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149 viewsZimsec Chemistry Data Booklet
Uploaded by
nokutendatmashayaCopyright
© © All Rights Reserved
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/ 11
ZIMBABWE SCHOOL EXAMINATIONS COUNCIL
(ZIMSEC)
DATA BOOKLET
FOR
CHEMISTRY (9189)
(Advanced level)
For use in all papers for the above syllabus, except practical examinations.
June 2006 ‘TABLES OF CHEMICAL DATA.
important values, constants and standards:
rmojar gas constant
the Faraday constant
the Avogadro constant
the Planck constant
speed of light ina vacuum
rest mass of proton, 'H
rest mass of neutron, fn
rest mass of election, "e
electronic charge
molar volume of gas
Ro =8315K"'mol!
F =9.65x10'C mol”
L 26.0210" mol"
ho =6.63x10%Js.
© =3.00x10°ms”
m, =1.67x10"kg
mm, 2167x107" kg
mm, =9.11x10 "kg
e
V, =22.4dm’mo!” at s.tp.
=24 dm’ mol” under room conditions
(where s.Lp. is expressed as 101 kPa, approximately, and 273 K (0°C))
ionic product of water
specific heat capacity of water
K,=1.00%10 “ mot*de®
{at 298 K [25°C))
= 4.18 kskg 'K"
(=4.18 JG" K") tontsation energies (1st, 2nd, 3rd and 4th) of selected elements, In kJ mort
ZrozoegezgT
z
zg
AL
Ba‘42e7 <——= Ba
Br+26 == 2B
Ca"420 == Ca
CL+2e = 20r
2HOCI+2H'+ 28° <= Ch+2H,O
Co*+26 === Co
Co +8 === Co”
[Co(NH),J° +22" <> Co + 6NH,
cr s2e° = Cr
crsge = Cr
CM +e oS Cr
C107 + 14H" +60" <== 2Cr"+7H,0
Cure == Cu
cu"+2e === Cu
cue” <= Cur
{Cu(NH,) "+22" <== Cu+4NH,
F420 —= oF
Fe"+2e <= Fe
Fe" +36" » Fe
Fo" +e” Fe"
IFe(On) +e” <= [Fe(cn
Fe(OH), +e Fe(OH), + OH
2H'+2e° =H,
ete — 2
Kre —= K
ui
ev
40.80
“1.66
-2.90
+107
2.87
41.38
+164
~0.28
182
-0.43
91
“0.74
om
41.33
+052
10.34
4015
~005
+287
0.44
0.04
40.77
40.36
~0.56
0.00
4054
-2.92
-3.04 Electrode reaction Eon
Mg" +2e === Mg 2.38
un 426° <== Mn a8
Mn 4e Mn +549
MnO, + 4H"4267 <== Mni*4-2H,0 41.23
MnO, +e === Mnf 40.56
MnO, +2H,0+3e <> MnO, + 40H" +0.58
MnO; +8H'+5e === Mal" +4H,0 41.52
NO}+2H'+6 <= NO,+H,0 +081
NO3+SH's 26° => HNO, +H, 40.94
NO,+ 10H" +86 =" NH{+3H,O +087
Nase == Na “271
Ne +2e <= Ni 0.25
INIINH),/" 420° s—* Ni 6NH, -05t
H,O,+2H"+2e° =< 2H,0 WIT
O, +4 ede == 2H,0 41.23
0,42H,0 +407 === 40H" 40.40
0,+2H'+2e" —= HO, +088
2H,O +267 <— = H,+ 20H” 083
Pot+2e <= Pb 0.13
Pos 28 == Pb 41.69
PbO, + 4H" 207 <= Poh 4 2H 1.47
SOP +4H'+28 === $0, +2H,0 40.17
8,0, +2e <== 2807 +2.01
SOF +26 <== 28,05 +0.09
Sn"42@ === Sn 0.14
Sn42e == sn” 40.18
Voage oss a2
Wee me ve 028
VO"+2H +e VFO 40.34
VOl+2H' +e === VO™"+HO +1.00
VO, 44H +e" = VO" 4 2H. 41.00
an 6267 2n ~0.76
Allionie states refer to aqueous ions but other state symbols have been omitted.
4a fb) E¥ in decreasing order of oxidisi.
{see also the extended alphabetical list on the previous pages)
Electrode reaction
Fe2e == OF
$,0; +28" —= 2807
H,0,42H'+2e" <= 2H,0
MnO; + 8H’ + 5e7 Mni* + 44,0
—
PDO, +4H'+2e” == Pb 2H.
Chez ach
Cr,OF + 14H'+ 68 === 2C1"47H,0
Br +267 eS 2B
NO} + 2H + NO, + HO
Age” === Ag
Fe"se <== Fe
1+28 == or
0,+2H,0+4e = 40H"
Cu" 422 —= Cu
Sn"+2e <—= sn*
SO} +4H' 426° <= $0,+2H,0
SOF +20 = = 25,08
2H 227 tH,
PU'42e = Pb
Sn" +26
Fe +267
dn +20"
Ma" « 26°
Ca +26
Kee = K
4287
42.01
+77
+152
+147
41.36
41.33
107
4081
+080
40.77
4984
+0.40
40.94
40.15
40.47
+0.09
0.00
0.43
014
~0.44
~0.76
2.38
~2.87
2.92 Bond energies
(a) Diatomic molecules
Bond Energy /kJ mot
HH 436
Dp 442
NeN 994
o=0 496
FF 158
clot 244
BrBr 193
MH 151
HF 562
HOI 431
HOB 366
Ho 299
(0) Polyatomic molecules
Bond Energy kmot*
cc 350
cmc 610
c= 840
G:C (benzene) 520
CoH 410
c~cr 340
CBr 280
cat 240
CoN 305
can 610
© 90
co 360
c=0 740
N-H 390
NN 160
Nun 410
on 460
o-0 150
si-ot 359
SHH 320
Sito 44g
i 202
250
347
264 Atomic and janie redil
(a) Petiod 3
{co}
(d)
fe)
metalic
single covalent
van der Waals
Group
Group iv
single covalent
metallic
Group Vil
single covalent
First row transition elements
single covalent
atomic/ run
z-@e7" F992 BeepEy RoQvrwREF
vEQ