Total Solution In Plasticizers & Polymer Compounds

Trust Built On Performance

Outline of Presentation
Brief on Group & recent Expansions

Global outlook on Plasticizers

Regulatory & Performance constraint

Trajectory of New Gen Plasticizers from KLJ

Segmented Orientation of Plasticizers in India

Concluding Remarks

2
Welcome to KLJ Group
Serving since 1967

Largest Manufacturer and Largest Manufacturer in

Manufacturing
Market Leader of Capacity Chlorinated Paraffin
Plasticizers & Polymer 1.4 Million + segment across the Globe
Compounds in South Asia tpa

Annual Turnover Sales Presence

US $1.4 Billion 400+ Cities
(Rs. 109 billion) 90+ Countries

Modern Infrastructure Dedicated Team

Modern Specialized Of Doctorates And Technical
Instruments, Rich Library Personnel to develop the
and Latest Application best products for Customer
Machineries to test products Satisfaction. 2200+ Strong
for specific applications Workforce
 Plasticizers
Overview
EXPANSION &
BACKWARD INTEGRATION
EXTENSIVE R&D
Largest Manufacturer of Greenfield backward
Plasticizers in South Asia integrated facility at Centre supported with
Bharuch instrumental in in-house compounding &
expanding the manufacturing application laboratory
Installed Capacity - 665,000 tpa capacity of Plasticizers to to develop new
665,000 tpa and 100,000 tpa products and
of Phthalic/Maleic applications
Anhydride

Advantage of Widest Range, COMPLIANCES

Consistent Quality and MULTI-LOCATIONAL
Assured Supplies IN-HOUSE PACKAGING Consistent Quality and
MANUFACTURING FACILITY Reliable Performance for
PLANT
standard and special
Primary Plasticizers at applications, along with
Largest Range of HDPE Drums Silvassa & Bharuch (India) the dedicated lines for
Plasticizers offered manufacturing Chlorinated Paraffin at Non-Phthalate, REACH
Globally facilities at India, Bharuch (India), Rayong compliant & Food Grade
Thailand and Qatar (Thailand) & Mesaieed Plasticizers
Plants (Qatar)

Dedicated lines for Non-

Phthalate, REACH Compliant and
Food Grade Plasticizers
4
Plasticizers
Highlights-KLJ Petroplast Ltd (Bharuch)

EXTENSIVE R&D

First time in India, KLJ- PA plant is installed

Centre with the latest
supported with
process control in-house compounding
instrumentation and the automation & system -
application laboratory
Distributed Control System (DCS) with:toRemote IO / Universal IO
develop new
Technology and Universal Safety Barriers coupled with the
products and
fastest Ethernet-IP communication protocols,
applications Regenerative
Thermal Oxidizer (RTO) for efficient air pollution control to
destruct Carbon Monoxide from the air emission, as a voluntary
environmental protection initiative. (Very few PA plants
globally have this RTO) COMPLIANCES
Plasticizer Process Technology is in-house developed,
Consistent Quality and
continuous process as well as batch process & Reliable In-House HMHDPE
Performance for
Drum production Facility standard and special
applications,
Total Plasticizer plants’ Power requirement is met by the along
Coalwith
the dedicated lines for
based Cogen power generation plant Non-Phthalate, REACH
compliant & Food Grade
World Class Quality Laboratories for testing Raw Materials,
Plasticizers In-
Process and Final Products Quality

5
 Plasticizers
Product Range

Product Category Brand

Phthalates Kanatol 1212 ,Kanatol 1210,Kanatol 1000L, Kanatol 1001,Kanatol 1010 Kanatol
900,Kanatol 800 Kanatol 800 s, Kanatol 1056**,Kanatol 8461 Kanatol 7720**,Kanatol
400 (M)**,Kanatol 400N, Kanatol 400(I), Kanatol 200,Kanatol 100,

Speciality Kanatol 10A ,Kanatol 9A*,Kanatol 8A*, Kanatol 3A,Kanatol 2A, Kanatol 1A,Kanatol
Plasticizers 3001, Kanatol 3000,Kanatol TM 8-10L,Kanatol TM 8-10,Kanatol 3900,Kanatol
3800,Kanatol 3400AC*, Kanatol 3400C,Kanatol 3200AC,Kanatol 3200C[100%Bio],Kanatol
3430E**,Kanatol 80S, Kanatol 40S, Kanatol 8S,Kanatol 4S,Kanatol 1S,Kanatol
DPGB50,Kanatol DGB,Kanatol 9449,Kanatol 9090, Kanatol 8080 (FG)*,Kanatol
1120**,Kanatol 9061**,Kanatol 9428**,Kanatol B-40 [Bio]

Maleate Kanatol 9M,Kanatol 8M,Kanatol 4M,Kanatol 2M,Kanatol 1M

Plasticizers

ESBO Kanamoll 620 [Bio],Kanamoll 650 [Bio] -Epoxidized Soybean Oil

Chlorinated An Extensive Range (incl. VLCCP & LCCP) of Chlorinated Paraffin grades are
Paraffin's manufactured with varying paraffin carbon chains, chlorine contents & stabilizers
to suit the specific needs of the customers.
*Approved for Food Contact Application,** Proprietary Plasticizers, REACh Registered Products Available, FDA Certified Plant 6
 Plasticizers-Global Scenario
Overview

The Global Plasticizers market is expected to grow at a CAGR of 5.7%

USD 14.92 billion in 2022 to USD 18.34 billion in 2027
The growing infrastructure development in developing countries, such as China, India, and
Brazil is driving the demand for Plasticizers

Indian Plasticizers demand growth estimated at ~10%

Types of Plasticizers used in INDIA: Phthalates, Non-Phthalates, Adipates, Sebacates,
Trimellitates, Citrates, Specialty Plasticizers, Polymeric Esters, Chlorinated Paraffin,
Flame Retardants, Epoxidized Soybean Oil etc
Chlorinated Paraffin's dominates consumption of Plasticizers in INDIA followed by DOP/DINP &
other Phthalates/Non-Phthalates
There is a shift towards MCCP & LCCP consumption in Indian subcontinent in articles made for
exports
Asia Pacific holds 60% share of global Plasticizer consumption, closely followed by North
America, China dominates the majority stake of Plasticizers consumption in Asia Pacific

Sources:
IHS Reports / Global Plasticizer market volume by Statista Research Department
7
Non Phthalate | Kanatol 8080
New Gen Plasticizer

To meet “Increasing challenges of Regulatory compliance, Product Performance"

Food Contact approved

Better bonding/compatibility due to unique structure

Lubricating itself, resultant

- Preparing Plastisols, Consuming Shorter Time & Less Energy

Rare combination of
- Low Volatility - Less Migration - Ease of Process

Non Compatible with Secondary Plasticizers

Non-Phthalate replacement of DOP

8
Non Phthalate | Kanatol 8080
Non Phthalates | Comparison
Attributes

• Low Cost • Resistance to

• UV Resistant hydrolysis
10 • Adhesion • Chemically resistant
• Heat Stable • Low maintenance
5 • Stain • Long service life
Performance Compatibility
0 Resistant • Non staining
• Low Emissions • Stability
• Low Fogging • Chemically stable
• Low • Good look & feel
Availability Processability Conductivity
DOP
• Low Volatility

10 10 10 10

5 5 5 5

0 0 0 0

Citrates ESO DOTP DINCH

Pperformance Lacking in Processability issues; long Slightly more Some processability
Permanence, High costs term compatibility problems difficult to process issues
9
Non Phthalate | Kanatol 9020
New Gen Plasticizer | Tailor Made

To meet “Increasing challenges of Regulatory compliance, Product Performance"

Fast Fusion as compared to available Higher Non-Phthalates

Good Mechanical properties in applications like- Shoe Compounds, Vinyl

Plastisols & Misc. Extrudates

Rare Non-Phthalate combination of

• Faster Fusion, Better Efficiency

Not Compatible with Secondary Plasticizers

Non-Phthalate replacement of DINP with Superior Processability

10
 Non Phthalate | Kanatol 9020
Comparative Performance

SE/KNm/Kg Product Behaviour

FT/HH:MM:SS
700 00:05:02

600 00:04:19

500 00:03:36

400 00:02:53

300 00:02:10

200 00:01:26

100 00:00:43

0 00:00:00
DOP DINP K-9020

Legends : SE-Specific Energy consumed during Extrusion : FT-Fusion Time 11

Trimellitate | Kanatol 3900
New Gen Plasticizer

To meet “Increasing challenges of Regulatory compliance, Product Performance"

An Ester for high temperature applications including Wires & cables meet
the requirements of standard like- EN 50363-3 (TI 3) (reduction in
elongation max. 25%)
Volume Resistivity is comparable and meeting most of the requirement

Very low volatility and thus high retention of mechanical properties

after heat ageing with better low temperature attributes

Imparting excellent low volatility and migration for demanding

applications with cost advantage

Replacement of TOTM in High Temperature applications

12
 Trimellitate | Kanatol 3900
Comparative Performance | Elongation

300
278
268

250
Elongation at break %

222

200 183

Original

Original
150

14 Days

14 Days

14 Days
100

50

0
K-3900 TOTM

TEST CONDITIONSElonon
23 °C, 50 % humidity ,14 d @ 135 °C ,Conditioning for 1 d, 23 °C

Source – KLJ Application LAB 13

 Trimellitate | Kanatol 3900
Comparative Performance | Loss of Mass

K-3900 TOTM
0

21
14 Days @ 135⁰C
-1

Days @ 135⁰C

14 Days @ 135⁰C
-2
Weight loss in %

-3 -2.6

21 Days @ 135⁰C
-3.3
-4

-5

-6
-6.1
-7

-8

-9 -8.6

-10

TEST CONDITIONSElo
135 °C, 14 & 21 days

Source – KLJ Application LAB 14

New Gen Plasticizers
Products | Application Orientation of Non-PVC Usage

Application Market experience with Kanatol series (1 to 4) *1

3400 AC DGB DPGB50 8080 900 8A/9A 1001 TPTM

Film Coatings (Nitro

- - - - - 1 - -
Cellulose)
Cosmetics 1 - - - - - - -
Vulcanized Rubbers/Rubber
- 1 1 - 1 - - -
Alloys
Lacquers and Paints - 3 3 - - - - -
PMMA based Coatings - 1 1 - - - - -
Water based PU Sealants - - - - 4 - 4 -
PU based Epoxy Flooring - 1 1 - - - - -
PU Injection Grout - 4 4 - - - - -
Heavy Duty/High Temperature
- - - - - - - 1
Machine Oils
Group V Synthetic Di Basic
- - - - - 4 - -
Ester
*1: Market experience categories interpretation: 1) Main alternative on market. 2) Significant market experience.
3) Examples of full scale experience. 4) Pilot/lab scale experience 15
New Gen Plasticizers
Tailor Made CHLORO PARAFFINS | KLJ-LCCP

To meet “Increasing challenges of Regulatory compliance, Product Performance"

Complying regulatory requirements with enhancement of FR properties

Loss of mass is much lower in compounds made with KLJ-LCCP

Thermal properties are lower and some more dosage of stabilizers has to
be incorporated in the formulation as compared to MCCP

Hardness is slight higher due to presence of higher C-Chain

Electrical properties are comparable

Additional advantage is low specific gravity ,an extra edge in

applications like- Metal Working Fluids, Industrial and Automotive
Lubricants, PVC Flooring, Rubber Processing, Carpets etc.
Regulatory replacement of MCCP(Continent Specific)
16
New Gen Plasticizers
Tailor Made CHLORO PARAFFINS | Comparative Specs

Parameters KLJ-MCCP KLJ-LCCP KLJ-LCCP

Colour (HU) 50 - 60 100 100

Specific Gravity/25°C 1.26 - 1.30 1.12 - 1.18 1.18 - 1.24
Viscosity (Poise)/25°C 15 - 35 11 - 16 15 - 25
Heat Stability
Yellow Yellow Yellow
180 °C/20 Min
Thermal Stability ; %
0.034 0.15 0.078
180 °C/4 Hrs
Volatile Loss ; %
1.50 2.00 1.40
180°C for 4 hrs. (Max)

Chlorine Content ; % 50 - 54 40 - 44 45 - 49

Refractive Index 1.509 + 0.002 1.501 + 0.003 1.503 + 0.003

17
New Gen Plasticizers
Tailor Made CHLORO PARAFFINS | Comparative Performance

3.00
2.44
2.50
%(Percentage)

2.00
1.44
1.50

1.00
0.41 0.46
0.50

0.00
VL LOM

Before Ageing WH AD-1 After Ageing

LCCP MCCP 18
New Gen Plasticizers
KANA BIO | Future Alternate of CP

To meet “Increasing challenges of Regulatory compliance, Product Performance"

KANA-BIO is a Chlorinated Bio based Ester & can be used as Secondary

Plasticizer
Is a green Plasticizer
Can work in both flexible and Plastisol applications

CP is been used in misc. application for many years to reduce cost, KANA-
BIO works similar to CP’s but has several advantages:
• Lower water extractability
• Increased flex strength
• Lower Plastisol viscosity
• Not considered a substance of very high concern (SVHC)
• Not listed on Prop 65

REACh/RoHS Compliant replacement of CP

19
New Gen Plasticizers
KANA BIO | Comparative Specs

Parameters KLJ-MCCP KANA-BIO-FPR 40 KANA-BIO-FPR 47

Colour (HU) 50 - 60 60 - 80 125 - 150

Specific Gravity/25°C 1.26 - 1.30 1.20 - 1.24 1.28 - 1.32

Viscosity (Poise)/25°C 15 - 35 15 - 30 300 - 350

Heat Stability
Yellow Yellow Yellow
180 °C/20 Min

Volatile Loss ; %
1.50 1.20 1.00
180°C for 4 hrs. (Max)

Chlorine Content ; % 50 - 54 40-44 45 - 49

Refractive Index 1.509 + 0.002 1.500 + 0.002 1.510 + 0.002

20
Plasticizers
Application | Wire & Cable

TRIMELLITATE

SEBACATES

BENZOATES
ADIPATES

CITRATES

K-1210
DBP-M

K-9CH
DIBP

DnBP

DINP

DIDP

DPHP

DOTP

ESBO
DMP

DEP

DOP
Segment Subset

S
Wire &
Wire & Cable √ √ √ √ √ √ √ √ √ √
Cable

Subset Desired Plasticizer Attributes KLJ Products Not Preferred

Very safe for long term use, Low

volatility, Low Conductivity, Ease of
Processing, Properties vary DOP, DINP, DOTP, Higher
depending upon Service Life MW Plasticizers such as
Low MW Phthalates, Citrates,
requirements or Low Temperature DIDP, DPHP,K-1210,
Wire & Cable Cyclohexanoates, Natural Oil
Flexibility, Migration Resistance to Trimellitates,
based Plasticizers
other Plastics, Resistance to Oil Adipates,Sebacates,CP,
and Grease or Automotive Interior ESBO
Fogging requirements, Good Ageing
21
Properties
Plasticizers
Application | Medical Products

TRIMALLIA

SEBACATES

BENZOATES
ADIPATES

CITRATES

K-1210
DBP-M

K-9CH
DIDP
DIBP

DnBP

DINP

DPHP

DOTP

ESBO
DMP

DEP

DOP

TE
Segment Subset

Invasive Use √ √ √ √ √
Other, Non Invasive √ √ √ √ √ √ √
Medical
PVC Examination
√ √ √ √ √
Gloves

Subset Desired Plasticizer attributes KLJ Products Not Preferred

Prior approvals, Long history of safe

C1-C7 Phthalates, DINP,
Invasive service, Resists colour change in DOP,DOTP, Trimellitates,
DIDP,
Use sterilization, Low colour, Low K-1210, Citrates
DPHP, Linear Phthalates
odor,High purity

Other, non Migration resistance, High clarity, DOTP, DINP, DIDP, DPHP,
C1-C7 Phthalates
invasive Low odor, Chemically stable Citrates, K-9CH, ESBO

PVC Food contact approval, No skin-

DINP,DOP,DOTP, C1-C7 Phthalates,
Examination irritation, Easy to process, No-
Sebacates, ESBO Trimellitates
gloves pinholes
22
Plasticizers
Application | Automotive Materials

TRIMALLIA

SEBACATES

BENZOATES
ADIPATES

CITRATES
K-9020

K-1210

K-9CH
DBP-M
DIBP

DnBP

DINP

DIDP

DPHP

DOTP

ESBO
DMP

DEP

DOP

TES
Segment Subset

Interior Trim √ √ √ √ √
Exterior Trim √ √ √ √ √ √
Automotive
Under
√ √ √ √ √ √ √ √
Coatings/Sealants

Subset Desired Plasticizer attributes KLJ Products Not Preferred

Low fogging, Ease of Processing,

Interior Chemically Stable, UV resistant, Heat DIDP, DPHP, Trimellitates, C1-C9 Phthalates,
Trim Stable, Long Service Life, Good Sebacates , Kanatol-1210 Citrates, DOTP
Surface Feel or Softness

Controlled volatility, Ease of

Exterior DINP, DIDP, DPHP, DOTP C1-C4 Phthalates,
Trim Processing, Chemically Stable, UV
Trimellitates, Kanatol-9020 Citrates
Resistant, Heat Stable

Undercoatin DIDP, DINP, DPHP, Benzoates, C1-C4 Phthalates,

g& Ease of Processing, Adhesion, Stability Adipates , DOTP, Kanatol- Citrates, Trimellitates,
Sealants
9020, ESBO DINCH
 Plasticizers-Consumption
Indian Pattern | Segment wise

Mats, 4.8 Others, 2.2

Adhesive, Paint &
Writing Instruments, 1.1 Ink, 1.9
Adhesive,Paint & Ink
Cable Compounding
Suction & Garden Hoses,
13.7 Leather Cloth/Calendering
Cable Plastisol/Sealant
Compounding, Polymer & Rubber Alloy
PVC Film & Tubing, 6.5 27.9
PVC Film & Tubing
Suction & Garden Hoses
Writing Instruments
Polymer & Rubber Alloy,
2.5 Mats
Leather
Cloth/Calendering, Others
33.8
Plastisol/Sealant, 5.6

24
Plasticizers
KLJ Insight

Many sources of sustainable competitive advantages are possible

Innovative Products Feedstocks

Unique Market Offerings Talent

Market Access Adaptability & Insight

Restricted Technology Operational Excellence

Infrastructure &
Access to Finance
Integration

25
Plasticizers
Factor | KLJ

What makes us Preferred Supplier

Transparent Business Practices leading to mutual trust across supply

chain
Customer focused Innovative R&D

Very strong QC systems covering the entire manufacturing process,

resulting in consistent quality of products

Our belief - “Cost Reduction” must not result into Cheap Quality but
should be achieved through Innovation and Value Engineering

26
 THANK YOU
Disclaimer : The information provided herein has been presented on request. The same is based
on data that KLJ believes to be reliable. KLJ makes no claim about the completeness or accuracy
thereof and assumes no liability resulting from its use or for any other claim, losses, or
damages of any third party. Recipients receiving this information must exercise their own
judgment regarding the correctness and appropriateness of its use and it is the user’s
responsibility to assess the information’s suitability (including safety) for a particular
purpose prior to such use (Apr 2024)

April, 2024 27