Peacock 1931
Peacock 1931
Peacock 1931
M. A. PEACOCK
University of British Columbia
ABSTRACT
Some rock series cannot be properly classified either as alkalic or as sub-alkalic.
To meet this situation a simple extension of the present twofold classification is pro-
posed; this takes the form of a fourfold division into alkalic, alkali-calcic, calc-alkalic,
and calcic groups. It is shown, from a partial graphical representation of thirteen rock
series, that the silica value at which the curves for total alkalis and for lime intersect
(the alkali-lime index) is characteristic of a rock series and is of classificatory value.
From a consideration of the curves of the thirteen rock series and their mineral as-
semblages, limits are suggested for the proposed four groups in terms of the alkali-lime
index and of characteristic minerals.
Other classifications of rock series are briefly noticed, and it is observed that they
are dependent on a chemical and mineralogical classification. Since an ideal genetic
classification is not in sight, it is concluded that a somewhat closely defined, descriptive
fourfold grouping on a chemical and mineralogical basis may be more useful than the
present rather vague twofold division.
I
A primary division of igneous rock series into two groups, alkalic
and sub-alkalic (calc-alkalic, calcic), has long been recognized.
Tables contrasting the mineralogical characters of rock types of the
two groups have been given by Harker' and by Tyrrell ; and in gen-
eral a rock series can be readily placed in this twofold classification.
It has been observed, however, that some rock series lie in a debat-
able zone between the two groups, where they cannot be properly
described either as alkalic or as sub-alkalic. Some rock series of the
Arctic Region belong to this class. Thus, in 1918 Holmes3 wrote:
". ... the Icelandic volcanic rocks belong neither to a typical
'calc-alkali' nor to a typical 'alkali' series, but share the characters
of both." In 1925 the present writer4 concluded that the Icelandic
suite is composite, consisting of an earlier calc-alkali series and a
later series of mildly alkalic character; and Cargill, Hawkes, and
' A. Harker, The Natural History of Igneous Rocks (New York, 1909), p. 91.
2 G. W. Tyrrell, The Principles of Petrology (New York, 1926), p. 137.
3 A. Holmes, "The Basaltic Rocks of the Arctic Region," Min. Mag., Vol. XVIII
(1918), p. 199.
4 M. A. Peacock, "A Contribution to the Petrography of Iceland," Trans. Geol. Soc.
Glasgow, Vol. XVII (1925), p. 328.
54
the curve for total alkalis rises from 3 to 4 per cent at the basic
end to 7 to 8 per cent at the acidic end, and often shows very little
curvature. The lime curve, on the other hand, falls from around 10
per cent in basic rocks to about i per cent in acidic rocks, and is
likewise nearly straight or somewhat concave upward throughout
the greater part of its course. In typical alkali series the curve for
the alkalis is systematically higher than in calcic series; furthermore,
the curve is strongly convex upward and reaches a pronounced maxi-
mum at intermediate silica percentages. The lime curve in alkalic
series falls more rapidly than in calcic series and exhibits more
strongly pronounced upward concavity. As a result of these rela-
tions, the alkali and lime curves in alkalic series intersect at much
lower silica percentages than is the case in calcic series, as Holmes'
has already pointed out.
Since the character of a rock series is expressed in the relations of
the alkali and lime curves, the abscissa of the point of intersection
of these curves becomes an important index to the character of the
rock series, and one which promises to be of value in defining the
limits of the proposed fourfold classification. But to have convinc-
ing significance, this index must show reasonably systematic rela-
tions to the mineralogy of the rock series. To test this, the diagram
(Fig. I) and the accompanying statement of component rock types
and essential primary minerals have been prepared. This diagram
gives the curves for NaO+KO (full lines) and for CaO (broken
lines), on a silica base, for thirteen described rock series including
the three Iceland series, A, B, C. The choice of series represented
was determined mainly by accessibility of data; beyond aiming at a
fair representation, the curves are those of practically the first
thirteen series for which adequate descriptions could be found. From
the point of intersection of each pair of curves a perpendicular is
dropped to the proper silica axis; the arrowhead thus gives the
abscissa of the point of intersection, which we shall call the "alkali-
lime index" of the rock series. The thirteen rock series are arranged
according to the alkali-lime index, No. i (Teneriffe) having the low-
est index and No. 13 (Katmai) the highest. Finally, the diagram is
traversed by three vertical chain-dotted lines marking the proposed
boundaries between the four groups of rock series.
I Loc. cit.
FIG. I.-Curves for Na20+K20 (full lines) and for CaO (broken lines) for thirteen
rock series arranged in four groups according to the "alkali-lime index" (SiO2 value at
which Na 0+ K2O= CaO).
Rock series.-Mugearite-syenite-trachyte-bostonite.
Mineral assemblage.-Olivine, enstatite-augite, augite, aegirine-
augite, aegirine, amphiboles allied to arfvedsonite, riebeckite and
' A. Logario, "Uber die Natur der Glasbasis, sowie der Krystallisationsvorgi~nge in
eruptiven Magma," TschermakMin. Pet. Mitth., Vol. VIII (1887), p. 440; H. Preiswerk,
"Sodalittrachyt vom Pico de Teyde (Teneriffa)," Centralb.f. Min., 1909, p. 396; A.
Holmes, "The Tertiary Volcanic Rocks of Mozambique," Quar. Jour. Geol. Soc.
London, Vol. LXXII (1917), pp. 268-69, Fig. 8.
2 The basalts do not appear to have been petrographically described. The analyses
given by Preiswerk show that they are certainly alkali-basalts, and the large amounts
of olivine and nepheline in their norms in Washington's Tables warrant the inclusion
of these minerals in the mineral assemblage.
3 A. Harker, op. cit., p. 122, Fig. 25; A. Holmes, The Nomenclature of Petrology
(London,1920).
Br gger's original descriptions of these rocks are not available to the writer; but
Harker's variation diagram and list of rock types, together with Holmes's definitions,
which are based on Br~gger's descriptions, are adequate for the present purpose.
4 E. B. Bailey and Others, "The Tertiary and Post-Tertiary Geology of Mull,
Lock Aline, and Oban," Mem. Geol. Sur. Scotland (Edinburgh, 1924), p. 26, Fig. 4.
Rock series."-Trachybasalt-trachyandesite-trachyte.
Mineral assemblage.-Olivine, purple augite, augite, aegirine-
augite, hornblende, red-brown biotite, titanmagnetite, ilmenite,
plagioclase (labradorite to oligoclase), sanidine, anorthoclase, quartz
(very small amount).
Alkali lime index.-51.2.
Classification.-Alkali-calcic, close to the boundary with alkalic.
6. ICELAND C4
Rock series.-Trachybasalt-trachyandesite'-trachyte-trachy-
rhyolite.
Mineral assemblage.-Olivine, aegirine-augite, magnetite, bytown-
ite, andesine, albite, anorthoclase, microperthite, soda-orthoclase,
orthoclase.
'G. W. Tyrrell, "The Petrography of Jan Mayen," Trans. Roy. Soc. Edinburgh,
Vol. LIV (1926), pp. 747-65.
2 The full series is: ankaramite-trachybasalt-trachyandesite-trachyte, which
give serial relations in a diagram based on percentage of felsic minerals as abscissas
(Tyrrell, ibid., p. 761, Fig. i). On a silica base, ankaramite, with a silica content sim-
ilar to that of trachybasalt, must be omitted.
3 A. Holmes, "The Tertiary Volcanic Rocks of Mozambique," Quar. Jour. Geol.
Soc. London, Vol. LXXII (1917), pp. 233-46, p. 266, Fig. 6.
4 M. A. Peacock, op. cit., pp. 289-91, pp. 299, 303-6; also new observations.
Alkali-lime index.-55.4.
Classification.-Alkali-calcic.
7. ICELAND B2
Rock series.-Olivine-basalt3-quartz-hornblende-diorite-horn-
blende-granodiorite-granophyre-granite-aplite.
Mineral assemblage.-Olivine, augite, hypersthene, soda-diopside
(?), hornblende, biotite, magnetite, bytownite, labradorite, andesine,
oligoclase, perthite, cryptoperthite,quartz.
Alkali-lime index.-56.4.
Classification.-Calc-alkalic.
8. ICELAND A4
Rock series.-Olivine-basalt-basalt-mugearite-rhyolite.
Mineral assemblage.-Olivine, hypersthene, enstatite-augite, pur-
ple augite, brown augite, aegirine-augite, magnetite, titan-magne-
tite, ilmenite, anorthite, bytownite, labradorite, andesine, oligoclase,
anorthoclase, quartz.
Alkali-lime index.-58.3.
Classification.-C alc-alkalic.
9. MULL (NORMAL MAGMA SERIES), SCOTLAND5
Rock series.-Olivine-diallage-rock-biotite-diorite-hornblende-
biotite-granite-porphyritic-biotite-granite-eurite.
Mineral assemblage.-Olivine, enstatite, augite, diallage, horn-
blende, biotite, plagioclase, microcline, orthoclase, quartz.
Alkali-lime index.-59.6.
Classification.-Calc-alkalic.
I I. LAS SEN PEAK2
Rock series.-Basalt-andesite-dacite-rhyolite.
Mineral assemblage.-Olivine, hypersthene, augite, hornblende,
biotite, magnetite, plagioclase, alkali-felspar, quartz.
Alkali-lime index.-62.4.
Classification.-Calcic.
12. MOZAMBIQUE B, EAST AFRICA3
Alkali-lime index.-63.8.
Classification.-Calci c.
Inspection of the diagram (Fig. i) and the accompanying data
shows that the order of the rock series as determined by the alkali-
lime index is broadly the same as that suggested by the mineral
assemblages of the rock series represented. The obviously alkalic
series, i (Teneriffe) and 2 (Kristiania), have the lowest alkali-lime
indices; the most calcic series, 13 (Katmai) and 12 (Mozambique B),
have the highest alkali-lime indices; while the three Iceland series
(6, 7, 8) with intermediate mineralogical characters, have alkali-
lime indices which place them in intermediate positions. The alkali-
lime index thus seems to be reliably connected with the mineralogical
characters of rock series; and since the index is also sensitive, ranging
from 46.8 to 63.8 in the diagram, the promise of its usefulness in
classification seems to be fulfilled.
We may now attempt to deduce the best boundaries for the four-
fold classification. In general, arbitrary numerical boundaries in
petrological classification are properly regarded with strong disfavor;
and it is not proposed to lay down inflexible dividing lines delimiting
the four groups of rock series on the basis of the alkali-lime index
alone. But if a division on this basis can be rationally correlated with
significant mineralogical distinctions, the odium attending the
division should be greatly mitigated.
The boundary between alkali-calcic and calc-alkalic series clearly
should fall between 6 (Iceland C) and 7 (Iceland B)-say at the
alkali-lime index value 56. By choosing this boundary, we make
Iceland C (trachybasalt-trachyandesite-trachyte-trachyrhyo-
lite) an alkali-calcic series, and Iceland B (olivine-basalt-quartz-
hornblende-diorite- hornblende-granodiorite - granophyre - gran-
ite-aplite) a calc-alkalic series, which is in keeping with their respec-
tive mineral assemblages.
The division between alkalic series and alkali-calcic series is best
made at the alkali-lime index where felspathoids cease to appear in
appreciable amounts. Series i (Teneriffe) and 2 (Kristiania) have
abundant felspathoids; in 3 (Mull, alkaline), with the alkali-lime
index 50.8, nepheline is "suspected." If we choose the alkali-lime
'Bowen's curvilinear modification of Fenner's rectilinear diagram would result in
only a slight reduction in the alkali-lime index.
sideration of these exceptions shows that they have but little sig-
nificance. Modal quartz is absent from the alkali-calcic Series 5
(Mozambique A) and 6 (Iceland C); but in both cases normative
quartz was revealed in analyzed specimens.' Quartz is present in the
alkalic Series 2 (Kristiania); but at the extreme acid end of an
alkalic series this is to be expected, although it is better to regard
quartz as normally absent in alkalic series, which often do not extend
TABLE I
ROCKSERIES
CHARACTERISTIC
MINERALS
Alkalic Alkali-Calcic Calc-Alkalic Calcic
Rhombic pyroxene X X
Soda-pyroxene X X ?X
Common hornblende*.. X X
Soda-amphibole* X X
Soda-potash-felspar X X X
Felspathoid . X
Quartz X X X
III
Rock series are designated according to two other methods: (i)
according to the name of a characteristic component rock type;
(2) according to petrographic provinces or magmatic regions. Thus
we have the tephrite series or kindred (the term "kindred" implying
that the component rock types are genetically related), the trachy-