BSC Chemistry

B. Sc.
Chemistry
Syllabus
AFFILIATED COLLEGES
Program Code: 22D
2021 – 2022 onwards
BHARATHIAR UNIVERSITY
(A State University, Accredited with “A” Grade by NAAC,
Ranked 13th among Indian Universities by MHRD-NIRF,
World Ranking: Times -801-1000,Shanghai -901-1000, URAP - 982)
Coimbatore - 641 046, Tamil Nadu, India
B. Sc. Chemistry 2021-22 onwards - Affiliated Colleges - Annexure No.20(a)
SCAA DATED: 23.06.2021
Program Educational Objectives (PEOs)

The B. Sc. Chemistry program describe accomplishments that graduates are
expected to attain within five to seven years after graduation
To produce efficient chemistry graduates with strong fundamentals in
PEO1
various fields of chemistry
To make students capable to assess and relate issues to environmental and
PEO2
practice it with integrity and ethics
To provide an in-depth knowledge in chemistry and enable them with tools
PEO3
needed for industrial applications
To integrate the inter-disciplinary knowledge of physics, mathematics or
PEO4
biological sciences to wide variety of fields
To develop the ability to communicate the scientific information in written
PEO5
and oral formats
To inculcate leadership qualities and mold them as good team players to
PEO6
function effectively in multidisciplinary teams
Page 1 of 74
Program Specific Outcomes (PSOs)

After the successful completion of B. Sc. Chemistry program, the students are
expected to
PSO1 Apply chemistry knowledge to solve the problems in various areas.
PSO2 Acquire a skill for safe handling of chemicals, apparatus and instruments
Identify and analyze problems and gain skills to interpret chemical

PSO3
information
Gain practical knowledge and analytical skills in designing and carrying

PSO4
out chemical experiments
Have enough chemistry knowledge to go for higher studies and become

PSO5
entrepreneur
Page 2 of 74
Program Outcomes (POs)

On successful completion of the B. Sc. Chemistry program
Understand the chemistry and apply their knowledge in day-to-day
PO1
life
Explore the knowledge of analytical techniques to the industries for
PO2
various analysis
PO3 Develop skills to carry out experiments in various fields of chemistry
Identify, formulate and solve the technological problems of the
PO4
industry
Apply their theoretical knowledge to make the common people to
PO5
understand the chemistry behind every chemical changes.
Confidence with skills and techniques necessary to succeed in the
PO6
competitive examinations
Have the knowledge of science principles to practical situations in
PO7
their respective professional career.
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BHARATHIAR UNIVERSITY: COIMBATORE 641 046

B. Sc. Chemistry – Revised Scheme of Examinations (CBCS Pattern)
(For the students admitted during the academic year 2021 – 22 onwards)
Examination
Hours/
Part Title of the Course Duration Maximum Marks Credits
Week
in Hours CIA CEE Total
Semester I
I Language - I 6 3 50 50 100 4
II English - I 6 3 50 50 100 4
III Core Paper I – General Chemistry - I 7 3 50 50 100 4
III Core Practical I (Inorganic Qualitative - - - -
3 3
Analysis)
Allied A: Paper I# (or) 6 3 50 50 100 4
III
Allied A: Paper I@ 4 3 30 45 75 3
III Allied A: Practical@ 2 - - - - -
IV Environmental Studies* 2 3 - 50 50 2
Total 30 180 245 425 17
Semester II
I Language – II 6 3 50 50 100 4
II English – II 6 3 50 50 100 4
III Core Paper II – General Chemistry - II 7 3 50 50 100 4
III Core Practical I (Inorganic Qualitative 50 50 100 4
3 3
Analysis)
Allied A: Paper II# (or) 6 3 50 50 100 4
III
Allied A: Paper II@ 4 3 30 45 75 3
III Allied A: Practical@ 2 3 25 25 50 2
IV Value Education – Human Rights* 2 3 - 50 50 2
Total 30 255 320 575 23
Semester III
I Language – III 6 3 50 50 100 4
II English – III 6 3 50 50 100 4
III Core Paper III – Inorganic Chemistry - I 3 3 50 50 100 4
III Core Paper IV – Physical Chemistry - I 3 3 50 50 100 4
Allied B: Paper I# (or) 6 3 50 50 100 4
III
Allied B: Paper I@ 4 3 30 45 75 3
III Core Practical II (Volumetric and
2 - - - - -
Organic Analysis)
III Allied B: Practical@ 2 - - - - -
IV Skill based Subject 1: Chemistry of
2 3 30 45 75 3
Natural and Synthetic Fibers
IV Tamil** / Advanced Tamil* (OR) Non-
major elective - I (Yoga for Human 2 3 - 50 50 2
Excellence)* / Women’s Rights*
Total 30 260 340 600 24
Page 4 of 74
Semester IV
I Language – IV 6 3 50 50 100 4
II English – IV 6 3 50 50 100 4
III Core Paper V – Organic Chemistry - I 4 3 50 50 100 4
III Core Practical II (Volumetric and
3 6 50 50 100 4
Organic Analysis)
Allied B: Paper II# 6 3 50 50 100 4
III
Allied B: Paper II@ 4 3 30 45 75 3
III Allied B: Practical@ 2 3 25 25 50 2
IV Skill based Subject 2: Technology of
3 3 30 45 75 3
Dyeing of Natural Fibers
IV Tamil**/Advanced Tamil* (OR)
Non-major elective -II (General 2 3 - 50 50 2
Awareness*)
Total 30 285 365 650 26
Semester V
III Core Paper VI (Inorganic Chemistry
5 3 50 50 100 4
II)
III Core Paper VII (Spectroscopy) 5 3 50 50 100 4
III Core Paper VIII (Electrochemistry) 5 3 50 50 100 4
III Core Paper IX (Analytical Chemistry) 4 3 50 50 100 4
III Core Practical III (Gravimetric And
4 - - - - -
Physical)
III Elective I 4 3 50 50 100 4
IV Skill based Subject 3: Water &
Effluent Treatment And Pollution 3 3 30 45 75 3
Control
Total 30 280 295 575 23
Semester VI
III Core Paper X (Organic Chemistry II) 5 3 50 50 100 4
III Core Paper XI (Physical Chemistry II) 5 3 50 50 100 4
III Core Practical III (Gravimetric And
7 7 50 50 100 4
Physical)
III Elective II 4 3 30 45 75 3
III Elective III 4 3 30 45 75 3
III Core Practical for Elective Subjects 3 3 50 50 100 4
IV Skill Based Subject 4:
2 3 30 45 75 3
(Textile Chemistry Practical)
V Extension Activities** - - 50 - 50 2
Total 30 340 335 675 27
Grand Total 180 1600 1900 3500 140
Note
#
For subjects without practical.
@
For subjects with practical.
* No Continuous Internal Assessment (CIA). Only University Examinations.
** No University Examinations. Only Continuous Internal Assessment (CIA).
Page 5 of 74
Allied Subjects(Colleges can choose any two subjects)

1. Mathematics, 2. Physics, 3. Botany, 4. Zoology, 5. Biochemistry
List of Elective papers
(Colleges can choose any one of the paper as electives)
A Polymer Chemistry
B Agro Industrial Chemistry
Elective – I
C Pharmaceutical Chemistry
A Leather Chemistry
Elective – II B Chemistry of Plant Based Products
C Dye Chemistry
A Analytical Chemistry II Lab Techniques
Elective – III B Environmental Chemistry
C Textile Chemistry
Page 6 of 74
First
Semester
Page 7 of 74
Course code 13A GENERAL CHEMISTRY - I L T P C

CORE Core I – Paper - I 6 1 - 4
Syllabus 2019-
Pre-requisite Higher Secondary Level Chemistry
Version 2020
Course Objectives:
The main objectives of this course are to:
1. Explain the properties of periodic table and bonding theories
2. Outline the reactivity of alkenes and alkynes and conformation of alkanes
3. Describe the laws of thermodynamics and black body radiation
Expected Course Outcomes:

On the successful completion of the course, student will be able to:
1 Understand the properties of period and groups in periodic table K1, K2
2 Able to name the hydrocarbons and Identify the products of elimination and K2-K4
addition reactions.
3 Discuss the various polar effects in alkanes and alkenes. Describe the K1-K3
preparation of cycloalkanes
4 Explain the theory of black body radiation K1, K2
5 Understand the first and second law of thermodynamics K1, K2
K1 - Remember; K2 - Understand; K3 - Apply; K4 - Analyze; K5 - Evaluate; K6 - Create
Unit:1 Periodic Properties and Theory of Bonding 21 hours

1. Periodic table-Introduction-Periodic properties- Ionisation energy, Electron affinity,
Electronegativity and their variations along the period and groups.
2. Hybridization and geometry of BeCl2, BF3, CH4, PCl5, IF7 and SF6. VSEPR Theory. Covalent
Bond-Molecular orbital theory-application to molecules such as H2+ He2, F2, O2, N2, CO and NO.
Unit:2 Reaction of Alkenes and Alkynes 21 hours

1. Nomenclature of acyclic alkane, alkene and alkyne.
2. Alkenes: Preparation by Wittig reaction – Mechanisms of beta elimination – E1, E2 and cis
elimination – Hoffmann’s rule and Saytzeff’s rule. Addition reactions with hydrogen, halogen,
hydrogen halide (Markownikoff’s rule) and hydrogen bromide (Peroxide effect). Dienes:
Stability of isolated and conjugated dienes-1, 2 and 1, 4 additions, Diels -Alder reaction. Free
Radical addition – Polymerization – synthetic rubber.
3. Alkynes: Acidity of Alkynes – formation of acetylides-addition of water with HgSO4 catalyst-
hydroboration.
Unit:3 Polar Effects and Conformations of Alkanes 21 hours

1. Polar effects – inductive effect, mesomeric effect, electromeric effect, hyper conjugation and
steric effects. Classification of reagents: Electrophiles, Nucleophiles and Free radicals. Types of
reaction: Polar reactions involving carbonium ions and carbanions with simple examples.
2. Aliphatic Hydrocarbons: Restricted rotation about single bond preferred rotational
conformations.
3. Cycloalkanes: Preparation by Dieckmann ring closure and by reduction of aromatic
hydrocarbons – ring opening reactions of cyclopropane with H2, Br2 and HI.
Page 8 of 74
Unit:4 Liquid Crystals and Black Body Radiation 21 hours

1. Liquid crystals–the concept of mesomorphic state-typical liquid crystalline substances and
their properties.
2. Failure of classical theory in explaining black body radiation- Planck’s theory of quantization
of energy – Einstein’s theory of photoelectric effect-Compton effect. de-Broglie theory of wave-
particle dualism. Particle in one dimensional box (Wave length determination only) -
Schrodinger equation.
Unit:5 Laws of Thermodynamics 21 hours

The laws of thermodynamics, generalities and Zeroth law – kinds of energy – Scope of the first
and second laws of thermodynamics-thermodynamic terms-definitions – heat – work of
expansion – work of compression – maximum and minimum quantities of work – Reversible
and irreversible transformations of energy. First law of thermodynamics – properties of energy
changes in relation to properties of system- isothermal and adiabatic changes – meaning of the
thermodynamic state function – properties of exact and inexact differentials – Joule Thomson
experiment.
Total Lecture hours 105 hours

Text Book(s)
1 Principles of Inorganic Chemistry, B.R. Puri L.R. Sharma, S.Chand& Co.
2 Inorganic Chemistry, P.L.Soni, Sultan Chand & Sons.
3 Organic Chemistry, Vol. 1, 2 & 3, S. M. Mughergee, S.P. Singh, R.P. Kapoor, Wiley
Eastern.
Reference Books
1 Advanced Organic Chemistry, B.S. Bahl, Arunbahl, S.Chand & Co.
2 Essentials of Physical Chemistry, B.S. Bahl and G.D. Tuli, S.Chand & Co.
3 Text book of Physical Chemistry, P.L.Soni, D.B. Dharmarke, S.Chand & Co.
4 Principles of Physical Chemistry, B.R.Puri, L.R.Sharma and M.S.Phathania, S.Chand &
Co.
Related Online Contents [MOOC, SWAYAM, NPTEL, Websites etc.]
1 https://nptel.ac.in/content/storage2/courses/104101005/downloads/LectureNotes/chapter
%207.pdf
2 https://www.youtube.com/watch?v=4LQ8jdKZTEo
3 https://www.khanacademy.org/science/organic-chemistry/bond-line-structures-alkanes-
cycloalkanes/conformations-alkanes-cycloalkanes/v/conformational-analysis-of-ethane
Course Designed By: Dr. S. P. Rajasingh
Mapping with Programme Outcomes

Cos PO1 PO2 PO3 PO4 PO5 PO6 PO7
CO1 S M M S S S S
CO2 M M M M S S M
CO3 M M S S S M M
CO4 S M S S M S S
CO5 S S M S S S M
*S-Strong; M-Medium; L-Low
Page 9 of 74
Second
Semester
Page 10 of 74
Course code 23A GENERAL CHEMISTRY - II L T P C

CORE Core II – Paper - II 6 1 - 4
Syllabus 2019-
Version 2020
Course Objectives:
1. Outline the fundamentals of volumetric estimations
2. Explain electrophilic and nucleophilic substitution reactions
3. Describe the application of boron and silicate chemistry
4. Discuss thermodynamics and solid state chemistry

1 Understand the principles of volumetric analysis and estimate an unknown K1, K2
ion
2 Outline the structure and properties of boron and silicate compounds K1, K2
3 Explain the aromatic electrophilic substitution and aliphatic nucleophilic K2-K4
substitution reactions with mechanism
4 Understand the relation between thermodynamic properties K1-K3
5 Understand the packing and structure of crystals K1, K2
Unit:1 Volumetric Analysis and Redox Reactions 21 hours

1.Principles of Volumetric Analysis: Terms used in volumetric analysis, primary and
secondary standard substances, standardization of solutions.
2. Concentration units: ppm, molality, formality, molarity, mole fraction, normality, weight
percent and volume percent. Determination of equivalent weight of acids, bases, oxidant, reductant
and simple salts. Types of volumetric titrations, acid-base, redox, precipitation and
complexometric titrations.
3. Indicators: Effect of change in pH, neutralization, redox, adsorption and metal ion indicators.
4. Oxidation and reduction reactions: balancing redox equations by oxidation number and ion-
electron method.
Unit:2 Boron and Silicates 21 hours

Chemistry of Boron family – Group discussion – Electron acceptor behaviour and electron
deficiency of boron hydrides; bonding in diboranes; NaBH4 and borazole - preparation,
properties, structure and uses. Silicates-Classification of silicate- simple silicates, chain silicates
and sheet silicates only.
Unit:3 Electrophilic and Nucleophilic Substitution 21 hours

Structure of benzene-Aromaticty-Huckel’srule. Electrophilic substitution in benzene with
mechanism - Nucleophilic substitution reaction – SN1, SN2 and SNi reactions – Grignard reagent
and synthetic applications-Elimination versus substitution-Benzyne mechanism and
intermediate complex mechanism.
Page 11 of 74
Unit:4 Thermodynamics 21 hours

Relation between E and H, CP and Cv. The heat of reaction – conventions in the values of H.
Hess’s law – heats of combustion – determination by Bomb Calorimeter – Bond energies –
Resonance energies – Heats of solution – integral and differential heat of dilution – Heats of
reaction at constant volume – dependence of the heat of reaction on temperature and Kirchoff’s
equation.
Unit:5 Solid State Chemistry 21 hours

Crystalline and amorphous solids, crystal systems, Bravis lattice, unit cell, law of rational indices
(Weiss indices), Miller indices, Symmetry elements in crystals (for cubic system only). X-ray
diffraction by crystals - derivation of Bragg’s equation - Bragg method - powder method. Crystal
structure of NaCl, Wurzite, CaF2 and TiO2- radius ratio rules and packing in crystals.

Text Book(s)
1 Principles of Inorganic Chemistry, B.R. Puri L.R. Sharma, S.Chand& Co.
2 Text book of Physical Chemistry, P.L.Soni, D.B. Dharmarke, S.Chand& Co.
3 Essentials of Physical Chemistry, B.S. Bahl and G.D. Tuli, S.Chand& Co.
Reference Books
2 Advanced Organic Chemistry, B.S. Bahl, ArunBahl, S.Chand& Co.
3 Physical chemistry, G. N. Castellan, Addison- Wesley Pub. Co.
1 https://web.iit.edu/sites/web/files/departments/academic-affairs/academic-resource-
center/pdfs/SN1_SN2.pdf
2 https://nptel.ac.in/content/storage2/courses/104101005/downloads/LectureNotes/chapter%20
9.pdf
Course Designed By: Dr. M. Sivakumar

COs PO1 PO2 PO3 PO4 PO5 PO6 PO7
CO1 S M M S S S S
CO2 M M M M S S M
CO3 M M S S S M M
CO4 S M S S M S S
CO5 S S M S S S M
Page 12 of 74
INORGANIC QUALITATIVE
Course code 23P L T P C
ANALYSIS
CORE CORE III - CHEMISTRY PRACTICAL I - - 3 4
Higher Secondary Level Practical Syllabus 2010-
Pre-requisite
Knowledge Version 2011
Course Objectives:
1. Impart knowledge to the students in handling laboratory equipment and reagents
2. Improve the skill of inorganic mixture analysis.
3. Make the students to analyze and identify the cations and anions in the mixture of salts.

1 Do preliminary tests and identify interfering and non-interfering K1-K5
radicals and confirm their presence
2 Remove interfering anions, carry out a systematic analysis and identify K1-K5
the cations in a given sample
Part I ANALYSIS OF CATIONS 45 hours

CATIONS TO BE STUDIED: Lead, Copper, Bismuth, Cadmium, Iron, Aluminum, Zinc,
Manganese, Cobalt, Nickel, Barium, Calcium, Strontium, Magnesium and Ammonium.
Part II ANALYSIS OF ANIONS 45 hours
ANION TO BE STUDIED: Carbonate, Sulphate, Nitrate, Chloride, Bromide, Fluoride, Borate,
Oxalate, and Phosphate.
Total Practical hours 90 hours

Text Book(s)
1 Basic Principles of Practical Chemistry, Kulandaivelu A.R., Veeraswamy
R., Venkateswaran, Sultan Chand & Sons, 2017.
2 Practical Chemistry for B.Sc Chemistry, A.O. Thomas
Reference Books
1 A Text Book of Qualitative Analysis including semi-micro methods, A.I.Vogel.
1 https://www.youtube.com/watch?v=O9ba90MJws0
2 https://www.youtube.com/watch?v=oz1LNl90SSU
3 https://www.youtube.com/watch?v=QQo1e-BUZWs

CO1 M S S M S M S
CO2 S M S S M S S
Page 13 of 74
Third
Semester
Page 14 of 74
Course code 33A INORGANIC CHEMISTRY - I L T P C

CORE Core IV – Paper III 3 - - 4
Syllabus 2020-
Version 2021
Course Objectives:
1. Explains the fundamental concepts involved metallurgical process for extraction of
metals.
2. Discuss the theories and stability of metal complexes.
3. Outline the importance of organometallic compounds and their catalytic applications.
4. Describe the structure & functioning of biomolecules and role of metals in biology

1 Explain various chemical and electrochemical principles involved in the
K1,K3
extraction of metals.
2 Make use of the occurrence and extraction of important metals and their
K2,K3
compounds
3 Outline the importance of solvents and solubility in chemical reactions K2
4 Define and classify the structure and properties of organometallic
K1-K3
compounds
5 Describe the structure & functioning of biomolecules and role of metals in
K1,K2
biology
Unit:1 Methods of Extraction 9 hours

General methods of Extraction: Concentration – Gravity separation, Froth Flotation, magnetic
separation, Extraction – Chemical and Electrolytic methods of refining, Zone refining, Van
Arkel refining and Electrolytic refining with examples. Occurrence, extraction, properties and
uses of Germanium and Titanium and their important compounds such GeCl4 and TiO2.
Unit:2 Extraction of Metals and Their Compounds 9 hours

Occurrence, extraction, properties and uses of Zirconium, Vanadium, Molybdenum and
Tungsten - their important compounds such as V2O5, ZrOCl2, (NH4)2MoO4, WO2, and
tungsten bronzes.
Unit:3 Role of Solvents 9 hours

The solvents- solubility of compounds – effect of temperature on solubility – Role of water as
solvent- chemical structure and solubility. Classifications of solvents – general behaviour –
properties of ionizing solvents. Types of reactions in non-aqueous solvents – protonic solvents
– ammonia, hydrogen fluoride. Non Protonic solvents-SO2 and BrF3. Organic solvents –
C2H5OH and Ether.
Page 15 of 74
Unit:4 Organometallic Compounds 9 hours

Definition – Nomenclature of Organometallic compounds – Synthesis of organometallic
compounds of Be, Mg, Zn, B and Al – Ferrocene: Preparation – Aromaticity of: Ferrocene,
cyclic CnHn Ligands – Application of: Grignard reagent and Gilman Reagent - alkene
polymerization using Ziegler-Natta catalyst.
Unit:5 Bioinorganic Chemistry 9 hours

Importance of metals in biological systems – chemistry of hemoglobin and myoglobin – Role
of: Na+ and K+ ions – Mg2+ and Ca2+ ions – Biological functions and toxicity of trace elements:
Cr, Mn, Co, Ni and Cu – Ultra trace elements: As, Se, Mo, I, Fe and Zn – Biological fixation
of nitrogen – Metallo-enzymes: Carbonic anhydrase, Carboxy peptidase.

Text Book(s)
1 Principles of Inorganic Chemistry, B.R. Puri L.R. Sharma, S.Chand & Co.
2 Principles of Inorganic Chemistry, B.R. Puri, L.R. Sharma and K.C. Kalia, , Milestone
Publishers (2012)
Reference Books
1 Huheey, J. E.; Keiter, E. A.; Keiter, R. L. Inorganic Chemistry, Principles of Structure
and Reactivity, 4th ed., Harper Collins, 1993.
2 Lee. J.D, Concise Inorganic chemistry, V edition, Chapman & Hall Ltd, London ,2000
3 Shriver, D. F.; Atkins, P. W.; Langford, C. H. Inorganic Chemistry, 3rd ed., Oxford
University Press, 2000.
4 Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic
Chemistry, 6th ed., John Wiley, 1999.

1 https://nptel.ac.in/content/storage2/courses/104101005/downloads/LectureNotes/chapter
%207.pdf
2 https://youtu.be/BZ_tY88o0oI, Co-ordination chemistry, IIT Kharagpur, Prof. D. RaY.
3 https://youtu.be/FziKko-ZQww for bioinorganic chemistry.
Course Designed By: Dr. S. P. Rajasingh and Dr. P. Rajesh

CO1 M S S S S S S
CO2 M M S M S M S
CO3 S M S M S S S
CO4 S M M M M S S
CO5 S M M M S S S
Page 16 of 74
Course code 33B PHYSICAL CHEMISTRY - I L T P C

CORE Core V – Paper IV 3 - - 4
Syllabus 2020-
Pre-requisite Basics of Physical Chemistry
Version 2021
Course Objectives:
1. Enable the students in understanding the second and third law of thermodynamics
2. Explain various system in phase rule and their application
3. Application of the computer C programming in chemistry

Understand the concepts of thermodynamics, Second law, and Entropy K1, K2
1 change.
Understand the Spontaneity and its conditions, Gibb’s free energy and K2, K3
2 knowledge of third law.
Understand the concepts of Phase rule and its applications to various K2 -K4
3 systems.
4 Know the different laws of solutions and evaluate the Colligative properties K3, K5
5 Understand the C-Program and evaluate the various parameters. K2, K5
Unit:1 Thermodynamics I 9 hours

Need of second law of thermodynamics – Carnot cycle – entropy – Definition – Entropy
changes in isothermal transformation –Trouton’s rule. Entropy as function of T and V –
Entropy as a function of T and P – Changes of entropy with T, Entropy changes in ideal gas –
entropy of mixing of ideal gases.
Unit:2 Thermodynamics II 9 hours

General conditions of equilibrium and spontaneity - conditions of equilibrium and
spontaneity– definition of A and G – physical significance of dA and dG - Temperature and
pressure dependence of G – Gibbs – Helmholtz equation. Chemical equilibrium – The concept
of chemical potential – chemical potential in a mixture of ideal gases – Van’t Hoff Isotherm,
and isochore – Third law of thermodynamics – statement and applications - Exception to third
law.
Unit:3 Phase Rule 9 hours

Phase equilibria – equilibrium condition - Stability of phase of a pure substance – Pressure
dependence of μ and T curves. The Clapeyron and Clapeyron-Clausius equations. Derivation
of Gibbs phase rule. Phase equilibria in one component system – Water and Sulphur systems.
Reduced phase rule – Phase diagram for two component system – construction of the phase
diagram-Thermal analysis method – Phase Diagram of Simple eutectic systems: Pb-Ag
System - extraction of Silver from Argentiferous Lead, Compound forming type – Congruent
melting point: Zn-Mg, Incongruent melting point: Na-K systems.
Page 17 of 74
Unit:4 Solutions 9 hours

Ideal and non-ideal – Raoult’s law- Positive and negative deviation Henry’s law – Nernst
distribution law and its applications. Colligative properties - relative lowering of vapour
pressure, elevation of boiling point, depression of freezing point and osmotic pressure- their
applications.
Unit:5 C Program for Chemistry 9 hours

Structure of C program, Variables in C, Keywords and constants in C, Operators in C –
Arithmetic, Increment, Decrement, relational and logical operators - Program: To calculate the
pH of solutions– Calculation of pH of solution using Henderson equation- to compute the rate
constant of a first order reaction – to compute half-life period of a reaction – to compute the
energy of activation of a reaction.

Text Book(s)
1 Principles of physical chemistry, B.P. Puri, L.R. Sharma and M.S. Phathania,
S.Chand& Company
2 Physical chemistry G,W.Castelan, Narosa Publishers.
3 Physical chemistry (Vol.ll) – N.B.Singh, ShivasaranDas, A.K.Singh – New Age
International Publishers – First edition (2009)
Reference Books
1 Elements of Physical Chemistry, Puri Sharma, Pathania, 2013-14 Edn., Vishal
Publishing Co. Jalandhar, Delhi.
2 Principles of Physical chemistry, Puri Sharma Pathania, 46thEdn. Vishal Publishing
Co. Jalandhar
3 Computer for Chemists – By Pundir Bansal – Pragati Prakasam Pubs.

1 https://nptel.ac.in/courses/112/108/112108148/
2 https://www.youtube.com/watch?v=2LywAiZBQW4
Course Designed By: Dr. P. Rajesh

CO1 S L M L S S M
CO2 S L S M M S S
CO3 M S M L L M M
CO4 S S M M S L L
CO5 M S L M M S M
Page 18 of 74
Course CHEMISTRY OF NATURAL AND

3ZA L T P C
code SYNTHETIC FIBERS
SBS Skilled Based Subject – I 2 - - 2
Syllabus 2010-
Version 2011
Course Objectives:
1. Detail explanation of the classification of natural fiber, its merits and demerits
2. Outline about the preparation, properties and uses of viscose, synthetic and acrylic fiber
3. Describe the reaction of nylon and polyester fiber

1 To understand the classification, properties and uses of natural fibers. K1, K2
Able to know about the chemical structure of cellulose fiber. Wet K1 – K3
2
spinning process.
Discuss about synthetic and acrylic fiber. Detail about fiber forming K1,K2,
3
polymer and schio process. K4, K6
Explain the naming reaction of nylon fiber. Explanation of structure and K1, K2
4
uses of Kevlar fiber.
Discuss about polyester fiber. Synthesis of DMT, ethylene glycol and K1, K3,
5
PET K4
Unit:1 Natural Textile Fibers 6 hours

Natural Textile Fibers: Definition, Classification of Natural Textile Fibers - Vegetable fibers,
Animal fibers. Properties, Uses and Features of Cotton, Wool, Silk and Jute fibers.
Genetically Modified Cotton: its merits and demerits.
Unit:2 Viscose Fiber 6 hours

Viscose Fibre: Chemical structure, chemistry of regenerated cellulose. Production of Viscose
Fibre: a simple flow chart, wet spinning of viscose filaments. Properties and uses of Viscose
Fibre.
Unit:3 Synthetic and Acrylic Fibers 6 hours

Synthetic Fibers: Definition of monomers, polymers and polymerization. Simple examples of
Condensation and Addition Polymerization reactions. Criteria for fibre forming polymers.
Acrylic fibers: Synthesis of Acrylonitrile from propylene (Sohio Process), solution
polymerization of acrylonitrile. Properties and uses of acrylic fibers.
Unit:4 Nylon Fibers 6 hours

Nylon Fibres: Synthesis of caprolactum from aniline, adipic acid from cyclohexane and
hexamethylene diamine from adiponitrile. Polycondensation reactions leading to the
formation of Nylon 6 and Nylon 6,6. Properties and uses of Nylon fibers. Structure and uses
of Kevlar fibers.
Page 19 of 74
Unit:5 Reaction of Polyester Fibers 6 hours

Polyester Fibers: Synthesis of Dimethyl Terephthalate (DMT) from p – xylene, terephthalic
acid from benzoic acid (Henkel-II process) and synthesis of ethylene glycol. Chemical
reactions of Poly Ethylene Terephthalate (PET). Preparation, properties and uses of Polyester
fibers.

Text Book(s)
1 Moses, J. Jeyakodi, and M. Ramasamy. "Quality Improvement on Jute and Jute Cotton
Materials Using Enzyme Treatment and Natural Dyeing". Man-Made Textiles in India.
Vol. 47, no. 7 (Jul. 2004): 252–255. (AN 14075527)
2 "cotton". The Columbia Encyclopedia, Sixth Edition. 2001-07.
3 A.A.Vidya,. ed.:Production of Synthetic Fibers, Prentice-Hall of India, 1988, New-
Delhi.
Reference Books
1 Stephen Yafa (2004). Cotton: The Biography of a Revolutionary Fiber. Penguin (Non-
Classics), 16. ISBN 0-14-303722-6.
2 Kadolph, Sara J., ed.: Textiles, 10th edition, Pearson/Prentice-Hall, 2007,
ISBN 0-13- 118769-4.
1 https://www.youtube.com/watch?v=ypUkIR894AM
2 https://www.youtube.com/watch?v=0hoHvN289Xs
Course Designed By: Dr. N. Sivakumar

CO1 S S S S S S S
CO2 M S M S S S M
CO3 S M S S S M M
CO4 S M S S M S S
CO5 S S M S S S S
Page 20 of 74
Fourth
Semester
Page 21 of 74
Course code 43A ORGANIC CHEMISTRY - I L T P C

CORE Core VI – Paper V 4 - - 4
Syllabus 2020-
Pre-requisite Basics of Organic Chemistry
Version 2021
Course Objectives:
1. Understand the carbonyl compound’s reactivity and various reduction reactions
2. Explain the reactivity of active methylene compounds with electrophiles
3. Outline the reactivity of monohydric alcohols and amines.

1 Know the knowledge of Preparation and Properties of Carbonyl K1
Compounds.
2 Understand the mechanism of certain name reactions. K2, K3
3 Understand the concepts of active Methylene compounds and Geometrical K2, K4
isomerism of certain organic compounds.
4 Know the classification of Phenols, Preparation of phenolic compounds K2
with chemical properties.
5 Know the concepts of amines, types, separation and their basic nature. K3, K4
Unit:1 Chemistry of Carbonyl Compounds – I 12 hours

Nomenclature, Preparation & Properties: Structure of carbonyl - general physical properties
- Reaction with: Grignard reagent, NH3, primary amine – Reaction Mechanism of haloform
reaction, Reformatsky reaction.
Reduction Reactions: with LiAlH4 and NaBH4– Clemmensen reduction, Wolff Kishner
reduction, MPV reduction
Unit:2 Chemistry of Carbonyl Compounds – II 12 hours

Mechanism of: - Aldol condensation, Cannizzaro reaction, Perkin reaction, Knoevanagel
reaction, Claisen- Schmidt reaction, benzoin condensation, Mannich reaction.
Unit:3 Active Methylene Compounds 12 hours

Acetoacetic ester: preparation from Ethyl acetate – synthesis of succinic acid, 1,3-diketones,
antipyrine - Malonic ester: Preparation from potassium cyanoacetate – synthesis of cinnamic
acid, keto acids, barbituric acid - cyanoacetic ester: preparation from chloroacetic acid –
synthesis of malonic acid and adipic acid - Tautomerism of acetoacetic ester.
Geometrical isomerism: Cis & Trans, E & Z notations – Geometrical isomerism in maleic
acid and fumaric acid - physical and chemical properties of geometrical isomers.
Page 22 of 74
Unit:4 Phenols 12 hours

Classification of phenols – Preparation of phenol from chlorobenzene, cumene – Reaction with
mechanism: Schotten – Bauman and Gattermann reactions
Di and Trihydric phenols: Preparation of Catechol, Resorcinol, Quinol, Pyrogallol and
Phloroglucinol – Houben-Hoesch reaction
Unit:5 Amines 12 hours

Preparation of aliphatic and aromatic primary, secondary and tertiary amines – their separation,
comparison of their basicity
Reactions of Aromatic Amine: ring substitution, diazotization and coupling reaction –
Diazomethane: preparation and synthetic applications

Text Book(s)
1 Advanced Organic Chemistry, B.S.Bahl, Arunbahl, S.Chand & Co.,
2 Text book Organic Chemistry, P.L. Soni, S.M. Chawla, Sultan Chand & Sons
Reference Books
1 Stereochemistry, Conformation and mechanisms, Kalsi, Wiley- Eastern Ltd.,
2 Organic chemistry, R.T.Morrison and R.W. Boyd, Prentice –Hall.
3 Fundamentals of Organic Chemistry, T.W.Graham Solomen, John-Wiley & Sons

1 https://nptel.ac.in/content/storage2/courses/104101005/downloads/LectureNotes/chapter%2
010.pdf
2 https://www.youtube.com/watch?v=JgmzmehMiWM
Course Designed By: Dr. S. P. Rajasingh and Dr. A. Thirumoorthi

CO1 S L M L M M L
CO2 M L S L L M M
CO3 L M S M L L S
CO4 S M S L M M L
CO5 S L M M L M L
Page 23 of 74
VOLUMETRIC AND ORGANIC

ANALYSIS
CORE PRACTICAL CORE VII - CHEMISTRY PRACTICAL II - - 3 4
Basics Knowledge on Volumetric and Syllabus 2010-
Pre-requisite
Organic Reactions Version 2011
Course Objectives:
1. Inculcate the students how to skilfully handle the laboratory equipments, reagents, lab
apparatus and preparation of standard solutions.
2. Impart the first-hand knowledge and experience on estimation of an ion, acid and base both
directly as well as indirectly.
3. Provide the student knowledge on analysis of an unknown organic substance using
Preliminary and confirmation test and prepare a suitable derivative.
4. Make the student skilful enough and prepare for a position in an analytical laboratory or a
company.

1 Estimate the amount of ion present in the given solution through K1-K6
volumetric analysis both by direct and indirect method
2 Find the groups/elements and characters present in the given organic K1-K6
substance through qualitative analysis and prepare a suitable
derivative.
K1 – Remember; K2 – Understand; K3 – Apply; K4 – Analyze; K5 – Evaluate; K6 – Create
Part I VOLUMETRIC ANALYSIS 45 hours

A. Acidimetry&Alkalimetry: Estimation of Na2C03
B. Permanganometry:
1. Estimation of Ferrous sulphate & Oxalic acid
2. Estimation of Calcium-Direct method.
C. Dichrometry: Estimation of Ferrous iron using internal indicator.
D. Iodimetry:
1. Estimation of K2Cr2O7
2. Estimation of Copper.
3. Estimation of As2O3.
Part II ORGANIC ANALYSIS 45 hours
Systematic analysis of an organic compound Preliminary tests, detection of elements present,
Aromatic or Aliphatic, Saturated or unsaturated, nature of the functional group, confirmatory
tests and preparation of derivatives.
Substances - Aldehydes, Ketones, Amines, Amides, Diamide, Carbohydrates, Phenols, Acids,
Esters & Nitro compounds.
Page 24 of 74
Text Book(s)
1 Basic Principles of Practical Chemistry, Kulandaivelu A.R., Veeraswamy R.Venkateswaran,
Sultan Chand & Sons, 2017.
2 Practical Chemistry, Pandey D.N., Sultan Chand Publishers, 2018
Reference Books
1 Vogel’s Text book of Practical Organic Chemistry, Brian S. Furniss, Antony J.
Hannaford, Peter W. G. Smith, Fifth Edition, Bath Press, Great Britan, 1989
2 Vogel’s Textbook of Quantitative Chemical Analysis, G H Jeffery, J Bassett, J
Mendham, R C Denney, Fifth Edition, Bath Press, Great Britan, 1989
2 https://www.youtube.com/watch?v=n4esSHxz_J8
3 http://wwwchem.uwimona.edu.jm/lab_manuals/c10expt25.html/
4 https://www.youtube.com/watch?v=7bmQkQW8bbs
5 https://www.youtube.com/watch?v=wRAo-M8xBHM

CO1 S S S S S S S
CO2 S S S S S S S
Page 25 of 74
Course TECHNOLOGY OF DYEING OF

4ZB L T P C
code NATURAL FIBERS
SBS Skilled Based Subject – II 2 - - 2
Syllabus 2010-
Pre-requisite Basic Knowledge in Fibers
Version 2011
Course Objectives:
1. To impart knowledge and skill in career oriented with a special reference to dying textile
industry.
2. To help students to acquire additional knowledge of dyeing auxiliaries and methods used
in textile industry.
3. To give students an over view on process and mechanism of dyeing.
1 State the basic aspects of colour and dyeing auxiliaries. K2,K4,
2 Outline various methods of dyeing. K2,K3
3 Demonstrate the process of azoic dyes and their applications. K2,K3
4 Acquire knowledge in vat dyes and the procedures followed for dyeing. K2,K3
Summarize the properties and mechanism of dyeing particularly sulfur K3,K4,
5
and acid dyes. K5
Unit:1 Introduction to Dyeing 6 hours

Theory of Colour, chromophore, auxochrome, chromogen. Primary and Secondary colour.
Chromatic and Achromatic Colours – Classification of dyes. Definition – Affinity,
Substantivity, Exhaustion, % Shade, Adsorption, Diffusion, Aggregation, Migration –
Effects of M:L ratio, salt, time and temp. of dyeing. Properties of direct dyes – Application
of direct dyes of Cotton: Mechanism of dyeing. Stripping and Redyeing. After treatment
with CuSO4, K2Cr2O7 and dye fixing agents.
Unit:2 Methods of Dyeing 6 hours

Reactive dyes – properties, Cold Brand, Hot Brand, Vinyl sulphone dyes, LS dyes, HE
dyes, bifuctional dyes, Mechanism of dyeing. Exhaust dyeing, pad-batch, pad-steam, pad-
cure, pad-silicate Methods. Stripping and redyeing.
Unit:3 Napthols and Fast Bases 6 hours

Naphthols and Fast Bases: properties and application – Diazotisation and coupling. Brief
study on dissolution (classification of naphthols, cold and hot dissolution methods). Bases
– direct and indirect method of diazotization. Application procedure of any one naphthols
and base using Jigger and pad-dry-develop method. Stripping and Redyeing.
Unit:4 Vat Dyes 6 hours

Types of Vat dyes. Details of vatting, dyeing, oxidation and soaping. Application procedure:
Leuco vat, vat acid – pigment padding – pad steam process. Merits and demerits of above
methods. Dyeing of yarn with vat dyes by conventional method.
Page 26 of 74
Unit:5 Properties and Application of Dyes 6 hours

Brief study – solubilised vat dyes – properties – advantages and disadvantages over vat dyes
– application – exhaust dyeing method. Sulphur dyes – Properties of Sulphur dyes –
application. Jigger and continuous dyeing defects. Bronziness and acid tendering – Stripping
and redyeing. Use of hydros. Properties of basic dyes mordants used for cotton. Dyeing wool
& silk with basic dyes. Eco-friendly sulphur dyeing. Acid dyes – Properties, classification of
dyes – leveling acid dyes, milling acid dyes – supermilling acid dyes – application to wool
and silk. Mechanism of dyeing – Dyeing of nylon with acid dyes.

Text Book(s)
1 Shenai V.A., Technology of Textile Processing Vol. 1 and 2, Chemistry of Dyes and
Principle of Dyeing Ed. 3, 1983, Sevak Publication, 306, Sri Hanuman Industrial
Estate, GC Ambedkar Road, Wadala, Bombay 400 031.
2 Chakravarthy RR and Trivedi S.S., Technology of Bleaching and Dyeing of Textile
Fibre Vol 1, Part 1, 1979, Mahajan Book Publi shres, Supermarket Basement, Near
Nataraj Cinema, Ashram Road, Ahmedabad 380 009.
3 Srivastava SB, Recent Process of Textile Bleaching, Dyeing and Finishig, 1981, SB
Srivastava, S B P Board Consultant, S B P Buildings, 4/45 Roopnagar, Delhi 110 007.
Reference Books
1 Trotman E.R, Dyeing and Chemical Technology of Textile Fibre, Charles
Griffin & Co, 42, Dhury lane, Londan WC2
2 Gokhle S.V. and Shah.R.C., Cotton Piece dyeing, 1981, Ahmedabad Textile Industrial
Research Assn. (ATIRA), PO Polytechnic, Ahmedabad 380 015.
3 Prayag R.S., The bleaching and deying of Cotton material 1983, Weaver’s Service
Cent., 15A, Mamparamanand Marg, Near Roxy Cinema, Bombay 400 004.
4 D.M. Lewis, Wool Dyeing, SDC Publications, UK.
5 J.K.Aspland, Textile Dyeing and Colouration, AATCC Publications, USA.
1 https://onlinecourses.swayam2.ac.in/cec19_te01/preview
2 https://www.classcentral.com/course/swayam-textile-finishing-14326
Course Designed By: Dr. S. Rajalakshmi

CO1 S S S S S S S
CO2 S S M M S S S
CO3 S M S M S S S
CO4 S S M M S M S
CO5 S S M M M M S
Page 27 of 74
Fifth
Semester
Page 28 of 74
Course code 53A INORGANIC CHEMISTRY - II L T P C

CORE Core VIII – Paper - VI 5 - - 4
Syllabus 2020-
Pre-requisite Basics of Inorganic Chemistry
Version 2021
Course Objectives:
1. To acquire knowledge on nuclear reactions, reactivity of atom bomb and hydrogen bomb,
the importance of nuclear reactors in production of electricity.
2. To describe the structure of metals and alloys along with its classifications and to impart
basics on semiconductors along with its uses.
3. To develop chemistry knowledge on isotopes, the importance of radioactive compounds in
food preservation, archaeological dating and medical diagnosis and treatment.
4. To study about the concepts related to the coordination compounds.

1 Rationalise the conductivity of metals, semiconductors along with its K1,
applications. K2,K3
2 Understand the types of nuclear reactions and its importance in generation K1,K2
of electricity.
3 Acquire enormous knowledge on uses of isotopes and radioactive K1,K2
substances.
4 Understand the terms - ligand, chelate, coordination number and various K3,K4
types of isomerism possible in coordination compounds.
5 Outline various theories of coordination compounds and complete K2,K3
understanding on Crystal Field and Valence Bond Theory.
Unit:1 Metals and Solid Solutions 15 hours

Structure of metals and alloys-substitutional and interstitial solid solution-Hume Rothery ratios-
metallic bonding-electrical, optical and mechanical properties of metals-semiconductors,
intrinsic and extrinsic-their uses. Super conductors-An elementary treatment.
Unit:2 Radioactivity and Nuclear Reactions 15 hours

Artificial radio activity. Artificial transmutation of elements, synthesis of radio isotopes and.
nuclear fission and fusion. Nuclear reactors – principle of working – production of electrical
energy – atomic projects in India – Safety measures; disposal of reactor wastes – pollution.
Nuclear reactions, mechanisms and different types of stellar energy.
Unit:3 Isotopes and Their Applications 15 hours

Nature of isotopes and isobars – detection and isolation of isotopes – various methods –
importance of discovery of istopes – uses of isotopes in various fields. Nuclear stability n/p
ratio, magic numbers, C-12 atomic weight scale, C-14 dating, mass defect and nuclear
Page 29 of 74
binding energies. Radioactive disintergration series.
Unit:4 Co-ordination Chemistry - I 15 hours

Co-ordination chemistry – I Types of ligands, IUPAC Nomenclature, Isomerism - Ionisation,
hydrate, linkage, ligand and coordination isomerism. Stereoisomerism-geometrical and
optical isomerism in 4 & 6 coordinated complexes. Theories of coordination compounds –
Werner’s and Sidgwick’s EAN concept , Valence Bond theory – hybridization, geometry and
magnetic properties of [Ni(CN)4]2-, [NiCl4]2-,[Fe(CN)6]4-, [Co(NH3)6]3+ and [CoF6]3-.
Unit:5 Co-ordination Chemistry - II 15 hours

Limitations of valance bond theory, an elementary idea of crystal field theory, crystal field
splitting in octahedral, tetrahedral and square planner complexes, low spin & high spin
complexes, factors affecting the crystal-field parameters. Explanation of colour and magnetic
properties using CFT, comparison of VBT and CFT. A brief outline of thermodynamics
stability of metal complexes and factors affecting the stability, stability constants of
complexes and their determination, substitution reactions of square planar complexes.

Text Book(s)
1 Malik,Wahid U., G.D. Tuli and R.D .Madan . Selected Topics in InorganicChemistry,7th
ed., New Delhi S. Chand& Company Ltd., 2007.
2 B. R. Puri, L. R. Sharma, K. C. Kalia, Principles of Inorganic Chemistry, Shoban Lal
Nagin Chand and Co., Delhi, 1996.
3 H. J. Arnikar, Essentials of Nuclear Chemistry, 4th ed., New Age International, New Delhi,
1995.
Reference Books
1 J. E. Huheey, E. A. Kieter and R. L. Keiter, Inorganic Chemistry, 4th ed., Harper Collins,
New York, 1993.
2 F. A. Cotton, G. Wilkinson, C. Murillo and M. Bochman, Advanced Inorganic Chemistry,
6th ed., John Wiley, New York, 1999.
2 https://www.encyclopedie-environnement.org/en/physics/radioactivity-and-nuclear-
reactions/
Course Designed By: Dr. S. P. Rajasingh and Mr. C. Sudhakar

CO1 M S M S M S S
CO2 M M M M S S M
CO3 S M S M S M M
CO4 M M S S S M M
CO5 S S M M S M S
Page 30 of 74
Course code 53B SPECTROSCOPY L T P C

CORE CORE IX - PAPER VII 5 - - 4
Knowledge on basic structure and reactions of Syllabus 2020-
Pre-requisite
simple organic compounds. Version 2021
Course Objectives:
1. Understand the basic concepts and theory behind the principles of different spectroscopic
methods.
2. Study the instrumentation and applications of UV-Visible, IR, Raman, NMR, Mass and
ESR spectroscopic techniques.
3. Predict the structure of organic compounds using IR, NMR and mass spectrometry.

On the successful completion of the course, students will be able to:
CO1 Gain the knowledge of different electromagnetic radiations, basic concepts, K2, K3
instrumentation and applications of UV-Visible spectra.
CO2 Know different types of vibrational frequencies, comparison between IR K2, K3
and Raman spectroscopy as well as their applications.
CO3 Study the basic principles, instrumentation and applications of NMR K2, K3,
spectroscopy pertaining to some simple organic compounds. K4
CO4 Acquire the knowledge on the basic concepts, instrumentation and K2, K3,
applications associated with ESR. K4
CO5 Understand the different concepts of mass spectrometry along with the K2 – K5
determination of molecular formula.
Unit:1 Ultra Violet – Visible Spectroscopy 15 hours

Spectroscopy: Absorption and Emission spectra – Fundamental concepts – Electromagnetic
spectrum with relative energies in each region.
Ultra Violet – Visible Spectroscopy: Introduction – Beer–Lambert’s law – Instrumentation
(block diagram) – Formation of absorption bands – Theory – Types of Electronic Transitions
– Transition probability – The Chromophore and Auxochrome concepts – Absorption and
Intensity shifts (Bathochromic, hypsochromic, hyperchromic and hypochromic shifts) – Types
of absorption bands – Frank Condon principle – Applications of UV – Visible spectra.
Unit:2 IR and Raman Spectroscopy 15 hours

IR Spectroscopy: Principle – Types of molecular vibrations – Vibrational frequencies –
Factors affecting vibrational frequencies – Instrumentation (block diagrams with description
of components) – Finger print region – Characteristic absorption bands of various functional
groups – Applications of IR spectra.
Raman Spectra: Theory - Comparison of IR and Raman spectra – Applications of Raman
Spectra.
Page 31 of 74
Unit:3 NMR Spectroscopy 15 hours

Introduction and basic principles – Spin – Spin relaxation, Spin – lattice relaxation –
Instrumentation ( Block diagram) – Chemical shift – Importance of TMS – Factors influencing
chemical shift – Shielding and deshielding effects – Number of signals – Applications of NMR
to simple molecules like Ethyl alcohol (Pure and Impure), Toluene, Phenol, Acetaldehyde and
Diethyl ether.
Unit:4 ESR Spectroscopy 15 hours

Basic Principle – The g factor – Hyperfine splitting – Instrumentation –Applications to methyl
radical and Naphthalene negative ion.
Unit:5 Mass Spectrometry 15 hours

Basic Principles – Theory – The molecular ion – Determination of molecular formula –
McLafferty rearrangement – Metastable peaks – Nitrogen rule – Retro Diels –Alder reaction.

Text Book(s)
1 Elementary Organic Spectroscopy (Principles and chemical applications) – Y.R.Sharma, S.
Chand & Company Ltd. Publications, Fifth revised Edn, 2017.
2 Organic Spectroscopy (Principles and Applications) – Jag Mohan, Narosa Publishing
House, Second Edn, 2012.
Reference Books
1 Spectroscopy of Organic compounds – P.S. Kalsi, New Age International Ltd. Publishers,
Sixth Edn, 2005.
2 Analytical Chemistry (Theory and Practice) – U.N. Dash, S. Chand & Sons, Second
Edition, 2005.

1 https://ndl.iitkgp.ac.in/
2 https://nptel.ac.in/course.html
3 https://ocw.mit.edu/
https://www.oercommons.org/advanced-search
Course Designed By: Dr. A. Thirumoorthi

CO1 M S S M M S M
CO2 M S S S M S S
CO3 S S H S M S S
CO4 M M M M L M M
CO5 M S M M M S M
Page 32 of 74
Course
53C ELECTRO CHEMISTRY L T P C
code
CORE Core X – Paper VIII 5 - - 4
Syllabus 2016-
Pre-requisite Higher Secondary Level Knowledge
Version 2017
Course Objectives:
1. Make the students understand basic electrochemical principles
2. Give them an insight into the types of storage cells & their applications
3. Enable the student to understand the construction & working of different types of electrodes

Describe the principle of solubility product and relate the pH of a solution K1-K3
1 containing a mixture of the two components to the acid dissociation
constant, Ka
Understand the difference between metallic conductance & electrolytic K1,K2
2
conductance
Recognize the different types of electrochemical cells and calculate the cell K2,K3
3
potential from standard cell potential
Distinguish between cells and use the Nernst equation for calculating EMF K1-K4
4
of a cell.
Understand the working principles of fuel cells, storage cells and battery K2-K4
5
design.
Unit:1 Ionic Equilibrium 15 hours

Ionic Equilibria -Solubility and solubility product-determination of solubility product- Applications
of solubility product principle. Dissociation of weak acids and bases-Dissociation constants-pH
scale-common ion effect-buffer solutions- Determination of pH values of buffer mixtures-
Henderson’s equation-Hydrolysis of salts-Degree of hydrolysis.
Unit:2 Conductivity of Ions 15 hours

Electrical conduction, conduction in metals and in electrolytic solutions. Measurement of
conductivity in electrolytic solutions. Migration of ions-Kohlrausch’s law. Arrhenius theory of
electrolytic dissociation-Ostwald’s dilution law. Theory of strong electrolytes-Debye-Huckel-
Onsagar theory (elementary account only) verification. Debye-Falkenhagen effect-Wien effect-
Transport numbers-Determination. Conductometric titrations.
Page 33 of 74
Unit:3 Electrochemical Cells 15 hours

Electrochemical cells. Electrode potentials-The standard hydrogen electrode kinds of electrodes
and their potentials-Nernst equation. EMF-computation and measurement of cell EMF. Single
electrode potential-Determination and significance of electrode potentials- electro chemical
series- temperature dependence of the cell EMF- Thermodynamic quantities of cell reactions.
Unit:4 Electrode Potential 15 hours

Reference electrodes-Electrodes for measurement of pH-concentration cells with and without
transport-liquid junction potential-applications of EMF measurements. Redox potential-Redox
indicators-uses. Potentiometric titrations.
Unit:5 Fuel and Storage Cells 15 hours

Fuel cells: Hydrogen- oxygen cell and hydrocarbon - oxygen cell. Storage cells. Lead storage
cell and Nickel cadmium cell. Decomposition voltage-over voltage-Deposition and discharge
potential.
Text Book(s)
1 B.R. Puri and L.R. Sharma, Principles of physical chemistry, Shoban Lal Nagin Chand
and Co. 33rd edition, 1992.
2 S.H. Maron and J.B. Lando, Fundamentals of physical chemistry, Macmillan limited, New
York, 1966.
Reference Books
1 S.K. Dogra and S. Dogra, Physical chemistry through problems, New age international,
4th edition 1996.
2 P.W. Atkins, Physical chemistry, Oxford university press, 1978
3 K. L. Kapoor, A textbook of Physical chemistry, (volume-2 and 3) Macmillan, India Ltd,
1994.
1 https://chem.pg.edu.pl/documents/175289/4235721/Electrochemistry-
supplement%20text.pdf
3 https://nptel.ac.in/content/storage2/courses/103108100/module6/module6.pdf
Course Designed By: Dr. N. Bhuvaneshwari

CO1 S M M S S M M
CO2 M S M S S L M
CO3 M M S M S S M
CO4 S S M M M S S
CO5 S L S M M M M
Page 34 of 74
ANALYTICAL
Course code 53D L T P C
CHEMISTRY
CORE Core XI – Paper IX 4 - - 4
Pre-requisite Higher Secondary Level Syllabus Version 2009-2010
Course Objectives:
1. Understand the principles of various analytical techniques and their applications
2. Analyze errors and perform various tests for analytical data
3. Outline the concepts of gravimetric methods in quantitative analysis
1 Understand the principles of various analytical techniques and K2, K3
their applications
2 Evaluate different types of errors and correct them. K1, K5
3 Perform various tests for set of analytical data K3, K4
4 Understand the theory of quantitative analysis K1, K6
5 Determine an analyte quantitatively using gravimetric methods K3, K5
Unit:1 Analytical Techniques 12 hours

Basic principles and applications of Analytical techniques such as Precipitation, filtration, sample
drying, transfer of precipitates, distillation, vacuum distillation, fractional distillation and steam
distillation. Sublimation, crystallization, fractional crystallization and Refractive Indices.
Unit:2 Data Analysis 12 hours

Evaluation of Analytical data: Accuracy and precision, methods for their expression, classification
of errors, detection and correction of determinate and indeterminate errors. The normal law of
Distribution of Indeterminate errors.
Unit:3 Statistical Tests and Significant Figures 12 hours

The F test and the T test, rejection of data- the method of least squares, propagation of errors in
computation- significant figures.
Unit:4 Quantitative Analysis and Chemical 12 hours

Equilibrium
Theory of Quantitative Analysis; Application of Chemical equilibrium to analytical separations and
estimations: The equilibrium constants, activity coefficients. Acid-Base equilibria, solubility
equilibria, distribution equilibria, Complex ion equilibria and stability constant Separations and
estimations: illustrated with examples.
Unit:5 Gravimetric Methods 12 hours

Theory of indicators, Theory of precipitation, Co-precipitation, Post-precipitation, theory of
purifying the precipitates, Acid-Base, redox, Complexometric and precipitation Titrations,
Volumetric analysis.
Page 35 of 74
Text Book(s)
1 Elements of Analytical Chemistry. R. Gopalan, Sultan Chand & Sons
Reference Books
1 Quantitative Chemical Analysis, A.I. Vogel.
2 Instrumental Methods of Analysis, Skoog.
3 Instrumental Methods of Analysis, Willard, Dean, Merrit and Settle, CBS.
4 Vogel’s Textbook of Quantitative Chemical Analysis, G H Jeffery, J Bassett, J Mendham, R
C Denney, Fifth Edition, Bath Press, Great Britan, 1989
1 https://www.mobt3ath.com/uplode/book/book-19965.pdf
2 https://chem.libretexts.org/Courses/University_of_California_Davis/UCD_Chem_105/Chapt
ers/5._Errors_in_chemical_analysis
Course Designed By: Dr. S. P. Rajasingh and Dr. S. Sivakumar

CO1 S M L S S S M
CO2 S M M S S M S
CO3 M M S S S M S
CO4 S S S M S M S
CO5 S M L M S S S
Page 36 of 74
Course WATER & EFFLUENT TREATMENT AND

5ZC L T P C
code POLLUTION CONTROL
SBS Skilled Based Subject – III 3 - - 2
Syllabus 2010-
Version 2011
Course Objectives:
1. Over view of impact of man on the environment
2. Detail view of pollutions and water softening techniques
3. Description about water effluent treatment and pollution analysis techniques

1 To understand urbanization and biodiversity along with environmental K1, K2
pollution.
2 Acquires the knowledge about water pollution and water softening K1,K2,
methods. K3, K4
3 Importance about water analysing methods along with determination of K2,K3,
BOD, COD and toxicity. K4,
4 Detail explanation of primary, secondary and tertiary water treatment K2,K3,
methods. K4,K5
5 Discuss about effect of noise pollution along with brief study on modern K1,K2,
methods for pollution analysis. K4
Unit:1 Sources of Pollution 6 hours

Impact of man on the Environment – an over view of Urbanization and Biodiversity.
Environmental pollution – classification of pollution – Effect of industrial effluents – a detailed
study of effluents discharged by Soap and detergent manufacture industry and Textile processing
industry (study includes origin of effluent, important characteristic and general mode of
treatment). Constituents of water and their effect on Textile wet processing – Water pollution –
Harmful effects of water pollution and source of water pollution.
Unit:2 Water Pollution and Softening Methods 6 hours

WHO, ISO standards for raw water criteria – A general study on raw water pollution and
consequence of river water pollution – Effluent discharge standards for inland surface water
public sewers, on land for irrigation, marine coastal areas and drinking water parameters- A
general study on boiler water requirements which includes problem caused by water and effect
and feed water requirements for low and medium pressure boilers and at a pressure of 450 – 500
psi. Water softening – study includes Cation Exchange softening, lime soda softening, softening
by Sequestering agents and De-mineralization with schematic diagram of removal of carbon di
oxide and silica.
Page 37 of 74
Unit:3 Analysis Techniques for Water 6 hours

Removal of colour and turbitity (simple Coagulation, Flocculation and Filtration methods).
General study on removal of Iron and Manganese by Aeration, setting and filtration method-
Water analysis – colour, pH value, dissolved solids, suspended solids, total hardness (Calcium +
Magnessium). EDTA Titrimetric method, total iron- thiocyanate method, Determenation of
Alkalinity by Titrimetric method – thiocyanate method, Determination of Alkalinity by
Titrimetric method- Datermination of chlorides by silver nitrate method- Determination of
dissolved oxygen by iodimetry – Determination of BOD,COD TDS and Toxicity.
Unit:4 Water Treatment Methods 6 hours

Effect of effluents – General treatment procedure parameters to be determined at Sizing,
Desizing, Kier boiling, Bleaching, Mercerizing, Dyeing, Printing, Combined effluent treatment
of industrial of wastes- Brief study on Screening, Sedimentation, Equalization, Neutralization,
Coagulation, Secondary treatment – Tricking filtration Activated sludge process, oxidation
ponds, Anaerobic Digestion, Tertiary treatment- Evaporation (solar & steam). Reverse osmosis,
ion exchange, chemical precipitation and removal by Algae and activated carbon treatment.
Unit:5 Analysis Techniques for Pollution 6 hours

Model schematic diagram for waste water treatment plant for textile mills-Primary & secondary
units –Effects of air pollution –Effects of Sulphur oxide on human health – Ambient air quality
standards- Noise pollution –ill effects of noise-Noise level in decibels. Brief study on modern
methods for pollution analysis like molecular luminescence, BOD incubator, ion exchange
chromatography and HPLC.

Reference Book(s)
1 Environment Pollution control Engineering by C.S.Rao. New age International Ltd &
Publishers.
2 Industrial safety & Pollution control Hand Book by National safety council and Associate
Data Publisher Pvt Ltd.
3 Industrial Effluents by N.Manivasakam, Sakthi Publications, Coimbatore.
4 Water used in Textile Processing by N. Manivaskam, Sakthi Publications, Coimbatore.
5 Tamilnadu state publications and Hand book of pollution control –Central Board of
pollution control.
6 Textile Effluents by Padma Varkar, NCUTE Publications, IIT,Delhi.
7 Environmental Chemistry and pollution Control, S.S.Dhara, S.Chand & Co., Delhi.
8 Pollution in Textile Industry, K.B.Krishnakumar, SSMITT Students Cooperative Stores,
Komarapalayam.
Course Designed By: Dr. S. P. Rajasingh and Dr. S. Rajalakshmi
Page 38 of 74

CO1 S S S M S S S
CO2 M S M S S S M
CO3 S M S S S M M
CO4 S M S S M S S
CO5 S S M S S S S
Page 39 of 74
Sixth
Semester
Page 40 of 74
Course code 63A ORGANIC CHEMISTRY - II L T P C

CORE CORE XII - PAPER X 5 -
- 4
2020
Knowledge on basic structure and reactions of Syllabus
Pre-requisite -
simple organic compounds. Version
2021
Course Objectives:
1. Understand the optical activity of various molecules and their naming patterns.
2. Study the mechanism of different rearrangement reactions.
3. Acquire the knowledge on reactions and structures of heterocyclic compounds, amines
and proteins.
4. Predict the structure of natural products like vitamins, alkaloids, terpenoids and
harmones.
On the successful completion of the course, students will be able to:
CO1 Gain the knowledge on different types of optically active molecules K2, K4, K5
and their naming methods.
CO2 Understand the mechanisms of inter and intramolecular rearrangement K2, K4
reactions with examples.
CO3 Acquire the knowledge on the preparation, properties and uses of K2, K3
heterocyclic compounds, amino acids and proteins.
CO4 Know the classification, structural elucidation and synthesis of K2, K4, K5
terpenoids and vitamins.
CO5 Understand the different types and structural elucidation of alkaloids K2, K4, K5
and harmones.
Unit:1 Stereochemistry 15 hours

Optical activity – Asymmetric carbon – Racemisation – Resolution – Asymmetric synthesis –
D, L and R,S notation. Optical activity due to restricted rotation in biphenyls, allenes and
spiranes – Molecular overcrowding.
Unit:2 Molecular Rearrangements 15 hours

Mechanism of Pinacol – Pinacolone rearrangement – Beckmann rearrangement – Hoffmann
rearrangement – Curtius rearrangement – Benzilic acid rearrangement – Schmidt
rearrangement – Lossen rearrangement – Cope rearrangement and Claisen rearrangement.
Unit:3 Heterocyclic Compounds and Proteins 15 hours

Heterocyclic Compounds: Chemistry of Furan, Pyrrole, Thiophene, Pyridine – Synthesis and
uses of Quinoline, Isoquinoline and Indole.
Proteins: Amino acids – Classification – Peptide linkage – Proteins – Classification based on
physical properties and biological functions – Primary, Secondary and Tertiary structure –
Uses.
Page 41 of 74
Unit:4 Terpenoids and Vitamins 15 hours

Terpenoids: Introduction – Classification – General methods of isolation – Isoprene rule-
structural elucidation and synthesis of Geraniol, Terpineol and dipentene.
Vitamins: Introduction – Importance of vitamins – Structural elucidation and synthesis of
Retinol, Riboflavin and Ascorbic acid.
Unit:5 Alkaloids and Hormones 15 hours

Alkaloids: Introduction – Classification and General Characteristics – General methods of
determining structures – Hoffmann’s exhaustive methylation – Structural elucidation and
synthesis of Nicotine, Piperine and Papaverin.
Harmones: Introduction – Structural elucidation and synthesis of Adrenaline and Thyroxine.

Text Book(s)
1 Advanced Organic Chemistry – B.S.Bahl and Arun Bahl, S.Chand & Co., 2012.
2 Organic Chemistry, R.T.Morrison and R.N. Boyd, Pearson Education, Sixth Edn., 2002.
3 Text book Organic Chemistry, P.L. Soni, S.M. Chawla, Sultan Chand & Sons, 2007.
Reference Books
1 Organic Chemistry – Vol. 1 and Vol. 2, I.L Finar, Pearson Education, Sixth Edn., 2006.
2 Stereochemistry of Organic compounds, D. Nasipuri, New Age International (P) Ltd,
Second Edn., 2005.
3 Stereochemistry: Conformation And Mechanism - P. S. Kalsi, New Age International
Private Ltd., 2015
Online References (Go to the following websites and search with the specific topics /
keywords)
1 https://ndl.iitkgp.ac.in/
2 https://nptel.ac.in/course.html
3 https://ocw.mit.edu/
4 https://www.oercommons.org/advanced-search
Course Designed By: Dr. A. Thirumoorthi

CO1 M S S S M S M
CO2 L M M S L S S
CO3 S S M M M S S
CO4 S M S S M S S
CO5 S S S S M S S
Page 42 of 74
Course code 63B PHYSICAL CHEMISTRY II L T P C

CORE Core XIII – Paper XI 5 - - 4
Syllabus 2010-
Version 2011
Course Objectives:-
1. Impart knowledge on electrical and magnetic properties of molecules
2. Describe the order and molecularity of reaction and determination of order of reactions
3. Broad description of theoretical aspects and experimental techniques of kinetics of
different types of reactions.

1 Understand the electrical properties of molecules and its application K1-K3
Understand magnetic properties of molecules and its application for K1-K3
2
solving problem for structure determination
Know about the order and molecularity of reaction and also K2-K4
3
determination of order of reactions
Understand and learn the theoretical and experimental aspects of kinetics K1-K4
4
of reactions
5 Gain detailed knowledge on photochemical and thermal reactions. K1-K3
K1 - Remember; K2 - Understand; K3 - Apply; K4 - Analyze; K5 - Evaluate; K6 – Create
Unit:1 Electrical Properties of Molecules 15 hours

Electrical properties of molecules: Molar polarization, Orientation polarization and
Distortion polarization polar and non-polar molecules. Determination of dipolemoment of
polar gases, liquids and solids-Applications of dipole moment in the study of simple
molecules.
Unit:2 Magnetic Properties of Molecules 15 hours

Magnetic properties of molecules; Meaning of the terms magnetic susceptibility, magnetic
moment, diamagnetism, paramagnetism and ferromagnetism, Determination of magnetic
susceptibility by Guoy’s method. Application of magnetic properties in solving structural
problems.
Unit:3 Order and Molecularity of Reactions 15 hours

Empirical laws and experimental aspects.Rate laws, Stoichiometry, order and molecularity of
reactions- Setting up and solving simple differential equation for first order, second order,
third order and zero order reactions. Characteristics of I,II,III and Zero order reactions.
Determination of order of reactions.
Page 43 of 74
Unit:4 Kinetics of Reaction 15 hours

Experimental techniques involved in following kinetics of reaction. Volumetry,
manometry, polarimetry and colorimetry, typical examples for each of the techniques.
Theoretical aspects. Effect of temperature on rate constant. The activation energy. The
collision theory of reaction rates and its limitation. Lindemann theory of unimolecular
reactions. The theory of Absolute reaction rates. Comparison of the collision theory with
the Absolute reaction rate theory.
Unit:5 Photochemical Reactions 15 hours

Thermal chain reaction H2/Br2 reaction.Kinetics of photochemical reactions. Absorption
of light and photochemical process. The Stark-Einstein law of photochemical equivalence.
Photochemical chain reaction H2/Br2 reaction. Quantum yield of photochemical ractions.
Comparison of thermal & photochemical kinetics of H2/Br2 reaction. Photosensitized
reactions. Fluoresence, phosphorescence and chemiluminesence.

Text Book(s)
1 Principles of Physical Chemistry, B.R.Puri, L.R.Sharma and M.S.Phathania,
Shobanlal Nagin Chand & Co
2 Essentials of Physical Chemistry, B.S.bahl and G.D. Tuli,S. Chand & Co
3 Text book of physical Chemistry, P.L.Soni, Dharmarke; Sultan Chand & Son
Reference Books
1 Physical Chemistry,P.W.Atkins, Oxford
2 Physical Chemistry, R.A.Alberty, John. Wiley &Sons
3 Elements of physical Chemistry, S.Glasstone and D.Lewis, McMillan
1 https://archive.org/details/2015.135344.ElementsOfPhysicalChemistryEd2nd/page/n9/mod
e/2up
2 https://nptel.ac.in/content/storage2/courses/122101001/downloads/lec-26.pdf
3 https://www.youtube.com/watch?v=W8FhlGNnMkg&t=5447s
Course Designed By: Dr. T. Selvaraju

CO1 S S M S M S S
CO2 M S S M S S S
CO3 S M S L S M M
CO4 S S L S M S S
CO5 S M S S M S M
Page 44 of 74
GRAVIMETRIC ANALYSIS AND

PHYSICAL CHEMISTRY
CORE PRACTICAL CORE XIV - CHEMISTRY PRACTICAL III - - 7 4
Basics Knowledge on Analytical and Physical Syllabus 2019-
Pre-requisite
Chemistry Version 2020
Course Objectives:
1. Make the students to learn a technique to determine the amount of an analyte (cation)
through the measurement of mass.
2. Impart understanding about conductance of a solution by the addition or removal of ions.
3. Realize and explore the fundamentals of basic physical chemistry experiments, including
chemical kinetics, phase diagram and molecular weight determinations.

1 Understand the concept of gravimetric analysis. K1-K6
2 Find a suitable precipitation method and perform effective precipitation to K1-K6
determine the amount of the cation.
3 Calculate the conductance of the solution at various stages of neutralization K2-K5
4 Determine the rate and dissociate constant for a reaction K2-K4
5 Perform graphical analysis to arrive experimental results based on the K1-K6
physical chemistry experiments.
Part I Sintered Crucible Based Gravimetric Analysis 45 hours

1. Estimation of Barium as Barium Chromate.
2. Estimation of Lead as Lead Chromate.
3. Estimation of Nickel as Nickel Dimethyl Glyoxime.
Part II Silica Crucible Based Gravimetric Analysis 30 hours
1. Estimation of Sulphate as Barium Sulphate
2. Estimation of Calcium as Calcium Oxalate.
Part III Conductometric Physical Experiments 45 hours

1. Conductometric titrations, strong-acid-strong base.
2. Conductometric titrations, Weak-acid-strong base.
3. Determination of cell constant, specific conductivity and equivalent conductivity of strong
electrolyte.
Part IV Physical Organic Experiments 30 hours

1. Determination of rate constant of acid-catalysed hydrolysis of an ester (Methyl acetate
or Ethyl acetate).
2. Determination of dissociation constant of a weak acid (acetic acid).
Page 45 of 74
Part V Temperature Based Physical Experments 60 hours

1. Determination of Kf / molecular weight by Rast’s macro method-Naphthalene, Diphenyl
and diphenylamine
2. Determination of critical solution temperature of Phenol-Water system.
3. Effect of impurity (NaCl, /succinic acid) on CST.
4. Phase Diagram – Simple Eutectic system.
5. Determination of the transition temperature

Text Book(s)
2 Practical Chemistry for B.Sc Chemistry, A.O. Thomas
Reference Books
1 Vogel’s Textbook of Quantitative Chemical Analysis, G H Jeffery, J Bassett, J Mendham,
R C Denney, Fifth Edition, Bath Press, Great Britan, 1989
2 Advanced Practical Physical Chemistry, Yadav J.B., Goel Publishing House, 2014.
1 https://www.youtube.com/watch?v=6Kd0qIczD24
2 https://www.youtube.com/watch?v=peMyqdJ57dA (Estimation of Nickel)
3 https://www.youtube.com/watch?v=-GS6uoFf3qQ (strong-acid-strong base)
4 https://www.youtube.com/watch?v=Dc4aUdADqY8 (week acid-strong base)
5 https://www.youtube.com/watch?v=xo1wNSZpE4w (Kinetics of Ester Hydrolysis)
6 https://www.youtube.com/watch?v=5oVnpYhmMVU (CST of Phenol-Water System)
7 https://www.youtube.com/watch?v=2VzEpsEZOYo (Rast’s Macro Method)
Course Designed By: Dr. S. P. Rajasingh and Dr. A. Thirumoorthi

CO1 S S S S S S S
CO2 S S S S S S S
CO3 M S S S M S M
CO4 M S M S M M M
CO5 M S M S S M M
Page 46 of 74
PRACTICAL FOR ELECTIVE

Course code 63Q L T P C
SUSBJECTS
CORE PRACTICAL CORE XV - - 3 4
Basics Knowledge on Organic, Inorganic and Syllabus 2010-
Pre-requisite
Physical Chemistry Version 2011
Course Objectives:
1. Impart skills in the student to analyse a substance by finding their physical constants.
2. Impart knowledge to prepare various organometallic and organic substances using
complexation, oxidation, reduction, hydrolysis and other techniques.
3. Make the students learn the technique of estimation of a substance using Complexometric
titrations.
4. Inculcate the knowledge and skills in the estimation of a substance using colour and light

1 Use the physical constants in the analysis of a substance. K1-K5
2 Prepare inorganic complexes K1-K6
3 Perform organic transformation involving substitution and oxidation K1-K5
reactions
4 Use effectively the Complexometric method to estimate hardness of K2-K6
water
5 Colorimetric methods in the estimation of various salts and ions. K1-K5
Part I Determination of Melting and Boiling Point 3 hours

1. Determination of Melting point/Boiling point of an organic substance.
Part II Preparation of Inorganic Complexes 18 hours
(a) Tetrammine copper (II) sulphate
(b) Potassium Trioxalato chromate (III)
(c) Prussian Blue
(d) Hexammine Cobalt (II) chloride
(e) Potassium Trioxalato Ferrate(III)
(f) Sodium Cuprous Thiosulphate.
Part III Organic Preparation 12 hours
Preparation involving, Hydrolysis, Oxidation, Halogenation, Nitration and Benzoylation.
Part IV Estimation Using EDTA Method 3 hours
Estimation of Hardness of Water using EDTA.
Part V Estimation Using Calorimetric Method 9 hours
Calorimetric experiments involving Nessler’s tubes.
(a) Extimation of Fe3+ with Ammonium thiocyanate.
(b) Extimation of Ni as Nickel Dimethyl glyoxime.
(c) Estimation of Mn2+ in Potassium permanganate
Page 47 of 74
Text Book(s)
2 Practical Chemistry, Pandey D.N., Sultan Chand Publishers, 2018
Reference Book
1 Vogel’s Textbook of Quantitative Chemical Analysis, G H Jeffery, J Bassett, J
Mendham, R C Denney, Fifth Edition, Bath Press, Great Britan, 1989
2 https://nptel.ac.in/content/storage2/courses/104105033/Questions%20Answers%20Coordi
nation.pdf
3 https://www.youtube.com/watch?v=EQxvY6a42Dw
4 https://www.youtube.com/watch?v=noUSORH5JWo
5 https://en.wikipedia.org/wiki/Colorimetric_analysis
Course Designed By: Dr. K. Velumani

CO1 S S S M S M S
CO2 S S S S S S S
CO3 S S S S S S S
CO4 S S S S S M S
CO5 S S S S S S S
Page 48 of 74
Skill Based
Subject
Page 49 of 74
Course code 6ZP TEXTILE CHEMISTRY PRACTICAL L T P C

SKILL BASED SUBJECT TEXTILE CHEMISTRY PAPER – IV - - 2 3
Knowledge of Higher Secondary Level Syllabus 2015-
Pre-requisite
and Dye Chemistry Version 2016
Course Objectives:
1. Impart skills and knowledge to the students in handling laboratory equipment and reagents
2. Make the students learn the technique in the analysis of water quality using pH and
volumetric techniques for industrial use.
3. Impart skills in the estimation of various industrial substances
4. Impart knowledge in the preparation of various industrial dyes and dyeing.

1 Analyze the quality of water for industrial use as well as various K1-K6
substances of industrial use
2 Learn the various methods of dye preparation and dyeing. K1-K6
Part I Analysis 15 hours

1. Estimation of pH- paper, digital pH meter, pH solution
2. Volumetric analysis of Sodium Nitrite
3. Estimation of available chlorine in bleaching powder
4. Analysis of acidity of water by Volumetry
5. Analysis of alkalinity of water by Volumetry
Part II Preparation of Dyes 15 hours

1. Methyl Red
2. Malachite Green
3. Methyl Orange
4. Para nitro benzene azo beta naphthol
5. Azo amino benzene.
Text Book(s)
1 Elementary Idea of Textile Dyeing, Printing and Finishing” Kanwar Varinder Pal Singh,
Kalyani Publishers, 2009
2 Instrumental Methods of chemical Analysis, B.K Sharma, 2014
3 The Complete Technology Book on Dyes & Dye Intermediates by National Institute of
Industrial Research, 2004
Reference Books
1 Handbook of Water Analysis, 3rd Edition by Nollet, Taylor and Francis, 2013.
2 Vogel's text book of quantitative Chemical Analysis, Sixth edition- J Mendham, R C
Denney, J D Barnes, M J K Thomas, Pearson Eduction Publshers, 2009.
Page 50 of 74

1 https://nptel.ac.in/content/storage2/courses/105101010/downloads/Lecture27.pdf
2 https://en.wikipedia.org/wiki/Analysis_of_water_chemistry
3 https://www.youtube.com/watch?v=cNiRWfMjQMU
5 https://study.com/academy/lesson/chemicals-dyes-used-in-the-textile-industry.html

CO1 S S S S S S S
CO2 S S S S S S S
Page 51 of 74
Elective
Courses
Page 52 of 74
Course code 5EA POLYMER CHEMISTRY L T P C

ELECTIVE Elective – I (A) 4 - - 4
Syllabus 2019-
Version 2020
Course Objectives:
1. To understand the types, nature and the various methods of preparation polymers.
2. To learn about the different types of polymerisation reaction mechanism, bonding and
properties of polymers.
3. To study the molecular weight determination methods, preparation and properties of
commercially important polymers.

1 Classify Polymers based on their origin, mechanism of formation, citing K1-K3
example. Understand the methods of preparation process and apply the -
correct method of preparation for a particular polymer.
2 Analyze the reaction mechanisms of polymerization. K1,K4
3 Understand the relation between the bond forces and structural properties of K2,K4
polymers.
4 Understand the principles behind the molecular determination methods and K2,K4
applying them to calculate the different molecular weights of polymers.
5 Explain the basic preparation methods and have a good knowledge on the K2,K3
Industrial Applications of Polymers.
K1 - Remember; K2 - Undestand; K3 - Apply; K4 - Analyze; K5 - Evaluate; K6 - Create
Unit:1 Classification and Preparation of Polymers 12 hours

1. Classification Of Polymers-Natural Polymers And Synthetic Polymers. Synthetic Polymers-
Addition Polymers, Condensation Polymers.
2. Methods Of Preparation Of Polymers-Bulk, Solution ,Suspension And Emulsion
Unit:2 Types of Polymerization 12 hours

Different Types Of Polymerization-Step Growth Polymerization, Addition Polymerization
And Co-Polymerization -Random, Alternate, Block And Graft Polymerization.
Unit:3 Properties of Polymers 12 hours

Primary And Secondary Bond Forces In Polymers-Coherence Energy-Structure Property
Relationship
i) Mechanical Properties ii) Thermal Stability-Glass Transition Temperature iii) Flame
Resistance iv) Chemical Resistance v) Degradability vi) Electrical Conductivity
Page 53 of 74
Unit:4 Determination of Molecular Weight Methods 12 hours

Molecular Weight Of Polymers-Number Average And Weight Average Molecular Weight
Methods.
Number Average Molecular Weight Methods.
1. Osmometry (membrane) 2. Cryoscopy & Ebullioscopy 3. Osmometry (Vapour
pressure)
4. Viscometry 5. End Group Analysis.
Weight Average Molecular Weight Methods.
1. Light scattering 2. Ultra centrifugation
Molecular weight distribution.
Unit:5 Industrial Polymers 12 hours

Important industrial polymers, preparation and applications of
i) Polyethylene, polypropylene ii) Polyamides iii) Polyvinyl chloride and
polymethylmethacrylate
iv) Polyesters and polycarbonates v) Polyurethanes vi) Phenol-formaldehyde and melamine-
formaldehyde vii) Polysilanes and polysiloxanes viii) Polyaniline

Text Book(s)
1 Polymer Science - V R Gowariker; N V Viswanathan; Jayadev Sreedhar -New Age
International - 2003
Reference Books
1 Polymer chemistry an introduction-M.P.Stevens, Oxford-1990
2 Textbook of polymer Science-FW Billmeyer, Wiley-1984.

1 https://youtu.be/k_RErdKwaAg
2 https://youtu.be/H1Y1oxQ5eUA
3 https://youtu.be/7AWQyFr_GLA
Course Designed By: Dr. S. P. Rajasingh and Dr. K. Velumani

CO1 S M L S S S M
CO2 S M M S S M S
CO3 M M S S S M S
CO4 S S S M S M S
CO5 S M L M S S S
Page 54 of 74
Course
AGRO INDUSTRIAL CHEMISTRY L T P C
code
ELECTIVE Elective I (B) 4 - - 3
Syllabus 2010-
Pre-requisite Basic Knowledge in Agriculture
Version 2011
Course Objectives:
1. Let students know the sources of water for agriculture. Impart the knowledge of water and
soil analysis.
2. Inculcate the students about available fertilizers and pesticides and their role
3. To describe the various stages of process in sugar production and starch fermentation.
4. Knowledge on oil, fats and waxes and their contribution to day to day life.

1 Have knowledge on the sources of water for agriculture and analysis of K2-K4
water and basics on waste water treatment
2 Acquires the knowledge about soil, soil fertility and various parameters K1-K5
involved in evaluation of soil.
3 Describe the importance of nutrients, fertilizers and pesticides for plant K2 –K4
growth
4 Understand the sources and production of sugar and uses of molasses. K1-K6
5 Outline the chemistry of oils, fats and waxes and their role in everyday life K2-K6
Unit:1 Water source for agriculture- Water Treatment & Analysis 12 hours
Sources of water supply for agriculture. Hard and soft water. Water softening methods: lime
soda process, phosphate conditioning, permutit and ion-exchange processes. Water analysis;
determination of hardness of water, acidity, alkalinity, pH value, amount of free CO2, fluoride
content, chloride content and their estimation. Biological oxygen demand (BOD), chemical
oxygen demand (COD), chlorine demand and their determinations. Recycling of water.
Unit:2 Chemistry of soil-soil classification and soil analysis 12 hours

Definition of soils. Classification of soils. Properties of soils-physical properties and mechanical
analysis. Structure and Texture. Soil water, soils air and soil temperature. Chemical properties-
soil mineral matter-soil colloids, ion-exchange reactions. Soil fertility and its evaluation. Soil
organic matter and their influence on soil properties –N ratio effects. Soil reactions. Soil pH,
acidity, alkalinity, buffering of soils and its effects on the availability of N, P, K, Ca, Mg, I, AI,
Mn & sulphuric acid. soils salinity, acid & alkaline soils- their formation and reclamation.
Unit:3 Fertilizers and Pesticides 12 hours

Fertilizers: 1. Effect of N,P,K, secondary nutrients and micro nutrients on plant growth and
development.
2. Importance of nitrogenous fertilizers. Nitrogen cycle and fixation of atmospheric nitrogen.
principle and manufacture of ammonium nitrate, ammonium sulphate, and urea
Page 55 of 74
3. Phosphate fertilizers. Preparation and uses of mono and diammonium phosphates, super
phosphate and triple super phosphate.
4. Potassium fertilizers-potassium nitrate, potassium chloride, potassium sulphate. Mixed
fertilizers. Methods of compost in green manuring, concentrated organic manures and their
chemical composition. Oil cakes, horn and hoof metal.
Pesticides Classification-Insecticides, fungicides and herbicides. General methods of
preparation, application and toxicity. Insect attractants and repellants-fluorine compounds, boron
compounds, arsenic compounds, organomercuric compounds, DDT, BHC,2,4 –D compounds,
pyridine compounds.
Unit:4 Chemistry of sugar and fermentation 12 hours

1. Details of manufacture of sucrose from cane sugar-extraction of juice, purification,
concentration, crystallization, separation and refining of crystals, recovery of sucrose from
molasses. Manufacture of sucrose from beetroot. Estimation of sucrose and inversion sugar by
polarimetry. 2. Manufacture of alcohol from molasses and starch by fermentation process.
Unit:5 OILS, fats and Waxes 12 hours

Classification of oils fats and waxes: distinction between oil, fats and waxes Hydrogenation of
oils-principle and manufacturing details. Definition and determination of soapanification value,
acid value, iodine value RM value and Hehner value and their signification. Elaidin test for oils.
Some common waxes like spermaceti, Bees wax, baybeery wax and their uses. Soap and its
manufacture; toilet and transparent soaps. Cleansing action of soap. Detergent.
Text Book(s)
1 Soil Chemistry – Shivanand Tolanur, CBS Publishers & Distributors 2nd Edition, 2018.
Insecticides, Pesticides and Agro based Industries – R.C.Palful, K.Goel, R.K.Gupta
2 Industrial Chemistry-B.N Chakrabarty, Oxford & IBH Publishing Co, New Delhi,1981
3 Industrial Chemistry-B.K.Sharma, GOEL Publishing House, 2000
Reference Book
1 Nature and properties of soils - Nyle C.Brandy, Ray R.Weil, Pearson Education India; 14th
Edition, 2013.
1 https://www.cdc.gov/healthywater/other/agricultural/index.html
2 http://nmsp.cals.cornell.edu/publications/NMSPLabManual2017.pdf
3 https://www.youtube.com/watch?v=R9J7pOU5FSg
https://webstor.srmist.edu.in/web_assets/srm_mainsite/files/2017/Oils-Fats-Waxes-
4
Notes.pdf
Course Designed By: Dr. S. P. Rajasingh and Dr. M. Sivakumar

CO1 S S S M S M S
CO2 S M M S S S S
CO3 S M S M S S S
CO4 S S S S S S S
CO5 S S S S S S S
Page 56 of 74
Course
PHARMACEUTICAL CHEMISTRY L T P C
code
ELECTIVE Elective I (C) 4 - - 3
Syllabus 2010-
Pre-requisite Basic Knowledge in Chemistry and Biology
Version 2011
Course Objectives:
1. Give an overview on pharmaceutical chemistry and terminologies used in.
2. Outline the structure and properties of molecules in biological systems
3. Impart knowledge about medicinally important compounds
4. Describe the role of various drugs in cardiovascular

1 Have knowledge on terminologies used in pharmaceuticals and their K1, K2
clinical chemistry
2 Understand the chemistry and uses of alkaloids, analgesics, antibiotics and K1,K2,
sulfonamides K3, K4
3 Understand how molecules play important role as medicine K2,K3,
K4,
4 Have knowledge on bioinorganic chemistry and their role in various K2,K3,
diseases K4,K5
5 Outline the importance of drugs with special emphasize on cardiovascular K1,K2,
related diseases K4
Unit:1 Introduction to Pharmaceutical Chemistry 12 hours

1. Important terminologies used in pharmaceutical chemistry-Definition of the following terms-
drug, pharmacology, pharmacognosy, pharmacy, therapeutics, toxicology, chemotherapy,
pharmacopoeia (BP, IP, USP), National formulary, pharmacophore, bacteria, virus, vaccines,
toxoids, primary immunization, additive effect, synergism, antagoinism, plaubo, LD50, ed50 and
therapeutic index
2. Routes of drug administration-local, enema, oral or external, parental-advantages and
disadvantages oral and parental routes-inhalation, intradermal, subcutaneous, intramuscular,
intravenous-intrathecal-intraarticular-transcutaneous-transmuscusal.
3. Clinical chemistry-A Diagnostic test and one method of estimation bilirubin and cholesterol in
serum or plasma or urine. Biuret test for urea.
4. First aid to prevent bleeding and maintain breathing
5. Causes and symptoms of food poisoning, botulism-mushroom and plant poisoning-first aid.
6. Causes, symptoms and treatment of anemia, diabetis, tuberclosis, asthma, jaundice, piles,
leprosy, typhoid, malaria, cholera and filarial.
7. Indian medicinal plants and their importance. Spices and their medicinal uses.
Page 57 of 74
Unit:2 Alkaloids, Analgesics, Antibiotics and Sulfonamides 12 hours

1. Alkaloids- definition-general methods of isolation-colour tests for identification-source,
isolation, structure and use of atropine-source, extraction, structure, SAR and uses of morphine
and quinine.
2. Analgesics-definition different types of pain (superficial, deep non visceral, visceral, referred
and pshycogeneic), classification – morphine and its derivatives. Synthesis assay and uses of
pethidine and methadone-antipyretic analgesics-salicylic acid derivatives-paracetamol,
phenacetin-propanoic acid derivative-Ibuprofen.
3. Antibiotics: definition –microbial synthesis structure, assay and uses of chloramphenicol and
pencilin-structure and use of streptomycin and tetracyclines.
4. Sulphanonamides: Definition-mechanism of action-classification-SAR- synthesis and use of
sulpha acetamide, sulpnathiazole, phthalyl sulphathiazole- sulphadiazine and sulpha pyridine-
assay.
Unit:3 Molecules to Medicine 12 hours

1. Antiseptics and disinfectants: Definition and distinction- phenol coefficient- examples-
phenolic compounds, dyes, cationic surfacts and chloro compounds. Tranquilizers-definition and
examples. Psychodelic drugs LSD and marijuana.
2. Anaesthetics – Definition –Classification –volatile anaesthetics (N2O, ethers,
halohydrocarbons, chloroform, haloethane)-ferguson principle –intravenous anaesthetics-
structure of thiopental sodium-local anaesthetic cocaine-source and structure – preparation and
uses of procaine orthocaine and benzocaine.
3. Vitamins-Definition-classification, sources and deficiency diseases of vitamins A,B,C,D,E
and K. Importance of vitamin A in vision (rhodopsin cycle).
4. Definition of cancer and antineoplastic drugs-examples antimetabolite, natural substances
harmones, alkylating agents, inorganic complexes and other compounds-definition of
hypoglycemic drugs-types and cause for diabetics-examples (Sulphonyl ureas and biguanides)
Unit:4 Medicinally Important Compounds 12 hours

1. Medicinally important compounds of Al2P2As, Hg and Fe. Uses of the following MgSO4
7H2O, milk of magnesia, magnesium trisilicate-Aluminium hydroxide gel, dihydroxy aluminium
amino acetate, Aluminium acetate and aluminium monostearate-paroxon-phosphorine,
cyclophosphosphomide-tricyclophos-preparation and use of thiotepa-sodium and copper
cacodylates-preparation and uses of aromatic aresericals (carbosone, triparasomide, acetarsonide,
neoarsphenamine, oxophenarisince)- HgCl2, Hgl2 and Hg(CN)2 as disinfectations-importance of
organic mercury compounds-structure and uses of thiomersal, netromersal merbromine and
mersalyl acid-Ferous gluconate, FeSO4, scale preparation (ferric ammonium acetate), ferrous
fumarate, ferrous succinate and ferrous chlorinate.
2. Organic pharmaceutical aids-Definition-agents for kidney function (aminophippuric acid)-
liver function (sulphobrophthalein sodium, rose Bengal)-corneal ulcer detection (Fluoescein
sodium)-Blood volume determination (Evans Blue) pituitary function (metyrapone)-ointment
bases-preservatives-antioxidants-sequeshants, colouring, sweetening, flavouring, emulsifying
and stabilizing agents.
3. AIDS-cause HIV-prepagation-prevention and treatment.
Page 58 of 74
Unit:5 Cardiovascular and related drugs 12 hours

1. Blood-composition-grouping-Rh factor-buffers in blood-Functions of plasma proteins-clotting
mechanism-blood pressure. 2. Coagulants and anticoagulants-definitions and examples. 3.
Antianemic drugs (iron, vitamin B12, folic acid). 4. Cardiovascular drugs : definition and names
of drugs for each of the following - antiarrythmic drugs - antihypertensive drugs-antianginal
agents-vasodilators-lipid lowering agents-sclerosing agents

Text Book(s)
1 Pharmaceutical Chemistry by S. Lakshmi, Sultan Chand & Sons, 2nd ed (1998).
2 Pharmacolgy and pharmatherapeutics, Vol.1 & 2, R.S. Satoskar and S.D. Bhandarkar 11th
Ed, Popular prakashan, Mumbai, 1989.
3 Bentleys, Text book of pharmacutics, 8th Ed. E.A. Raubins, 1992, All India traveler book
sellers, Delhi.
4 Medicinal Chemistry, Ashutosh kar, New Age International, 1992.
5 A text book of pharmaceutical chemistry, Jayashree ghosh, S. Chand, 1997.
Reference Book(s)
1 From molecules to medicines-J.L.Sussman, P. Spadon, Springer; 2009th edition.
2 Organic medicinal and pharmaceutical chemistry-J.M. Beale, J.H. Block, Wolters Kluwer
India Pvt. Ltd.; 12th edition 2010.
1 https://www.youtube.com/watch?v=jN34FZJ_--U
2 https://www.youtube.com/watch?v=Wn33DQhmLbg
3 https://www.youtube.com/watch?v=9xSqezCMHnw
Course Designed By: Dr. M. Asaithambi

CO1 M S M M S M S
CO2 M M S M M S S
CO3 S M S L S M M
CO4 S M M M M M L
CO5 M S M L M M M
Page 59 of 74
Course
LEATHER CHEMISTRY L T P C
code
ELECTIVE Elective II (A) 4 - - 3
Syllabus 2010-
Version 2011
Course Objectives:
1. To understand the basics of skins, leather and their composition.
2. Impart the principle involved in pre-tanning and structure and process of various tannings
3. Inculcate the methods of curing hides and skins and process of dyeing leather
4. Knowledge on the water pollution by tannery industry and it’s effluent treatment

1 Understand the structure and composition of hides and skins and principle K1-K3
involved in pre-tanning
2 Have knowledge on various types of tanning and their physic-chemical K2, K3
properties
3 Interpret the chemistry behind the chrome tanning process K2-K4
4 Analyze the process involved in curing of hides and skin and their K1-K4
preservation
5 Have clear idea on sources of tannery effluents and their treatment K2,K3
Unit:1 Hides, Skins and Leather 12 hours

1. Hides, Skins,Leather-An elementary knowledge of the structure and composition of hides and
skins. Proteins and their characteristics, Anatomy and histology of protein constituents of leather
(an elementary concept).
2. Basic principle involved in pre-tanning such as soaking, liming, deliming, bating , pickling
involved in pre-tanning such as soaking, liming, deliming, bating, pickling and depickling.
Unit:2 Types of Natural and Synthetic Tannings 12 hours

1. Types of tanning-vegetable and mineral tanning, Different types of vegetable tanning-
materials classification and chemistry of vegetable tanning. Factros and Physio-chemical
principle involved in vegetable tanning, Fixation of vegetable tanning.
2. Synthetic tannings-their classifications, general methods of manufacture and use.
Unit:3 Chemistry of Chrome Tanning 12 hours

1. The preparation and chemistry of chrome tanning liquids, Olation, Oxolation and hydrolysis
of chrome liquids. Effect of adding tanning agents-Role of pH in the reaction of chromium
complexes with hide proteins. Factors governing chrome tanning-chemistry of neutralization
process. A brief survey of chemistry of other tanning like Al, Zr and Te salts and their relative
merit in contrast with chrome tanning 2. Chemistry of combination of tannages involving
vegetable tanning aldehydes, chrome and other mineral tanning agents.
Page 60 of 74
Unit:4 Preservation of Hides and Skins and Leather Dyeing 12 hours

1. Chemical methods of curing and preservation of hides and skins in acid and alkaline solution.
2. Principles of analytical methods employed in curing, liming, deliming, bating, pickling.
Analysis of vegetable tanning materials and extract.
3. Process of dyeing leather-Use of mordants, dyeing auxillaries such as leveling, wetting and
dispersing agents-Dye fixations.
Unit:5 Source and Treatment of Tannery Effluents 12 hours

1. Animal bye-products-their collection, handing and preservation methods (such as hair, blood,
bones, glands, Kerationus materials and their utilization).
2. Tannery effluents and treatment: Types of water pollution-phsical, chemical, physiological
and biological. Different types of tannery effluents and wastes-beam-house waste-liquors-
tanning and finishing yard waste liquors, solid waste-origin and disposal.

Reference Book(s)
1 Tanning Chemistry: The Science of Leather-A.D. Covington, W.R.Wise, Royal Society of
Chemistry, 2019.
2 Tanning processes- A.C. Orthmann, Read Books Publishers, 2011.
3 The Chemistry of Leather manufacture- G.D.Mclaughlin, Read Books, 2011.
4 Vegetable tanning materials- F.N. Howes, Butterworths Scientific Publications, 2007.

https://blog.walnutstudiolo.com/2019/04/25/kinds-of-leather-by-tanning-process-veg-tan-
1
vs-chrome-tan/
2 https://www.lowimpact.org/lowimpact-topic/skins-hides/
3 https://envibrary.com/wastes-from-tannery-industries/
Course Designed By: Mr. C. Sudhakar

CO1 M M S M S M S
CO2 S S M L M S M
CO3 M L S M M L M
CO4 L M M L M M S
CO5 M M S L M M S
Page 61 of 74
Course
CHEMISTRY OF PLANT BASED PRODUCTS L T P C
code
ELECTIVE Elective II (B) 4 - - 3
Basic Knowledge about Starch, Cellulose and Syllabus 2010-
Pre-requisite
Protein Version 2011
Course Objectives:
1. To impart the knowledge about structure and properties of starch, cellulose and proteins
2. Describe the students the process involved in the manufacture of them and their applications
3. To inculcate the chemistry of various cellulose derivatives and their application in paper
industry

1 Understand the structure, physical and chemical properties and manufacture K1-K5
of starch and their applications
2 Identify the sources, structure, properties and reactions of cellulose K1,K2,
K4
3 Describe the structure, Properties, manufacture and uses of proteins K1-K5
4 Give the structure of derivatives of cellulose K1-K3
5 Outline the chemistry behind paper industry with special emphasis on K1-K6
cellulose
Unit:1 Chemistry of Starch 12 hours

Structure, physical and chemical properties. Manufacture and uses of unmodified and modified
starch, dextrin, sugar syrup, hydrolysis of starch to edible and industrial glucose applications of
starch in textile sizing and in fermentation industries.
Unit:2 Chemistry of Cellulose 12 hours

Structure physical and chemical properties general reactions, major sources and uses of
cellulose, chemical and enzymatic hydrolysis of cellulose. Statistics and economics and
cellulose. Chemistry of minor products of wood like lignin, pentosans, resins etc, laboratory
preparation, manufacture and uses of chemical cellulose.
Unit:3 Chemistry of proteins 12 hours

Structure, Properties, Major sources, technological uses, hydrolysis of proteins and protein
isolates. Manufacture, Properties and uses of gelatin, casein, collagen, protein isolates.
Unit:4 Cellulose Derivatives 12 hours

Cellulose nitrate, cellulose acetate, ethyl and methyl cellulose, sodium cellulose sulphate,
sodium, carboxy, hydroxyl, methyl, cellulose, regenerated cellulose, major cellulose-platics-
sodium carboxy methyl cellulose.
Page 62 of 74
Unit:5 Application of Cellulose 12 hours

Different methods of pulping, manufacture and uses of different quality of paper products like
card-board, newsprint, writing paper, tissue piper and filter paper. A short discussion of the
pollution problems and by-products utilization of industries based on starch cellulose and
proteins.

Text Book(s)
1 Fundamentals of Biochemistry-J.L.Jain, S.Jain, N.Jain, S Chand; Seventh edition, 2016.
2 Cellulose Derivatives: Synthesis, Structure, and Properties – T. Heinze, O.A.El Seoud, A.
Koschella, Springer International Publishing, 2018.
Reference Book(s)
1 Starch: Chemistry and Technology-J.N. BeMiller, R. L. Whistler, Academic Press; 3rd
edition, 2009.
2 Cellulose chemistry and its application-T.P.Nevell, Halsted Press, 1985.
1 https://starch.eu/starch/
2 https://en.wikipedia.org/wiki/Cellulose
3 https://www.youtube.com/watch?v=gDJ0QvtGjVE
Course Designed By: Dr. M. Sivakumar and Mr. C. Shudhakar

CO1 S M M S S M S
CO2 S S M M S S S
CO3 M M M M S M S
CO4 S S S S M S S
CO5 S M S S S S S
Page 63 of 74
Course
6EC DYE CHEMISTRY L T P C
code
ELECTIVE Elective II (C) 4 - - 3
Knowledge on Structure of Organic Syllabus 2019-
Pre-requisite
Molecules Version 2020
Course Objectives:
1. Outline the fundamentals of volumetric estimations
2. Explain electrophilic and nucleophilic substitution reactions
3. Describe the application of boron and silicate chemistry
4. Discuss thermodynamics and solid state chemistry

1 Understand the principles of colour and its relation with K1 – K5
compound’s structure
2 Analyze and classify dyes based on their chemical structure and K1 – K3
applications
3 Describe the synthesis of di and triphenyl methane dyes and their K2, K3,
applications
4 Understand chemistry of nitrogen containing dyes and their K2, K3
applications
5 Outline the importance of pigments in various fields K1 – K4
Unit:1 Chemistry and Theory of Colours 12 hours

Colour and constitution-Relationship of colour observed-to wave length of light absorbed-
Terms used in colour chemistry-Chromophores, Auxochromes, Bathochromic shift,
Hypsochromic shift. Colour of a substance-Quinonoid theory and molecular orbital
approach.
Unit:2 Classification of Dyes 12 hours

Classification of Dyes-chemical classification-classification according to their applications-
Acid dyes-Basic dyes. Azoic dyes, mordant dyes, vat dyes, Sulphur dyes, Disperse dyes,
Nitro dyes-and Nitroso dyes process of dyeing (simple treatment).
Azo dyes-Principles governing azo coupling-mechanism of diazotization-Coupling with

amines, coupling with phenols Classification according to the number of azo group &
application-Tautomerism in azo dyes.
Unit:3 Synthesis and Applications of Dyes - I 12 hours

Synthesis, reactions and applications of Di and Triphenyl methane dyes-phthalein dyes-
Xanthen dyes-acridine dyes-sulphur dyes. Phthalocyanines-Cyanine dyes. Malachite
green, Para-rosaniline, crystal violet.
Page 64 of 74
Unit:4 Synthesis and Applications of Dyes - II 12 hours

Azine, Oxazine and Triazine Dyes. Synthesis and applications of quinonoid dyes including
vat dyes based on anthraquinone.
Unit:5 Pigments and Their Applications 12 hours

Requirements of a pigment: Typical Organic and Inorganic pigments-application and their
uses in paints. Reaction of dyes with fibres and water-Fluorescent Brightening agents.
Application of dyes in other areas-medicine, chemical analysis, cosmetics, colouring
agents, food and beverages.

Text Book(s)
1 Synthetic Dyes – G.R. Chatwal, Himalaya Publishing House, 2009.
2 The chemistry of synthetic dyes Vol, I, II, III & IV - K.Venkataraman, Academic Press
N.Y., 1949.
3 The Hand book of Synthetic Dyes and Pigments – K.M. Shah, Publisher Edutech,
2013.
Reference Books
1 The chemistry of synthetic dyes and pigments - H.A. Lubs, New York, Hafner Pub.
Co., 1965.
2 Organic chemistry Vol.I - I.L.Finar, Pearson India, 6th edition, 2012.
3 Dyes and Pigments: New Research – A.R. Lang, Nova Science Publishers, Inc.; UK
ed. Edition, 2013.
2 https://www.internetchemistry.com/chemistry/dye-chemistry.php

CO1 S S S S S S S
CO2 S M M M S S M
CO3 S M M M S M M
CO4 S M M M S M S
CO5 S S S S S S S
Page 65 of 74
Course ANALYTICAL CHEMISTRY II-LAB

L T P C
code TECHNIQUES
ELECTIVE Elective III (Group A) 4 - - 3
Syllabus 2010-
Version 2011
Course Objectives:
1. The students understand the basic principles and components of chromatography
2. To inculcate the theory, instrumentation and applications of various spectrophotometry
3. Introduce the theory, techniques and applications of polarimetry and electrochemical
Methods
4. Give an insight into synthesis and purification of some organic and inorganic
compounds

1 Describe the principles of various chromatography K1-K4
2 Understand the theory behind UV, IR and NMR spectrophotometry and K1-K3
their applications.
3 Describe the instrumentation of polarimetry K2,K3
4 Know the various electrochemical methods of analysis and their K2-K4
applications
5 Outline the synthesis and purification steps of some of organic and K2, K3
inorganic compouds
Unit:1 Chromatography 12 hours

Classification of the chromatographic methods, principles of differential migration, Adsorption
phenomenon, nature of the adsorbent, solvent systems. Rf. Values. Column chromatography,
Partition chromatography, paper chromatography, TLC, -theory and techniques.
Unit:2 Spectroscopy 12 hours

Theory, instrumentation and application of (i) UV and visible spectrophotometry (ii) IR
spectrophotometry (iii) Flame Photometry (iv) NMR spectroscopy
Unit:3 Polarimetry 12 hours

Theory, instrumentation, experimental procedure and application.
Unit:4 Electrochemical Methods of Analysis 12 hours

Polarography, cyclic voltametry, differential pulse polarography and calorimetry: Theory,
techniques and applications.
Unit:5 Preparation and Purification of Compounds 12 hours

Preparation and purification of organic and inorganic compounds like, (i) Aspirin from salicylic
acid (ii) Acetanilide from aniline (iii) Benzanilide from aniline (iv) iodoform from ethanol/and
(v) Meta di nitro benzene acetone (vi) Methyl orange/methyl red (vii)preparation of Nylon 66
Page 66 of 74
(viii) Caffine from tea leaves (ix) Caesin and lactose from milk (x) Nicotine and Nicotine
sulphate (xi) Bakelite from phenol and From tobacco waste formaldehyde (xii)As2 O3 Sol, Fe
(OH)3 Sol (xiii) Tetrammine-copper sulphate (xiv) Tetrammine Cobalt carbonate (xv) Sodium
thiosulphate and (xvi) Cuprous chloride dithionate

Text Book(s)
1 Vogel’s Text Book of Quantitative Chemical Analysis – J. Mendham, RC Denney, JD
Barnes, M. Thomas, B. Sivasankar, Pearson Publishers 6th edition 2009.
Reference Book(s)
1 Physical methods for chemistry-R.S.Drago, W B Saunders Co Ltd; 2nd Revised edition,
1992.
2 Spectroscopy in Inorganic chemistry-C.N.R Rao and JR Ferraro Academic Press Inc, 1971.
3 Fundamentals of Analytical Chemistry - D.A.Skoog, D.M.West, S. Jose, F.J.Holler
Cengage Learning, 2004
4 Instrumental methods of Chemical Analysis-B.K. Sharma Krishna Prakashan Media (P)
Ltd. 2014.

1 https://www.youtube.com/watch?v=Zp-BHsdqsRw
https://www.slideshare.net/SihamAbdallaha/electrochemical-method-of-analysis-
3
31352857
https://gtu.ge/Agro-
4 Lib/Vogels_TEXTBOOK_OF_QUANTITATIVE_CHEMICAL_ANALYSIS_5th_ed__-
_G_H_Jeffery.MsuCity.pdf
Course Designed By: Dr. M. Sivakumar and Dr. A. Thirumoorthi

CO1 M S S M M M M
CO2 S S S M M M M
CO3 S M M M M L M
CO4 L S M L L M M
CO5 M M L M L M M
Page 67 of 74
Course
6EE ENVIRONMENTAL CHEMISTRY L T P C
code
ELECTIVE Elective III (B) 4 - - 3
Syllabus 2019-
Pre-requisite Basics of Environment Science
Version 2020
Course Objectives:
1. Explain clearly Environmental segments and composition of atmosphere
2. Understand the Natural Cycles of the environment
3. Detailed explanation of the different types of pollution

1 Understand the concepts ,environmental segments and composition of the K1,K2
atmosphere
2 Know about the environment cycles and their significance K1
3 Discuss the water pollution,sewage and Industrial waste water treatment K1,K2
4 Describe the reactions in air pollution ,particulates and analysis of K2,K4
pollutants
5 Explain the thermal,noise and radioactive pollution and their effects and K1-K3
methods of control
Unit:1 Chemistry of Environment and Atmosphere 12 hours

Concept and scope of environmental chemistry-Nomenclature: Pollutant, contaminant, receptor,
sink, pathways of a pollutant, speciation, dissolved oxygen, chemical oxygen demand (COD),
biochemical oxygen demand (BOD)-Environmental segments.
Composition of the atmosphere-atmospheric structure-earth’s radiation balance – particles, ions
and radicals in the atmosphere-formation of inorganic particulate matter- formation of organic
particulate matter-ions and radicals-photochemical reactions in the atmosphere-formation of
NO2, SO2, organic compounds, greenhouse effect.
Unit:2 Cycles of Environment 12 hours

Biological cycles & their significance-Gaseous and sedimentary cycles.
(a) Oxygen cycle and ozone chemistry (b) Carbon cycle (c) Nitrogen cycle
(d) Sulphur cycle (e) Phosphours cycle
Unit:3 Water Pollution and Treatment 12 hours

Water pollution: Hydrological cycle –aquatic environment-classification of water pollution –
organic pollutants, inorganic pollutants, sediments, radioactive materials, thermal pollution,
BOD & COD –signification-experimandal determination. Trace elements in water. Chemical
speciation of copper, lead and mercury.
Eutrophication-sewag treatment-primary and secondary treatments. Industrial waste water
treatment by 1) activated charcoal/synthetic resins 2) membrane techniques.
Page 68 of 74
Unit:4 Air Pollution 12 hours

1. Air pollutants-primary pollutants-sources of carbon monoxide, nitrogen oxides, sulphur
dioxide; sink and control. Hydrocarbons, photochemical smog, acid rain.
2. Particulates: sources-inorganic and organic particulate matters-effects on human beings,
materials, climate control of particulate emission- of atmospheric pollution, corrosion of metals-
indoor reactions of air pollutants-sinks of atmospheric gases.
Air quality standards: Monitoring –Analysis of carbon monoxide-nitrogen oxides-sulphur
dioxides-hydrocarbons.
Unit:5 Thermal and Electromagnetic Pollution 12 hours

1. Thermal pollution-definition, sources-environmental effects-control and prevention. Solar
energy as alternative source of energy, strategies for energy conservation.
2. Noise pollution: Sources and effects of noise pollution-control and prevention-solutions to
abuse. Supersonic jets and its effects.
3. Radioactive pollution: Sources of radioactive pollution-environmental threat of nuclear
reactors-breeder reactors-environmental conflicts between nuclear powers Methods of control
and prevention.

Text Book(s)
1 Environmental Chemistry-A.K .De, New Age International(P) Ltd., New Delhi(2010).
2 Environmental Chemistry- V.K. Ahluwalia,Ane Books India., New Delhi(2013).
3 Sodhi, G.S., Fundamantal Concepts of Environmental Chemistry, Narosa Publishing House
Pvt. Ltd., New Delhi, Third Edition, (2009).
Reference Books
1 A text book of Environmental Chemistry-Krishnan & Kannan, Anmol Publications, New
Delhi (1992).
2 Environmental chemistry & pollution control – Dhar, S.Chand &Co., New Delhi (1995).
2 https://nptel.ac.in/noc/courses/noc20/SEM2/noc20-ce57/
3 https://nptel.ac.in/content/storage2/courses/105101010/downloads/Lecture27.pdf
Course Designed By: Dr. T. Selvaraju and Mr. C. Sudhakar

CO1 S M L S S S M
CO2 S M M S S M S
CO3 M M S S S M S
CO4 S S S M S M S
CO5 S M L M S S S
Page 69 of 74
Course
TEXTILE CHEMISTRY L T P C
code
ELECTIVE Elective III (C) 4 - - 3
Syllabus 2010-
Version 2011
Course Objectives:
1. Make the students to understand the structure, Properties and uses of natural and
synthetic fibers.
2. Outline the impurities present in cotton and silks and the way to remove them.
3. Impart the knowledge about various dyes and dyeing of wools and silks

1 Understand the structure, production, properties and uses of natural fibers K1-K3
2 Understand the structure, production, properties and uses of synthetic fibers K2- K5
3 Identify the impurities present in cotton and silk and know the processes to K2, K3
remove them
4 Describe the various dyeing methods and natural dyes used for cotton fiber K1-K6
5 Outline different methods available for dyeing wools and silks K2-K6
Unit:1 Classification and Structure of Natural Fibers 12 hours

1. Fibre theory –polymers and polymerization-Morphology of fibres – Molecular arrangements
in fibres.
2. General classification of fibres-chemical structure, production, properties and uses of the
following natural fibres (a)natural cellulosic fibres (cotton and jute) (b) natural protein fibre
(wool and silk).
Unit:2 Properties and Uses of Synthetic Fibers 12 hours

Chemical structure, production, properties and uses of the following synthetic fibres. (i) Man
made cellulosic fibres (Rayon, modified cellulosic fibres) (ii) Man made protein fibres (Azions)
(iii) Poly amide fibres (different types of nylons) (iv) Poly ester fibres (v) Acrylic fibres and (vi)
Olefin fibres.
Unit:3 Impurities in fibers and their removal 12 hours

Impurities in raw cotton and grey cloth, wool and silk- general principles of the removal –
Scouring – bleaching – Desizing – Kierboiling- Chemicking –Chemical and machinery use-
Degumming and Bleaching of silk Scouring and Bleaching of wool.
Unit:4 Classification of Dyes 12 hours

Dyeing – Classification of dyes and their properties- applications – direct, basic, sulphur and
azoic dyes on cotton. Application of Vat and solubilised vat dyes on cotton and viscose. Mordant
mineral colours and black. Application of vegetable and other colour to cotton.
Page 70 of 74
Unit:5 Dyeing of Fibers 12 hours

1. Dyeing of wool and silk –Fastnerss properties of dyed materials – dyeing of nylon, terylene
and other synthetics.
2. Finishes given to fabrics- Mechanical finishes on cotton, wool and silk, method used process
of mercerizing –Anti-crease and Anti-shrink finishes –Water proofing.

Text Books(s)
1 Text Book of Applied Chemistry-M.A.Islam, Sonali Publications; 1st edition, 2011.
2 Chemistry of dyes & Principles of Dyeing -V.A.Shenai, Sevak Publications, 1983.
Reference Book(s)
1 The Identification of Textile Fibres – Bruno Luniak, Isaac Pitman & Sons, Limited, 1953.
2 Dyeing and chemical Technology of Textile fibres-5th Edition, E.R.Trotman, Charles
Griffin & Co Ltd, 1970. (Digitalized 2010).
3 Chemical Technology of fibrous Materials – F.I. Sadov, M.V. Horchagin and A.Matetsky,
Mir Publishers, 1978. (Digitalized 2008).
4 Textile Scouring and Bleaching E.R.Trotman, Charles Griffin & Co Ltd.1968.

1 https://blogionik.org/blog/2017/04/02/natural-synthetic-fiber/
2 https://www.assignmentpoint.com/science/textile/textile-fiber.html

CO1 S S M M M M S
CO2 M S S M S L M
CO3 M S S S M M L
CO4 S S S M S S M
CO5 S M S S S S M
Page 71 of 74
Annexure
Page 72 of 74
B. Sc. CHEMISTRY
Syllabus
(2021-2022)
Program Code: 22D
DEPARTMENT OF CHEMISTRY
(Affiliated Colleges)
Bharathiar University
(A State University, Accredited with “A“Grade by NAAC and
13th Rank among Indian Universities by MHRD-NIRF)
Coimbatore 641 046, INDIA
Page 73 of 74
BHARATHIAR UNIVERSITY: COIMBATORE 641046

DEPARTMENT OF CHEMISTRY
(Affiliated Colleges)
MISSION
To provide the fundamental knowledge of chemistry, empower students for

higher studies and acquire potential jobs.
Page 74 of 74

BSC Chemistry

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B. Sc.

Program Code: 22D

2021 – 2022 onwards

Program Educational Objectives (PEOs)

Program Specific Outcomes (PSOs)

PSO1 Apply chemistry knowledge to solve the problems in various areas.

Identify and analyze problems and gain skills to interpret chemical

Gain practical knowledge and analytical skills in designing and carrying

Have enough chemistry knowledge to go for higher studies and become

Program Outcomes (POs)

BHARATHIAR UNIVERSITY: COIMBATORE 641 046

Allied Subjects(Colleges can choose any two subjects)

Course code 13A GENERAL CHEMISTRY - I L T P C

Expected Course Outcomes:

Unit:1 Periodic Properties and Theory of Bonding 21 hours

Unit:2 Reaction of Alkenes and Alkynes 21 hours

Unit:3 Polar Effects and Conformations of Alkanes 21 hours

Unit:4 Liquid Crystals and Black Body Radiation 21 hours

Unit:5 Laws of Thermodynamics 21 hours

Total Lecture hours 105 hours

Mapping with Programme Outcomes

Course code 23A GENERAL CHEMISTRY - II L T P C

Expected Course Outcomes:

Unit:1 Volumetric Analysis and Redox Reactions 21 hours

Unit:2 Boron and Silicates 21 hours

Unit:3 Electrophilic and Nucleophilic Substitution 21 hours

Unit:4 Thermodynamics 21 hours

Unit:5 Solid State Chemistry 21 hours

Total Lecture hours 105 hours

Mapping with Programme Outcomes

Expected Course Outcomes:

Part I ANALYSIS OF CATIONS 45 hours

Total Practical hours 90 hours

Mapping with Programme Outcomes

Course code 33A INORGANIC CHEMISTRY - I L T P C

Expected Course Outcomes:

Unit:1 Methods of Extraction 9 hours

Unit:2 Extraction of Metals and Their Compounds 9 hours

Unit:3 Role of Solvents 9 hours

Unit:4 Organometallic Compounds 9 hours

Unit:5 Bioinorganic Chemistry 9 hours

Total Lecture hours 45 hours

Related Online Contents [MOOC, SWAYAM, NPTEL, Websites etc.]

Mapping with Programme Outcomes

Course code 33B PHYSICAL CHEMISTRY - I L T P C

Expected Course Outcomes:

Unit:1 Thermodynamics I 9 hours

Unit:2 Thermodynamics II 9 hours

Unit:3 Phase Rule 9 hours

Unit:4 Solutions 9 hours

Unit:5 C Program for Chemistry 9 hours

Total Lecture hours 45 hours

Related Online Contents [MOOC, SWAYAM, NPTEL, Websites etc.]

Mapping with Programme Outcomes

Course CHEMISTRY OF NATURAL AND

Expected Course Outcomes:

Unit:1 Natural Textile Fibers 6 hours

Unit:2 Viscose Fiber 6 hours