The Nalco Guide: Authored by

The Nalco Guide
to Cooling Water System
Failure Analysis
Nalco Chemical Company
Authored by
Harvey M. Herro
Robert D. Port
McGraw-Hill, Inc.
New York St. Louis San Francisco Auckland Bogota
Caracas Lisbon London Madrid Mexico City Milan
Montreal New Delhi San Juan Singapore
Sydney Tokyo Toronto
Library of Congress Cataloging-in-Publication Data
Herro, Harvey M.
The Nalco guide to cooling water system failure analysis / Nalco
Chemical Company ; authored by Harvey M. Herro, Robert D. Port.
p. cm.
Includes bibliographical references and index.
ISBN 0-07-028400-8
1. Cooling towers. 2. Heat exchangers—Corrosion. I. Port,
Robert D. II. Nalco Chemical Company. III. Title.
TJ563.H47 1993
621.1'97—dc20 92-22428
CIP
Copyright © 1993 by McGraw-Hill, Inc. All rights reserved. Printed in

the United States of America. Except as permitted under the United
States Copyright Act of 1976, no part of this publication may be repro-
duced or distributed in any form or by any means, or stored in a data
base or retrieval system, without the prior written permission of the
publisher.
891011 KGPKGP 054321
ISBN D-D7-DSflL4DD-fl
The sponsoring editor for this book was Robert W. Hauserman, the
editing supervisor was David E. Fogarty, and the production supervisor
was Suzanne W. Babeuf. It was set in Century Schoolbook by North
Market Street Graphics.
Printed and bound by Kingsport Press.
Information contained in this work has been obtained by McGraw-

Hill, Inc. from sources believed to be reliable. However, neither
McGraw-Hill nor its authors guarantee the accuracy or complete-
ness of any information published herein, and neither McGraw-
Hill nor its authors shall be responsible for any errors, omissions, or
damages arising out of use of this information. This work is pub-
lished with the understanding that McGraw-Hill and its authors
are supplying information but are not attempting to render engi-
neering or other professional services. If such services are required,
the assistance of an appropriate professional should be sought.
To our families for their patience, understanding,
and support.
Preface
Cooling water system corrosion causes immediate and delayed prob-

lems. Difficulties spread from a failure like ripples from a pebble
thrown into a pool. A single failure may force an unscheduled outage,
redirect worker efforts, contaminate product, compromise safety, in-
crease equipment expense, violate pollution regulations, and decrease
productivity.
The closer one is to the failure, the more its direct effects are appar-
ent. The cumulative effects of failure are often overlooked in the rush
to "fix" the immediate problem. Too often, the cause of failure is
ignored or forgotten because of time constraints or indifference. The
failure or corrosion is considered "just a cost of doing business."
Inevitably, such problems become chronic; associated costs, tribula-
tions, and delays become ingrained. Problems persist until cost or con-
cern overwhelm corporate inertia. A temporary solution is no longer
acceptable; the correct solution is to identify and eliminate the failure.
Preventative costs are almost always a small fraction of those associ-
ated with neglect.
The solution to any cooling water system failure begins with a thor-
ough understanding of the cause. Careful, meticulous investigation
will almost always reveal the failure source and any attendant accel-
erating factors. Ideally, potential problems will be identified before
failure. The identification of cooling water system potential problems
begins with a knowledge of how to recognize such problems. Knowing
where particular forms of damage might occur, what damage looks
like, how critical factors influence damage, and, most importantly, how
such problems can be eliminated are the objectives of this book.
This book follows the format used in The Nalco Guide to Boiler Fail-
ure Analysis, also authored by Robert D. Port and Harvey M. Herro,
copyright 1991 by McGraw-Hill, Inc. Each chapter is divided into eight
sections, giving specific information on damage:
General Description
Locations
Critical Factors
Identification
Elimination
Cautions
Related Problems
Case Histories
All areas of the cooling water system where a specific form of dam-
age is likely to be found are described. The corrosion or failure causes
and mechanisms are also described. Especially important factors influ-
encing the corrosion process are listed. Detailed descriptions of each
failure mode are given, along with many common, and some not-so-
common, case histories. Descriptions of closely related and similarly
appearing damage mechanisms allow discrimination between failure
modes and avoidance of common mistakes and misconceptions.
Many sources contain scattered information concerning cooling
water system corrosion and defects, and many literature studies
describe corrosion processes and mechanisms from a predominantly
theoretical viewpoint. Until now, however, no source discusses cooling
water system corrosion with emphasis on identification and elimina-
tion of specific problems. Much of the information in this book is
unique; every significant form of attack is thoroughly detailed. Color
photos illustrate each failure mechanism, and case histories further
describe industrial problems.
Visual inspection techniques are stressed as the most important
tools used to study failures. This text is not a substitute for rigorous
failure analysis conducted by experts, but it will help the reader iden-
tify and eliminate many cooling water system problems. Still, on occa-
sion, the experienced, skilled, failure analyst using sophisticated
analytical techniques and specialized equipment may be required to
solve complex or unusual problems. Common sense, appropriate expe-
rience, and systematic investigation are, however, often superior to the
more elaborate, but less effective, techniques used by some.
Acknowledgments
Thanks are extended to Nalco Chemical Company for its support dur-
ing this work. Our colleagues James J. Dillon and James G. Tomei are
the recipients of special appreciation for their contributions of selected
photos and case histories. Thanks are extended to Michael J. Danko for
his contribution of selected photos and aid in sample preparation. We
are indebted to Richard W. Cloud for his excellent scanning electron
microscopy work. Warmest thanks to Ted R. Newman, our mentor.
Thanks are extended to Dr. William K. Baer for his support and guid-
ance during this work. Credit is due James E. Shannon and Bruce
Thompson for their manuscript review. Special thanks to Christopher
Wiatr for his review of Chap. 6, "Biologically Influenced Corrosion."
Constance Szewczyk deserves special thanks for aid in manuscript
preparation. Thanks also to Alice LaMaide for her secretarial assis-
tance. Finally, sincere gratitude is given to Pamela J. Entrikin for final
manuscript edits, cover design direction, and assistance in coordinat-
ing the production of this book with McGraw-Hill.
Harvey M. Herro
Robert D. Port
ABOUTTHEAUTHORS
HARVEY M. HERRO obtained a B.S. in Physics from

Marquette University and a Ph.D. in metallurgical engi-
neering from Iowa State University. Dr. Herro, who has
been with Nalco since 1982, holds patents for corrosion mon-
itoring using chemical techniques, is the author of numer-
ous papers on corrosion and failure analysis, and is a
frequent lecturer. He is an active member in the National
Association of Corrosion Engineers (NACE) and the Ameri-
can Society for Metals (ASM). Dr. Herro currently chairs
Task Group T-3A-12 Underdeposit Corrosion at NACE and
is an active member of many of its committees. At Nalco, he
leads the Nalco Corrosion Detection Group and conducts
training on recognizing forms of industrial corrosion.
ROBERT D. PORT is a metallurgical engineer with more than

twenty years' experience in failure analysis, at both Nalco
Chemical Company and at independent metallurgical labo-
ratories. Mr. Port is the author of numerous papers on fail-
ure analysis, and frequently speaks to technical societies
and industrial groups. He is a member of NACE and is
active on its committee for Failure Analysis in Steam
Generating Systems and its committee on Corrosion in
Steam Generating Systems. Mr. Port attended the
University of Illinois where he received his B.S. in
Metallurgical Engineering.
Mr. Port and Dr. Herro have made presentations at profes-

sional societies such as the Electric Power Research
Institute (EPRI), NACE, ASM, the American Boiler
Manufacturer's Association (ABMA), and the American
Chemical Society (ACS). Together, the authors have com-
pleted more than 4700 failure analyses.
Nalco Chemical Company, headquartered in Naperville,

Illinois, has worldwide sales of over one billion dollars.

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The Nalco Guide

to Cooling Water System

Nalco Chemical Company

Copyright © 1993 by McGraw-Hill, Inc. All rights reserved. Printed in

891011 KGPKGP 054321

Printed and bound by Kingsport Press.

Information contained in this work has been obtained by McGraw-

Cooling water system corrosion causes immediate and delayed prob-

HARVEY M. HERRO obtained a B.S. in Physics from

ROBERT D. PORT is a metallurgical engineer with more than

Mr. Port and Dr. Herro have made presentations at profes-

Nalco Chemical Company, headquartered in Naperville,

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