Numbers: 3090 LITHIUM METAL BATTERIES: Shipment of cells and batteries in bulk
3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL
BATTERIES PACKED WITH EQUIPMENT: Cells and batteries contained in
equipment or packed with it

Shipping name LITHIUM METAL BATTERIES


Hazard Classification: 9
Depending on their lithium metal content, some single cells and small multi-cell battery
packs may be non-assigned to Class 9. Refer to Transport Certificate.
Packaging: Group II

14.2 International agreements


By Air International: IATA/ICAO: UN 3090 or UN3091
By Sea International: IMDG: UN 3090 or UN 3091
European road transportation: ADR
European rail transportation: RID

15. REGULATORY INFORMATION

Regulations specifically applicable to the product:


- ACGIH and OSHA: see exposure limits of the internal components of the battery in section 14.
- IATA/ICAO (air transportation): UN 3090 or UN 3091.
- IMDG (sea transportation) : UN 3090 or UN 3091.
- Transportation within the US-DOT, 49 Code of Federal Regulations
- UK regulatory references: Classified under CHIP.
- Battery Directive (2006/66/EC): see section 9

16. OTHER INFORMATION

This information has been compiled from sources considered to be dependable and is, to the best of our knowledge and
belief, accurate and reliable as of the date compiled. However, neither exhaustively nor perfect reliability can be granted.
Information does not imply implicit or specific warranty of it.

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 7
This information relates to the specific products designated and may not be valid for such products used in combination
with any other materials or in any process. It is the user’s responsibility to satisfy himself as to the suitability and
completeness of this information for his particular use.

Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or consequential,
from the use of this battery information sheet provided as a service to our customers. Saft does not offer warranty against
patent infringement.

Saft S.A.S.
Doc N˚ BIS04-11-12 Data in this document is subject to change
26 quai Charles Pasqua,
Edition: February 2018 without notice and becomes contractual
92300 LEVALLOIS-PERRET – France
Version 2.0 only after written confirmation.
Phone : +33 1 58 63 16 00
Fax : +33 1 58 63 16 18
www.saftbatteries.com

February 2018 – Version 2.0 – Li-SOCl2 single cells and multi-cell battery systems Page 8
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

A.2 Lithium-ion Cells and Batteries

Appendix A – Safety Datasheets/Battery Information Sheets 31


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Appendix B – Cell Specifications


B.1 Lithium Cells
Lithium cells used with Sonardyne products are described in Table B–1 below. Refer to the
manufacturers website for the latest specifications, safety, datasheet and transportion certificate or
contact Sonardyne Support for more information.
Table B–1 Lithium Cells

Manufacturer Type Voltage Size Manufacturers Website


Saft LS33600 3.6 V D Bobbin https://www.saftbatteries.com/
LS26500 C Bobbin
LSH20 D Spiral
LSH14 C Spiral
LSH14 Light C Spiral
LS14500 AA Bobbin

B.2 Lithium-ion Cells


Lithium-ion cells used with Sonardyne products are described in Table B–2 below. Refer to the
manufacturers website for the latest specifications, safety, datasheet and transportion certificate or
contact Sonardyne Support for more information.
Table B–2 Lithium-ion Cells

Manufacturer Type Voltage Size* Link


Salt MP144350 3.75 V L 55.5 mm https://www.saftbatteries.com/
W 43.9 mm
H 14.9 mm
Molicel ICR18650H 3.7 V Dia 18.4 mm http://www.molicel.com/ca/
H 65.2 mm
Varta LPP503759 DL 3.7 V L 59.5 mm http://www.varta.com/
W 37.5 mm
H 5.2 mm
Panasonic NCR18650B 3.7 V Dia 18.5 mm https://eu.industrial.panasonic.com/
L 65.3 mm
Inspired Energy NL2024HD22 14.4 V L168 mm https://www.inspired-energy.com
W107 mm Datasheet
H22 mm
Enix MGL28321 15.0 V - MGL28321 Safety Information
MGL28321 Datasheet**

*Sizes shown are approx; see manufacturers datasheet for exact sizes.
**Safety information and datasheet for this battery are not published and are included in this document (see
following pages).

Appendix B – Cell Specifications 38


B.2.1 MGL28321 Safety Information
Material Safety Data Sheet
MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
LI-MN BATTERY Page 1 of 6

1. Identification Of Substance
Product Details
Product Name: LI-MN BATTERY
Product Model: 10440 350mah
Manufacturer/Supplier By: SHENZHEN FEST TECHNOLOGY CO., LTD
Baoshan Industrial Park, Longhua, Bao'an, Shenzhen, Guangdong, China
Tel & Emergency Tel: +86-755-89304183
Fax: +86-755-27764602

2. Composition/Data On Components

COMPONENT CAS # % by wt.


Lithium Cobaltat Dioxide 12190-79-3 38.80%
Aluminum 7429-90-5 5.56%
PVDF 24937-79-9 1.17%
Graphite 7782-42-5 24.2%
Copper 7440-50-8 9.6%
SBR 9003-55-8 1.76%
Polyethylene 9002-88-4 0.09%
Polypropylene 9003-07-0 0.80%
Lithium Hexafluorophoshate 21324-40-3 15.30%
Electrolyte Carbonate Carbonate / 2.72%

3. Hazards Identification

Information pertaining to particular dangers for man and environment:


The product has to be labeled due to the calculation procedure of international guidelines.
Irritating to skin.
Risk of serious damage to eyes.
May cause sensitization by inhalation and skin contact.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon from
USA
Material Safety Data Sheet
MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
LI-MN BATTERY Page 2 of 6

company and literature data.

4. First aid Measures


Eyes: Irrigate thoroughly with water for at least 15 minutes. Obtain medical attention.
Skin: Wash off skin thoroughly with water. Remove contaminated clothing and wash
before reuse. In severe cases obtain medical attention.
Inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical
attention.
Ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain
medical attention.
Further treatment: All cases of eye contamination, persistent skin irritation and casualties who
have swallowed this substance or been affected by breathing its vapours
should be seen by a Doctor.

5. Fire Fighting Measures


Hazardous Combustion Products: When burned, hazardous products of combustion including fume of carbon
monoxide and carbon dioxide can occur.
Extinguishing Media: Water, carbon dioxide, dry chemical or foam.
Basic Fire Fighting Procedures: Wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus and protective clothing to prevent contact with skin and eyes.

6. Accidental Release Measures


Person related measures: Wear personal protective equipment adapted to the situation (protection gloves,
face protection, breathing protection).
Environment protection measures: Bind released ingredients with powder (rock salt, sand).
Dispose off according to the local law and rules.
Avoid leached substances to penetrate into the earth, canalization or water.
If battery casing is dismantled, small amounts of electrolyte may leak. Package
Treatment for cleaning: the battery tightly including ingredients together with lime, sand or rock salt.
Then clean with water.

7. Handling And Storage


Guideline for safe handling:
Always follow the warning information on the batteries and in the manuals of devices. Only use the recommended
battery types.

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MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
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Keep batteries away from children.


For devices to be used by children, the battery casing should be protected against unauthorized access.
Unpacked batteries shall not lie about in bulk.
In case of battery change always replace all batteries by new ones of identical type and brand.
Do not swallow batteries.
Do not throw batteries into water.
Do not throw batteries into fire.
Avoid deep discharge.
Do not short-circuit batteries
Use recommended charging time and current.
Storage:
Storage preferably at room temperature (approx. 20℃).
Avoid large temperature changes.
Do not store close to heating devices.
Avoid direct sunlight. At higher temperature the electrical performance may be reduced.
Storage of unpacked batteries can cause short circuit and heat generation.
Storage of large amounts: If possible, store the batteries in original packaging (because of short circuit protection and
exemptions according to transport regulations).
A fire alarm is recommended.
For automatic fire extinction consider chapter 5 “Fire fighting measures”.

8. Exposure Controls And Personal Protection


Under normal conditions (during charge and discharge) release of ingredients does not occur.
In the event of release of ingredients, the following TLVs have to be considered (U.S.A.):
Material TLV*
Cobalt and compounds: 0.1 mg/m3 (TWA)
Graphite: C 5.0 mg/m3 (TWA)
*Source: OSHA CFR 29 1910.1000 Table Z-1, 2 or 3 3-01-2007.

9. Physical And Chemical Properties


Nominal Voltage: 3.7V
Capacity: 350mah
Watt-hour: 1.295WH
Appearance characters: Multi-color with odorless battery

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MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
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10. Stability And Reactivity


Thermal decomposition /
conditions to be avoided: No decomposition if used according to specifications.
Dangerous Reactions: No dangerous reactions known.
Dangerous products of
decomposition: No dangerous decomposition products known.

11. Toxicological Information


Primary irritant effect: None, unless battery ruptures. In the event of exposure to internal contents,
corrosive fumes will be very irritating to skin, eyes and mucous membranes.
Overexposure can cause symptoms of non-fibrotic lung injury and membrane
irritation.
Inhalation: Lung irritant.
Skin contact: Skin irritant
Eye contact: Eye irritant.
Ingestion: Tissue damage to throat and gastro-respiratory tract if swallowed.
Medical conditions generally In the event of exposure to internal contents, eczema, skin allergies, lung
aggravated by exposure: injuries, asthma and other respiratory disorders may occur.

12. Ecological Information


General notes: Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.

13. Disposal Considerations


Waste Disposal Method: Waste Lithium ion batteries are classified by the federal government as
non-hazardous waste and are safe for disposal in the normal municipal waste
stream.
Large quantities of open batteries should be treated as hazardous waste.
Dispose of in accordance with state regulations.
Do not incinerate, since batteries may explode at excessive temperatures.

14. Transport Information


Lithium ion batteries are tested according to IATA dangerous goods regulations 57th edition and all applicable carrier
and government regulations and 38.3 of the “UN Manual of Tests and Criteria” for compliance with the requirements of
special provisions ADR 188, IMDG 188, DOT / 49 CFR §173.102, 49 CFR Part 171 Subpart C. 49 CFR Parts

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MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
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171–180, 49 CFR 175 and the requirements of IATA DGR packing instruction 965 Section IB or 966 Section I.
Corrugated Box (Thickness>6mm). Each package is labeled with lithium battery handing label UN CLASS: UN3480
or UN3481. Positive test results required for classification as “non-restricted” are stated in dedicated “Declarations of
Conformity”. In addition, the following conditions for non-dangerous goods classification are fulfilled by our products in
original
Each consignment is accompanied with a document with an indication that:
the package contains lithium ion cells;
the package must be handled with care, and that a flammability hazard exists if the package is damaged;
special procedures must be followed in the event the package is damaged, to include inspection and repacking if
necessary; and a telephone number for additional information.
Transport fashion: By air, by sea.

15. Regulations
•Sara
· Section 355 (extremely hazardous substances):
None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):


None of the ingredient is listed.

· TSCA (Toxic Substances Control Act):


None of the ingredient is listed.
Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational Safety and Health Administration
(OSHA) Hazard Communication Standard, 29 CFR Subpart 1910.1200. This Hazard Communication Standard does
not apply to various subcategories including anything defined by OSHA as an "article". OSHA has defined "article" as a
manufactured item other than a fluid or particle; (i) which is formed to a specific shape or design during manufacture;
(ii) which has end use function(s) dependent in whole or in part upon its shape or design during end
use; and (iii) which under normal conditions of use does not release more than very small quantities, e.g. minute or
trace amounts of a hazardous chemical, and does not pose a physical hazard or health risk to employees.
Because all of our batteries are defined as "articles", they are exempted from the requirements of the Hazard
Communication Standard.

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MSDS Code: EBO1905068-M174 Date of Issue: May 20, 2019
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16. Other Information


The above information is based on the data of which we are aware and is believed to be correct as of the data hereof.
Since this information may be applied under conditions beyond our control and with which may be unfamiliar and since
data made available subsequent to the data hereof may suggest modifications of the information, we do not assume any
responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make
his own determination of the suitability of the material for his particular purpose.

USA
B.2.2 MGL28321 Datasheet
[键入文字]

LI-MN battery
Specification
锂猛电池
规格书
Model/型号:IMR10440
Capacity/容量:350mAh
Voltage/电压:3.7V

Prepared By/Date Checked By/Date Approved By/Date

编制/日期 审核/日期 批准/日期

Amendment Records
(修正记录)
Edition Description Prepared by Approved by Date

(版本) (记述) (编制) (批准) (日期)

A First Edition
[键入文字]

1 Scope(使用范围)
This specification is applied to the reference battery in this Specification and manufactured by
Shenzhen Fest Technology Co.,Ltd.
本规格书适用于本书中所提及的深圳费思特科技有限公司制造的电池。
2 Product Specification(产品技术规格)
Table 1(表 1)
No. Item General Parameter Remark
(序号) (项目) (常规参数) (备注)
Typical Standard discharge ( 0.2C )
350mAh
Rated Capacity (标称容量) after standard charge
1
(额定容量) Minimum (标准充电后 0.2C 标准放
320mAh
(最小容量) 电)
2 Nominal Voltage 3.7V Mean Operation Voltage
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(正常电压) (即工作电压)
Voltage at end of Discharge Cut-off Voltage
3 Dischargr 3.0V (放电截止电压)
(放电终止电压)
Charging at end of
4 Voltage 4.20V
(充电最高电压)
Constant Current 0.2C Constant Voltage 4.20V Charge time:Approx 6.0h
Standard charge 0.02C cut-off (充电时间:大约 6 个小时)
5
(标准充电) (持续电流:0.2C 持续电压:4.20V 截止电流:
0.02C)
Standard discharge Constant Current 0.2C end Voltage 3.0V
6
(标准放电) (持续电流:0.2C 截止电压 3.0V)

Continuous the table 1(续表 1)


No. Item General Parameter Remark
(序号) (项目) (常规参数) (备注)
Constant Current 1C Constant Voltage Charge time:Approx
Fast charge 4.20V 0.02C5A cut-off 2.5h
7
(快速充电) (持续电流:1C 持续电压:4.20V 截止 (充电时间:大约 2.5
电流:0.02C) 个小时)
Fast discharge Constant Current 1C end Voltage 3.0V
8
(快速放电) (持续电流:1C 截止电压 3.0V)
Maximum Continuous
9 Charge Current 1C
(最大充电持续电流)
Maximum Continuous
10 Discharge Current 4C 瞬间最大电流 5C
(最大放电持续电流)
11 Operation Temperature Charge(充电):0~45℃ 60±25%R.H. Bare Cell
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Range (单体电池储存湿度范
Discharge(放电)
:-10~60℃
(工作温度范围) 围)
Less than 1 year:-20~25℃
60±25%R.H. at the
Storage Temperature Range (小于 1 年:-20~25℃)
12 shipment state(出货状
(储存温度范围) Less then 3 months:-20~40℃
态时的湿度范围)
(小于 3 个月:-20~40℃)
Weight
13 FYI
(重量)
Height:(h)
Pack Dimension (高度):43.8±0.3mm) Initial Dimension
14
(包装后尺寸) Width:(d) (初始尺寸)
(直径):10.1±0.2mm)

3 Performance And Test Conditions(电池性能及测试条件)


Standard Test Conditions(标准测试条件)
Test should be conducted with new batteries within one week after shipment from our factory and
the cell shall not be cyded more than five times before the test. Unless otherwise specified,test and
measurement shall be done under temperature of 20± 5 ℃ and relative humidity of 45~48%.if it is
judged that the test results are not affected by such conditions,the tests may be conducted at
temperature 15~30℃ and humidity 25-85%R.H.
测试必须使用出厂时间不超过一个星期的新电池,且未进行过 5 次以上的充放电循环。除
非特别说明,否则测试会在温度 20±5℃,相对湿度在 45-85%的条件下进行。如果经鉴定测试
结果不受上述条件影响,测试也可以在温度 15-30℃,相对湿度在 25-85%RH 的条件下进行。
Measuring Instrument or Apparatus(测量器具及设备)
Dimension Measuring Insturment(尺寸测量器具)
The dimension measurement shall be implemented by instruments with equal or more precision scale
of 0.01mm.
尺寸测量器具的精度等级应不小于 0.01mm。
3.2.2 Voltager(伏特计)
Standard class specified in the national standard or more sensitive class having inner impedance
more than 10kΩ/V.
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按照国家标准指定规格等级或采用灵敏度更高的,测量电压时内阻不应小于 10kΩ/V。
Ammeter(安培计)
Standard class specified in the national standard or more sensitive class.Total extermal resistance
including ammeter and wire is less than 0.01Ω.
按照国家标准指定规格等级或采用灵敏度更高的,包括电流表及电线在内的总外阻应小于 0.01
Ω。
Impedance Meter(电阻计)
Impedance shall be measured by a sinusidal alternating current method(1kHz LCR meter)
内阻测试仪测量原理应为交流阻抗法(1kHz LCR)。
Standard Charge/Discharge(标准充放电)
Standard charge:Test procedure and its criteria are referred as follows:
标准充电:测试过程即标准如下:
0.2 C
Charging shall consist of charging at a 0.2 C constant current rate until the cell reaches 4.20V.
The cell shall then be charged at constant voltage 0f 4.20 volts while tapreing the charge current
Charging shall be terminated when the charging current has tapreed to 0.02 C.Charge time:Approx
6.0h,The cell shall demonstrate no permanent degradation when charged between 0℃ and 45℃.
电池先 0.2C 恒流充至 4.20V,当充电电流逐渐减小时,再以 4.20V 恒压充至电流减小到 0.02 C,
充电时间大约为 6 个小时。在 0℃-45℃内,充电电池应没有永久损害。
Standard Discharge(标准放电)
0.2 C
Cells shall be discharged at a constant current of 0.2 C to 3.0 volts @20℃±5℃.
电池以 0.2 C 恒流放电至 3.0V,@20℃±5℃。
If no otherwise specified,the rest time between Charge and Discharge amount to 30min.
如果没有特别说明,电池充放电间隔时间为 30 分钟。

Appearance(外观)
There shall be no sucu defect as flaw,crack,rust,leakage,which may adversely affect commercial
value of battery.
电池外观应没有划痕、破裂、污迹、生锈、漏液等影响市场的缺陷存在。
Initial Performance Test(初始性能测试)
Table 2(表 2)
Item Test Method Condition Requirements
(项目) (测试方法及条件) (要求)
(1) Open-circuit The open-circuit voltage shall be measured within 24 hours
Voltage after standard charge.
(开路电压) (标准充电后 24 小时内测量开路电压)
(2) Intermal Intermal resistance measured at AC 1KHz after 50% charge.
impedance (半充电状态下,测量其 AC 1KHz 下的交流阻抗)
(初始内阻)
(3) Minimal The capacity on 0.2 C discharge till the voltage tapered to
Rated 2.0V shall be measured after rested for 30min then finish
Discharge Capacity(放电容量)
Capacity standard charge.
(最小额定容量) (标准充电后,搁置 30 分钟,测量 0.2 C 放电至 3.0V 截
[键入文字]

止电压所放出的容量)
Temperature Dependence of discharge capacity(放电温度特性)
Cells shall be standard charged and discharged @ 0.2 C to 3.0 volts.Except to be discharged at
temperaures per Table 3. Cells shall be stored for 3 hours at the test temperature prior to discharging and
then shall be discharged at the test temperture.The capacity of a cell at each temperture shall be compared
to the capacity achieved at 23℃ and the percentage shall be calculated.Each cell shall meet or exceed the
requirements of Table 3.
电池按标准充电。按表 3 的温度中放电,电池必须先在该试验温度中放置 3 个小时。在每一个
温度中的放电容量应不小于表 3 的要求。
Table 3(表 3)
Discharge Temperature
-10℃ 0℃ 23℃ 60℃
(放电温度)
Discharge Capacity(0.2 C)
70% 80% 100% 95%
(放电容量/0.2 C)

Cycle Life and Date(循环寿命以及倍率)


Table 4(表 4)
No. Item Criteria Test Conditions
(序号) (项目) (标准) (测试条件)
Carry out 300 cycle
Charging/Discharging in the below condition.
◆ Charge:Standard
◆ Discharge:0.5 Cto 3.0V
◆ Rest Time belween charge/discharge:30min.
Cycle Life Higher than 80% of the Initial
◆ Temperayure:20±5℃
1 (循环寿命) Capacities of the Cells
循环 300 次
(0.5 C) (初始容量的 80%)
充放电按以下条件:
◆ 充电:标准充电,
◆ 放电:0.5C 放至 3.0V
◆ 搁置:30min
◆ 温度:20±5℃
After full charge with standard charge,store at 60
No leakage
Leakage-Proof ±3℃,60±10%RH for 1 month.
2 (visual inspection)
(漏液试验) 标准充电条件下,充满电后在温度 60±3℃,湿
(没有漏液/目测)
度 60±10%RH 下储存一个月
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4.Mechanical characteristies and Safety Test(安全测试及机械特性)


Table5(表 5) (Mechanical characteristies)
No. Item Test Method and Condition Criteria
(序号) (项目) (测试方法及条件) (标准)
After standard charging,fixed the cell to vibration table and subjection cycling
No
that the frequeney is to be varied at the rate of 1Hz per minute between 10Hz
Vibration leakage
an 55Hz,the excursion of the vibration is 1.6mm.The cell shall be vibrated for
1 Test 无泄漏
30minutes per axis of XYZ axes.
振动测试 No fire
将标准充电后的电池固定在振动台上,沿 X、Y、Z 三个方向各振动 30
不起火
分钟,振幅 1.6mm,振动频率为 10Hz~55Hz,每分钟变化 1Hz。
No
The cdll is to be dropped from a height of 1 meter twice conto concrete explosion,
Drop Test
2 ground. No fire,
跌落测试
将标准充电后的电池从 1 米高度跌落至混凝土地面 2 次 无爆炸、
无起火、

Table 6(表 6) (Safety Test)


Item Battery Condition Test Method Requirements
(项目) (电池要求) (测试方法) (要求)
Crush between two flat plates.Applied force is No explosion,No
Crush Fresh,Fully charged about 13kN(1.72Mpa) for 30min. fire
(挤压试验) (充满电的新电池) (电池放置在两块平面金属板间,施加 13KN (无爆炸,无起
(1.72Mpa)的作用力,且持续保持 30 分钟) 火)
Each test sample battery,in turn,is to be No explosion,No
short-circuited by conneting the (+)and (-) fire.The
terminals of the battery with a Cu wire Temperature of
Short Circuit having a maximum resistance load of 0.1Ω. the surface of the
Fresh,Fully charged
(短路试验 Test are to be conducted at room temperature Cells are lower
(充满电的新电池)
20℃) (20℃±2℃). than 150℃
(在常温下约 20±2℃,依次把每个样品电池正 (无起火,无爆炸,
负极用铜线连接起来,是电池外部短路,线路 电池表面温度应
总电阻不超过 0.1Ω) 低于 150℃)
Each test sample battery,in turn,is to be No explosion,No
short-circuited by connecting the (+)and (-) fire.The
terminals of the battery with a Cu wire Temperature of
Short Circuit
Fresh,Fully charged having a maximum resistance load of 0.1Ω. the surface of the
(短路试验
(充满电的新电池) Test are to be conducted at temperature (60 Cells are lower
60℃)
℃±2℃). than 150℃
(在温度约 60±2℃下,依次把每个样品电池正 (无起火,无爆炸,
负极用铜线连接起来,是电池外部短路,线路 电池表面温度应
[键入文字]

总电阻不超过 0.1Ω) 低于 150℃)


A 56mm diameter bar is inlayed into the bottom of
a 10Kg weight.And the weight is to be dropped
from a height of 1m onto a sample battery and
No explosion,No
Impact Fresh,Fully charged then the bar will be across the center of the
fire
(冲击试验) (充满电的新电池) sample.(用一条直径为 56mm 的圆棒放置在电池
(无起火,无爆炸)
中央,将一 10 公斤的重锤从 1 米的高度垂直落
下在电池的中心位置)

Forced No explosion,No
Fresh,Fully charged Discharge at a current of 1 C for 2.5h.
Discharge fire
(充满电的新电池) (以 1 C 的电流放电 2.5 小时)
(过放试验) (无起火,无爆炸)

5.Protection circuit(保护电路)
5.1 PCM Specification(保护板说明)
Item Test Condition
(项目) (测试条件)
The battery should be charged under 4.0V/1C.The charging should be shut off when the internal
Over charge Protection cell voltage becomes more than the specified protection voltage.
(过充电保护) (电池在不大于 4.20V/1C 的情况下充电,当电池电压高于指定保护电压时,充电就会停
止)
Overs discharge The battery should be discharged with 1C,The discharging should be shut off when the internal
Protection cell voltage becomes less than the specified protection voltage.
(过放电保护) (电池在 1C 的电流下放电,当电池电压低于指定保护电压时,放电就会停止)
After rated charge,(+) and (-) terminals are connected with 10mΩ mental resistor
Short protection
or equivalence.
(短路保护)
(额定充电后,用 10mΩ的电阻器连接电池的正负极,电池符合标准要求)
5.2 PCM Standard(保护板标准)
Symbol Name MIN. TYP. MAX. Unit
(符号) (名称) (最小值) (典型值) (最大值) (单位)
Over-Charge detect voltage
Vdet 1 V
(过充保护电压)
Over-discharge detect voltage
Vdet 2 V
(过放保护电压)
Over-current detect voltage
Vdet 3 V
(过流检测电压)
Excess Current threshold
IBC A
(最大过流值)
Internal resistance in normal
RD mΩ
operation
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(导通内阻)

6.Handling of Cells(电池操作注意事项)
Prohibition short circuit(禁止电池短路)
Never marke short circuit cell.It generates very high current which causes heating of the cells and may
cause electrolyte leakage are very dangerous.
The Li-Fe tabs may be easily short-circuited by putting them on conductive surface.
Such outer short circuit may lead to heat generation and damage of the cell.
An appropriate circuitry with PCM shall be employed to protect accidental short circuit of the battery
pack.
避免电池短路。短路会产生很高的电流而使电池发热以及电解液泄漏,产生有毒气体使非常危险
的。极片连接在导电物体表面很容易短路,外部短路会导致发热及损害电池。选用一个适当的保
护电路可以在意外短路时保护电池。
7.Notice for Designing Battery Pack(电池外壳设计注意事项)
7.1 Pack toughness(外壳坚韧度)
Battery pack should have sufficient styength and the Li-Fe cell inside should be protected from
mechanical shocks.
电池外壳应该有足够的机械强度,使铁锂电池免受机械撞击。
7.2 Cell fixing(电池的固定)
The Li-Fe cell should be fixed to the battery pack by its large surface area.
No cell movement in the battery pack should be allowed.
电池最大面积的一面应该固定在外壳上,安装后电池不能有松动。
7.3 Inside design(外壳内部设计)
No sharp edge components should be insides the pack containing the Li-Fe cell.
外壳内安装电池的部位不应有锋锐边。
7.4 Tab connection(极片连接)
Spot welding is recommended for Li-Fe tab connection method.
Battery pack should be designed that shear force are not applied to the Li-Fe tabs.
If apply manual solder met hod to connect tab with PCM.below notice is very important to ensure battery
◆·performance:
◆·The solder iron should be temperature controlled and ESD safe;
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◆·Soldering temperature should not exceed 350℃;


◆·Soldering time should not be longer than 3s;
◆·Soldering times should not exceed 5 times,Keep battery tab cold down before next time soldrictly g;
◆·Directly heat cell body is strictly prohibited,Battery may damaged by heat above approx.100℃.
建议使用点焊焊接方法:外壳设计应考虑使极片不受外力。
如果使用人工焊接保护板,下面的注意事项对于确保电池性能非常重要:
◆·焊接烙铁的温度必须可控且可防静电;
◆·焊接时对烙铁的温度不能超过 350℃;
◆·焊锡时间不能超过 3 秒钟;
◆·焊锡次数不能超过 5 次,待极片冷却后才能进行下一次焊锡;
◆·严禁直接加热电池,高于 100℃会损害电池。
7.5 For mishaps(针对意外事件)
Battery pack should be designed not to generate heat even when leakage occurs due to mishaps.
1)Isolate PCM (Protection Circuit Module) form leaked electrolyte as perfectly as perfectly as possible.
2)Avoid narrow spacing between bare circuit patterns with different voltage.(Including around connector)
3) Li-Fe battery should not have liquid from electrolyte,but in case if leaked electrolyte as possible touch
bare circuit patterns,higher potential terminal material may dissolve and precipitate at the lower potential
terminal,and may cause short circuit,The design of the PCM must have this covered.
发生意外时,外壳设计应考虑即使在电池出线漏液时也不会发热。
1)尽量把保护电路与渗透的电解液隔离开。
2)在不同的电压情况下避免出现小间距的裸露电路—包括插头的周围。
3)锂电池不应该有来自电解液的液体,但是一旦发生电解液渗透触及裸露电路,高电势端接子材料
可能会溶解然后沉淀到低电势端接子,可能会造成短路。保护板的设计须含有覆盖保护层。
8.Notice for Assembling Battery Pack(电池装配注意事项)
Shocks,high temperature,or contacts of sharp edge components should not be allowed in battery pack
assembling process.
在电池装配过程中不允许撞击、高温或接触尖锐部分。
9.Others (其它)
9.1 Cell connection(电池连接)
1)Direct soldering of wire leads or devices to the cell is strictly prohibited.
2) Lead tabs with pre-soldering may cause damage of components,such as separator and insulator.by heat
generation.
1)严禁直接焊接引线或设备到电池上。
2)极片在焊接引线之前应该先点焊到电池上,直接与电池热焊接,产生的热量会使电池的隔离体及
绝缘体受损。
9.2 Prevention of short circuit within a battery pack(电池内部的短路预防)
Enough insulation layers between wiring and the cells shall be used to maintain extra safety protection.
The battery pack shall be structured with no short circuit within the battery pack ,which may cause
generation of smoke or firing.
在电池和引线之间应该有足够的绝缘层用于安全保护。电池的包装构成应没有导致起烟起火的短路情
况。
9.3 Prohibition of disassembly(禁止拆卸)
1)Never disassemble the cells
The disassembling may generate internal short circuit in the cell,which may cause gassing,firing,explosion,or
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other problems.
2) Electrolyte is harmful
Li-Fe battery should not have liquid from electrolyte flowing,but in case the electrolyte come into contace
with the skin,or eyes,physicians shall slush the electrolyte immediately with fresh water and medical advice
is to be sought.
1) 不要拆卸电池。
拆卸电池会发生电池内部短路,会引起起火、爆炸、有害气体或其它问题。
2) 电解液是有害的。
9.4 Prohibition of dumping of cells into fire(不要把电池倾倒于火中)
Never incinerate nor dispose the cells in fire.These may cause explosion of the cells,which is very
dangerous and is prohibition.
不要把电池扔入火中,容易引起爆炸。
9.5 Battery cells replacement(更换电池)
The battery replacement shall be done only by either cells supplier or device supplier and never be done by
the user.
更换电池应由电池生产商或设备供应商完成,用户不用自行更换。
9.6 Prohibition of use of damaged cells(禁止使用损坏的电池)
The cells might be damaged during shipping by shock.If any abnormal features of the cells are found
such as damages in a plastic envelop of the cell,deformation of the cell package,smelling of an electrolyte ,an
electrolyte leakage and others,the cells shall never be used any more.
The cells with a smell of the electrolyte or a leakage shall be placed away from fire to avoid firing or
explosion.
电池可能在出货途中碰撞而受损。如果发现电池有异常,例如包装损坏、包装包裹变形,有电解
液的味道、发现漏液等等,不要再使用这些电池如果有电解液的味道或出现漏液,电池放置应该远离
火源避免起火爆炸。
10.Period of Warranty(保质期)
The period of warranty is half a year from the date of sh ipment.Sanchuan guarantees to give a
replacement in case of cells with defects proven due to manufacturing process instead of the customer abuse
and misuse.
电池的保质期从出货之日算起为半年。如果证明电池的缺陷是在制造过程中形成的而不是由于用
户滥用及错误使用造成,本公司负责退换电池。
11.Storing the Batteries(电池的存放)
The batteries should be stored at room temperature,charged to about 30% to 50% of capacity.
We recommend that batteries be charged about once per half a year to orevent over discharge.
电池应当在温室下存放,应充到 30%至 50%的电量。如长时间储存,建议每半年充一次电,以防
止电池过放电。
12.Other The Chemical Reaction(其它的化学反应)
Because batteries utillize a chemical reaction,battery performance over time even if stored for a long
period of time without being used.In addition,if the various usage conditions such as charge,ambient
temperature,etc.are not maintained within the specified ranges the life expectancy of the battery may be
shortened or the device in which the battery is used may be damaged by electrolyte leakage.if the batteries
cannot maintain a charge for long periods of time,even when they are charged correctly,this may indicate it is
time to change the battery.
由于电池是利用化学反应的原理,所以随时间的增加电池的性能会降低,即使是存放很长一段时
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间而不使用。如果使用条件如充电、放电及周围环境温度等情形不在指定的使用范围内,会缩短电池
的使用寿命,或者会产生漏液导致设备损坏。如果电池长时间不能充电,即使充电方法正确,就要更
换电池了。
13.Note:(注释)
Any other items which are not covered in this specation shall be agreed by both parties.
本说明书包括事项应由双方协议确定。
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Definitions
Definitions of Loads, Loading and General Terms
Term Definition
Breaking Load / The load that induces structural failure in one or more parts of the instrument causing the
Static Failure Load load to part from the release mechanism.
Competent Person An individual who, by way of training and/or experience, is knowledgeable of applicable
standards, is capable of identifying workplace hazards relating to the specific operation,
is designated by the employer, and has authority to take appropriate actions.
Dynamic Load A time varying load resulting from the motion and inertia of connected masses and forcing
functions such as wave action on the vessel. This may include transient and steady state
harmonically alternating loads.
Maximum The maximum in-line load the whole assembly can release whilst guaranteeing safe and
Buoyancy for reliable operation. Note that as the load is released in water this is determined by the
Release / Release maximum up-thrust from the buoyancy.
Loads The maximum in-line load the instrument can withstand and successfully release without
overloading any part of the release mechanism or demanding an unsupportable quantity of
energy from the battery supply (at its specified end point).
Proof Load The load to which the actual unit has been tested in the factory. This load should be
periodically applied to demonstrate the unit is still in a safe condition. This is usually twice
the WLL.
Responsible Body The Responsible Body is the organisation responsible for Health and Safety for lifting
operations at the worksite.
Safe Working Load The maximum load (as determined by a competent person) that an item of lifting
(SWL) equipment may raise, lower or suspend under particular service conditions, e.g. the SWL
can be lower than, but can never exceed the WLL.
Shock Load or A time transient load generally caused by the sudden acceleration (positive or negative) of
Snatch Load the load. Examples are the sudden snatch of a load off the deck or a sudden arrest of a
load falling under gravity.
Static Load An unvarying long term load
Working Load Limit The maximum recommended working load. This is set as a maximum 25% of the
(WLL) Breaking Load and allows for factors such as corrosion, fatigue shock loads, harmonic
loads, manufacturing defects and material defects. Please note this does not account for
extreme offshore service conditions.

Abbreviations
Abbreviation Definition
BIS Battery Information Sheet
°C Degree Centigrade/Celsius
Hz Hertz
kg kilogram
kHz kilo Hertz
Lith-X Ansul Lith-X Class D extinguishing agent was developed for use on lithium fires and will
also extinguish magnesium, sodium, and potassium fires

Definitions 59
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

Abbreviation Definition
mm millimetre
NiMH Nickel Metal Hydride
PCB Printed Circuit Board
ppm parts per million
SDS Safety Datasheet
SWL Safe Working Load
V Volt
WEEE Waste from Electrical and Electronic Equipment Directive 2002/96/EC
WLL Working Load Limit

Definitions 60
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B2

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