Total Marks: 70 11th CBSE (Ch-1,2,3,4 and 7) Time: 3 hour

DAV SCHOOL

• General Instructions :
Read the following instructions very carefully and follow them:
(i) This Question Paper contains 35 questions. All questions are compulsory.
(ii) Question Paper is divided into Five sections – Section A, B, C, D and E.
(iii) In section A – question number 1 to 18 are multiple choice (MCQ) type questions carrying
1 mark each.
(iv) In section B – question number 19 to 25 are very short answer (VSA) type questions
carrying 2 marks each.
(v) In section C – question number 26 to 30 are short answer (SA) type questions carrying 3
marks each.
(vi) In section D – question number 31 and 32 are cased-based questions carrying 4 marks
each.
(vii) In section E – question number 33 to 35 are long answer (LA) questions carrying 5 marks
each.
(viii) There is no overall choice. However, an internal choice has been provided in 2 questions in
section B, 2 questions in section C, 2 questions in section D and 2 questions in section E.
(ix) Use of calculator is NOT allowed.

SECTION-A
MCQs: [1 mark each]
1. If the concentration of glucose (C6H12O6) in blood is 0.9 g L–1, what will be the
molarity of glucose in blood?
(a) 5 M (b) 50 M (c) 0.005 M (d) 0.5 M
2. What will be the molality of the solution containing 18.25 g of HCl gas in 500 g of
water?
(a) 0.1 m (b) 1 M (c) 0.5 m (d) 1 m
3. If r is the radius of the first orbit, the radius of nth orbit of H-atom is given by
(a) rn2 (b) rn (c) r/n (d) r2n2
4. Total number of orbitals associated with third shell will be _______
(a) 2 (b) 4 (c) 9 (d) 3
5. The correct order of negative electron gain enthalpy (ΔegH) of the halogen atoms is
(a) F > Cl > Br > I (b) Cl > F > Br > I
(c) I > Br > Cl > F (d) Cl > Br > I > F
6. Isostructural species are those which have the same shape and hybridisation.
Among the given species identify the isostructural pairs.
(a) [NF3 and BF3] (b) [𝐵𝐹4− and 𝑁𝐻4+ ]
(c) [BCl3 and BrCl3] (d)[NH3 and NO3-]
7. In which of the following molecule/ion all the bonds are not equal?
(a) XeF4 (b) BF4- (c) C2H4 (d) SiF4
8. Which of the following is not an example of redox reaction?

9. Two solutions of a substance (non electrolyte) are mixed in the following manner.
480 ml of 1.5 M first solution + 520 ml of 1.2 M second solution. What is the
molarity of the final mixture?
(a) 2.70 M (b) 1.344 M (c) 1.50 M (d) 1.20 M

10. The number of radial nodes for 3p orbital is

(a)3 (b) 4 (c)2 (d) 1
11. Mass% of carbon in ethanol (C2H5OH) is
(a) 52 (b) 13 (c) 34 (d) 90
12. The molecular formula of chloride of Eka-Aluminium and Eka-Silicon respectively
are
(a) GaCl3 and SiO4 (b) GaCl3 and AlCl3
(c) AlCl3 and SiCl4 (d) GaCl3 and GeCl4
13. Oxidation number of Mn in K2MnO4
(a) +6 (b) +5 (c) -4 (d) +3
14. What is the IUPAC name of the element with atomic number 114?
(a) Unununnium (b) Unnilquadium
(c) Ununquadium (d) Unnilennium.
15. Which of the following elements does not show disproportionation tendency?
(a) Cl (b) Br (c)F (d) I
Given below are two statements labelled as Assertion (A) and reason (R). Select the
most appropriate answer from the options given below:

16. Assertion: Oxidation state of hydrogen in H2O is +1 and in CaH2 it is –1.

Reason: CaH2 is metal hydride and for hybrides, hydrogen is assigned the oxidation
state of –1.
(a) If both assertion and reason are CORRECT and reason is the CORRECT
explanation of the assertion.
(b) If both assertion and reason are CORRECT, but reason is NOT THE CORRECT
explanation of the assertion.
(c) If assertion is CORRECT, but reason is INCORRECT.
(d) If assertion is INCORRECT, but reason is CORRECT.
(e) If both assertion and reason are INCORRECT.
17. Assertion: The first ionization enthalpy of aluminium is lower than that of
magnesium.
Reason: Atomic radius of aluminium is smaller than that of magnesium.
(a) If both assertion and reason are CORRECT and reason is the CORRECT
explanation of the assertion.
(b) If both assertion and reason are CORRECT, but reason is NOT THE CORRECT
explanation of the assertion.
(c) If assertion is CORRECT, but reason is INCORRECT.
(d) If assertion is INCORRECT, but reason is CORRECT.
(e) If both assertion and reason are INCORRECT.

18. Assertion: For the outermost electron in Na atom, the orbital angular momentum
is zero.
Reason: For 3s electron, l = 0 and orbital angular momentum is zero.
(a) If both assertion and reason are CORRECT and reason is the CORRECT
explanation of the assertion.
(b) If both assertion and reason are CORRECT, but reason is NOT THE CORRECT
explanation of the assertion.
(c) If assertion is CORRECT, but reason is INCORRECT.
(d) If assertion is INCORRECT, but reason is CORRECT.
(e) If both assertion and reason are INCORRECT.

Section – B
Very short answer questions : [2 marks each]

19. Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with
aqueous hydrochloric acid (HCl) according to the reaction:
MnO2(s) + 4HCl(aq)→ MnCl2 (aq) + 2H2O(l) + Cl2(g)
How many grams of HCl react with 5.0 g of manganese dioxide?

20. Would you expect the second electron gain enthalpy of O as positive, more
negative or less negative than the first? Justify your answer.
21. Why is the electron gain enthalpy of O and F less negative than that of succeeding
element in the same group?
22. Is there any changes in the hybridisation of B and N atoms as a result of the
following reaction:
23. Determine the empirical formula of an oxide of iron which has 69.9% iron and
30.1% oxygen by mass.
24. Calculate the oxidation states of underlined elements in the following compounds.
a)KMnO4 b) CaOCl2
OR
The compound AgF2 is unstable compound. However, if formed, the compound
acts as a very strong oxidising agent. Why?

25. What is Hund’s rule of maximum multiplicity? Illustrate this by taking the example
of carbon.
OR
Write the electronic configuration and indicate the number of unpaired electrons
in case of
(i) P and (ii) Cr
Section – C

Answer any 3 of the following : [3 marks each]

26. Balance the following equation using half reaction method
P4 + -OH → PH3 + H2PO2-

27. (i) Give De-Broglie hypothesis.

(ii) Two particles A and B are in motion. If the wavelength associated with the
particle A is 5 × 10–8 m, calculate the wavelength of particle B if its momentum is
half of A.
28. Among the second period elements the actual ionization enthalpies are in the
order:
Li < B < Be < C < O < N < F < Ne Explain why:
(i) Be has higher ΔHi than B
(ii) O has lower ΔHi than N and F
(iii) Why Ne has highest value of I.E.

29. If the density of methanol is 0.793 kg L–1, what is its volume needed for making 2.5
L of its 0.25 M solution?
OR
50.0 kg of N2 (g) and 10.0 kg of H2 (g) are mixed to produce NH3 (g)
(a) Calculate the NH3 (g) formed and
b) Identify the limiting reagent in this reaction if any
30. Describe the hybridisation in case of PCl5. Why are the axial bonds longer as
compared to equatorial bonds?
OR
Draw the shapes and give the geometries of the following molecules on the basis
of VSEPR theory:
(i) CH4 (ii) SF4 (iii) NH3

Section – D
The following questions are case based questions. Read the passage carefully and
answer the questions that follow : [4 mark each]
31. In the modern periodic table, elements are arranged in order of increasing atomic
numbers which is related to the electronic configuration. Depending upon the type
of orbitals receiving the last electron, the elements in the periodic table have been
divided into four blocks, viz, s, p, d and f. The modern periodic table consists of 7
periods and 18 groups. Each period begins with the filling of a new energy shell. In
accordance with the Aufbau principle, the seven periods (1 to 7) have 2, 8, 8, 18, 18,
32 and 32 elements respectively. The seventh period is still incomplete. To avoid the
periodic table being too long, the two series of f-block elements, called lanthanoids
and actinoids are placed at the bottom of the main body of the periodic table.
(i) The last element of the p-block in 6th period is represented by the outermost
electronic configuration.
(ii) Give the position of element with the atomic number of an element is 33
(ii) Give general electronic configuration of s and d block elements
OR
(iii) Give the general electronic configuration for halogens and noble gases.

32. A mole is a collection of 6.022 × 1023 particles and the number 6.022 × 1023 is called
Avogadro number. The mass of this number of atoms in an element is equal to its
gram atomic mass and mass of this number of molecules in a compound is equal to
its gram molecular mass. The volume occupied by this number of molecules of a
gas at N.T.P is 22.4 L. When 6.022 × 1023 molecules of a substance are dissolved in 1
L of solution, the solution is known as 1 molar volume.

(i) Calculate the number of oxygen atoms in 4.4 g of CO2

(ii) Calculate the total number of electrons present in 3.2 g of methane
(iii) What is the number of total atoms in 11.2 L of CO 2?
OR
(iii) What is the number of electrons in 11.2 L of nitrogen gas?

Section – E
Long answer questions : [5 marks each]
33. a) Among the following pairs of orbitals which orbital will experience the larger
effective nuclear charge?
(i) 2s and 3s, (ii) 4d and 4f, (iii) 3d and 3p.
 b) How many sub-shells are associated with n = 4? And how many electrons will
be present in the sub-shell having ms value of –1/2 for n = 4?
OR
a) Calculate the total number of angular nodes and radial nodes present in 3p
orbital.
b) Nickel atom can lose two electrons to form Ni2+ ion. The atomic number of
nickel is 28. From which orbital will nickel lose two electrons?
c) Draw the shape of an orbital which has l = 0
d) Which energy levels do not have p-orbital?
34. a) Permanganate ion reacts with bromide ion in basic medium to give manganese
dioxide and bromate ion. Write the balanced chemical equation for the reaction
using any method of balancing.
b) Assign oxidation number of phosphorus in each of the following species:
i. NaH2PO4
ii. H4P2O7
OR
a) Consider the reaction between iron (II) ions and dichromate ions in acidic
solution as:
Cr2O72– + Fe2+ → Cr3+ + Fe3+ + H2O
b) Explain following terms:
i. Oxidising agent
ii. Disproportionate reaction
35. a) Write the complete sequence of energy levels in the increasing order of energy
in the N2 molecule.
b) Compare the relative stability and the magnetic behaviour of the following
species calculating the bond order.
N2, N2+, N22+, N2-
OR
a) Write the complete sequence of energy levels in the increasing order of energy
in the O2 molecule.
b) Compare the relative stability and the magnetic behaviour of the following
species:
O2+, O22+,O2, O2- , O22-