Form 4 Radioactivity
Form 4 Radioactivity
Form 4 Radioactivity
Contents
A INTRODUCTION/CAUSES OF RADIOCTIVITY
Gamma(y) particle
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(ii)Uranium nuclide with 23792 U has 206 neutrons and 92 protons in the nucleus
therefore an n/p = 2.2391 thus more unstable than 23592 U and thus more readily
decays / disintegrates to try to attain n/p = 1.
(iii) Chlorine nuclide with 3717 Cl has 20 neutrons and 17 protons in the nucleus
therefore an n/p = 1.1765 thus more unstable than 3517 Cl and thus more readily
decays / disintegrates to try to attain n/p = 1.
(iv)Uranium nuclide with 23592 U has 143 neutrons and 92 protons in the nucleus
therefore an n/p = 1.5543 thus more stable than 237 92U but also readily decays /
disintegrates to try to attain n/p = 1.
All unstable nuclides naturally try to attain nuclear stability with the production
of:
226 222 4 2+
Ra
88 -> Rny + 2He
226 222 4 2+
88 Ra -> 86 Rn + 2He
x 234 4 2+
y U -> 90 Th + 2He
238 234 4 2+
92 U -> 90 Th + 2He
x 230
yU -> 88 Ra + 2 42He 2+
238 230
92 U -> 88 Ra + 2 42He 2+
210 x
84 U -> y W + 10 α
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210 170
84 U -> 64 W + 10 α
210 x
92U -> yW + 6α
210 186
92U -> 80W + 6α
2. 234 x Th -> y
Pa
91 + 0
-1e
234 y 0
90 Th -> 91 Pa + -1e
5. 1 x n -> y
1H + 0
-1e
1 1 0
0n -> 1H + -1e
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7. 22888Ra -> 228
90Th + xβ
228 228
88Ra -> 92Th + 4β
232 212
8. 90Th -> 82Pb + 2β + xα
232 212
90Th -> 82Pb + 2β + 5α
238 226
9. 92U -> 88 Ra + xβ + 3α
238 226
92U -> 88 Ra + 2β + 3α
218 206
10. 84Po -> 82Pb + xβ + 3α
218 206
84Po -> 82Pb + 4β + 3α
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α-rays β-rays y-rays
The sketch diagram below illustrates the effect of electric /magnetic field on the
three radiations from a radioactive nuclide
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Write the nuclear equation for the disintegration from :
(i)238 92 U to 234
90 T
238 234 4 2+
92 U -> 90 T + 2 He
238 234
92 U -> 90 T + α
(ii)238 92 U to 222 84 Rn
238 222
92 U -> 84 Rn + 4 4 2 He 2+
238 222
92 U -> 84 Rn + 4α
230
Th undergoes alpha decay to 222 86 Rn. Find the number of α particles emitted.
90
Write the nuclear equation for the disintegration.
Working
230 222
90 Th -> 86 Rn + x 4 2 He
Method 1
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Using atomic numbers only and substituting the 21 α (above)
238 214
92 U -> 83Bi + 21 4 2 He + y 0 -1 e
92 = 83 + 42 + -y
=> 92 – (83 + 42) = - x
x = 33 β
Nuclear equation
298 210
92 U -> 83 Bi + 21 4 2 He + 33 0 -1 e
1 27 28
0n + 13 Al -> 13 Al + y + a
1 28 b 4
0n + a Al -> 11 Na + 2 He
a 14 14 1
0n + 7N -> bC + 1H
1
0n + 11 H -> 2
1H + a
1 235 95 139
0n + 92 U -> 42 Mo + 57 La + 210 n + 7 a
b) Nuclear fusion
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Nuclear fusion is the process which smaller nuclides join together to form larger /
heavier nuclides and releasing a large quantity of energy.
Very high temperatures and pressure is required to overcome the repulsion
between the atoms.
Nuclear fusion is the basic chemistry behind solar/sun radiation.
Two daughter atoms/nuclides of Hydrogen fuse/join to form Helium atom/nuclide
on the surface of the sun releasing large quantity of energy in form of heat and
light.
2
1H + 21H -> abHe + 10 n
2 3
1H + a -> 2He
2 2 1
1H + 1H -> a + 1H
1 4
4 1H -> 2He + a
14 17 1
7H + a -> 8O + 1H
The half-life period is the time taken for a radioactive nuclide to spontaneously
decay/ disintegrate to half its original mass/ amount.
It is usually denoted t 1/2.
The rate of radioactive nuclide disintegration/decay is constant for each nuclide.
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210
0.0002 seconds
Po
84
The less the half life the more unstable the nuclide /element.
The half-life period is determined by using a Geiger-Muller counter (GM tube)
.A GM tube is connected to ratemeter that records the count-rates per unit time.
This is the rate of decay/ disintegration of the nuclide.
If the count-rates per unit time fall by half, then the time taken for this fall is the
half-life period.
Examples
a)A radioactive substance gave a count of 240 counts per minute but after 6
hours the count rate were 30 counts per minute. Calculate the half-life period
of the substance.
If t 1/2 = x
then 240 --x-->120 –x-->60 –x--->30
From 240 to 30 =3x =6 hours
=>x = t 1/2 = ( 6 / 3 )
= 2 hours
b) The count rate of a nuclide fell from 200 counts per second to 12.5 counts
per second in 120 minutes.
Calculate the half-life period of the nuclide.
If t 1/2 =x
then
200 --x-->100 –x-->50 –x--->25 –x--->12.5
From 200 to 12.5 =4x =120 minutes
=>x = t 1/2 = ( 120 / 4 )
= 30 minutes
c) After 6 hours the count rate of a nuclide fell from 240 counts per second to
15 counts per second on the GM tube. Calculate the half-life period of the
nuclide.
If t 1/2 = x
then 240 --x-->120 –x-->60 –x--->30 –x--->15
From 240 to 15 =4x =6 hours
=>x = t 1/2 = ( 6 / 4 )= 1.5 hours
d) Calculate the mass of nitrogen-13 that remain from 2 grams after 6 half-
lifes if the half-life period of nitrogen-13 is 10 minutes.
If t 1/2 = x then:
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2 --x-->1 –2x-->0.5 –3x--->0.25 –4x-->0.125–5x--->0.0625–6x--->0.03125
After the 6th half life 0.03125 g of nitrogen-13 remain.
g) How old is an Egyptian Pharaoh in a tomb with 2grams of 14C if the normal
14
C in a present tomb is 16grams.The half-life period of 14C is 5600years.
If t 1/2 = x = 5600 years then:
16 --x-->8 –2x-->4 –3x--->2
3x = ( 3 x 5600 )
= 16800years
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(i)From the graph show and determine the half-life period of the isotope.
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(iii)-Some for of energy transfer/release/absorb from/to the environment
take place.
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During photosynthesis the ‘O’ released was discovered comes from water.
e) Dating rocks/fossils:
The quantity of 14C in living things (plants/animals) is constant.
When they die the fixed mass of 14C is trapped in the cells and continues to
decay/disintegrate.
The half-life period of 14C is 5600 years .
Comparing the mass of 14C in living and dead cells, the age of the dead can be
determined.
F: DANGERS OF RADIOCTIVITY.
All rays emitted by radioactive isotopes have ionizing effect of changing the
genetic make up of living cells.
Exposure to theses radiations causes chromosomal and /or genetic mutation in
living cells.
Living things should therefore not be exposed for a long time to radioactive
substances.
One of the main uses of radioactive isotopes is in generation of large cheap
electricity in nuclear reactors.
Those who work in these reactors must wear protective devises made of thick
glass or lead sheet.
Accidental leakages of radiations usually occur
In 1986 the Nuclear reactor at Chernobyl in Russia had a major explosion that
emitted poisonous nuclear material that caused immediate environmental disaster
In 2011, an earthquake in Japan caused a nuclear reactor to leak and release
poisonous radioactive waste into the Indian Ocean.
The immediate and long term effects of exposure to these poisonous radioactive
waste on human being is of major concern to all environmentalists.
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(a) Explain why isotope X emits radiations. (1mk)
-is unstable //has n/p ratio greater/less than one
(c) Arrange the radiations labeled P and T in the increasing order of ability to be
deflected by an electric filed. (1mk)
T -> P
a) Calculate the mass and atomic numbers of element B formed after 21280 X has
emitted three beta particles, one gamma ray and two alpha particles.
Mass number
= 212 – (0 beta+ o gamma + (2 x 4 ) alpha = 204
Atomic number
= 80 – (-1 x3) beta + 0 gamma + (2 x 2 )) alpha =79
b)Write a balanced nuclear equations for the decay of 21280 X to B using the
information in (a) above.
212
80 X -> 20479B + 242He + 3 0-1 e + y
Identify the type of radiation emitted from the following nuclear equations.
(i) 146 C -> 147N + ………
β - Beta
(ii) 11 H + 10 n -> 21H + ……
y -gamma
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235 95 139 1
(iii) 92 U -> 42Mo + 57La + 0n +……
7 β – seven beta particles
238 234
(iv) 92 U -> 90Th +……
α-alpha
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(v) 6C + 11 H -> 15
7N + ……
y-gamma
b)If one milligram of radium contains 2.68 x 10 18 atoms ,how many atoms
disintegrate during 3240 years.
The graph below shows the mass of a radioactive isotope plotted against time
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Using the graph, determine the half – life of the isotope
From graph 10 g to 5 g takes 8 days
From graph 5 g to 2.5 g takes 16 – 8 = 8 days
Calculate the mass of the isotope dacayed after 32 days
Number of half lifes= 32/8 = 4
Original mass = 10g
10g—1st -->5g—2nd-->2.5—3rd –>1.25—4th -->0.625 g
Mass remaining = 0.625 g
Mass decayed after 32 days = 10g - 0.625 g = 9.375g
A radioactive isotope X2 decays by emitting two alpha (a) particles and one
beta (β) to form 214 83Bi
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(c) After 112 days, 1/16 of the mass of X2 remained. Determine the half life of
X2
(a)126 C and 146 C are isotopes. What does the term isotope mean?
Atoms of the same element with different mass number /number of neutrons.
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Identify the particles emitted in steps I and III (2mks)
I - α-particle
III - β-ray
ii)Write the nuclear equation for the reaction which takes place in (a) step I
214 210
83Bi -> 81Bi + 4 2 He
(b) step 1 to 3
214 210
83Bi -> 81Bi + 4 2 He + 2 0 -1 e
(c) step 3 to 5
210
82Pb -> 20682Pb + 4 2 He + 2 0 -1 e
(c) step 1 to 5
214 206
83Bi -> 82Pb + 2 4 2 He + 3 0 -1 e
The table below give the percentages of a radioactive isotope of Bismuth that
remains after decaying at different times.
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ii)Using the graph, determine the:
I. Half – life of the Bismuth isotope
II. Original mass of the Bismuth isotope given that the mass that remained
after 70 minutes was 0.16g (2mks)
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a) Identify the rays S,R and Q
S- Beta ( β )particle/ray
R- Alpha (α )particle/ray
Q- Gamma (y )particle/ray
b) State what would happen if an aluminium plate is placed in the path of ray
R,S and Q:
R-is blocked/stopped/do not pass through
Q-is not blocked/pass through
S-is blocked/stopped/do not pass through
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(a)Which letter represent the : Explain.
(i)shortest lived nuclide
L-has the shortest half life
(ii)longest lived nuclide
P-Is stable
(iii) nuclide with highest n/p ratio
L-has the shortest half life thus most unstable thus easily/quickly
decay/disintegrate
(iv) nuclide with lowest n/p ratio
P-is stable thus do not decay/disintegrate
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