Name: k EY Class; Dat W:A AP Chemistry Chapter 17 Practice Test ¢ 1. For which process is AS negative? le 54 disorder $12 A) evaporation of 1 mol of CCL(Q) 144 B) ing 5 mL ethanol with 25 mL water 4 65 © compressing 1 mol Ne et constant temperature from 1.5L 10051) yy the temperature of 100 g Cu from 275K to E) grinding a large crystal of KCI to powder +f C2 Atwvo-butbed fask contains 5 particles, What isthe probability of finding all 5 particles on the left side? A) 2.50% I B)_2.24% a [93.23% a 0.20% E) 6.25% D5. Consider the following processes: 1 condensation of a liquid -4 $ TI increasing the volume of 1.0 mol of an ideal gas at constant temperature * 4S II. dissolving sugar in water +S IV. heating 1.0 mol of an ideal gas at constant volume +6 For how many of these is AS positive? mire luprder A) 0 B) 1 c E) 4 D) 4. Which ofthe fottowing statements is true? |A) The total energy and entropy of the universe are both inoreasing, B) The total energy of the universe is increasing, but the entropy is constant. C)_ The total energy of the universe increases, wile the entropy decreases. ie total energy of the universe is constant, but the entropy Is mereasing, fone of these. 5. Ifthe change in entropy of the surroundings for a process at 431 K and constant pressure is -326 JIK, what is the heat flow absorbed by for the system? A) 326k) - ~OH B) 1.32kd ASson a TT les ©) -141 ks D)_105 -bH ~f, y2 Ae [2 a4ue Soo Yc 51K -/4¥05 -—-AH bite #1405eee DA iG 83356 6. The enthalpy of vaporization of ammonia is 23.35 kJ/mol at its boiling point (-33.4°C). Calculate the value of AS when 1.00 mole of ammonia is vaporized at —33.4°C and 1.00 atm. ao Wear = “SH. -bS - bSpow B) -6.99 x 10? J/K mol fe (43350 Tm) _ 9 74x10! Dy -9.74 x 10' JK mol seeeeees B) 6.99% 102J/K mol (38. 44273) Consider two perfectly insulated vessels. Vessel #1 initially contains an ice cube at 0°C and water at 0°C. Vessel #2 initially contains an ice cube at 0°C and a saltwater solution at 0°C. In each ‘vessel, consider the "system" to be the ice, and the "surroundings" to be the liquid. 8 7. Determine the sign of AS.ys, ASyur, atid ASyaiy for the contents of Vessel #1. AS ASuur AS ok AS une 2 AS sur +4 Sips A) 0 i} ox + [B)_+— apiew ctw pO Dee u E) + 0 a iu + C &, Forthe vaporizatbh of aliquid given pressure, DH -TAS A) AGis positive atall temperatures, B) _AGis negative at all temperatures. ‘AG is positive at low temperatures, but negative at high temperatures (and zero at 4 some temperature). Dy AG is negative at low temperatures, but positive at high temperatures (and zero at some temperature). E) None of these (A-D). ) 9, Fora particular chemical reaction AH™=4,3 kl end AS=—19 1K. Under what temperature condition is the reaction spontaneous? oA A) When T<~226K. DH-Tb f fe Ye) B) When 7'< 226 K. 4300S -(T C)_The reaction is spontaneous at all temperatures. T+d27 G5 PIS D) The reaction is not spontaneous af any temperature i fan } When T> 26K. T2aaS 06% 959Name: wD: A C. 10. Forthe process ofa certsin liquid vaporizing at | atm, AHP y= 54.2 kI/mol and AS ap" 74.1 Jmol K. Assuming these values are independent of T, what is the normal boiling point of this liquid? oo DG=0 A) 731°C a - B) 1004% a: AH -ThS TAS = OH D) 0.731 °C ea Y200 . 2 E) none of these 7 Oh ao 731K 75 6 Bh 11. Atconstant Pressure, the following esetion 2NOx(g) > N:Og) is exothermie, aa written) is OS -SH A) always spontancous M6 = au Fas ‘Spontaneous at high temperatures, Dut WOT Tow TEMpETaNITes ©) -(7-) D) never spontaneous FE) cannot tell When ignited, solid ammonium dichromate decomposes in a fiery display. This is the reaction for a "volcano" demonstration. The decomposition produces nitrogen gas, water vapor, and chromium(III) oxide. The temperature is constant at 25°C. @99K Substance AH? (kdimol) —_-S* (ki/mol K) Cr203(g) -1147 0.08118 #00) 242 0.1187 Nag) 0 0.1915 (NH):CH:0x8) 225 0137 wads Cre > Cr 0,4 MM P12, Determine ASiy® (in kI/mol K), AH. -C-gomste) ee 2 AH. tale ) 6.39 WSunwe dS + bbear Bbw ’ : aw ©) 843 e 0 oles 888+ 7.00% 9 oS E) 603 13. Determine AS? reaction (in ki/mol K). A) 02777 nye 191] -L: HST] B) 0.8612 Gl) +. OME J ©) 0.7475 Cores} e 0.1590 ane fie) * a7 ]- L225 B14. Determine AG* tn kstmol). B) Sari BG = 44 -TAS ~ 2098.5 * Yd prio: AG = -aanas0o- (ane. 6338) 2074500 B) -15554 -228).37Name: ID: A Cy 15. The third law of thermodynamics states: A). The entropy of the universe is increasing. B)_The entropy of the universe is constant. :)_The entropy is zero at 0 K for a perfect erystal, ~D) The absoTute entropy of a substance decreases with increasing temperature. E) The entropy of the universe equals the sum of the entropy of system and surroundings. E16, Wena stable diatomic molecule spontaneously forms from its atoms, what are the signs of AH?, AS®, and AG? 2640 see -bS AH AS AG oH At + + Bye - = ° + + D)- = + © 17, Deteuine 56° rte following reaction: CH.(g) + 202(g) > CO2(g) + 2FO(), Semmes acrtinod) —La-aana) + gang] [-50.69] 0 O28) COx(g) 394.4 P15 HO) 237.4 A) $8110 B) -919.9 D) 082: E) 131.1kI 10 10 1.76 D 18. At 699 K, AG°=~23.25 KI for the reaction H(g) + Ia(g) —=* 2HI(g). Calculate AG for this reaction if the reagents are both supplied at 10.0 atm pressure and the product is at 1.76 atm pressure. 3 mai AG= AG? + RT Inky (ie / ,) O31 i vy e99q) In (ba) nG= 432507 + (85 E) 43.4 éName: DA iC 19. The standard molar free energies of formation of NO:(g) and N,O,(g) at 25°C are $1.840 and 98.035 kJ/mol, respectively. What is the value of K, (in atm) for the aes written as follows at OI no M0. D6 B6°4RT In hp = M0. a) e2axio® gags 219 9 2 says: + B31 a91) ne a B) 10 2544S : : SOI ke C331 1036 Valet ink p227FY= 7.76 E) 7.99% 10° Par gy ok 6xt0) M6 = AG Rak E20. Determine AG° for the weak acid HF, at 25°C. (K ir He wrk os a6 alas lol, Dire 6° 17.9 | 3S 21. Which item (a, b or c) in each of the three groups below has the lowest entropy? L — @ 1 gice (6) 10 g water vapor (c) 10 g liquid water WH. (@ L mole NaCl solid (b) 1 moi NaCl in 1 M aqueous solution (c) 1 mol molten NaCl UL__(a) 1 mole CzHs(g), (b) 1 mole CH4(g), (c) 1 mol C3H(g) all at 25 °C and 1 atm (Bab, — B) cb,c ©) bbe D) a,b,c E) aac © 2», whichorthe following reactions will have a positive value of AS°? pave cl ts ueder LPb(s) + Ch(g) — PbCl(s) - Il, 2H,S(g)_ + 3 >__2Hy + _2802(g) - TH. K,S0,@)_> 2K) + SO?@a), A) Tonly B) Monly iti D) Tand It E) Mand I 23. For the reaction, X + Y + A+B, AG is ~1324 kJ. Which one of the following statements is NOT valid concerning the reaction? ea A) The reaction is thermodynamically favorable, T B) The reaction is spontaneous as written. T C)_The products are more stable than the reactants, 7 : D)_The reaction will proceed rapidly from left to rahi. + Cant dell TE) Three of these statements are valid.AP Chemistry Chapter 17 Practice Test Answer Section 1. 10. i 12. 13. 14, ANS: C PTS: 1 DIF: Easy REF: 17.1 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy MSC: Conceptual ANS: C PTS: 1 DIF: Moderate REF: 17.1 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy MSC: Conceptual ANS: D PIS: 1 DIF: Easy REF: 17.1 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | third law of thermodynamics | entropy change for a reaction MSC: Conceptual ANS: D PTS: 1 DIF: Easy REF: 172 Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics — MSC: Conceptual ANS: E PTS: 1 DIF: Moderate REF: 173 Chemistry | general chemistry | thermochemistry | thermodynamies | second law of thermodynamics | entropy change for a phase transition, MSC: Quantitative ANS: C PTS: 1 DIF: Easy REF: 174 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy change for a phase transition, MSC: Quantitative ANS: B PTS: 1 DIF: Easy REF: 174 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy ‘MSC: Conceptual ANS: C PIS: 1 DIF: Easy REF: 174 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy change for a phase transition MSC: Conceptual ANS: D PIS: 1 DIF: Easy REF: 174 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy | spontaneity MSC: Coneeptual ANS: C PIS: 1 DIE: Easy REF: 17.4 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy MSC: Quantitative ANS: B PIS: 1 DIF: Easy REF: 174 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy | spontaneity MSC: Conceptual ANS: A PIS: 1 DIF: Difficult REF: 17.4 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics MSC: Quantitative ANS: D PIS: 1 DIF: Easy REF: 175 + Chemistry | general chemistry | thermochemistry | thermodynamics | third law of thermodynamics | entropy change for a reaction MSC: Quantitative ANS: B PIS: 1 DIF: Moderate REF: 17.6 +: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy | standard fie energy change MSC: QuantitativePIs: 1 DIF: Easy REF: 17.5 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | third law of thermodynamics MSC: Conceptual . ANS: B PTS: 1 DIF: Easy REF: 17.5 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy MSC: Conceptual . ANS: C PIS: 1 DIF: Easy REF: 17.6 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy | standard free energy change MSC: Quantitative . ANS: D PIS: 1 DIF: Moderete REF: 17.7 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free-energy dependence on pressure MSC: Quantitative |. ANS: C PIS: 1 DIF: Moderate REF: 17.8 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | thermodynamic equilibrium constant (K) MSC: Quantitative . ANS: E PTS: 1 DIF: Easy REF: 17.8 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | thermodynamic equilibrium constant (K) MSC: Quantitative . ANS: A PIS: 1 DIF: Easy REF: 17.5 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | second law of thermodynamics | entropy MSC: Conceptual . ANS: C PIS: i DIF: Easy REF: 17.3 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | third law of thermodynamics | entropy change for a reaction ‘MSC: Conceptual . ANS: D PIs: 1 DIF: Easy REF: 17.4 KEY: Chemistry | general chemistry | thermochemistry | thermodynamics | free energy | spontaneity MSC: Conceptual