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Experimental Study of the Analysis Method for Paste Content in the Waste Concrete

Donghee An*, Hyunkook Choi, and Jaeyoung Kim


SungShin Cement Research and Development, 48-37, Bugangoecheon-ro, Bugang-myeon, Sejong-si, Republic of Korea
*anzilda@sscem.com

1. Introduction between the measure values of CaO with cement


pastes contents in mortars (Fig.1).
The greatest amount of waste that occurs during For three type of sand, ignition loss of mortar at
the dissolution of nuclear power plants is concrete. In 600ଇ showed few differences but the good
the concrete of the radioactive elements of the relationship for cement paste content (Fig.2).
cement paste is present in most cases, separating the
parts of the aggregate, a radioactive concrete waste Table 1. XRF analysis of Sand
volume can be greatly reduced. Chemical Composition(%)
Sand
The purpose of this study is to obtain the basic No
Type CaO SiO2 Al2O3
data necessary for developing a method of effectively
1 ISO 0.1 97.7 0.6
Solidifying cement paste separating the aggregate
2 Crushed 0.9 80.5 7.6
from the waste concrete and finding a method for
3 Sea 2.9 70.4 12.1
inferring the paste content of the waste concrete.

Table 2. Test results for mixtures (paste, sand)


2. Experiments
Mixture
Results(wt.%)
ratio(%)
2.1 Materials No Type
Ignition
Paste Sand CaO
Loss
The cement paste was made W/C = 0.40 and cured 1 - 100 0.1 0.1
for 3 months in room temperature. After cured, the 2 20 80 9.6 2.5
paste was crushed to several millimeters using jaw- 3 ISO 40 60 21.7 5.1
Standard
crusher. And they were dried at 100ଇ to remove 4 Sand 60 40 36.1 7.7
moistures. Dried powers were mixed with three types 5 80 20 49.5 10.5
of sand up to 100wt.% each 20% at a constant 6 100 - 70.8 13.0
ratio(ISO standard sand, Crushed sand, Sea sand). 7 - 100 0.9 0.4
8 20 80 10.8 2.8
2.2 Experiment Methods and Items 9 Crushed 40 60 23.7 5.4
10 Sand 60 40 34.5 7.9
In order to get the reference guide for a portion of 11 80 20 51.0 10.5
cement paste in a mortar, we use X-ray fluorescence 12 100 - 70.8 13.2
analysis method (XRF, Rigaku, Japan, ZSX Primus 13 - 100 2.9 0.6
II) and measurements of loss on ignition at 600ଇ for 14 20 80 14.4 3.0
90 min. using the electric furnace. 15 Sea 40 60 24.1 5.5
To estimate cement pastes contents in the mortar, 16 Sand 60 40 39.5 8.0
we used CaO content which get from XRF analysis 17 80 20 55.5 10.5
results and weight loss of mixtures. 18 100 - 70.8 13.2

2.3 Result of Paste Content calculation The result according to CaO contents of XRF
analysis or weight loss of mixtures at 600ଇ, we
The results of the XRF analysis for the sand and found to predict approximate contents of cement
mixtures are shown in table 1~2. XRF analysis paste in the recycled concrete is possible. And this
results showed that there is a good relationship method will be useful to solidifying process concrete

2019 ⦽ǎႊᔍᖒ⠱ʑྜྷ⦺⫭ ⇹ĥ⦺ᚁ‫ྙם ⫭ݡ‬᫵᧞Ḳ 231


waste from decommissioning a nuclear plant. If we solidification process for concrete waste that occurs
know cement paste contents in concrete waste, during the dissolution of nuclear power plants,
solidified concrete waste would be made more safe solidifications would be more safe and durable.
and durable by control portions of mixtures(waste,
solidifying agent and water etc.) ACKNOWLEDGEMENT

This work was supported by the Energy Technology


Program of the Korea Institute of Energy Technology
Evaluation and Planning(KETEP) granted financial
resource from the Ministry of Trade, Industry &
Energy, Republic of Korea (No. 20161510300420)

REFERENCES

[1] Jang Jong-+R ³$ 6WXG\ RQ WKH )XQGDPHQWDO


Properties and Application as Cementious
Admixture by heating Temperature of Recycled
3RZGHU´3URFHHGLQJRI.RUHD&RQFUHWH,QVWLWXWH
Fig. 1. Analysis of CaO contents of mixtures. May 12, 635-40 (2001).
>@ $KQ -& /HH -+ .DQJ %+ ³3URSHUWLHV RI
Recycle Cement made of Cementitious Powder
from Concrete Waste by Conditions of BurQLQJ´
Journal of Architectural Institute of Korea,
Nov,19(11):109-12 (2013).
>@ 0XQ <% &KRL +. ³$ )XQGDPHQWDO 6WXG\ IRU
Development of Radioactive Waste Content and
Solidifying During the Dissolution of Concrete in
'HFRPPLVVLRQLQJ 1XFOHDU 3RZHU 3ODQW´ Journal
of the Korean Radioactive Waste Society,
Vol.2018 No.05, 295-296.

Fig. 2. Analysis of Ignition Loss of mixtures.

3. Discussion and Conclusion

In this study, we used cement paste cured for 3


months and maybe there are some differences in
periods of curing time for cement pastes. Therefore it
should be considered that periods of curing time
could effect on the results of analysis. To make sure
this, we prepared specimens cured for 12 months or
more, and we will carry same research to get more
data.
Fig. 1 and Fig. 2 show there are good relationship
CaO contents get from XRF analysis data or weight
loss of mortar at 600ଇ with cement paste content in
the mixtures. Therefore, if we use these analysis
methods to estimate approximate cement paste
contents in a mortar and apply obtained data in the

232 2019 ⦽ǎႊᔍᖒ⠱ʑྜྷ⦺⫭ ⇹ĥ⦺ᚁ‫ྙם ⫭ݡ‬᫵᧞Ḳ

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