Shapes of Molecules

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Shapes of Molecules

Mr. E. Ncube
Shapes overview
3 e- pairs
a) Linear
b) Angular
c) Trigonal planar 2 e- pairs
d) Pyramidal
e) -
f) Tetrahedral
g) - 4 e- pairs
h) -
i) Trigonal bi-
pyramidal
j) -
k) Octahedral 5 e- pairs 6 e- pairs

l) -
Tetrahedral
ch4

ch4

ch4

tetrahedron
Ammonia – NH3 PYRAMIDAL!
Bond pairs LONE pair
Lewis-NH3

NH3

nh3

nh3

◼ 4 e- pairs – basic shape is


tetrahedral!
◼ Lone pairs repel MORE so distort the
molecule shape.
◼ When naming the shape the lone pair
is IGNORED!
VSEPR

◼ Valence Shell Electron Pair Repulsion


◼ Electrons negative
◼ Bond pairs & lone pairs repel
◼ Lone pair repulsion greater than bond
pairs
◼ BPBP<BPLP<LPLP
◼ Predict ALL shapes
Carbon – tetra chloride

Cl

Cl
C
Cl
Cl

◼ Tetrahedral
◼ 4 bond pairs repelling equally
Water
Bond pairs = 2
Lone pairs = 2
Total pairs = 4
• • . .

• O H •
x Basic shape = tetrahedral 109.5o
•x
H O H

O
H H
105.4O
H
The LONE PAIRS repel MORE than the BOND pairs so they
PUSH the bond pairs CLOSER TOGETHER.

Distorted angles = 105.4O


◼ Bent or angular molecule!
Non-Polar Molecules with Polar Bonds
◼ The molecule is
symmetrical
◼ There is no overall polarity
F
on the molecule.
◼ The MOLECULE IS NON-
POLAR! F
C
F
F
CF4
Eneg = 4 - 2.5 = 1.5
.: Polar Bonds!!
Polar/Non-polar molecules
Bond Molecule
Substance ΔEneg
Polarity Symmetry Polarity
CF4
NH3
PCl3
PCl5
SF6
CH3Cl
CH3OH

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