Revision Assignment - Inorganic Chemistry

Each of the following Question has 4 choices A, B, C & D, out of which ONLY ONE Choice is Correct.
However, questions with '*' may have MORE THAN ONE correct option :

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Revision Assignment 1 Inorganic Chemistry-I | JEE-2022

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Revision Assignment 2 Inorganic Chemistry-I | JEE-2022

 20.

*21. Which of the following are correct order(s):

(A) F > O > N > Cl (Electron affinity)
(B) F > N > O > C (2nd Ionisation Enthalpy)
(C) N3  O 2  F  Na  (Ionic size)
(D) S > Se > Te > O (Electron gain enthalpy)

*22. Select equations having endothermic step:

(A)  S2 (g)
S (g)  (B)  Ne (g)
Ne(g) 
(C)  N  (g)
N(g)  (D) Al2 (g) 
 Al3 (g)

Paragraph for Q. 23 - 24

The IE1 and the IE 2 in kJ mole 1 of a few elements designated by P, Q, R, S (out of which one is noble gas)
are shown below.
Atom IE1 IE 2
P 2372 5251
Q 520 7300
R 900 1760
S 1680 3380

23. Which of the elements is likely to be reactive non-metal?

(A) P (B) Q (C) R (D) S

24. Which of the above elements form a stable binary halide of the formula MX 2 ?
(A) P (B) Q (C) R (D) S

25. Match the following Column-I and Column-II.

Column-I (elements) Column-II (Periodic properties)
(A) F (p) Maximum ionization energy
(B) Cl (q) Maximum electronegativity
(C) Fe (r) Maximum electron affinity
(D) He (s) Variable oxidation state

*26. Select the correct statement(s) regarding BF2 NH 2 molecule:

(A) FBF bond angle < 120° (B) HNH bond angle > 109°28'
(C) HNH bond angle < 109°28' (D) FBF bond angle > 120°

Revision Assignment 3 Inorganic Chemistry-I | JEE-2022

*27. Correct order of bond angles in the given compounds is/are:

(A)    (B)     (C)    (D)   

*28. Correct statement(s) regarding As(CH3 )F2Cl2 molecule is/are:

(A) Maximum three halogen atoms can lie in same plane
(B) Both axial and equatorial plane may have equal number of atoms
(C) As  Cl bond length is longer than As  F bond length
(D) Maximum five atoms can lie in equatorial plane

*29. Which of the following statements are not correct?

(A) All C  O bonds in CO32 are equal but not in H 2CO3
(B) All C  O bonds in HCO 2 are equal but not in HCO2 H
(C) C  O bond length in HCO 2 is longer than C  O bond length in CO32
(D) C  O bond length in HCO 2 and C  O bond length in CO32 are equal

*30. In the structure of H 2CSF4 , which of the following statement is/are correct?
(A) Two C  H bonds are in the same plane of axial S  F bonds
(B) Two C  H bonds are in the same plane of equitorial S  F bonds
(C) Total six atoms are in the same plane
(D) Equitorial S  F plane is perpendicular to the nodal plane of  -bond

*31. Select the correct statement(s) about the compound NO[BF4 ].

(A) If has 5 and 2 bond
(B) Nitrogen-oxygen bond length is higher than nitric oxide (NO)
(C) It is a diamagnetic species
(D) B  F bond length in this compound is lower than in BF3

*32. Incorrect order between following compound is/are:

(A) O(CH3 ) 2  O(SiH3 ) 2 : Number of sp3 - hybrid atoms
(B) O(CH3 ) 2  O(SiH3 ) 2 : Bond angle w.r.t. common atoms
(C) O(CH3 ) 2  O(SiH3 ) 2 : % s-character of hybrid orbital on central atoms
(D) O(CH3 ) 2  O(SiH3 ) 2 : Reactivity towards Lewis acid

Paragraph for Q. 33 - 34

The distribution of electron among various molecular orbital is called the electronic configuration of the
molecule which provides us the following very important informations about the molecule.
(A) Stability of molecule : The molecule is stable if number of bonding molecular orbital electrons
(N b ) is greater than number of antibonding molecular orbital electrons (N a ).
1
(B) Bond order : Bond order  (N b  N a )
2
A positive bond order means a stable molecule while a negative or zero bond order means an
unstable molecule.

Revision Assignment 4 Inorganic Chemistry-I | JEE-2022

(C) Nature of the bond : Bond order 1, 2 and 3 corresponds to single, double and triple bonds
respectively.
(D) Bond length : Bond length decreases as bond order increases.
(E) Magnetic nature : Molecular orbitals in a molecule are doubly occupied, the substance is
diamagnetic and if one or more molecular orbitals are singly occupied, it is paramagnetic.

33. Which of the following statements is incorrect?

(A) Among O 2 , O 2 and O 2 the bond length decreases as O 2  O 2  O2
(B) He 2 molecule does not exist as the bonding and anti-bonding orbitals cancel each other
(C) C, O22 and Li 2 are diamagnetic
(D) In F2 molecule, the energy of 2pz is more than 2p x and 2p y

34. N 2 has greater dissociation energy than N 2 , where as O 2 has a lower dissociation energy than O 2
because:
(A) Bond order is reduced when O 2 is ionized to O 2 and bond order is increased when N 2 is

ionized to N 2

(B) Bond order is increased when O 2 is ionized to O 2 and bond order is decreased when N 2 is

ionized to N 2

(C) Bond order is decreased when O 2 is ionized to O 2 and bond order is increased when N 2 is

ionized to N 2
(D) None of these

35. How many of the following compounds have significant involvement of d-orbital in p-bonding?
H 2 PO 2 , BCl3 , H 2S4O6 , XeOF4 , Fe(CO)5 , SF6 , NH 4 Cl, ClO2 , NO 2

36. How many maximum atoms lie in the same place in the structure of methylenesulphurtetrafluoride
(CH 2SF4 ) ?

37. BrF3 is a liquid which considerably undergoes self-ionization to form cationic and anionic species.
Based on VSEPR theory, number of 90 degree F  Br  F bond angles are ________ in anionic
species.
 [BrF2 ]  [BrF4 ]
2BrF3 

38. If the dipole moment of AB molecule is given by 2.4 D and A  B the bond length is 1Å then %
covalent character of the bond is ________.

*39. Select the INCORRECT order:

(A) CH 4  SiH 4  GeH 4  SnH 4 (Bond angle)
(B) CH 4  SiH 4  GeH 4  SnH 4 (Boiling point)
(C) CHCl3  CHF3 (Acidic character)
 
(D) CH3  CF3 (Bond angle)

Revision Assignment 5 Inorganic Chemistry-I | JEE-2022

*40. Select the CORRECT order about the given property:
(A) LiH  NaH  KH  RbH (Thermal stability)
(B) CdCO3  CaCO3  K 2CO3 (Covalent character)
(C) BeCO3  MgCO3  CaCO3 (Ease of oxide formation on heating at same temperature)
(D) MgF2  BeF2  CaF2  SrF2 (Solubility in water)

*41. Select the CORRECT for microcosmic salt:

(A) Its aqueous solution gives brown ppt. with KOH and K 2 [HgI 4 ]
(B) It produces transparent white solid on heating
(C) Resulting gas produced on heating turns lime water milky
(D) It is used to identify cations of transition metal salts.

*42. Which of the following ionic compound is paramagnetic and coloured?

(A) KO3 (B) KO2 (C) K 2O 2 (D) KNO 2

*43. Select CORRECT statement(s) about:

(A) All the boron atoms are in sp 2 hybridisation

(B) It is planar
(C) It is trimetaborate ion
(D) It is isostructural with Si3O96 type silicate

*44. Correct statement(s) for reaction Ca(OH)2  Cl2 (g) 

 Product is/are:
(A) Chlorine undergoes disproportionation (B) Bleaching powder is obtained as product
(C) Product on heating gives CaCl2 (D) Oxidation state of oxygen changes

*45. Which of the following compound gives H3BO3 / H  B(OH) 4  on hydrolysis?

(A) B2 H 6 (B) Na 2 B4O 7 (C) BCl3 (D) B2 O 3

*46. Select the correct statement(s) about boron nitride and graphite:
(A) Both BN and graphite have layered structure
(B) Both BN and graphite are soft
(C) BN and graphite are isoelectronic
(D) BN is non-conducting while graphite is conducting

*47. Which of the following statements are correct about syn gas?
(A) It is used in production of methanol
(B) On reaction with steam, composition of hydrogen changes
(C) It is used in oxo process
(D) It is a mixture of N 2 , CO and H 2

Revision Assignment 6 Inorganic Chemistry-I | JEE-2022

*48. Which of the following reactions are correct?
(A) B2 H 6  H 2O 
 H3BO3  H 2
(B) B2 H 6  MeOH 
 B(OMe)3  H 2
(C) B2 H 6  CH3  CH  CH 2 
 CH3  CH 2  CH 2  BH 2
(D) B2 H 6  O2 
 H3BO3  H 2

ether
*49. K 2Cr 2 O7  H 2SO 4  4H 2O 2   2X  K 2SO 4  5H 2O

4X  6H 2SO 4 
 2Y  6H 2O  7Z(g)
The correct statement(s) regarding the above equation:
(A) The oxidation state of central atom in X is +10 and has butterfly structure
(B) The oxidation state of central atom in Y is +3 and gas green colour
(C) Z is a colourless paramagnetic gas
(D) The oxidation state of central atom in X is +6 and has 2 peroxy linkages with butterfly like
structure
*50. Select the correct statement(s) about zeolites:
(A) They are formed by the replacement of some of the silicon atoms of the SiO 2 lattice by
aluminium
(B) They have a more closed structures than feldspar
(C) They can absorb CO2 , NH3 and EtOH
(D) They can separate straight chain hydrocarbon from a mixture of straight chain and branched
chain hydrocarbons

Paragraph for Q. 51 - 52

Pb3O 4 (red lead) on heating forms PbO and O 2 .

51. Pb3O 4 is insoluble in H 2SO4 forming:

(A) Paramagnetic coloured gas (B) Paramagnetic colourless gas
(C) Diamagnetic gas (D) No gas is evolved

52. Pb3O 4 reacts with HNO3 forming:

(A) Pb(NO3 ) 2 (B) PbO2
(C) Both (A) and (B) (D) None of these

Paragraph for Q. 53 - 54
electrolysis by
Brine solution 
Nelson method
 X(aq)  Y(g)  Z(g)
Y is a gas which disproportionates on passing through hot and concentrated solution of X. Z is a gas which
can be obtained by the action of solution of X on zinc.

53. The gas Z can be obtained by the action of concentrated solution of X on:
(A) P4 (B) Si (C) S (D) F2

54. In the reaction of Y with hot and concentrated solution of X, the equivalent weight of Y is ______.
(Molecular weight of Y is M)
(A) M/6 (B) M/2 (C) 3M / 5 (D) 5M / 3

Revision Assignment 7 Inorganic Chemistry-I | JEE-2022

Paragraph for Q. 55 - 56
Boron forms many compounds like boric acid, borax, inorganic graphite etc. Orthoboric acid contain
triangular BO33 units. In the solid the B(OH)3 units are hydrogen bonded together into 2-D sheets with
almost hexagonal symmetry. Borax is used in borax bead best.

55. The number of the H-atoms replaced from boric acid when it is dissolved in water is:
(A) 2 (B) 1 (C) 3 (D) Zero

56. Boric acid can behave as a strong acid in presence of:

(A) H 2SO4 (B) Glycerol (C) Mannitol (D) All of these

57. How many of the following compounds cleave diborane symmetrically?

CH3 NH 2 , (CH3 ) 2 NH, (CH 3 )3 N, CO, (CH3 ) 2 O, NH3 , C5 H5 N, THF, H 2O, R 3COH

58. The number of electron deficient bonds in Al2Cl6 is:

59. Four moles of NaNO3 when heated to 800°C, totally how many moles of paramagnetic gas
molecules liberated?
60. Find out total number of sp 2 hybridized boron and nitrogen atoms present in product formed on
reaction between borazine and HCl.
180C
61. 2BF3 (g)  6NaH  P(g)  Q(solid).
Find out maximum number of atom(s) that can lie in plane of covalent molecule 'P'.
62. Which of the following undergoes hydrolysis.
B2 H 6 , CaCl2 , AlF3 , AlCl3 , SnCl4 , NaF, K 2SiF6 , KN3 , NF3 , BF3

63. Which of the following hydrated salts on heating gives anhydrous salt.
gypsum, MgCl2  6H 2 O, LiCl  6H 2O, CaCl2  6H 2 O, ZnCl2  6H 2 O, AlCl3  6H 2O, FeCl3  6H 2O,
BaCl2  2H 2 O, washing soda, glauber's salt.

64. Match the matrix.

Column-I (Pair) Column-II (Correct for reaction)
(1) NaH  H 2 O 
 (p) Redox reaction
(2) Na 2O  H 2O 
 (q) Product H 2
(3) Na  H 2O 
 (r) Produce alkaline solution
(4) NaOH  H 2 O  Zn 
 (s) O 2 is not produced

(t)  M(OH)4 2 type ion is formed

65. Match the matrix.

Column-I Column-II
(1) Ca 2 Mg 5  (Si4 O11 )2  (OH) 2 (p) Cyclic silicate
(2) Mg 3 (OH)4 Si2 O5  (q) Chain silicate
(3) Ca 3Si3O9 (r) Each tetrahedron share two oxygen with
other tetrahedral
(4) LiAl  (SiO3 ) 2  (s) Sheet silicate
(t) Each tetrahedron share three oxygen atom
per tetrahedron with other tetrahedral

Revision Assignment 8 Inorganic Chemistry-I | JEE-2022

66. Match the matrix.
Column-I Column-II
(1) 0.2 mole H3BO3  0.1 mole NaOH(aq) 
 (p) Resulting product contain H3BO3
(2) Na 2 B4O 7 (s)  H 2O 
 solution (q) Alkaline solution
(3) K 3BO3 (limiting reagent)  H 2SO 4 
 (r)  B(OH)4  in solution
(4) B2 H 6  H 2O(excess) 
 (s) Volatile product
(t) Buffer solution

67. Match the matrix.

Column-I Column-II
(1) (NH 4 ) 2 CO3  NaOH 
 (p) Disproportion reaction
(2) Al  NaOH 
 (q) Gases product
(3) Na  H 2O 
 (r) Acidic solution
(4) NO 2  H 2 O 
 (s) Alkaline solution

68. Which of the nitrates on strong heating leaves the metal as the residue?
(A) AgNO3 (B) Pb(NO3)2 (C) Cu(NO3)2 (D) Al(NO3)3
69. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C).
Gas (C) on reaction with magnesium give compound(D) which on hydrolysis gives again gas (B).
Identify (B), (C) and (D).
(A) NH3 , N2 , Mg3 N 2 (B) N2 , NH3 , MgNH
(C) N2 , N 2O5 , Mg(NO3 ) 2 (D) NH3 , NO2 , Mg(NO2 )2

70.(B) A  H 2 O 
 B  HCl
B  H 2 O 
 C  HCl
Compound (A), (B) and (C) will be respectively:
(A) PCl5 , POCl3 , H3PO3 (B) PCl5 , POCl3 , H3PO4
(C) SOCl2 , POCl3 , H3PO3 (D) PCl3 , POCl3 , H3PO4
Paragraph for Q. 71 - 72

When 16.8 g of white solid (X) was heated 4.4 g of acid gas (A) that turned lime water milky was driven off
together with 1.8 g of a gas (B) which condensed to a colorless liquid. The solid that remained (Y) dissolved
in water to given an alkaline solution, which with excess of BaCl2, solution gave a white precipitate (Z). The
precipitate effloresces with acid giving off CO2 gas.

71. Compounds A and B are respectively:

(A) CO 2 and H 2 O (B) SO 2 and H 2 O
(C) CO 2 and N 2 O 4 (D) SO 2 and N 2 O 4

72. Compounds X and Y are respectively:

(A) Na 2 CO3  10H 2 O and Na 2 O
(B) KHCO3 and CO 2
(C) NaHCO 3 and Na 2 CO 3
(D) Na 2 CO3  NaHCO 3  1.5H 2 O and Na 2 CO3

Revision Assignment 9 Inorganic Chemistry-I | JEE-2022

73. Compound Z is:
(A) BaSO3 (B) BaSO4 (C) Ba(HCO3)2 (D) BaCO3

74. Find the number of molecules which are planar:

(a) ClF3 (b) SF6 (c) XeF6 (d) XeF2
(e) XeF4 (f) H 2O (g) H2S (h) NH3
(i) PH3 (j) PCl5 (k) PCl3 (l) OCl2

75.

Find the sum of number of p  p and p  d bonds in trimer of ‘C’.

Revision Assignment 10 Inorganic Chemistry-I | JEE-2022

 Answers to JEE Advanced-2022
Revision Assignment | Inorganic Chemistry-I
1 2 3 4 5 6 7 8
C B B AC BC ACD ABCD D
9 10 11 12 13
[A-p, q, r, s] [B-r, s, t] [C-p, t] [D-r, t] [A-p] [B-r] [C-q] [D-s] 6 5 4
14 15 16 17 18 19 20 21 22 23
5 3 3 4 5 10 10 CD ABCD D
24 25 26 27 28 29 30 31
C [A-q] [B-r, s] [C-s] [D-p] AB ABCD ABCD CD ACD AC
32 33 34 35 36 37 38 39 40 41
AD D B 6 6 4 50 ABD ABC ABD
42 43 44 45 46 47 48 49 50 51
AB ABC ABC ABCD ACD ABC AC BCD ACD B
52 53 54 55 56 57 58 59 60 61
C B C D D 6 0 5 0 6
62 63 64 65
7 4 [1-q, r, s] [2-r, s] [3-p, q, r, s] [4-p, q, p, s, t] [1-q] [2-s, t] [3-p, r] [4-q, r]
66 67 68 69
[1-p, q, r, t] [2-p, q, r, t] [3-p] [4-p, r, s] [1-q, s] [2-q, s] [3-q, s] [4-r, p] A A
70 71 72 73 74 75
B A C D 6 6

Revision Assignment 11 Inorganic Chemistry-I | JEE-2022