MOLE CONCEPT (Physical Chemistry)

EXERCISE-I
(JEE MAIN LEVEL)
DPP-01
Introduction of Mole
Q.1 1 a.m.u equals to (a.m.u = atomic mass unit.)
(A) 6.022 × 1023 gm (B) 6.022 × 1023 kg
(D) 1.66 × 10−24 gm (C) 1.66 × 10−24 kg
Q.2 Define atomic mass
mass of an atom (in gm)
(A) atomic mass = 1 a⋅m⋅u.
mass of an atom (in gm)
(B) Atomic mass = 1
of mass of single atom of C−12 (in gm)
12

mass of an atom (in gm)

(C) Atomic mass = 1
th of mass of single atom of C−12 in a mu
12

mass of an atom (in gm)

(D) Atomic mass = 6.022×1023

Q.3 Unit of atomic mass is

(A) a.m.u (B) gm (C) kg (D) Unit less
Q.4 Mass of an atom of Sodium (Given atomic mass of Sodium : 23)
(A) 23 gm (B) 23 kg (C) 23 amu (D) 23 × 1.66 × 10−23 amu
Q.5 If mass of one apple is 50 gm, then mass of 1 mole apple (Given NA = 6 × 1023 )
(A) 3 × 1025 gm (B) 1.2 × 1022 gm (C) 3 × 1025 amu (D) 50 amu
Q.6 One dozen mangoes weigh 3 Kg. Find mass of 1 mole mangoes (in kg)
(Given NA = 6 × 1023 )
(A) 1.5 × 1023 (B) 2 × 1023 (C) 6 × 1023 (D) 18 × 1023
Q.7 Molar mass of electron is nearly (NA = 6 × 1023)
Given: Mass of 1 electron = 9.1 × 10–31 kg
(A) 9.1 × 10–31 kg mol–1 (B) 9.1 × 10–31 gm mol–1
(C) 54.6 × 10–8 gm mol–1 (D) 54.6 × 10–8 kg mol–1
Q.8 Mass of 1 mol (Molar mass) of Al is (Given; Atomic mass of Al = 27)
27
(A) 27 kg (B) 27 amu (C) 27 gm (D) gm
NA

Q.9 Mass of 1 molecule of CO2 is

(A) 44 gm (B) 44 amu (C) 44 kg (D) 44 NA gm
Q.10 Mass of an atom is 80 amu, its atomic mass will be
80
(A) 80 (B) N (C) 80 NA (D) 80 × 1.66 × 10−24
A

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Q.11 Find the molar mass of the following molecules:

Given : Atomic mass : O = 16, N = 14, S = 32, C = 12, Cu = 63.5

(i) O2 (ii) N2 (iii) NO2 (iv) H2O

(v) NH3 (vi) N2O4 (vii) SO2 (viii) H2SO4

(ix) CO2 (x) Glucose (C6H12O6)

(xi) Acetic acid (CH3COOH)

(xii) Sucrose (C12H22O11)

(xiii) Blue vitriol (CuSO4.5H2O)

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DPP-2
PROBLEMS RELATED WITH INTERCONVERSION OF MOLE, MASS AND NUMBER
Q.12 The number of moles of ammonia in 4.25 g of ammonia is :
(A) 0.425 (B) 0.25 (C) 0.236 (D) 0.2125
Q.13 The weight of a molecule of the compound C6H12 is :
(A) 1.39 × 10–21 g (B) 1.39 × 10–22 g (C) 5.025 × 10–23 g (D) 16.02 × 10–23 g
Q.14 The approximate number of molecules of CO2 present in 44 g of CO2 is :
(A) 6.0 × 1023 (B) 3 × 1023 (C) 12 × 1023 (D) 3 × 1010
Q.15 The number of carbon atoms present in a signature, if a signature written by carbon pencil by
1.2 × 10–3 gm carbon is
(A) 12.04 × 1020 (B) 6.02 × 1019 (C) 3.01 × 1019 (D) 6.02 × 1020
Q.16 The weight of 1  1022 molecules of CuSO4. 5H2O is :
(A) 41.59 g (B) 415.9 g (C) 4.159 g (D) 2.38 g
Q.17 Find the number of moles of the following :
(i) 28 g of N2 (ii) 28 g of N (iii) 64 g of O2 (iv) 64 g of O
(v) 54 mg of H2O (vi) 48 mg of CH4 (vii) 23 mg of NO2 (viii) 15 mg of CH3COOH
Q.18 Find the following for 180 gm of Urea:
Give: Urea (NH2CONH2)
Atomic weight :( C = 12 , H = 1 , O = 16, N=14 )
(i) Number of moles of Urea (ii) Number of molecules of Urea
(iii) Number of moles of carbon atom (iv) Number of moles of hydrogen atom
(v) Number of moles of oxygen atom (vi) Number of moles of nitrogen atom
(vi) Number of atoms of carbon, hydrogen, nitrogen and oxygen
(vii) Total number of atoms
Q.19 For 49 g of H2SO4, Find the following:
(i) Number of moles of H2SO4
(ii) Number of moles of hydrogen, sulphur and oxygen atom
(iii) Number of molecules of H2SO4
(iv) Number of atoms of hydrogen, sulphur and oxygen
(v) Total number of atoms

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Q.20 Find:
(i) No. of moles of Cu atom in 1020 atoms of Cu.
(ii) Mass of 200 atoms of 16
8 𝑂 in amu
(iii) Mass of 100 atoms of 14
7 𝑁 in gm.
(iv) No. of molecules & atoms in 54 gm H2O.
(v) No. of atoms in 88 gm CO2.
Q.21 Calculate the number of electrons, protons and neutrons in 1 mole of O–2 ions.

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DPP-3
PROBLEMS RELATED WITH INTERCONVERSION OF MOLE, MASS AND NUMBER

Q.22 Ethanol, C2H5OH, is the substance commonly called alcohol. The density of liquid alcohol is 0.8
g/ml at 293 K. If 1.2 mole of ethanol are needed for a particular experiment, what volume of
ethanol should be measured out?
(A) 55 ml (B) 58 ml (C) 69 ml (D) 79 ml
Q.23 Which of the following has the Maximum mass ?
1
(A) 1 g-atom of Carbon (B) 2mole of CH4

(C) 10 mL of water (D) 3.011 × 1023 atoms of oxygen

Q.24 Which of the following contain largest number of carbon atoms?
(A) 15 gm ethane, C2H6 (B) 40.2 gm sodium oxalate, Na2C2O4
(C) 72 gm glucose, C6H12O6 (D) 35 gm pentene, C5H10
Q.25 A sample of aluminium has a mass of 54.0 g. What is the mass of the same number of magnesium
atoms? (At. wt. Al = 27, Mg = 24)
(A) 12 g (B) 24 g (C) 48 g (D) 96 g
Q.26 A gaseous mixture contains CO2 (g) and N2O (g) in a 2 : 5 ratio by mass. The ratio of the number
of molecules of CO2 (g) and N2O (g) is
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4
Q.27 What is the mass of one 12C atom in gram?
Q.28 Calculate the weight of 12.046 × 1023 atoms of carbon.
Q.29 Calculate mass of O atoms in 6 gm CH3COOH?
Q.30 Calculate mass of water present in 499 gm CuSO4.5H2O?
(Atomic mass – Cu = 63.5, S = 32, O = 16, H = 1)
Q.31 What mass of Na2SO4.7H2O contains exactly 6.023 × 1022 atoms of oxygen?

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DPP-4
PROBLEMS RELATED WITH PV= nRT
Q.32 How many moles are there in 0.821 L of any gas at 50 atm and 200 K.

(A) 2 moles (B) 4 moles (C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
Q.33 How many moles are there in 2.24m3 of any gas at 190 torr and 273ºC.

(A) 1.25 moles (B) 12.5 moles (C) 1.25 × 10–3 moles (D) 1.25 × 103 mole
Q.34 If V ml of the vapours of substance at 1 atm and 273 K weighs W gm. Then molar mass of
substance is:

𝑉 𝑊×1
(A) (W/V) × 22400 (B) × 22.4 (C) (W – V) × 22400 (D) 𝑉×22400
𝑊

Q.35 80 gm of SOx gas occupies 15 lit at 2 atm & 300 K . The value of x is -
(Given : R = 0.08 L-atm/K-Mole)

(A) 3 (B) 2 (C) 1 (D) None

Q.36 While resting, an average 70 kg human male consumes 16.628 L of oxygen per hour at 27°C and
100 kPa. How many moles of oxygen are consumed by the 70 kg man while resting for 1 hour?

(A) 0.67 (B) 66.7 (C) 666.7 (D) 67.5

Q.37 At same temperature and pressure, two gases have the same number of molecules. They must
(A) have same mass (B) have equal volumes
(C) have a volume of 22.7 dm3 each (D) have an equal number of atoms
Q.38 Four 1-1 litre flasks are separately filled with the gases H2, He, O2 and O3 at the same temperature
and pressure. The ratio of total number of atoms of these gases present in different flask would
be :
(A) 1 : 2 :3 : 4 (B) 2 : 1 :2 : 4 (C) 2 : 1 :2 : 3 (D) 2 : 1 :2 : 3
Q.39 For the ideal gas, find the number of moles:
(i) P = 0.8314 Pa V = 6000 m3 T = 300 K
(ii) P = 5 atm V = 8.21 L T = 200 K
(iii) P = 831.4 Pa V = 5000 L T = 250 K

Q.40 For the ideal gas, find pressure:

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(iv) V = 8.21 L T = 500 K n = 10

(v) V = 100 m3 T = 300 K n=3
(viii) V = 45.4 m3 T = 2730 K n=5
Q.41 For the ideal gas, find the missing parameter in each part among P, V, T and n:
(vi) P = 831.4 Pa V = 1000 L n = 0.1
(vii) P = 22.4 atm T = 273 K n=2
Q.42 Find the volume of ideal gas at STP:
(i) 2 moles of PCl5 (ii) 0.25 moles of NH3
(iii) 0.5 moles of NO2 (iv) 4 moles of N2
Q.43 Find the moles of ideal gas at STP:
(i) 22.7 L of O2 (ii) 45.4 L of N2 (iii) 45.4 mL of NO2 (iv) 11.35 mL of NH3
(v) 2.27 dm3 of SO3 (vi) 113.5 m3 of CO2

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DPP-5
Balancing of chemical reactions
Q.44 C + O2 ⎯→ CO
Q.45 H2 + O2 ⎯→ H2O
Q.46 P + O2 ⎯→ P2O5
Q.47 S8 + O2 ⎯→ SO3
Q.48 C3H8 + O2 ⎯→ CO2 + H2O
Q.49 C2H6 + O2 ⎯→ CO2 + H2O
Q.50 CxHy + O2 ⎯→ CO2 + H2O
Q.51 PCl5 + H2O ⎯→ H3PO4 + HCl
Q.52 NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l)
Q.53 KOH + H2CO3 ⎯→ K2CO3 + H2O
Q.54 Ba(OH)2 + H3PO4 ⎯→ Ba3(PO4)2 + H2O
Q.55 Pb(OH)4 + Cu2O ⎯→ PbO2 + CuOH
Q.56 ZnS + AlP ⎯→ Zn3P2 + Al2S3
Q.57 CaSiO3 + HF ⎯→ SiF4 + CaF2 + H2O
Q.58 Ca(ClO3)2 + Na2SO4 ⎯→ CaSO4 + NaClO3
Q.59 FeS2 + O2 → Fe2O3 + SO2
Q.60 P4S3 + O2 ⎯→ P4O10 + SO2
Q.61 BCl3 + P4 + H2 ⎯→ BP + HCl
Q.62 Cl2 + Ca(OH)2 ⎯→ Ca(ClO3)2 + CaCl2 + H2O
Q.63 KMnO4 + HCl ⎯→ KCl + MnCl2 + H2O + Cl2

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DPP-6
Limiting reactant
Q.64 For the reaction 2P + Q → R, 8 mol of P and excess of Q will produce :
(A) 8 mol of R (B) 5 mol of R (C) 4 mol of R (D) 13 mol of R
Q.65 If 1.5 moles of oxygen combine with Al to form Al2O3, the weight of Al used in the reaction is:
(A) 27 g (B) 40.5 g (C) 54g (D) 81 g
Q.66 The mass of Mg3N2 produced if 48 gm of Mg metal is mixed with 34 gm NH3 gas is
Mg + NH3 ⎯→ Mg3N2 + H2
200 100 400 150
(A) gm (B) gm (C) gm (D) gm
3 3 3 3

Q.67 The mass of P4O10 produced if 440 gm of P4S3 is mixed with 384 gm of O2 is
P4S3 + O2 ⎯→ P4O10 + SO2
(A) 568 gm (B) 426 gm (C) 284 gm (D) 396 gm
Q.68 Mass of sucrose C12H22O11 produced by mixing 84 gm of carbon, 12 gm of hydrogen and 56 lit. O2
at 1 atm & 273 K according to given reaction, is
C(s) + H2(g) + O2 (g) ⎯→ C12H22O11(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5
Q.69 Calculate the volume of O2 needed for combustion of 1.2 kg of carbon at STP.
𝛥
Reaction: C + O2 → CO2.
Q.70 Methyl-t-butyl ether, C5H12O, is added to gasoline to promote cleaner burning. How many moles
of oxygen gas, O2 are required to burn 1.0 mol of this compound completely to form carbon
dioxide and water?
Q.71 Aluminum carbide (Al4C3) liberates methane on treatment with water:

Al4C4 + 12H2O→ 3CH4 + 4Al(OH)3.

Find mass of aluminum carbide required to produce 11.35 L of methane under STP conditions.

Q.72 Reaction 4A + 2B + 3C→ A4 B2 C3 , is started from 2 moles of A, 1.2 moles of

B & 1.44 moles of C. find number of moles of product formed.
Q.73 Carbon reacts with chlorine to form CCl4. 36 gm of carbon was mixed with 142 g of Cl2. Calculate
mass of CCl4 produced and the remaining mass of reactant.

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DPP-7
Problems related with mixture, % Yield
Q.74 A mixture containing 3 moles each of C4H8 and C6H6 undergoes complete combustion with O2 to
form CO2 and H2O. Calculate total mass of CO2 produced

(A) 1320 gm (B) 610 gm (C) 528 gm (D) 792 gm

Q.75 12.46g of a mixture of MgO and MgCO3 on strong heating lost 4.4g in weight what is the % MgO
in the initial mixture.

(A) 32.58 (B) 64.42 (C) 17.79 (D) 82.21

Q.76 Aluminium reacts with sulphur to form aluminium sulphide. If 5.4 gm of Aluminium reacts with
12.8gm sulphur gives 12gm of aluminium sulphide, then the percent yield of the reaction is-
2Al + 3S ⎯⎯→ Al2S3

(A) 100 % (B) 95 % (C) 80 % (D) 75 %

Q.77 Two successive reactions, A → B and B → C, have yields of 90% and 80%, respectively. What is
the overall percentage yield for conversion of A to C?
(A) 90% (B) 80% (C) 72% (D) 85%
Q.78 Hydrazine N2H4 (used as a fuel in rocket system) can be produced according to the following
reaction.
CINH2 + 2NH3 → N2H4 + NH4Cl
When 1.0 kg CINH; is reacted with excess of NH3, 473 g of N2H4 is produced. What is the
percentage yield?
(A) 76.12 (B) 67.21 (C) 26.17 (D) 16.72
Q.79 When 4 gm of a mixture of NaHCO3 and NaCl is heated, 0.66 gm CO2 gas is evolved. Determine
the percentage composition (by mass) of the original mixture.
Q.80 One gram of an alloy of aluminium and magnesium when heated with excess of dil. HCl forms
magnesium chloride, aluminium chloride and hydrogen. The evolved hydrogen collected at 0°C
has a volume of 1.12 litres at 1 atm pressure. Calculate the composition of (% by mass) of the
alloy.
Q.81 Cyclohexanol is dehydrated to cyclohexene on heating with conc. H2SO4. Find %yield of this
reaction, if 61.5 gm cyclohexene is obtained from 100 g of cyclohexanol?
𝑐𝑜𝑛.𝐻2 𝑆𝑂4
C6H12O→ C6H10 + H2O

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Q.82 200 g impure CaCO3 on heating gives 11.35 L CO2 gas at STP. Find the percentage of calcium in
the lime stone sample.

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DPP-8
PROBLEMS RELATED WITH SEQUENTIAL AND PARALLEL REACTION
Q.83 The following process has been used to obtain iodine from oil-field brines in California.

NaI + AgNO3 → AgI + NaNO3 ;

2AgI + Fe → Fel2 + 2Ag

2FeI2 + 3Cl2 → 2FeCl3 + 2I2

How many grams of AgNO3 are required in the first step for every 254 kg 2 produced in the third
step?
(A) 340 kg (B) 85 kg (C) 68 kg (D) 380 kg
Q.84 10 g of a sample of a mixture of CaCl2 and NaCl is treated to precipitate all the calcium as CaCO3.
This CaCO3 is heated to convert all the Ca to CaO and the final mass of CaO is 1.62 g . The percent
by mass of CaCl2 in the original mixture is:
(A) 32.1 % (B) 16.2 % (C) 21.8 % (D) 11.0 %
Q.85 Consider the following reaction
2Na + 2NH3 ⎯→ 2NaNH2 + H2(g)
2NaNH2 + C ⎯→ Na2CN2 + 2H2 (g)
Na2CN2 + C ⎯→ 2NaCN
51gm dry ammonia gas is passed over excess heated sodium to form sodamide (NaNH2) which
is further reacted with carbon (excess) to finally form NaCN. Find the total volume of H 2(g)
evolved at 0.5 atm, 273K

(A) 201.6 L (B) 100.8 L (C) 403.2 L (D) 50.4 L

Q.86 25.4 g of iodine and 14.2g of chlorine are made to react completely to yield a mixture of Cl and
Cl3. Calculate The number of moles of Cl and Cl3 formed.
(A) 0.1 mole, 0.1 mole (B) 0.1 mole, 0.2 mole
(C) 0.5 mole, 0.5 mole (D) 0.2 mole, 0.2 mole
Q.87 Sulphur trioxide may be prepared by the following two reactions :
S8 + 8O2(g) → 8SO2(g)
2SO2(g) + O2(g) → 2SO3(g)
How many grams of SO3 will be produced from 1 mol of S8?
Q.88 2PbS + 3O2 → 2PbO + 2SO2
3SO2 + 2HNO3 + 2H2O → 3H2SO4 + 2NO
According to the above sequence of reactions, how much H2SO4 will 1075.5 gm of PbS produce?
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Q.89 Moles of ABC3 produced in the following set of reaction when 180 gm of A, 180gm of B and 200
gm of C are mixed in a container (given molar masses of A,B,C are 20, 30 & 10 respectively.
2A + 3B + 5C ⎯⎯→ A2BC2 + B2C3
B2C3 + 3C ⎯⎯→ 2BC3
BC3 + A ⎯⎯→ ABC3

Q.90 Total weights (in gm) of P4O6 and P4O10 will be produced by the combustion of 31g of P4 in 32g
of oxygen leaving no P4 and O2.

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DPP-9
% by Mole, % by Mass and Mavg
Q.91 Average mol. wt. of a gaseous mixture which contains 80% by mole N2 & rest O2 gas is-
(A) 28 (B) 30.6 (C) 28.8 (D) 29.2

Q.92 The percentage by mole of NO2 in a mixture of NO2(g) and NO(g) having average molecular mass
34 is :
(A) 25% (B) 20% (C) 40% (D) 75%
Q.93 The vapour density of a sample of SO3 gas is 28. Its degree of dissociation into SO2 and O2 is
(A) 1/7 (B) 1/6 (C) 6/7 (D) 2/5
Q.94 An organic compound contains 40% carbon and 6.67% hydrogen by mass. Which of the following
represents the empirical formula of the compound?
(A) CH2 (B) CH2O (C) C2H4O (D) CH3O
Q.95 A quantity of 1.4 g of a hydrocarbon gives 1.8 g water on complete combustion. The empirical
formula of hydrocarbon is
(A) CH (B) CH2 (C) CH3 (D) CH4
Q.96 Calculate the atomic mass (average) of chlorine using the following data:
% Natural Abundance Molar Mass
35Cl 75.77 34.9689
37Cl 24.23 36.9659
Q.97 Average atomic mass of Magnesium is 24.31 amu. This magnesium is composed of 79 mole
% of 24Mg and remaining 21 mole % of 25Mg and 26Mg. Calculate mole % of 26Mg.
Q.98 An organic compound contains carbon, hydrogen and nitrogen. If weight ratio of C, H, N (in same
order) is 9 : 1 : 3.5 and molar mass of compound is 216 gm/mole and number of atoms present
𝑥
in 1 molecule of compound are x then calculate value of 4.

Q.99 A compound has carbon, hydrogen and oxygen in 3 : 3 : 1 atomic ratio. If the number of moles in
1 g of the compound is 6.06 × 10–3, then the molecular formula of the compound will be
Q.100 A 60 gm sample of organic compound having empirical formula CxHyO on complete combustion
gives 88 gm of CO2 & 36 gm of H2O. The value of (x + y) is.

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DPP-10
MISCELLANEOUS PROBLEM
Q.101 If the mass of neutron is double and that of proton is halved, the molecular mass of H 2O
containing only H1 and O16 atoms will
(a) increase by about 25%
(b) decrease by about 25%
(c) increase by about 16.67%
(d) decrease by about 16.67%
Q.102 The mass of CO2 produced from 620 gm mixture of C2H4O2 & O2, prepared to produce maximum
energy is (Combustion reaction is exothermic)
(A) 413.33 gm (B) 593.04 gm (C) 440 gm (D) 320 gm
Q.103 X gm A atoms on combining with Y atoms of B form 5 molecules of a compound containing A &
B. Find the molecular weight of compound formed. (Atomic weight of B = M)
(𝑋𝑁𝐴 +𝑀𝑌) 𝑋+𝑀 𝑋+𝑀𝑌 𝑋+𝑀𝑌𝑁𝐴
(A) (B) (C) (D) ( )
5 5 5 5

Q.104 The minimum mass of mixture of A2 and B4 required to produce at least 1 kg of each product is:
(Given At. mass of 'A' = 10 ; At. mass of 'B' = 120)
5A2 + 2B4 ⎯⎯→ 2AB2 + 4A2B
(A) 2120 gm (B) 1060 gm (C) 560 gm (D) 1660 gm
Q.105 In the quantitative determination of nitrogen, N2 gas liberated from 0.42 gm of a sample of
100
organic compound was collected over water. If the volume of N2 gas collected was mL at total
11

pressure 860 mm Hg at 250 K, % by mass of nitrogen in the organic compound is

[Aq. tension at 250 K is 24 mm Hg and R = 0.08 L atm mol–1 K–1 ]
10 5 20 100
(A) % (B) 3 % (C) % (D) %
3 3 3

Q.106 40 gm of a carbonate of an alkali metal or alkaline earth metal containing some inert
impurities was made to react with excess HCl solution. The liberated CO2 occupied 12.315 lit. at
1 atm & 300 K. The correct option is
(A) Mass of impurity is 1 gm and metal is Be
(B) Mass of impurity is 3 gm and metal is Li
(C) Mass of impurity is 5 gm and metal is Be
(D) Mass of impurity is 2 gm and metal is Mg
Q.107 Industrially TNT (C7H5N3O6, explosive material) is synthesized by reacting toluene
(C7H8) with nitric acid in presence of sulphuric acid. Calculate the maximum weight of C7H5N3O6
which can be produced by 140.5 gm of a mixture of C7H8 and HNO3.

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C7H8 + 3HNO3 ⎯→ C7H5N3O6 + 3H2O

140.5
(A) 140.5 (B) 113.5 (C) (D) 140.5 – (3 × 18)
2

Q.108 One gram of the silver salt of an organic dibasic acid yield, on strong heating, 0.5934 g of silver.
If the weight percentage of carbon in it 8 times the weight percentage of hydrogen and one-half
the weight percentage of oxygen, determine the molecular formula of the acid.
[Atomic weight of Ag = 108]
(A) C4H6O4 (B) C4H6O6 (C) C2H6O2 (D) C5H10O5

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ANSWER KEY
Exercise:1
(JEE MAIN LEVEL)

DPP-01
1. (C) 2. (B) 3. (D) 4. (C) 5. (A) 6. (A) 7. (D)
8. (C) 9. (B) 10. (A)
11. (i) 32 g (ii) 28 g (iii) 46 g (iv) 18 g

(v) 17 g (vi) 92 g (vii) 64 g (viii) 98g

(ix) 44 g (x) 180 g (xi) 60 g (xii) 342 g

(xiii) 249.5 g

DPP-02
12. (B) 13. (B) 14. (A) 15. (B) 16. (C)
17. (i) 1 (ii) 2 (iii) 2 (iv) 4

(v) 3 × 10–3 (vi) 3 × 10–3 (vii) 0.5 × 10–3 (viii) 0.25 × 10–3
18. (i) 3 (ii) 3 × NA (iii) 3 (iv) 12

(v) 3 (vi) 6 (vii) 3NA , 12NA , 6NA , 3NA (viii) 24NA

19. (i) 0.5 (ii) 1, 0.5, 2 (iii) 0.5NA (iv) NA, NA/2, 2NA
(v) 3.5NA
𝟏𝟎𝟐𝟎
20. (i) moles , (ii) 3200 amu ,
𝑵𝑨

(iii) 1400 × 1.66 × 10–24 g (iv) 3NA , 9NA , (v) 6NA

21. 10 × 6.022 × 1023, 8 × 6.022 × 1023, 8 × 6.022 × 1023

DPP-03
22. (C) 23. (A) 24. (D) 25. (C) 26. (B) 27. (1.99  10-23 g)
28. (24g) 29. (3.2 g) 30. (180 g) 31. (2.5g)

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DPP-04
32. (A) 33. (B) 34. (A) 35. (B) 36. (A) 37. (B) 38. (C)
39. ((i) n = 2 (ii) n = 2.5 (iii) n = 2)
40. ((iv) P = 50 atm (v) P = 74.8 Pa (viii) P = 2500 Pa)
41. ((vi) T = 1000 K (vii) V = 2 L)
42. ((i) 45.4 L (ii) 5.675 L (iii) 11.35 L (iv) 90.8 L)
43. (i) 1 (ii) 2 (iii) 2 × 10–3 (iv) 5 × 10–4

(v) 0.1(vi) 5000

DPP-05
44. 2C + O2 ⎯→ 2CO
45. 2H2 + O2 ⎯→ 2H2O
46. 4P + 5O2 ⎯→ 2P2O5
47. S8 + 12O2 ⎯→ 8SO3
48. C3H8 + 5O2 ⎯→ 3CO2 + 4H2O
7
49. C2H6 + O2 ⎯→ 2CO2 + 3H2O
2
𝑦 𝑦
50. CxHy + (𝑥 + 4) O2 ⎯→ xCO2 + 2H2O

51. PCl5 + 4H2O ⎯→ H3PO4 + 5HCl

52. 2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l)
53. 2KOH + H2CO3 ⎯→ K2CO3 + 2H2O
54. 3Ba(OH)2 + 2H3PO4 ⎯→ Ba3(PO4)2 + 6H2O
55. Pb(OH)4 + 2Cu2O ⎯→ PbO2 + 4CuOH
56. 3ZnS + 2AlP ⎯→ Zn3P2 + Al2S3
57. CaSiO3 + 6HF ⎯→ SiF4 + CaF2 + 3H2O
58. Ca(ClO3)2 + Na2SO4 ⎯→ CaSO4 + 2NaClO3
59. 4FeS2 + 11O2 → 2Fe2O3 + 8SO2

60. P4S3 + 8O2 ⎯→ P4O10 + 3SO2

61. 4BCl3 + P4 + 6H2 ⎯→ 4BP + 12HCl

62. 6Cl2 + 6Ca(OH)2 ⎯→ Ca(ClO3)2 + 5CaCl2 + 6H2O
63. 2KMnO4 + 16HCl ⎯→ 2KCl + 2MnCl2 + 8H2O + Cl2

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DPP-06
64. (C) 65. (C) 66. (A) 67. (B) 68. (B) 69. (2270L)
70. (7.5 moles) 71. (24) 72. (0.48) 73. wc = 24 gm ; 𝑾𝑪𝑪𝒍𝟒 = 154 gm

DPP-07
74. (A) 75. (A) 76. (C) 77. (C) 78. (A) 79. 63 % , 37%
80. Al = 60%; Mg = 40% 81. (75) 82. (10 %)

DPP-08
83. (A) 84. (A) 85. (A) 86. (A) 87. (640.0) 88. (441 gm)
89. (4) 90. (63)
DPP-09
91. (C) 92. (A) 93. (C) 94. (B) 95. (B) 96. (35.4527)
97. (10) 98. (8) 99. (C9H9O3) 100. (3)

DPP-10
101. (C) 102. (C) 103. (A) 104. (A) 105. (A) 106. (B) 107. (B)
108. (B)

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SOLUTION
DPP-01
7. Mass of 1 electron = 9.1 × 10–31 kg
Mass of 1 mole electron = 9.1 × 10–31 × 6 × 1023 = 54.6 × 10–8 kg/mol
DPP-02
4.25
12. 𝑛𝑁𝐻3 = i.e. mole
17
 option (B) is correct.

13. Weight of molecule of compounds C6H12

= (6 × 12 + 12 × 1) amu = 84 amu
= 84 × 1.66 × 10–24 g = 1.39 × 10–22 gm
 Option (B) is correct.

44
14. 𝑛𝐶𝑂2 = 44 = 1 mole
 the molecules of CO2 = NA i.e. 6 × 1023.
 correct option is (A)

1.2×10−3
15. nC ⎯→ 𝑚𝑜𝑙𝑒
12
1.2×10−3
 number of carbon atoms = × 𝑁𝐴
12

= 6.02 × 1019 atoms

 Correct option is (B).

1×1022
16. 𝑛𝐶𝑢𝑆𝑂4.5𝐻2𝑂 = (6.022×1023) = 1.66 × 10–2 mole
 weight = 1.66 × 10–2 × 249.5 = 4.159 gm
 Correct option is (C)
1020
20. (i) Number of moles of Cu atom in 1020 atoms of Cu = ( 𝑁 ) 𝑚𝑜𝑙𝑒𝑠
𝐴

(ii) Mass of 200 atoms of 16

8 𝑂 in amu → Mass of 1 atom = 16 amu

 Mass of 200 atoms = 16 × 200 amu = 3200 amu

(iii) Mass of 100 atoms of 14

7 𝑁 in gm → Mass of 1 atom of 14
7 𝑁 in gm = 14×1.66×10–24 gm

 Mass of 100 atom of 14

7 𝑁 = 14 × 100 × 1.66 × 10–24gm i.e. 1400 × 1.66 × 10–24 gm
54
(iv) Number of molecules in 54 gm H2O = ( × 𝑁𝐴 ) = 3NA
18
Number of atoms in 54 gm H2O = (3NA) × 3 = 9NA

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88
(v) Number of atoms in 88 gm CO2 = (44) × 3𝑁𝐴 i.e. 6NA

21. In 1 mole of O–2 ions

Number of Electrons = 10NA i.e. 10 × 6.022 × 1023
Number of Protons = 8NA i.e. 8 × 6.022 × 1023
Number of Neutrons = 8NA i.e. 8 × 6.022 × 1023
DPP-03
22. mass of 1.2 mole ethanol = (1.2 × 46) g
𝑚𝑎𝑠𝑠 1.2×46
 Volume = 𝑑𝑒𝑛𝑠𝑖𝑡𝑦 = = 69 ml
0.8

 Correct option is (C).

23. (A) 1 g - atom of carbon = 12 g
1
(B) 2 mole CH4 = 8 g

(C) 10 ml of H2O = 10 g
(D) 3.011 × 1023 atoms of oxygen = 8g
 option (A) is
15 1
24. (A) 𝑛𝐶2 𝐻6 = 30 = 2 mole
𝑁𝐴
 number of carbon atoms = ×2 i.e. NA
2
40.2
(B) 𝑛𝑁𝑎2𝐶2 𝑂4 = 134 = 0.3 mole

 number of carbon atoms = 0.3 × 2NA = 0.6 NA

72
(C) nglucose = 180 = 0.4

 number of carbon atoms = 0.4 × 6NA = 2.4 NA

35
(D) 𝑛𝐶5 𝐻10 = 70 = 0.5

 number of carbon atoms = 0.5 × 5NA = 2.5 NA

 Correct option is (D)
54
25. 𝑛𝐴𝑙 → = 2 mol
27

 mass of same number of magnesium atoms = 48 gm

 Correct option is (C).
26. Ratio of number of molecules of CO2 & N2O
2𝑥 44
= 44 × 𝑁𝐴 × 5𝑥×𝑁 = 2 : 5
𝐴

 correct option is (B)

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27. Mass of 6.023 × 1023 atom = 12 gm

12
 Mass of 1 atom = 6.023×1023 𝑔𝑚

= 1.99 × 10–23gm
28. Weight of 6.023 × 1023 atoms = 12 gm
12×12.046×1023
 Weight of 12.046 × 1023 atom = = 24 gm
6.023×1023
6 1
29. Mass of O atoms in 6 gm CH3COOH = 𝑛𝐶𝐻3 𝐶𝑂𝑂𝐻 = 60 i.e. 10

In 1 mole of CH3COOH, mass of O atom = 32 gm

1 32
 Mass of O atom in 10 mole CH3COOH = 10 i.e. 3.2 gm
499
30. 𝑛𝐶𝑢𝑆𝑂4.5𝐻2𝑂 = 249.5 = 2 mole

1 mole of CuSO4.5H2O contains 90 gm H2O

 2 mole of CuSO4.5H2O contains (90 × 2) i.e. 180 ;gm H2O.

31. 1 mole of Na2SO4.7H2O contains 11NA'O' atoms
6.023×1022 6.023×1022 1
 6.023 × 1022 atom of 'O' are present in = 11×6.022×1023 = 110 mole
11×𝑁𝐴

i.e. 2.5 gm
DPP-04
190
33. Pressure = 760 atm , temperature = 273 + 273.15 K

Volume = 2.24 m3 = 2.24 × 103 L

𝑃𝑉 1 1
Moles = 𝑅𝑇 = 4 × 22.4 × 103 × 0.0821×546

 12.5 moles
Volume of gas (in ℓ)
34. At 1 atm and 273 K, number of moles of gas = 22.4

𝑉×10−3
 For vapour, no. of moles = 22.4

𝑉×10−3 𝑊
According to question, =
22.4 𝑀
𝑊
⇒𝑀= × 22.4 × 103 gm.
𝑉

35. Molar mass of SOx = 32 + 16x

80
 Number of moles of SOx = 32+16𝑥

Putting in equation PV = nRT

80
 2 × 15 = 32+16𝑥 × .08 × 300

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 16x + 32 = 64
 x=2
PV
36. n=
RT
100×103 ×16.628×10−3
= 0.67
8.314×300

37. By Avogadro's Hypothesis,

for gas A, P.VA = nA· RT
for gas B, P.VB = nB· RT
If nA = nB
 vA = vB
 Correction option is (B).
38. Ratio of number of atoms = 2 : 1 : 2 : 3
 Correct option is (C).

DPP-05
44. 2C + O2 ⎯→ 2CO
45. 2H2 + O2 ⎯→ 2H2O
46. 4P + 5O2 ⎯→ 2P2O5
47. S8 + 12O2 ⎯→ 8SO3
48. C3H8 + 5O2 ⎯→ 3CO2 + 4H2O
7
49. C2H6 + 2 O2 ⎯→ 2CO2 + 3H2O
𝑦 𝑦
50. CxHy + (𝑥 + 4) O2 ⎯→ xCO2 + 2H2O

51. PCl5 + 4H2O ⎯→ H3PO4 + 5HCl

52. 2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l)
53. 2KOH + H2CO3 ⎯→ K2CO3 + 2H2O
54. 3Ba(OH)2 + 2H3PO4 ⎯→ Ba3(PO4)2 + 6H2O
55. Pb(OH)4 + 2Cu2O ⎯→ PbO2 + 4CuOH
56. 3ZnS + 2AlP ⎯→ Zn3P2 + Al2S3
57. CaSiO3 + 6HF ⎯→ SiF4 + CaF2 + 3H2O
58. Ca(ClO3)2 + Na2SO4 ⎯→ CaSO4 + 2NaClO3
59. 4FeS2 + 11O2 → 2Fe2O3 + 8SO2
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60. P4S3 + 8O2 ⎯→ P4O10 + 3SO2

61. 4BCl3 + P4 + 6H2 ⎯→ 4BP + 12HCl

62. 6Cl2 + 6Ca(OH)2 ⎯→ Ca(ClO3)2 + 5CaCl2 + 6H2O
63. 2KMnO4 + 16HCl ⎯→ 2KCl + 2MnCl2 + 8H2O + Cl2
DPP-06
64. 2P + Q ⎯→ R
mole : 8 (Excess) 0
0 4
 Correct option is (C).
65. 4 Al + 3O2 ⎯→ 2Al2O3
(Excess) 1.5 0
0 1
 weight of Al 54 gm.
66. 3Mg + 2NH3 ⎯→ Mg3N2 + 3H2
48 34
Mole : 24 17

=2 =2

 Mg is L. R.
2 200
 mass of Mg3N2 produced is 3 × (100)𝑔 = 𝑔
3

 Correct option is (A)

67. P4S3 + 8O2 ⎯→ P4O10 + 3SO2
440 384
Mole : 220 32

=2 = 12

 O2 is L.R
(12×284)
 mass of P4O10 produced = 𝑔 = 426 gm.
8

 Correct option is (B).

11
68. 12C + 11 H2 + 𝑂2 ⎯→ C12 H22 O11
2
84 12 56
Mole : 12 2 22.4

= 7 6 2.5

 O2 is L.R.

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2
 Mass of sucrose produced = (11 × 2.5) × 342𝑔 = 155.5 g

 Correct option is (B).

69. C + O2 ⎯→ CO2
1.2×103
nC → i.e. 100 mole.
12

Mole of O2 needed for 1 mole C = 1 mole

 Mole of O2 needed for 100 mole C = 100 mole
 Volume of O2 needed = 100 × 22.7 = 2270 lits.
15
70. C5H12O + O2 ⎯→ 5CO2 + 6H2O
2

 Moles of O2 required to burn 1 mole of this compound completely is 7.5 moles.

71. Al4C3 + 12H2O ⎯→ 3CH4 + 4Al(OH)3
11.35 1
𝑛𝐶𝐻4 = 22.70 = 2 mole

3 mole CH4 is produced from 1 mole Al4C3.

1 1 1
 2 mole CH4 is produced from 1 mole (3 × 2) mole Al4C3
1 1
i.e. 6 mole Al4C3 or × 144
6

i.e. 24 gm Al4C3
72. 4A + 2B + 3C ⎯→ A4 B2 C3
Moles 2 1.2 1.44
𝑚𝑜𝑙𝑒𝑠 2 1.2 1.44
→4
𝑆.𝐶 1 3

 C is L.R
1.44
 moles of product formed = = 0.48 moles.
3

73. C + 2Cl2 ⎯→ CCl4

36 142
moles→ 12 71

i.e. 3 2
𝑚𝑜𝑙𝑒𝑠
→3 1
𝑆.𝐶

 Cl2 is L.R.
(i) Mass of CCl4 produced = 1 × 154 i.e. 154 gm
(ii) Remaining mass of reactants = (3 – 1) × 12 = 24 gm

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DPP-07
74. C4H8 + O2 ⎯→ 4CO2 + 4H2O
Given, 3 mol. 3 × 4 =12 mol produced
15
C6H6 + 𝑂2 ⎯→ 6CO2 + 3H2O
2

Given, 3 mol. 6×3=18 mol produced

Total moles of CO2 produced = 18 + 12 = 30
Total mass of CO2 produced = 30 ×44 = 1320 gm
75. Weight of mixture of MgO and MgCO3 =12.46 gm
On heating due to this reaction
MgCO3 (s) ⎯→ MgO(s) + CO2 (g)
CO2 (g) releases in atmosphere
 Mass of mixture decreases
4.4
Number of moles of CO2 = 44 = 0.1 mol.
1
 Number of moles of MgCO3 = 1 × 0.1 = 0.1 mol.

Mass of MgCO3 = 0.1 × 84 = 8.4 gm

Mass of MgO in initial mixture = 12.46 – 8.4 = 4.06
4.06
Mass % of Mg O in initial mixture = 12.46 × 100

= 32.58
5.4
76. Moles of Aluminium = 27 = 0.2 mole
12.8
Moles of Sulphur = = 0.4 mole
32

2Al + 3S ⎯⎯→ Al2S3

Moles 0.2 0.4
𝑀𝑜𝑙𝑒𝑠 0.2 0.4
𝑆.𝐶𝑜𝑒𝑓𝑓. 2 3

Since, Al is limiting reagent

1
 Number of moles of Al2S3 produced theoretically = 2 × 0.2
Actual number of moles
% yield = Theoretical number of moles × 100
12
Actual moles of Al2S3 produced =
150
12 1
 % yield = 150 × 0.1 × 100 = 80%

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80
77. Overall percentage yield = 90 × 100 = 72 %
32
78. Theoretical yield of N2H4 = 51.5 × 1000 = 621.36𝑔

Hence, the percentage yield

473
= 621.36 × 100 = 76.12%

79. NaCl ⎯→ x Let NaCl be x gm & NaHCO3 be (4 – x) gm

2NaHCO3 ⎯→ Na2CO3 + CO2 + H2O

4−𝑥
Mole→ 0 0 0
84

(4−𝑥)
- 84×2

Now, According to question

(4−𝑥)
44 × = 0.66
84×2

0.66×84
 (4 – x) = 22×100

 x = 1.48 gm & Weight of NaHCO3 = 2.52 gm

1.48
 % by mass of NaCl → × 100 = 37 %
4

& % by mass of NaHCO3 is 63%

80. 2Al + 6HCl ⎯→ 2AlCl3 + 3H2
𝑥
Moles (excess)
27
3 𝑥
 moles of H2 obtained = (2 × 27) .....(1)

mg + 2HCl ⎯→ MgCl2 + H2
(1−𝑥)
Moles→ (excess)
24
1−𝑥
 moles of H2 obtained = ( 24 ) .....(2)
3𝑥 1−𝑥
 Total moles of H2 obtained = (54 + ) .....(3)
24

Now,
1.12
 𝑛𝐻2 = 22.4 i.e. 0.05 .....(4)
Now, equation (3) & (4)
3𝑥 1−𝑥
+ = 0.05
54 24
12𝑥+9−9𝑥
 = 0.05
216
1.8
m = 10.8 – 9 = = 60%
3

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3x + 9 = 10.8
 3x = 1.8  x = 0.6
 % by mass Al ⎯→ 60% & % by mass mg ⎯→ 40%
𝑐𝑜𝑛𝑠.𝐻2 𝑆𝑂4
81. C6H12O → C6H10 + H2O
 1 mole C6H12O will produces 1 mole C6H10. If yield is 100%.

 moles of C6H10 produced = 0.75

 % yield = 75%
82. CaCO3 ⎯→ CaO + CO2
11.35 1
𝑛𝐶𝑂2 = 22.70 → 2 mole

𝑛𝐶𝑎𝐶𝑂3 ⎯→ 2 mole

 1 mole CaCO3 produces 1 mole CO2

 2 mole CaCO3 produces 2 mole CO2
1
But produced mole is 2 mole
20
 % of Ca in lime stone sample = (200 × 100) i.e. 10%

DPP-08
83. NaI + AgNO3 ⎯→ AgI + NaNO3.
2AgI + Fe ⎯→ FeI2 + 2Ag
2FeI2 + 3Cl2 ⎯→ 2FeCl3 + 2I2.
𝑛𝐼2 = (1 × 103)
𝑚𝑜𝑙𝑒𝑜𝑓𝐴𝑔𝑁𝑂3 𝑚𝑜𝑙𝑒𝑜𝑓𝐴𝑔𝐼
= .....(1)
1 1
𝑚𝑜𝑙𝑒𝑜𝑓𝐴𝑔𝐼 𝑚𝑜𝑙𝑒𝑜𝑓𝐹𝑒𝐼2
= .....(2)
2 1
𝑚𝑜𝑙𝑒𝑜𝑓𝐹𝑒𝐼2 𝑚𝑜𝑙𝑒𝑜𝑓𝐼2
= .....(3)
2 2

From (1), (2) & (3)

𝑚𝑜𝑙𝑒𝑜𝑓𝐴𝑔𝐼
 Mole of I2 = mole of FeI2 = 2

𝑚𝑜𝑙𝑒𝑜𝑓𝐴𝑔𝑁𝑂3
= 2

𝑤𝑡𝑜𝑓𝐴𝑔𝑁𝑂3
 103 = 170×2

 wt. of AgNO3 = 340 kg

 Correct option is (A)

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84. Let CaCl2 be x g & NaCl be (10 – x) g

CaCl2 ⎯→ CaCO3 ⎯→ CaO

𝑥 𝑥 𝑥
Moles 111 111 111
1.62
moles of CaO ⎯→ 56
1.62
 moles of CaCl2 = 56
1.62 𝑥
 = 111
56
111×1.62
x= 56

 x = 3.21
3.21
 % by mass of CaCl2 = × 100 = 32.1 %
10

 Correct option is (A)

85. Since sodium and carbon are present in excess.
 Other reactants of all 3 reactions get completely converted into products.
 All 3 reactions can be added & converted into a single reaction.
2Na + 2NH3 ⎯→ 2NaNH2 + H2 (g)

2NaNH2 + C ⎯→ Na2CN2 + 2H2 (g)

Na2CN2 + C ⎯→ 2NaCN
2Na + 2NH3 + 2C ⎯→ 2NaCN + 3H2 (g)
Excess Excess
51
Moles of NH3 = 17 = 3
3 9
Number of moles of H2 produced from NH3 = × 3 = 𝑚𝑜𝑙.
2 2
9
×0.821×273
Using PV = nRT, 𝑉𝑜𝑙. = 2 0.5

= 201. 6 

86. I2 + 2Cl2 ⎯→ ICl + ICl3

25.4 14.2
Mole: 254 71

= 0.1 0.2
No. L. R
 moles of ICl produced = 0.1

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& moles of ICl3 produced = 0.1

 Correct option is (A)
87. S8 + 8O2 ⎯→ 8SO2
2SO2 + O2 ⎯→ 2SO3
1 mole S8 = 8 mole SO2 .....(1)

 2 mole SO2 = 2 mole SO3

i.e. 8 mole SO2 = 8 mole SO3 .....(2)
From (1) & (2)
SO3 obtained from 1 mol of S8 = (8 × 80)g SO3 i.e. 640g SO3

88. 2Pbs + 3O2 ⎯→ 2PbO + 2SO2

3SO2 + 2HNO3 + 2H2O ⎯→ 3H2SO4 + 2NO
1075.5
nPbs = = 4.49
239.2

2 mole Pbs = 2 mole SO2 .....(1)

3 mole SO2 = 3 mole H2SO4
 2 mole SO2 = 2 mole H2SO4 .....(3)
From (1) & (3)
1 mole Pbs = 1 mole H2SO4
 4.49 mole Pbs = 4.49 mole H2SO4 or 4.50 mole H2SO4
 mass of H2SO4 = (4.50 × 98) = 441 gm

180
89. Moles of A = = 9 mol.
20
180
Moles of B = = 6 mol.
30
200
Moles of C = = 20 mol.
10

2A + 3B + 5C ⎯→ A2BC2 + B2C3
Moles 9 6 20
Moles 9 6 20
𝑆.𝐶𝑜𝑒𝑓𝑓. 2 3 5

B is limiting Reagent
1
 Moles of B2C3 produced = 3 × 6 = 2

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5
Consumed Moles of C = 3 × 6 = 10

 Remaining moles of C = 20 – 10 = 10
2
Consumed moles of A = 3 × 6 = 4

Remaining moles of A = 9 – 4 = 5
Now for the 2nd Reaction,
B2C3 + 3C ⎯→ 2BC3
Moles 2 10
Moles 2 10
𝑆.𝐶𝑜𝑒𝑓𝑓 1 3

B2C3 is limiting Reagent

2
 Number of moles of BC3 produced = 1 × 2 = 4

Now for the 3rd Reaction,

BC3 + A ⎯→ ABC3
Moles 4 5
Moles 4 5
𝑆.𝐶𝑜𝑒𝑓𝑓 1 1

BC3 is limiting Reagent

1
 Number of moles of ABC3 produced = 1 × 4 = 4

90. 2P4 + 8O2 ⎯→ P4O6 + P4O10

31 32
Mole : 124 32
1
= 1
4

No. L. R
1 1
 Weights of P4O6 produced = 2 × 4 × 220 = 27.5 g
1
& weight of P4O10 produced = 8 × 284 = 35.5 g

DPP-09
Total mass
91. Average molecular mass = 𝑇𝑜𝑡𝑎𝑙 moles

Let total moles of mixture = 100

Moles of N2 = 80
Moles of Oxygen = 20
Total mass of mixture = mass of nitrogen + mass of oxygen

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 80 × 28 + 20 × 32 = 2880 gm
2880
Avg. molecular mass of mixture = = 28.8
100

92. Let % of NO2 be x

NO % of number be (100 – x)
𝑥×46+(100−𝑥)×30
 34 =  x = 25 %
100

 Correct option is (A)

80−56 6
93. 𝛼= 3 =7
( −1)
2

94. Mass percent of oxygen

= 100 – (40 + 6.67) = 53.33
Now,
40 6.67 53.33
𝑁𝐶 : 𝑁𝐻 : 𝑁𝑂 = : : = 1: 2: 1
12 1 16
Empirical formula = CH2O
95. Mass per cent of hydrogen
2 1.8 100
= × × 100 =
18 1.4 7
and mass per cent of carbon
100 600
= 100 − =
7 7
Now, atomic ratio of C and H
600/7 100/7
= : = 1: 2
12 1
Hence, the empirical formula =CH2
75.77×34.9689+24.23×36.9659
96. mass of chlorine = 100

2649.59355+895.683757
= = 35.4527
100

79×24+(21−𝑥)×25+𝑥×26
97. 24.31 = 100

 2431 = 1896 + 525 – 25x + 26x

 x = 10
98. Mass mole simplest ratio
9 3 3 1
C 9 =4 ÷4=3
12 4

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1 1
H 1 =1 1÷4=4
1

3.5 1 1 1
N 3.5 =4 4÷4=1
14

 Empirical formula is C3H4N

Empirical formula mass is 54

Given:
216
Molecular mass = 216 𝑛= =4
54

 Molecular formula is C12H16N4

 Total number of atoms present in

1 molecule of compound = x = (12 + 16 + 4)

 x = 32
𝑥
=8
4
99. Molecular mass of the compound
1
= 6.06×10−3 ≈ 165

Empirical formula mass = 3 × 12 + 3 × 1 + 1 × 16 = 55

165
Now, 𝑛 = = 3 and hence the molecular
55

formula = (C3H3O)3= C9H9O3

88
110. Number of moles of CO2 = 44 = 2𝑚𝑜𝑙

36
Number of moles of H2O = 18 = 2𝑚𝑜𝑙

Mass of carbon = 2 × 12 = 24 gm

Number of moles of H = 4 mol

Mass of Hydrogen = 4 × 1 = 4

Mass of oxygen = 60 – 28 = 32
32
Number of moles of oxygen = 16 = 2

Molecular formula = C2H4O2

Empirical formula = CH2O

The value of (x + y) is = 1 + 2 = 3

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DPP-10
101. New molecular mass of H2O
= 2 × 0.5 + 1 × 20 = 21
Percentage increase in molecular mass of H2O
21−18
= × 100 = 16.67%
18

102. C2H4O2 + 2O2 ⎯→ 2CO2 + 2H2O.

1 mole C2H4O2 & 2 mole O2 produces 2 mole CO2
i.e. 124 g mixture produces 88 gm CO2
88
 620g mixture will produces 124 × 620 = 440 gm

 Correct option is (C)

103. Let the molecule be AxBy

𝑋𝑁𝐴 +𝑀𝑌
Molecular weight of compounds formed = ( )
5

 Correct option is (A).

104. 5A2 + 2B4 ⎯→ 2AB2 + 4A2B.

5 mole A2 produce 2 mole AB2
 (2 × 250)g AB2 is produced from 100g A2
100
 1000g AB2 is produced from (2×250) × 1000𝑔 of A2

= 200 g of A2
Also, 2 mole AB2 is produced from 2 mole B4

 (2 × 250)g AB2 is produced from (2 × 120 × 4) g of B4

2×120×4
 1000 g AB2 is produced from ( ) × 1000 = 1920 gm.
2×250

 Minimum mass of mixture of A2 & B2 is (1920 + 200)

i.e. 2120 gm

 Correct option is (A)

105. mass of substance = 0.42 gm.
100
Volume of N2 = ml
11

Temperature = 250 K

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Pressure = 860 – 24 = 836 mm Hg

Step (1)
𝑃1 𝑉1 𝑇
Volume of N2 at S.T.P. i.e. V2 = × 𝑃2
𝑇1 2

836×100×273
 V2 =  V2 = 10.92 ml
760×11×250

Step (2)
28×10.92 10
% of N2 in organic compound = 22700×0.42 × 100 = %
3

 Correct option is (A)

106. for Alkali metal carbonate

M2CO3 + HCl ⎯→ MCl + CO2 + H2O

(Excess)
𝐹𝑜𝑟 𝐴𝑙𝑘𝑎𝑙𝑖𝑛𝑒 𝐸𝑎𝑟𝑡ℎ 𝑚𝑒𝑡𝑎𝑙𝑐𝑎𝑟𝑏𝑜𝑛𝑎𝑡𝑒
𝑀𝐶𝑂3 +𝐻𝐶𝑙→ 𝑀𝐶𝑙2 +𝐶𝑂2 +𝐻2 𝑂

1×12.315
𝑛𝐶𝑂2 = 0.0821×300 = 0.5 mole

Li2CO3 + 2HCl ⎯→ 2LiCl + CO2 + H2O

1 mole CO2 is produced from 1 mole Li2CO3

 0.5 mole CO2 is produced from .5 mole Li2CO3 OR = .5 × (74)

= 37 gm. of Li2CO3 & mass of impurity = 3 gm

 Correct option is (B)

107. C7H8 + 3HNO3 ⎯→ C7H5N3O6 + 3H2O
As, C7H8 & HNO3 reacts in 1 : 3 ratio

 x × 92 + 3x × 62 = 140.5  x = 0.5

 Maximum weight of C7H5N3O6 which can be produced is 0.5 × 227 i.e 113.5 gm
Correct option is (B).

108. Method-1

Let the compound be CxHyOz

Now, weight % of C = 8 × (weight % of H)

𝑥 2
 =3
𝑦

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1
Also, weight % of C = 2 × (weight % of O)
𝑥 2
 =3
𝑧

 The correct option is (B)

Method-2

Ag2A ⎯→ Ag

P.O. A.C. on Ag
1 0.5934
2 × 216+𝑀 = ×1
𝐴 108

 MA → 148

 molar mass of Acid = 150

C H O

weight % 8 1 16

mole % 2 3 3

 Empirical formula = C2H3O3

n=2  molecular formula is C4H6O6

 Correct option is (B)

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