Organic Lecture

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LECTURE: ORGANIC - Is the study of molecules containing he

CHEMISTRY: carbon-hydrogen (C-H) bond and their


CARBON CHEMISTRY reactions.

What organic chemists do?


NH3 or ammonium hydroxide - Usually conduct research and
- Colorless, highly pungent gas development in a laboratory setting.
- Would include the development of a
Graphite and clay better painkilling drug, formulating a
- pencil lead made of other than pb. shampoo that would result in silkier
hair, making a stain resistant carpet, of
Why is it that the human body is called a finding a non-toxic insect repellant.
complex machine? - Common household chemicals, foods,
- Your body is an incredibly complex plastics, drugs, fuels…
chemical machine taking in chemicals
and food, causing countless reactions Why organic chemistry important?
to occur every second. - It is the study of life and all of the
chemical reactions related to life.
Your body is made up of: - Several careers apply an understanding
- 25 elements make up living things of organic chemistry, such as doctors,
- 97% of the body is made of: veterinarians, dentists, pharmacologist,
oxygen, carbon, hydrogen, nitrogen chemical engineer, and chemists.
- The two main elements are
Phosphorous and sulfur Importance of organic chemistry:
1. Medicine:
Elements in our body - Is the prime storage of organic
- 0.004% iron compounds.
- 53% carbon - Organic chemistry can be studied in
three parts in medicine as:
Major compounds a. Drugs to cure disease
- The human body relies on water and b. Pathophysiology of the diseases
salt. 60-65% or 2/3 of our body c. To diagnose the disease
consists of water. - Organic chemistry in diagnosis aims to
check for the organic functional group
Carbon compounds levels as a parameter of the disturbed
- Also known as organic compound substance in the body.
- Carbon is important in all living things
because of its ability to bond
- Example of forms of carbon that are
not living things are diamond, graphite, 2. Food:
and charcoal - Food materials are solely made of
- Non-organic compounds, and carbon compounds carbohydrates
compounds without carbon are called (CHO), proteins (NH2-CH-COOH),
inorganic compounds. and fats (CH-COO-CH)
- Even vitamins are organic in nature.
What is organic chemistry? - Among beverages, alcohol is inorganic
- Chemistry of living things substance.
- The chemistry of compound
- Is the study of carbon and the
chemistry of life.
3. Cleansing Agents: 5. Explosives
- In industries and labs, organic solvents - Nitroglycerine, nitrocellulose, T.N.B,
are widely used to clear of impurities. T.N.T, etc.

4. Sterilizing Agents: 6. Dyes


5. Analytical Substances - Indigo, malachite green, alizarin etc
6. Valuables
7. Insecticides
Applications of organic chemistry - D.D.T, gammaxene, malathion, etc

1. For analysis 8. Household and other common articles


- Not all organic substances are soluble - Soaps, cosmetics, perfumes,
in water. So, they analyze by non- detergents, paper, rubber, plastics,
aqueous titration. For this they use leather, etc
organic solvent like pyridine,
methanol, acetone etc. Why is life-based on the element
carbon?
2. For synthesis
- Organic chemistry helps us synthesis 1. Carbon atoms can link together to form
many compounds which are needed on stable chains of great length
a large scale. 2. Carbon atoms bind strongly to each
other and form very large molecules
3. For better molecules which are built around this carbon
- If a molecule has already been used for backbone.
a long time, It can be replaced by
similar molecule with slight change in Monomers
its chemistry. This change is aimed at - Simple sub-units are linked together by
more effective performance. condensation reactions.

Importance role of organic chemistry in


human life

1. Food What makes carbon so special?


- Carbohydrates, proteins, fats, vitamins
enzymes, etc. • It has a central role in all living
2. Clothes organisms.
- Cotton, silk, wool, nylon, rayon, • It has 4 valence electrons
dacron, etc. • It makes 4 covalent bonds
• It can bond with any element
3. Fuels • Loves to bond with other atoms and
- Coal, wood, natural gas, petrol, etc. make long chains
4. Medicines 3 Types of Carbon Bonds
- Penicillin, streptomycin,
chloromycetin, sulphadiazine, 1. Single bond
morphine, aspirin, iodoform, cocaine, 2. Double bond
etc. 3. Triple bond
3 Types of Carbon Backbones Why are there no life forms based on
silicon? Silicon is similar to carbon
1. Straight chain
- Carbon atoms are connected one after Silicon is unsuitable because, although it is
another. a valence IV element like carbon (4
2. Branched-chain electrons to share), BUT the silicon-silicon
- The chain of carbon atoms branches covalent bond is not strong enough for it to
when a carbon atom bonds to more form long stable chains.
than two other carbon atoms.
So, it cannot form molecules of the
3. Ring complexity needed to make up cells like
- The chain of carbon atoms forms a carbon can!
ring.
Why are there no life forms based on
Carbon forms long chains silicon?

• One carbon chain may contain • Reactions of Silicon are much slower
hundreds of carbon atoms. than reactions of Carbon.
• Unlike other elements, carbon atoms
can bond to each other to form very • Bonds between Si and Si or between Si
long chains. and H are not as stable as the bond
between Si and O.
• One carbon chain may contain
hundreds of carbon atoms. Notice how
• Molecules based on Si and H are not
the CH2 units repeat.
very stable in the presence of water.
• A very large carbon-based molecule • Silicone is a substance that comes in
made of repeating units is called a liquid, gel, or rubber-like form. It is
polymer. Each unit of a polymer is used in breast implants during
called a monomer. Polymers can be augmentation or reconstructive surgery.
thousands of atoms long.
• Solid silicone (dimethyl siloxane)
implants have been using in facial
Carbon forms Rings
cosmetic surgery since the 1950's.
Unlike liquid-filled silicone breast
• Carbon-based molecules also can be implants, solid silicone implants do not
shaped like rings. Most carbon rings leach into the body and have been used
contain 5 or 6 carbon atoms. for many years in medical procedures
• One of the most important carbon rings such as joint prostheses and heart valve
is benzene. replacement.
• It has 6 carbons & 6 hydrogens, with
alternating double bonds.
• Many compounds are based on
Benzene.
• They often have very strong smells or
aromas, so they are called aromatic
compounds.
• An example of one aromatic
compound is a molecule called
vanillin.

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