Pervade 10ec Sds

Download as pdf or txt
Download as pdf or txt
You are on page 1of 4

SAFETY DATA SHEET

PRODUCT : PERVADE 10EC


EFFECTIVE DATE : June 2018
REVISION NO : 3
PAGE : 1 of 4

SECTION 1 – IDENTIFICATION OF THE


MATERIAL AND SUPPLIER

NOVA AGRO (HK) LTD.


Rooms 1101A – 4 Mass Mutual Tower/
China Evergrande Centre
38 Gloucester Rd GHS Signal word: WARNING
HONG KONG. Hazard statements
H302 Harmful if swallowed.
Trade Name PERVADE 10EC H317 May cause an allergic skin reaction.
Common Name Permethrin H319 Causes serious eye irritation.
Chemical Name 3-phenoxybenzyl(1RS)-cis,trans-3- H335 May cause respiratory irritation.
(2,2-dichlorovinyl)-2,2-dimethyl- H410 Very toxic to aquatic life with long
cyclopropanecarboxylate lasting effects.
CAS No. 52645-53-1 EUH401 To avoid risks to human health and
Chemical Family Synthetic Pyrethroid the environment, comply with the
Chemical Formula C21H20Cl2O3 instructions for use.
Use Non-systemic insecticide for Precautionary statements
household use against flies and P280 Wear protective gloves/protective
mosquitoes. clothing/eye protection/face
protection.
SECTION 2 – HAZARDS IDENTIFICATION P308 + P311 IF exposed or concerned: Call a
POISON CENTER/ doctor/
physician.
Statement of Hazardous Nature P501 Dispose of contents/container to a
Toxicity class: WHO IV; Unlikely to present acute
licensed hazardous-waste disposal
hazard in normal use.
contractor or collection site except
Likely routes of exposure: Skin and eye contact, ingestion and
for empty clean containers which
inhalation.
can be disposed of as nonhazardous
Ingestion: Toxic by ingestion.
waste.
Inhalation: Toxic by inhalation.
Skin contact: Moderately irritating.
Eye contact: Very irritating. SECTION 3 - COMPOSITION / INFORMATION
Risk Phrases: R24, R52 ON INGREDIENTS
R20/22 Harmful by inhalation and if
swallowed. Hazardous components: Permethrin 52645-53-1 100g/litre
R50 Very toxic to aquatic organisms.
R57 Toxic to Bees. SECTION 4 - FIRST AID MEASURES
Safety phrases:
S2 Keep out of reach of children. General Information:
S13 Keep away from food, drink and Acute exposure effects in humans include the following: ataxia,
animal foodstuffs. convulsions leading to muscle fibrillation and paralysis,
S28 After contact with skin, wash dermatitis, edema, diarrhea, dyspnea, headache, hepatic
immediately with plenty of water microsomal enzyme induction, irritability, peripheral vascular
and non-abrasive soap. collapse, rhinorrhea, serum alkaline phosphatase elevation,
S36/37/39 Wear protective clothing, gloves and tinnitus, tremors, vomiting and death due to respiratory failure.
eye/face protection Allergic reactions have included the following effects:
UN Number 3082. Environmentally hazardous anaphylaxis, bronchospasm, eosinophilia, fever, hyper-
substance, Liquid, N.O.S. sensitivity pneumonia, pallor, pollinosis, sweating, sudden
swelling of the face, eyelids, lips and mucous membranes, and
SAFETY DATA SHEET
PRODUCT : PERVADE 10EC
EFFECTIVE DATE : June 2018
REVISION NO : 3
PAGE : 2 of 4

tachycardia. Studies have shown many cases of dermal vapours. Keep upwind.
deltamethrin poisoning after agricultural use with inadequate Personal protective equipment:
handling precautions, and many cases of accidental or suicidal Wear full protective clothing and single or double cartridge
poisoning by the oral route at doses estimated to be 2 -250 respirators.
mg/kg. Oral ingestion caused epigastric pain, nausea, vomiting
and coarse muscular fasciculations. With doses of 100 -250
mg/kg, coma was caused within 15 -20 minutes. SECTION 6 - ACCIDENTAL RELEASE
Inhalation: MEASURES (SPILLAGE)
Remove source of contamination or move victim to fresh air.
Keep affected person warm and at rest. Supply oxygen if Personal precautions:
necessary. Treat symptomatically and supportively. Seek Do not inhale fumes. Ventilate area of spill or leak, especially
medical advice immediately. confined areas. Avoid contact with skin, eyes or clothes. For
Skin contact: personal protection see Section 8.
Remove contaminated clothing, shoes and leather goods. Environmental precautions:
Gently wipe of excess chemical. Wash skin gently and Do not allow to enter drains or water courses. When the
thoroughly with water and non-abrasive soap. Seek medical product contaminates public waters, inform appropriate
advice if necessary. authorities immediately in accordance with local regulations.
Eye contact: Occupational spill:
Immediately flush eyes with gently flowing cold water or saline For small spills, soak up sand or suitable non-combustible
solution for 20 minutes, holding the eyelid(s) open. Seek absorbent material, place into containers for subsequent
medical attention immediately. disposal. Thoroughly wash body areas, which come into
Ingestion: contact with the product. Avoid runoff to sewer as it may cause
Have victim rinse mouth thoroughly with water. Do not induce fire/explosion. Do not allow the product to come in contact
vomiting, due to the aromatic solvent. Seek medical advice with water systems. For large spills contact the manufacturer.
immediately. Contain liquid far ahead of spill. Contain spillage and
Advice to physician: contaminated water for subsequent disposal. Do not flush
There is no specific antidote if this product is ingested. spilled material into drains. Keep spectators away and upwind.
If a large amount has been ingested and emesis is inadequate,
lavage stomach. Treat symptomatically. An aqueous suspension SECTION 7 - HANDLING AND STORAGE
of activated charcoal can be administered to absorb remaining
toxicant.
Handling:
Remove sources of naked flame or sparks. Harmful by
SECTION 5 - FIRE FIGHTING MEASURES
inhalation or if swallowed. Avoid contact with eyes and skin
and inhalation of fumes. Use with adequate ventilation. Wash
Fire and explosion hazard:
hands before eating, drinking, chewing gum, smoking or using
Product is highly flammable and explosive due to the formulant
the toilet. Operators should change and wash clothing daily.
(solvent) content.
Remove clothing immediately if the insecticide gets inside.
Extinguishing agents:
Then wash skin thoroughly using a non-abrasive soap and put
Extinguish small fires with carbon dioxide, dry powder, or
on clean clothing. Do not apply directly to areas where surface
alcohol-resistant foam. Water spray can be used for cooling of
water is present, or to intertidal areas below the mean high
unaffected stock, but avoid water coming in contact with the
water mark. Water used to clean equipment must be disposed
product. Contain water used for firefighting for later disposal.
of correctly to avoid contamination
Avoid the accumulation of polluted run-off from the site.
Storage:
Fire fighting:
Store in its original container in isolated, dry, cool and well-
Remove spectators from surrounding area. Remove container
ventilated area. Avoid cross contamination with other
from fire area if possible. Fight fire from maximum distance.
pesticides and fertilizers. Keep under lock and key out of reach
For massive fire, use unmanned hose holder or monitor nozzles.
of unauthorized persons, children and animals. Store away from
Contain fire control agents for later disposal. Use a recom-
incompatible substances. Not to be stored next to foodstuffs
mended extinguishing agent for the type of surrounding fire.
and water supplies. Local regulations should be complied with.
Water can be used to cool unaffected containers but must be
contained for later disposal. Avoid inhaling hazardous
SAFETY DATA SHEET
PRODUCT : PERVADE 10EC
EFFECTIVE DATE : June 2018
REVISION NO : 3
PAGE : 3 of 4

SECTION 8 - EXPOSURE CONTROL / PERSONAL Relative density: 1.07g/l at 200C.


PROTECTION Storage stability: Stable for up to 2 years
under normal warehouse and field conditions.
The following recommendations for exposure The product was found to be stable after 14 days at 54oC
controls/personal protection are intended for the ( 1oC) and 00C ( 1oC) in accelerated storage test.
manufacture, formulation, packaging and use of this Suspensibility: Not applicable.
product. For commercial applications and/or on-farm Dilution stability: Stable.
applications consult the product label. Solubility in water: Immediately forms an
Eye protection: emulsion in water.
Protective eyewear or chemical safety glasses with side shields
or chemical goggles when working in non-ventilated spaces. SECTION 10 - STABILITY AND REACTIVITY
Skin protection:
Long-sleeve shirt, long pants, shoes plus socks. Stability: The product is stable at room temperature.
Hand protection: No significant active ingredient degradation occurs after more
Chemical-resistant gloves. than 14 days at 54oC ( 1oC). The product is considered stable
Respirator requirements: after 7 days at 0oC ( 1oC).
None likely to be needed. NIOSH approved P class filtering Incompatibility: This product is compatible with most other
face piece or respirator may be used to minimize inhalation of insecticides used in cotton.
aerosols. Conditions and materials to avoid: Avoid exposure to
Work hygienic practices: extreme temperatures. Strong oxidizers.
Clean water should be available to rinse eyes and skin in case
Hazardous decomposition products: May release irritating
of chemical exposure. Wash thoroughly with soap and water
and toxic gases due to thermal decomposition. Products of
after handling and before eating, drinking, chewing gum, or
combustion include CO and CO2.
using tobacco.
Hazardous polymerization: Will not occur.
Additional protective measures:
Follow manufacturer’s instructions for cleaning/maintaining
PPE. If no such instructions for washables, use detergent and SECTION 11 - TOXICOLOGICAL INFORMATION
hot water. Keep and wash PPE separately from other laundry.
User safety recommendations: Acute toxicity/irritation studies:
Users Should: Acute Oral LD50 (Rat): 500 – 2,000 mg/kg
 Wash hands before eating, drinking, chewing gum, using Acute Dermal LD50 (Rabbit): >5,000 mg/kg
tobacco or using the toilet. Acute Inhalation LC50 (Rat): >2.08 mg/L
 Remove clothing immediately if pesticide gets inside. Then Eye Irritation: Mildly irritating
wash thoroughly and put on clean clothes. Skin Irritation: Moderately irritating
 Remove PPE immediately after handling this product. Dermal Sensitization: Contact sensitizer
Wash the outside of gloves before removing. As soon as Routes of exposure: Skin, eye, inhalation,
possible, wash thoroughly and change into clean clothing. ingestion.
Potential health effects:
Skin contact: Moderately irritating. Permethrin may cause
SECTION 9 - PHYSICAL AND CHEMICAL tingling sensation known as parasthesia at point of contact.
PROPERTIES Eye contact: Mildly irritating. May cause redness and tearing.
Ingestion: Permethrin is a neurotoxin. Ingestion may induce
Appearance: Clear, amber-brown liquid. neurotoxic symptoms including diarrhea, salivation, tremors,
Odour: Aromatic. convulsions, hyperactivity and hypersensitivity to touch or
Flammability: Extremely flammable (due to sound.
solvent). Inhalation: May cause nasal or respiratory irritation.
Explosive properties: Explosive (due to solvent) in Other toxicological information: (Based on Permethrin
enclosed space (between 1% and 7% Technical)
in air). Carcinogenicity:
Flash point: 35oC (Tag Closed Cup method). Studies did not detect any carcinogenic activity.
pH: Not available. Teratogenicity:
SAFETY DATA SHEET
PRODUCT : PERVADE 10EC
EFFECTIVE DATE : June 2018
REVISION NO : 3
PAGE : 4 of 4

Studies did not detect any teratogenic effects. UN3082, Environmentally hazardous substance, liquid, n.o.s.
Mutagenicity: (permethrin),
Studies did not detect any mutagenic activity. 9, PG III, marine pollutant
IATA (air):
SECTION 12 - ECOLOGICAL INFORMATION UN3082, Environmentally hazardous substance, liquid, n.o.s.
(permethrin),
Environmental hazards: This pesticide is highly toxic to fish. 9, PG III, marine pollutant
Do not apply directly to water. Avoid contamination of
ornamental fish ponds. Drifts and runoff from treated areas may SECTION 15 - REGULATORY INFORMATION
be hazardous to aquatic organisms in treated areas. Do not
contaminate water when cleaning equipment or disposing of
CAUTION - Harmful if swallowed, inhaled or absorbed
equipment wash water. This product is highly toxic to blooming
through skin. Causes moderate eye irritation. Avoid breathing
crops or weeds while bees are actively visiting the treatment
spray mist. Avoid contact with skin, eyes or clothing. Remove
area.
contaminated clothing and wash before reuse. Wash thoroughly
Bioaccumulation: Unlikely to bioaccumulate due to acute
with soap and water after handling. Prolonged or frequently
toxicity.
repeated skin contact may cause allergic reactions in some
Environmental fate: The average half-life of permethrin in individuals.
aerobic soils is 39.5 days, with a range from 11.6 to 113 days.
Permethrin binds tightly to soil and is broken down primarily
by microorganisms, but also by photolysis. 16. OTHER INFORMATION
Ecotoxicological information:
Rainbow trout LC50 (24h): 0.62 μg/l All information and instructions provided in this Material
Bluegill sunfish LC50 (48h): 0.79 μg/l Safety Data Sheet (MSDS) are based on the current state of
Bobwhite quail LD50 (8-day): 5,200 ppm scientific and technical knowledge at the date indicated on the
present MSDS and are presented in good faith and believed to
be correct. This information applies to the PRODUCT AS
SECTION 13 - DISPOSAL CONSIDERATIONS SUCH. In case of new formulations or mixes, it is necessary to
ascertain that a new danger will not appear.
Pesticide disposal: It is the responsibility of persons in receipt of this MSDS to
Contaminated absorbents, surplus product, etc., should be
ensure that the information contained herein is properly read
burned in a high-temperature incinerator (1000oC) with and understood by all people who may use, handle, dispose or
effluent gas scrubbing. Where no incinerator is available in any way come in contact with the product. If the recipient
surplus product should be or diluted and buried in designated subsequently produces formulations(s) containing this product,
landfill. Never pour untreated waste or surplus products into it is the recipients sole responsibility to ensure the transfer of
public sewers or where there is any danger of run-off or all relevant information from this MSDS to their own MSDS.
seepage into water systems. Comply with local legislation
applying to waste disposal.
Package product wastes:
Emptied containers retain vapour and product residues.
Observe all labeled safeguards until container is destroyed.
Combustible containers should be disposed of in pesticide
incinerators. Non-combustible containers must be triple rinsed
with water and then be punctured and transported to a scrap
metal facility for recycling or disposal in approved landfill site.
Comply with any local legislation applying to disposal.

SECTION 14 - TRANSPORT INFORMATION

DOT (ground)
Not regulated
IMO (vessel):

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy