4 Reactors
4 Reactors
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Chapter 5. Reactors
All the figures and tables in this material are from the reference below unless specified otherwise.
Reference: Bruce E. Rittmann and Perry L. McCarty, "Environmental Biotechnology: Principles
and Applications", McGraw-Hill, 2001.
Changha Lee
√ Reactors
• Many different types exist for environmental engineering,
generally designed as suspended growth or biofilm reactors
• Basic reactors
• Biofilm reactors
5.1 Reactor Types
5.1.1 Suspended Growth Reactors
√ Batch reactors:
• The simplest suspended-growth reactor
• Biochemical reactions take place without new additions until the reaction is complete.
• Commonly used in laboratory-scale
• Kinetics of contaminant removal is similar to that of an ideal plug-flow reactor.
- If other conditions are the same, a higher S gives a higher rate of reaction.
So a PFR generally produces a higher conversion of S in a given volume than a CSTR.
(advantage of PFR)
- It exceeds the ability to supply sufficient oxygen (high DO demand at the entrance and
low DO demand at the exit) in an aerobic system. Thus the aerators for PFR should be
designed to provide more oxygen in the inlet region. (disadvantage of PFR)
• The CSTR and PFR are idealized models that are difficult to achieve in large scale
biological reactors.
- In actual CSTR, short-circuiting of fluid and stagnant zones may occur because of
incomplete mixing with the bulk of the reactor fluid.
- In PFR, aeration of the fluid causes longitudinal mixing and a distribution of residence
times. Thus, long biological reactors with aeration are often better simulated by an axial
dispersion model or a CSTR in series model.
- Tracer techniques are useful in establishing an appropriate hydraulic model for a biological
reactor.
5.1.1 Suspended Growth Reactors
• This type of flow should be avoided since it always lowers the performance of the unit.
• The problems of non-ideal flow are intimately tied to those of scale-up.
• Often the uncontrolled factor differs widely between large and small units.
Therefore ignoring this factor may lead to gross errors in design.
5.1.3 Reactor Arrangement
√ Reactor arrangements
5.1.3 Reactor Arrangement
5.1.3 Reactor Arrangement
• Reactors in series:
e.g., organic oxidation (1st reactor) nitrification (2nd reactor) denitrification (3rd reactor)
• Reactors in parallel:
- They are used to provide redundancy in the system so that some reactors can be out
of service, while others on a parallel track remain in operation.
- When the total flow to be treated far exceeds the capacity of the largest practical units
available.
- It maintains more of a completely mixed nature, compared to the more plug-flow nature of
reactors in series.
5.2 Mass Balances
√ Reactor design
- The mass balance is defined in terms of rates of mass change in the control volume.
- Each component must have its own mass balance
Components : COD, TOC, biomass, oxygen, electron acceptor, nitrate, ammonium etc.
- In the development of equations useful for a reactor system, mass balances on several different
components of interest and around several different control volumes sometimes are required.
Accumulation : total mass of the component or the reactor volume x the concentration
Mass in / out : mass crossed the control-volume boundaries
Generation : formation of the component of interest within the control volume
If negative, component destroyed rather than being formed
endogenous respiration or predation
If positive, bacteria cells produced through consumption
5.2 Mass Balances
ii) The manner in which mass flows into and out of the control volume,
- bacteria
- limiting substrate: the electron donor
• Assumption
- sufficiently high concentration of all other bacterial requirements such as electron
acceptor and nutrients
dS
V Vrut
dt
If rate of substrate utilization follows Monod kinetics
dS q̂S
qˆS V V( X)
dt K S a
rut Xa
K S
dS qˆS
X
dt K S a
5.3 A Batch Reactor
√ Mass balance for microorganisms
dX a
V V X a
dt
If the organism growth rate follows Monod kinetics,
V ˆ
dX a S
V bX
K S
a
S
dt
1 dX a syn dec ˆ b
X dt K S
ˆ b X
dX a S
K S
a
dt
5.3 A Batch Reactor
√ Initial conditions
X a 0 X a0 S0 S 0
dS q̂S
Xa
dt K S
dX a S
ˆ bXa
dt K S
• In order to solve for Xa and S as functions of time, all above equations should be
considered simultaneously.
• Due to the nonlinear Monod forms, the systems of above equations cannot be solved
analytically. It must be done with a numerical solution.
• If organism decay is considered to be negligible (b =0),
an analytical solution can be obtained. This is reasonable for cases of batch growth
where the organism decay is small while they are growing rapidly.
5.3 A Batch Reactor
• Assumption :
The organism decay is negligible while the microorganisms are growing rapidly.
X a0 X a0 S0 S 0
dS q̂S
Xa
dt K S
dX a S
ˆ X a
dt K S
X a Y S
X a X a0 Y S0 S
5.3 A Batch Reactor
By substitution of Xa of the equation below
dS qˆS
X
dt K S a
dS
dt
q̂S
K S
X a0 Y S 0 S
By integration, subject to the initial conditions,
1 1 SX a0 1
t 0
K
ln X a0 YS 0 YS 0
qˆ X a YS 0 Y
K
X YS 0
ln 0 ln X a0
a S Y
lag period
- The higher the intial concentration of biomass, the lower the substrate utilization time.
- For the lowest initial organism con., a lag period occurs before the onset of significant
substrate utilization.
- The increase of biomass between t=0 and t = t at S=0 is the same in all cases
( = ( Xa – Xa0 ) = Y S0 = 0.6 X 100 = 60 mg/L )
X a X a0 Y S 0 S X a0 0.6(100 0)
5.4 A Continuous-Flow Stirred–Tank Reactor
with Effluent Recycle
𝑄 + 𝑄𝑟 𝑄𝑋𝑎0 + 𝑄𝑟𝑋𝑎𝑟
𝑖 = & 𝑋𝑎𝑖 =
𝑄𝑖 𝑄𝑖
𝑄𝑖 = 𝑄 + 𝑄𝑟
= 𝑄𝑖 𝑖 𝑄𝑖 + 𝑟 =𝑄 +𝑟
Identical to the equation for chemostat without recycle (Chapter 3)
5.5 A Plug-Flow Reactor
• PFR
: the substrate and active-organism concentrations vary over the length of the reactor.
• Mass Balance
- Substrate
- Active microorganisms
5.5 A Plug-Flow Reactor
• At steady-state, influent flow rate (Q), substrate concentration (S) and active organism
concentration (Xa) do not change with time, the left sides of the equations are zero (no
accumulation
=𝑄 𝑄 + +𝑟
= 𝑄𝑋 𝑄𝑋 + 𝑋 +𝑟
= 𝑄𝑋 𝑄𝑋 + 𝑋 +𝑟
u = Q x Δz /ΔV
5.5 A Plug-Flow Reactor
𝑙𝑖𝑚
𝑧→
𝑑
= 𝑞ො 𝑋
𝑑𝑧 𝐾+
If we ignore the
microorganism decay
(b=0), then analytical
solution is possible.
5.5 A Plug-Flow Reactor
- Integration gives
z 1 K 1 K SX a 0 1
{( ) ln{X
0
YS
0
YS} ( ) ln ln X a
0
}
u qˆ X a YS
0 0
Y a
X a YS
0 0
S 0
Y
An expression for the effluent concentration (Se) from the batch reactor is obtained
by letting z = L.
L 1 K 1 K S eXa0 1
{( ) ln{X a
0
YS 0
YS e } ( ) ln ln X a
0
}
u qˆ X a YS
0 0
Y X a YS
0 0
S 0
Y
1 K 1 K S eX 0
{( 0 a 1 ln X 0 }
) ln{X 0
YS 0
YS e } ( ) ln
qˆ X a YS 0 Y a
X a 0 YS 0 S0 Y
a
5.5 A Plug-Flow Reactor
- A PFR has no mixing or short-circuiting of the fluid along the flow direction.
This is impossible to achieve in a real continuous-flow reactor.
- Wall effects slow the fluid near the wall boundaries relative to the velocity near the middle.
- Aeration or mixing to keep the biomass in suspension introduces a large amount of
mixing in all directions.
- If achieving the reaction kinetics represented by the theoretical kinetic equation is of paramount
importance, a batch reactor is a prudent choice, although it presents its own problems:
For example, time is required to fill and empty a batch reactor, time that might otherwise be used
for treatment. In order to minimize downtime (e.g., idle time), a batch reactor can be operated
while it is filling.
5.6 A Plug-Flow Reactor with Effluent Recycle
If no organisms are introduced in PFR, then the system fails to do any treatment.
using effluent recycle, a portion of microorganisms in the effluent is brought
back to the influent stream.
a a a
5.6 A Plug-Flow Reactor with Effluent Recycle
- Solved in the same manner as with the PFR without effluent recycle except that
Q 0 , X 0 and S0 Q i , X i and Si
- Ignoring the organism decay (b=0), we have
Which are similar to the equations below for the PFR without effluent recycle
Xa Xa 0 Y (S 0 S)
z 1 K 1 K SX a 0 1
{( 0 ) ln{X 0
YS 0
Y S} ( ) ln ln X 0
a }
u qˆ X a YS 0
a 0
Y X a YS
0 0 S Y
5.6 A Plug-Flow Reactor with Effluent Recycle
- Recycle ratio R, 𝑄𝑟
𝑅= (1 + 𝑅)
𝑄
𝜃= =
𝑄 𝑄𝑖
𝑄𝑖 =𝑄 + 𝑄𝑟
0 𝑟 0 𝑟 0
+ + +𝑅
Si = 𝑖 = 𝑟 =
+ 1+𝑅
0 𝑟 0 𝑟 0 0 0 0
i 𝑎 + 𝑎 𝑎 + 𝑎 𝑎 +𝑅 𝑎 𝑎 +𝑅( 𝑎 + ( )
Xa = 𝑖 = 𝑟 = =
+ 1+𝑅 1+𝑅
𝜃
1+𝑅
We have a Se as a function of 𝜽
5.6 A Plug-Flow Reactor with Effluent Recycle
√ Se as a function of 𝜽
with different R values
Washout
time
• Washout time:
- A detention time below which the
effluent concentration equals the
influent concentration (S0 = Se = Si),
- In which no treatment takes place
- Similar concept to 𝜽𝒎𝒊𝒏
𝒙 for the CSTR
The disadvantage: the cost of the settler and the recycling system.
• Assumptions
• Mass balance for microorganisms
• Mass balance for substrates
• Solids retention time (SRT)
CSTR
with Settling and Cell Recycling
Applicable Equations : S, Xa
5.7.1 CSTR with Settling and Cell Recycling
√ Assumptions:
• Biodegradation of substrates takes place in the reactor only,
no biological reactions take place in the settling tank, and biomass in the settler
is insignificant.
• No active microorganisms are in the influent to the reactor (Xa0 = 0).
• The substrate is soluble so that it cannot settle down in the settling tank.
5.7.1 CSTR with Settling and Cell Recycling
√ Mass balance
- At steady state,
active biomass in the system 𝑋
𝜃𝑥 = =
remova rate of active biomass 𝑄 𝑋𝑎 + 𝑄 𝑋𝑎
5.7.1 CSTR with Settling and Cell Recycling
- At steady state, mass balance for microorganism
= 𝑄 𝑋𝑎 + 𝑄 𝑋𝑎 + 𝑌 𝑟 𝑏𝑋
𝑄 𝑋𝑎 + 𝑄 𝑋𝑎 𝑌( 𝑟 ) 1 𝑌( 𝑟 )
= 𝑏 = 𝑏
𝑋 𝑋 𝜃𝑥 𝑋
𝑋
𝜃𝑥 =
𝑄 𝑋𝑎 + 𝑄 𝑋𝑎
1 𝑌( 𝑟 ) 𝑞ො 1 + 𝑏𝜃𝑥
= 𝑏=𝑌 𝑏 =𝐾
𝜃𝑥 𝑋 𝐾+ 𝜃𝑥 𝑌𝑞ො 𝑏 1
- This equation is identical to the one developed for the chemostat (CSTR) without settling
and recycle (in Chapter 3)
- So then, what is unique about the CSTR with settling and microorganism recycle?
5.7.1 CSTR with Settling and Cell Recycling
√ What is unique about the CSTR with settling and microorganism recycle?
θx ≠ θ
- Usually, θ x > θ in order to obtain high efficiency of substrate removal
5.7.1 CSTR with Settling and Cell Recycling
- From the previous equation (originally from the mass balance for microorganism),
1 𝑌( 𝑟 ) 𝑌( 𝑟 )
= 𝑏 𝑋 = 𝜃𝑥
𝜃𝑥 𝑋 1 + 𝑏𝜃𝑥
=𝑄 𝑄 +𝑄 +𝑟
𝑄 𝑄 𝑄
𝑟 =
𝑄( ) ( )
𝑟 = =
𝜃
- Substituting rut, 𝑌( 𝑟 ) 𝜃𝑥 𝑌( )
𝑋 = 𝜃𝑥 =
1 + 𝑏𝜃𝑥 𝜃 1 + 𝑏𝜃𝑥
5.7.1 CSTR with Settling and Cell Recycling
√ Solids concentration ratio
𝑌( 𝑟 ) 𝜃𝑥 𝑌( )
𝑋 = 𝜃𝑥 =
1 + 𝑏𝜃𝑥 𝜃 1 + 𝑏𝜃𝑥
𝜃𝑥
: 𝑺𝒐𝒍𝒊𝒅𝒔 𝒄𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒓𝒂𝒕𝒊𝒐
𝜃
- Active biomass concentration in the reactor depends on the ratio of solids retention
time to the hydraulic detention time.
𝜃𝑥
In Chapter 3, for a CSTR without sett ing and recyc e, = 1, so 𝑋 = 𝑌
𝜃 1 + 𝑏𝜃𝑥
√ Mass rate of active biomass production
• At steady state, the mass rate of active biomass production must equal the rate at which the
biomass leaves the system from the effluent stream and the waste stream.
𝑋
𝜃𝑥 = Net rate of cell growth
𝑄 𝑋𝑎 + 𝑄 𝑋𝑎
* rnet Xa
𝑟 𝑏𝑝 = 𝑄 𝑋𝑎 + 𝑄 𝑋𝑎 =
𝑋 = Xa/x
𝜃𝑥
𝑟 𝑏𝑝 ∶ 𝑐 𝑖𝑣 𝑏𝑖𝑜𝑚 𝑠𝑠 𝑝𝑟𝑜𝑑 𝑐 𝑖𝑜 𝑟 (𝑀/𝑇)
5.7.1 CSTR with Settling and Cell Recycling
√ Table 5.2
• Summary of a series of equations to design a CSTR with settling and recycle
• Assumptions for Table 5.2
- Operating at steady state
- Treating a soluble substrate
- No input of active biomass
• The equations in Table 5.2 can be used for a CSTR without a settler by letting θx = θ
5.7.1 CSTR with Settling and Cell Recycling
√ Table 5.2
5.7.1 CSTR with Settling and Cell Recycling
√ Table 5.2
5.7.1 CSTR with Settling and Cell Recycling
- At a constant SRT, the effluent concentration (S) remains independent on the
influent concentration (S0). Only θx affects S because all other parameters in the
equations are coefficients.
1 + 𝑏𝜃𝑥
=𝐾
𝜃𝑥 𝑌𝑞ො 𝑏 1
Why?
2) The organisms’ growth rate and SRT are equal to the inverse of each other.
𝑐 𝑖𝑣 𝑏𝑖𝑜𝑚 𝑠𝑠 𝑖 ℎ 𝑠𝑦𝑠 𝑚 1
𝑞ො
𝜃𝑥 = =𝜇 𝜇=𝑌 𝑏
𝑝𝑟𝑜𝑑 𝑐 𝑖𝑜 𝑟 𝑜𝑓 𝑐 𝑖𝑣 𝑏𝑖𝑜𝑚 𝑠𝑠 𝐾+
Constant SRT (θx) → Constant specific growth rate (μ) → Constant substrate (S)
5.10 Engineering Design of Reactors
𝜃𝑥𝑑 ∶ 𝑑 𝑠𝑖𝑔 𝜃𝑥
- High Rate: Highly skilled operator or the removal efficiency and high reliability is not as critical.