FS3 Module 1
FS3 Module 1
FS3 Module 1
FORENSIC
CHEMISTRY
AND
TOXICOLOGY
COURSE OVERVIEW
Welcome to CICOSAT COLLEGES for the first Semester, AY 2023-2024. You are
enrolled in the course, Forensic 3- Forensic Chemistry and Toxicology-Lecture and Laboratory.
This is a 5-unit course (3 units for the lecture and 2 units for the laboratory) in the College of
Criminal Justice Education program that will guide you in the investigation processes.
In order to widen your knowledge in Forensic Chemistry and Toxicology, theories are
expanded and explained in details. Experiments are provided that are useful and intended to
serve as your guide. It will introduce you to the fruitful device in the field of Forensic Science. It
aims to acquaint you on the importance of chemical test of compounds and the use of
instruments which are the basic tools in conducting investigation necessary in solving crimes and
resolving legal issues and case report writing.
This course enables you to complete the experimentation process step by step. Thus, your
active participation is important. Learn how to become resourceful and creative. Try to find other
alternatives in order to accomplish the process.
After completion of the course, you will be able to demonstrate the following: 1) an in-depth
knowledge and understanding of the stages in the practice of Forensic Chemistry; 2) the value of
Forensic Chemistry and Toxicology in criminal investigation and detection; 3} theories and
concepts that serve as framework of the study; 4) scope and procedures in Forensic Chemistry
and Toxicology analysis; and 5) equipment used in the examination of Forensic and Toxicology
Analysis.
To ensure that you will successfully demonstrate all the desired competencies, the course
is given in four modules. Each module is divided into lesson topics and activities. Assessment
Tasks are given for you to better understand the concept and apply these in specific situations.
The Modules are as follows:
MODULE 1: The Nature and Scope of Forensic Chemistry and Toxicology- This
module will enable you to learn a brief introduction of Forensic Chemistry and Toxicology. You
will be able to know the simple definition, how it plays a very important role in the speedy
investigation and in the administration of justice. It includes roles of a Forensic Chemist.The Six
Golden Rules in the Practice of Forensic Chemistry are also discussed. Different units on the
crime laboratory are also discussed one by one, the different Forensic Laboratories in the
Philippines, physical evidence, chain of custody and dangerous drugs.
MODULE 2. Chemistry Cases- In this module Drug Analysis, Explosives and
procedures of paraffin testing is studies. Gunshot residue is also discussed.
MODULE 3. Toxicology and Evidence- This module focuses on the explaining
toxicology, poisons and biological and physical evidence
MODULE 4. Instrumentation and Legal Aspect-This module centers on the different
forensic instrumentation and their uses and how to write a case report.
1. Schedule your study time such that you accomplish the activities on the scheduled date of
submission.
2. Illustrative examples are provided for you to serve as your guide in working on the activities.
3. If you cannot fully understand the concepts and procedures, engage all other possible
resources available. There are video tutorials on YouTube that can help you further understand
the concepts.
4. In case these resources still cannot help, do not hesitate to contact me through SMS at
09105231935 or through email address at rhikaannarabe@gmail.com or via Facebook Messenger
(Group Chat) created for the class.
5. The Major Examinations schedule are posted and therefore you can study
beforehand.
MODULE 1
INTRODUCTION
This module will enable you to learn a brief introduction of Forensic Chemistry and
Toxicology. You will be able to know the simple definition, how it plays a very important role in
the speedy investigation and in the administration of justice. It includes roles of a Forensic
Chemist.The Six Golden Rules in the Practice of Forensic Chemistry are also discussed.
Different units on the crime laboratory are also discussed one by one, the different Forensic
Laboratories in the Philippines, physical evidence, chain of custody and dangerous drugs.
forensic chemistry and toxicology [ARABE, RA E.] |
“If the law has made you a witness remain a man of science. You have no victim to
avenge, no guilty or innocent person to ruin or save. You must bear witness in the limits of
science”
LESSON 1
INTRODUCTION TO FORENSIC CHEMISTRY AND TOXICOLOGY
Forensic Chemistry is defined as that branch of Chemistry which deals with application of
chemical principles in the solution of crimes. Like the other forensic sciences, Forensic
Chemistry plays a very important part in the speedy investigation and in the administration of
justice.
Forensic Science is the marriage of science and law. Forensic professionals use their scientific
backgrounds to help law enforcement personnel solve problems.
Forensic Toxicology deals with examination of human internal organs, food samples and water
and gastric contents for the purpose of detecting the presence of poisonous substance, its dosage,
effects, and treatment.
HISTORY OF FORENSIC CHEMISTRY AND TOXICOLOGY
Democritus-was probably the first chemist to study poisons, he communicated some of
his findings to Hippocrates.
(1836) James Marsh- he was the first to use toxicology (arsenic detection) in a jury or
trial.
(1851) Jean Servais Stas- a chemist professor from Brussels, Belgium, was the first to
successfully identify vegetable poison in body tissue.
(1910) Edmund Locard-professor of forensic medicine at the University of Lyons,
France, established the first police crime laboratory.
Locard’s Exchange Principle: “Every contact leaves a trace”
(1960) Lucas- He described the application of gas chromatography to the identification
of petroleum products in the forensic laboratory and discussed potential limitations in the
brand of gasoline.
(1976) Zoro and Hadley- First evaluated the gas chromatography- mass spectrometry
LESSON 2
PHYSICAL EVIDENCE AND CHAIN OF CUSTODY
Physical evidence cannot be intimidated. It does not forget. It sits there and waits to be
detected, preserved, evaluated, and explained.
Herbert Leon Macdonell
PHYSICAL EVIDENCE- Refer to any material that would be present at a crime scene,
on the victims, or found in a suspect’s possession. It is also called real evidence-any kind
of object associated with the investigation, but it must be a tangible item
TRACE EVIDENCE- Refers to any material that is found in small but measurable
amounts, such as strands of hair, fibers, or skin cells.
IMPLICATIONS OF PROPER EVIDENCE PROCESSING TO FORENSIC
EXAMINATION:
1. To obtain the maximum information upon which scientific examination shall be based.
2. Unaltered, unspoiled, or unchanged specimens in the course of handling would provide
more and better scientific information upon examination.
WHEN IS THE COLLECTION OF EVIDENCE ACCOMPLISHED?
After the search is completed, the rough sketch finished and photographs taken-
GOLDEN RULE IN INVESTIGATION
CHAIN OF CUSTODY
The movement and location of physical evidence from the time it is obtained
until the time it is presented in court.
The chronological documentation or paper trail, showing the seizure, custody,
control, transfer, analysis, and disposition of evidence, physical or electronic.
BIOLOGICAL EVIDENCE
1. BLOOD
A. Liquid Blood Samples
2. Do not dry the blood-stained materials directly under the sunlight; electric fan.
3. Separately place in a paper bag.
4. Bring along with the stained material unstained portion to serve as control in
the analysis.
B. Dried Blood Stains
1. On clothing - wrap the items in clean paper, place in a brown paper bag or box; seal
and label container.
2. On small solid objects - send the whole stained object to the laboratory.
3. On large solid objects - cover the stained area with clean paper; seal the edges down
with tape.
4. For immovable or large objects - scrape stain onto a clean piece of paper; fold,
and place in an envelope. Get also unstained portion as control.
DRUGGIST FOLD
5
5. Do not scrape dried blood stain directly into evidence envelope. Scrape using a freshly
washed and dried knife or similar tool.
How to do a Paper Bindle
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B. Dried Blood Stains
6. Do not mix dried stain. Place each in a separate envelope.
7. Never attempt to wipe dried stain from an object using a moistened cloth or paper
2. Seminal Stains
a. On clothing, blankets and sheet - air dry.
b. Wrap in paper and package in paper bags.
c. Do not use plastic bags
3. Hair Strands
a. Have the person bend over a large clean paper, rubbing or massaging their hands through
the hair so loose hair will fall.
8.Blood samples in liquid form must be stored frozen or placed in an ice pack.
DON’T’S
1. DNA test is very sensitive and vulnerable to contamination by other DNA sources. Avoid
contamination with other human DNA.
2. Do not handle samples with bare hands.
6. Avoid drying of wet stained garments under direct sunlight or exposing it to an electric fan.
7. Do not collect a wet garment or garment with a wet bloodstain in a sealed
air-tight container.
8. Do not use plastic bag in the collection of blood specimen.
If the amount of DNA specimen to be collected is too small, focus on the tip of the cotton.
Also swab the immediate surrounding of the specimen to serve as control. This will
determine whether there is background contamination.
5.Glass Fractures/Fragments
a. Shoes, clothing other objects. Wrap in paper.
b. In a hit-and-run scene. The search should not be limited to the point of impact.
c. Glass from different
Locations - keep in different containers.
d. Small glass fragments – place in paper packet, then in pill boxes or film cans.
forensic chemistry and toxicology [ARABE, RA E.] |
e. Large glass fragments – place in boxes. Separate individual pieces with cotton or tissue to
prevent breakage of damaged edges. Seal and mark the box containing them.
6.Fibers
a. Large threads or fibers - pick up with the fingers, place in a paper packet and then
place in another paper envelope.
b. Never place loose fibers directly into a mailing envelope. They can be lost.
- mark at the back portions of the lifting tapes. (date, time, place of collection, case
no., name, signature of collecting officer and of at least two witnesses.
e. Standard fingerprints –
Complete ridge detail should be clearly, neatly recorded. Don’t use stamp pad and other
ordinary ink.
f. Containers of specimen may conceal fingerprints so dusting them is a must.
8.Paint
a. Paint on the garment (hit-and-run victim) - mark garment and carefully wrap by
rolling it in paper.
b. Obtain samples from all areas showing fresh damage on suspected vehicles. The paint
may be different in type or composition.
c. Flake-off or otherwise scrape or chip the paint off, using a clean knife blade
Carefully wipe the blade before collecting each sample. Collect all layers down to the
metal.
d. Place each sample in a separate container.
e. In hit and run cases, flake off chips or scrape paint from the vehicle, including
transferred paint.
f. Keep each specimen separately. Do not place samples directly into envelope - place
into paper packet/pill box first.
9.Arson Evidence
a. Collect materials from the lower layer with apparent traces of gasoline/other
incendiary.
Pack materials collected from separate areas in separate containers.
Best container for arson evidence is clean tin can with cover.
References:
Diangson, R.G. (2020) Special Crime Investigation with Legal Medicine
Revised Crime Laboratory SOCO Manual, Revised 2014.
Salangad, M.M. (2012) Crime Scene Investigation 1st Edition
Galero-Muftuoglu, E. (2015). Fundamentals of Criminal Investigation.
Amador Q.A. & Eeazar, S.B. (2022), Specialized Crime Investigation with Simulation on
Interrogation and Interview
Crime Scene Examiners Notes, The National Training Center for Scientific Support to Crime
Investigation 1992
Philippine National Police Criminal Investigation Manual, Revised 2010.
Field Manual on Investigation of Crimes of Violence and Other Crimes (2011)
(n) Drug Syndicate - Any organized group of two (2) or more persons forming or joining
together with the intention of committing any offense prescribed under this Act.
CONTENTS OF SHABU
Ephedrine - (Classified as Dangerous Drugs) Main ingredient of Shabu causing brain
damage
Toluene – Chemical used for paints, adhesives, etc.
Acetone – Nail cleaner
Lithium Batteries – Cancer causing component
Battery Acid – Corrosive chemical
Drain Cleaner – Liquid Soap
Hydrochloric Acid – (Muriatic Acid)
Chloroform – Cancer causing solvent.
Meth Bugs/ Sore
The sores on the body from obsessively picking at the skin.
2) DEPRESSANTS
also called as “downers” or “barbs”
any drug or chemical that decreases the activity of any bodily function. The
term is most often used to refer to drugs that reduce the activity of the central
nervous system
Ex: Sedatives, Sleeping Pills, Tranquilizers
Side Effects and Long-Term Effects:
Loss of body control may result to bone fractures
Impaired blood pressure regulation and balance control
Cognitive impairment, memory loss and pseudo-dementia
Nocturnal urinary incontinence
Worsening sleep
Respiratory problems
Dependency
Over sedation may lead to death
SLEEPING PILLS
BENZODIAZEPINES – commonly known as tranquilizers and sleeping pills. They
are classified as short, medium and long acting. This relates to the length of the drug
CT SCAN