MSDS - Treatment
MSDS - Treatment
MSDS - Treatment
HazardᆞRisk Classification
Flammable aerosols 1
Flammable gases 1
Flammable liquids 2
Skin corrosion/irritation 2
Eye damage/irritation 2
Aspiration hazard 1
Category Indication
Symbol
Eye contact; Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Skin contact; Immediately flush skin with plenty of water. Get medical attention if irritation develops and
persists. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately
before reuse. Take off immediately all contaminated clothing.
Inhalation; Move to fresh air. Oxygen or artificial respiration if needed. Call a physician if symptoms
develop or persist.
Ingestion; Immediately call a POISON CENTER or doctor/physician. Never give anything by mouth to a
victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison
control center. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
medical device. Rinse mouth thoroughly. If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs.
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Indication of immediate medical attention and notes for physician; Consult a physician. Show this safety
data sheet to the doctor in attendance.
Suitable (and unsuitable) extinguishing media; Use water spray to keep fire exposed containers cool. If
substance does ignite, use CO2, dry chemical or foam.
Specific hazards arising from the chemical (e.g. nature of any hazardous combustion products); No
information found
Special protective equipment and precautions for fire fighters; In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the
pressure demand or other positive pressure mode. Combustion by-products include phosgene and
hydrogen chloride gases. Structural firefighters' clothing provides only limited protection to the
combustion products of this material.
Personal precautions, protective equipment and emergency procedures; Ensure adequate ventilation.
Keep unnecessary personnel away. Keep out of low areas. Keep people away from and upwind of
spill/leak. Ventilate closed spaces before entering them. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Wear appropriate protective equipment and
clothing during clean-up.
Environmental precautions and protective procedures; Do not contaminate water.
Methods and materials for containment and cleaning up;
- Large Spills: Dike far ahead of spill for later disposal. Use a non-combustible material like vermiculite,
sand or earth to soak up the product and place into a container for later disposal. Use only non-sparking
tools.
- Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).
Precautions for safe handling; Vapors may form explosive mixtures with air. Do not smoke. Take
precautionary measures against static discharges. All equipment used when handling the product must
be grounded. Use only in area provided with appropriate exhaust ventilation. Wear personal protective
equipment. Avoid prolonged exposure. Wash thoroughly after handling. DO NOT handle, store or open
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near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Use
non-sparking tools and explosion-proof equipment.
Conditions for safe storage (including any incompatibilities); Store in cool place. Store in a well-ventilated
place. Keep container tightly closed. Keep away from heat, sparks and open flame. Outside or detached
storage preferred. The pressure in sealed containers can increase under the influence of heat. This
material can accumulate static charge which may cause spark and become an ignition source. Prevent
electrostatic charge build-up by using common bonding and grounding techniques. Keep in an area
equipped with sprinklers. Keep out of the reach of children. Keep from contact with oxidizing materials.
Control parameters (e.g. occupational exposure limit values, biological limit values);
Methylcyclohexane; TWA 400 ppm
Heptane; TWA 400 ppm, STEL 500 ppm
Engineering controls; A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because
it can control the emissions of the contaminant at its source, preventing dispersion of it into the general
work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended
Practices, most recent edition, for details.
Personal protective equipment;
- Eye / face protection; Chemical goggles are recommended. Face-shield. Provide eyewash station and
safety shower.
- Skin protection; Wear chemical protective equipment that is specifically recommended by the
manufacturer. It may provide little or no thermal protection. Wear protective gloves.
- Respiratory protection; Wear positive pressure self-contained breathing apparatus (SCBA). When
workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Chemical stability and possibility of hazardous reactions; Stable under ordinary conditions of use and
storage
Conditions to avoid (e.g. static discharge, shock or vibration, etc); Heat, flames and sparks. Incompatible
materials.
Incompatability (Materials to Avoid); Strong oxidizing agents.
Hazardous Decomposition Products; carbon oxide
- Methylcyclohexane -
Information on the likely routes of exposure; No information found
Acute toxicity
- Oral; No information found
- Dermal; LD50> 2000 ㎎ / ㎏ Species: Guinea pig (OECD Guideline 402) ※ Source: ECHA
- Inhalation; LC50> 26.3 ㎎ / ℓ 1 hr Species: Mouse Source: ECHA
Skin corrosion/irritation; No information found
Serious eye damage/irritation; No information found
Respiratory or skin sensitization; No information found
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Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.