Sodium Oxalate

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SAFETY DATA SHEET

1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY


Catalogue No. : S 16029
Product Name : SODIUM OXALATE

Manufacturer/supplier identification
Company : NICE Chemicals (P) Ltd., Cochin, India
Tel - 0484 2800212, 2802755

Contact for information : Tel. No.- 0484 2802536 Fax : 0484 2802483
Emergency Telephone No. : 0484 2801583 Tele fax No. : 0484 2802483

2. COMPOSITION/INFORMATION ON INGREDIENTS

CAS-No : 62-76-0 Ec-Index No. : 607-007-00-3


Molar Mass : 134.01 EC-No. : 200-550-3
Molecular formula : (COONa) 2

3. HAZARDS INDEX

Harmful in contact with skin and if swallowed.

4. FIRST AID MEASURES : After inhalation : Fresh air.


After skin contact : Wash off with plenty of water. Remove contaminated clothing.
After eye contact : Rinse out with plenty of water, with the eyelid held wide open.
After swallowing : Make victim drink plenty of water, induce vomiting,
summon doctor.

5. FIRE-FIGHTING MEASURES : Suitable extinguishing media : In adaption to materials stored in the


immediate neighbourhood.
Special risks : Not known to date.
Other information : Non-combustible.

6. ACCIDENTAL RELEASE MEASURES

Person-related precautionary measures: Avoid generation of dusts; do not inhale dusts.


Procedures for cleaning/absorption : Take up dry. Forward for disposal.
Clean up affected area.

7. HANDLING AND STORAGE : Handling : No further requirements.


Storage : Tightly closed. Dry.
Storage temperature : No restrictions.

8. EXPOSURE CONTROL/ PERSONAL PROTECTION

Respiratory protection : Required when dusts are generated.


Eye protection : Required
Hand protection : Required
Industrial hygiene : Change contaminated clothing.
Wash after working with substance.
9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquid
SAFETY DATA SHEET
Catalogue No. : S 16029
Product Name : SODIUM OXALATE

Colour : White
Odour : Odourless
pH value at 30gm/lt.H2O(20o C) : ~8
Melting temperature : Not available
Boiling temperature : 250 - 270 o C (decomposition)
Ignition temperature : Not available
Flash Point : Not available
Explosion limit lower : Not available
upper : Not available
Relative vapour density : Not available
Density : Not available
Bulk Density : ~600 km/m 3
Solubility in Water (20 o C) : 37 gm/lt.
Water (100 o C) : 63 gm/lt.

10. STABILITY & REACTIVITY : Conditions to be avoided : Strong heating


Substances to be avoided : Not known to date
Hazardous decomposition products : Not known to date

11. TOXICOLOGICAL INFORMATION: Acute toxicity : LD50 (oral, rat) : 7500 mg/kg(calculated on the free acid)

Further toxicological information :


After inhalation of dust : Mucosal irritations.
After skin contact : Danger of skin absorption.
After eye contact : Slight irritation symptoms.

The following applies to oxalates in general : nausea and vomiting after swallowing.
Mucosal irritations, coughing & dyspnoea after inhalation. Systemic effect : drop in
the blood calcium level,toxic effect on kidneys, cardiovascular disorders.

Further data :
The product should be handled with the care usual when dealing with chemicals.

12. ECOLOGICAL INFORMATION : Biologic degradation : Oxalic Acid; Biodegradable.

Ecotoxic effects :
Quantitative data on the ecological effect of this product are not available.

13. DISPOSAL METHOD

There are no uniform EC Regulations for the disposal of chemicals or residues.


Chemical residues generally count as special waste. The disposal of the latter is
regulated in the EC member countries through corresponding laws and regulations.
We recommend that you contact either the authorities in charge or approved waste
disposal companies which will advise you on how to dispose of special waste.

Disposal in compliance with official regulations. Handle contaminated packaging


in the same way as the substance itself. If not officially specified differently, non-
contaminated packaging may be treated like household waste or recycled.
SAFETY DATA SHEET
Catalogue No. : S 16029
Product Name : SODIUM OXALATE

14. TRANSPORT INFORMATION : GGVS/GGVE class : 6.1 Number and letter : 35c
Transport over land ADR/RID class : 6.1 Number and letter : 35c
ADR/RID and GGVS/GGVE : Name of material : SODIUM OXALATE

Sea Transport IMDG : IMDG class : 6.1 UN No. : 3282 Packing group : III
Ems : 6.1 - 04 MFAG : 4.2
Correct Technical Name : SODIUM OXALATE

Air Transport ICAO-TI ICAO/IATA class : 6.1 UN No. : 3282 Packaging group : III
and IATA-DGR : Correct Technical Name : SODIUM OXALATE

15. REGULATORY INFORMATION :

Labeling according to EC Directives

Symbol : Xn Harmful

R-phrases : 21/22 Harmful in contact with skin and if swallowed.

S-phrases : 24/25 Avoid contact with skin and eyes.

EC-No. : 200-550-3 EC label

Water pollution class : 1 (slightly polluting substance)

16. OTHER INFORMATION

Reason for alteration

Change in transport classification


General update.

The information contained herein is based on the present state of our knowledge.
It characterises the product with regard to the appropriate safety precautions. It
does not represent a guarantee of the properties of the product.

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