Date Printed: 18/08/2015 Product: 1000A1NL

Safety Data Sheet

prepared to UN GHS Revision 3

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 1000A1NL

Product Name: CARBOGUARD 893 SG PART A Revision Date: 08/18/2015

Supercedes Date: 05/30/2015
Component of multicomponent
1.2 Relevant identified uses of the industrial coatings - Industrial
substance or mixture and uses use.
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Company

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Burst, Chris - ehs@stoncor.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Hazardous to the aquatic environment, Chronic, category 2

Carcinogenicity, category 1A
Eye Irritation, category 2
Flammable Liquid, category 3
STOT, single exposure, category 1
Skin Irritation, category 2
Skin Sensitizer, category 1

Page 1 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

MICROCRYSTALLINE SILICA, EPOXY RESIN

GHS HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Irritation, category 2 H315 Causes skin irritation.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Carcinogenicity, category 1A H350-1A May cause cancer.
STOT, single exposure, category 1 H370 Causes damage to organs.
Hazardous to the aquatic environment, H411 Toxic to aquatic life with long lasting effects.
Chronic, category 2
GHS PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P307+311 IF exposed, call a POISON CENTER or doctor/physician.
P308+313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
Not applicable

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures

Page 2 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

Hazardous Ingredients
CAS-No. Chemical Name %
14808-60-7 MICROCRYSTALLINE SILICA 25-50
13463-67-7 TITANIUM DIOXIDE 25-50
25036-25-3 EPOXY RESIN 10-25
25068-38-6 EPOXY RESIN 10-25
108-38-3 META-XYLENE 2.5-10
106-42-3 PARA-XYLENE 2.5-10
7779-90-0 ZINC PHOSPHATE 2.5-10
1333-86-4 CARBON BLACK 2.5-10
100-41-4 ETHYL BENZENE 2.5-10
108-65-6 1-METHOXY-2-PROPANOL ACETATE 2.5-10
95-47-6 ORTHO-XYLENE 2.5-10
13517-08-3 BARIUM PHOSPHATE 0.1-1.0
1317-65-3 LIMESTONE <0.1

CAS-No. GHS Symbols GHS Hazard Statements M-Factors

14808-60-7 GHS08 H350-370 0
13463-67-7 0
25036-25-3 GHS07 H315-317-319 0
25068-38-6 GHS07-GHS09 H315-317-319-335-411 0
108-38-3 GHS02-GHS07 H226-312-315-332 0
106-42-3 GHS02-GHS07-GHS08 H226-312-315-332-335-371 0
7779-90-0 GHS09 H332-400-410 0
1333-86-4 GHS08 H351 0
100-41-4 GHS02-GHS07 H225-332 0
108-65-6 GHS02 H226 0
95-47-6 GHS02-GHS07 H226-312-315-332 0
13517-08-3 0
1317-65-3 GHS07 H315-319 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open

Page 3 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
For personal protection see section 8. Ensure adequate ventilation. Ensure adequate ventilation. Evacuate personnel to safe
areas. Evacuate personnel to safe areas. Remove all sources of ignition. Remove all sources of ignition. To avoid ignition of
vapours by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective
equipment.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
transfer to a container for disposal according to local / national regulations (see section 13). Contain spillage, soak up with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal
according to local / national regulations (see section 13).
6.4 Reference to other sections

Please refer to disposal requirements or country specific disposal requirements for this material. See Section 13 for further
information.

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal
protection.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.
STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

Page 4 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- OEL Note
TWA STEL TWA CEILING
MICROCRYSTALLINE SILICA 25-50 0.025 MG/M3 N/E 0.1 MG/M3 N/E
(respirable) (respirable)
TITANIUM DIOXIDE 25-50 10 MGM3 N/E 10 MGM3 N/E
EPOXY RESIN 10-25 N/E N/E N/E N/E
EPOXY RESIN 10-25 N/E N/E N/E N/E
META-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E
PARA-XYLENE 2.5-10 100 PPM 150 PPM 435 MGM3 N/E
ZINC PHOSPHATE 2.5-10 10 mg/m3 10 mg/m3 N/E N/E
CARBON BLACK 2.5-10 3.0 MG/M3 N/E 3.5 MG/M3 N/E
ETHYL BENZENE 2.5-10 20 PPM N/E 435 MGM3 N/E
1-METHOXY-2-PROPANOL ACETATE 2.5-10 N/E N/E N/E N/E
ORTHO-XYLENE 2.5-10 100 PPM 150 PPM 435 MG/M3 N/E
BARIUM PHOSPHATE 0.1-1.0 N/E N/E N/E N/E
LIMESTONE <0.1 N/E N/E 5 MGM3 N/E

FURTHER INFORMATION: Refer to the regulatory exposure limits for the workforce enforced in each country.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier.
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
Lightweight protective clothing
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Viscous Liquid, Various Colors

Physical State Liquid

Odor Solvent

Odor threshold N/D

pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 149 F (65 C) - 500 F (260 C)
Flash Point, (°C) 24

Page 5 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

Evaporation rate Slower than Ether

Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 0.9 - 13.1

limits
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 336

Specific Gravity (g/cm3) app. 1.47

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

Page 6 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Unknown

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

14808-60-7 MICROCRYSTALLINE SILICA Not Available Not Available

13463-67-7 TITANIUM DIOXIDE 25000 mg/m3, oral (rat) Not Available

>2000 mg/kg, dermal,

25036-25-3 EPOXY RESIN >2000 mg/kg, oral, rat Not Available
rat
23000 mg/kg, dermal,
25068-38-6 EPOXY RESIN 11400 mg/kg, rat, oral >20 mL/kg skin, sensitizer
rabbit

108-38-3 META-XYLENE Not Available Not Available

106-42-3 PARA-XYLENE Not Available Not Available

7779-90-0 ZINC PHOSPHATE 3846mg/kg, oral rat Not Available 11.54 mg/L, inh

1333-86-4 CARBON BLACK 8000 mg/kg oral, rat Not Available

>5000 mg/l, dermal

100-41-4 ETHYL BENZENE 3500 mg/kg rat, oral 17.2 mg/L Inh, Rat, 4Hr
rabbit

108-65-6 1-METHOXY-2-PROPANOL ACETATE 8532 mg/kg, oral (rat) >5000 mg/kg 101 ppm/4 hr, rat, inh

95-47-6 ORTHO-XYLENE Not Available Not Available

1317-65-3 LIMESTONE 6450 mg/kg, oral, rat Not Available

Additional Information:
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.

Page 7 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

12. Ecological Information

12.1 Toxicity:

EC50 48hr (Daphnia): Unknown

IC50 72hr (Algae): Unknown

LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

14808-60-7 MICROCRYSTALLINE SILICA No information No information No information

13463-67-7 TITANIUM DIOXIDE No information No information No information
25036-25-3 EPOXY RESIN No information No information No information
25068-38-6 EPOXY RESIN 2.1 mg/l (daphnia) 11 mg/l (algae) 1.3 mg/l (fish)
108-38-3 META-XYLENE No information No information No information
106-42-3 PARA-XYLENE No information No information No information
0.136 - 0.150 mg/l
0.04 - 0.86 mg/l 0.14 - 0.26 mg/l (Rainbow
7779-90-0 ZINC PHOSPHATE (Daphnia Magna)
(Selenastrum
Trout)
capricornutum)
1333-86-4 CARBON BLACK No information No information No information
100-41-4 ETHYL BENZENE No information No information No information
108-65-6 1-METHOXY-2-PROPANOL ACETATE No information No information No information
95-47-6 ORTHO-XYLENE No information No information No information
13517-08-3 BARIUM PHOSPHATE No information No information No information
1317-65-3 LIMESTONE No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

Page 8 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A
14.4 Packing group III
14.5 Environmental hazards Marine Pollutant: Yes (Epoxy Resin)
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
META-XYLENE 108-38-3
PARA-XYLENE 106-42-3
ZINC PHOSPHATE 7779-90-0
ETHYL BENZENE 100-41-4
ORTHO-XYLENE 95-47-6
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name CAS-No.
No TSCA 12(b) components exist in this product.
U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS-No.

No NJ Right-To-Know components exist in this
product.

Page 9 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

Pennsylvania Right-To-Know
The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

IRON OXIDE 1309-37-1
COLOR PIGMENT 5567-15-7
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.

MICROCRYSTALLINE SILICA 14808-60-7
TITANIUM DIOXIDE 13463-67-7
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4
FORMALDEHYDE 50-00-0
METHYL ISOBUTYL KETONE 108-10-1
BENZENE 71-43-2
CUMENE 98-82-8
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other
reproductive hazards.
Chemical Name CAS-No.
TOLUENE 108-88-3
METHYL ALCOHOL 67-56-1
METHYL ISOBUTYL KETONE 108-10-1
BENZENE 71-43-2

International Regulations: As follows -

* Canadian DSL:

No Information

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H351 Suspected of causing cancer.
H370 Causes damage to organs.
H371 May cause damage to organs.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Reasons for revision

No Information

Page 10 / 11
Date Printed: 18/08/2015 Product: 1000A1NL

No Information

Page 11 / 11