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    Chap 7

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    The document discusses naming conventions, drawing structures, and conformational analysis of alkanes. It includes exercises to name alkanes using IUPAC nomenclature, draw structures of specific alkanes, and identify the highest and lowest energy conformations of various alkanes by analyzing molecular structure and bond rotations.

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    Chap 7

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    The document discusses naming conventions, drawing structures, and conformational analysis of alkanes. It includes exercises to name alkanes using IUPAC nomenclature, draw structures of specific alkanes, and identify the highest and lowest energy conformations of various alkanes by analyzing molecular structure and bond rotations.

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    The document discusses naming conventions, drawing structures, and conformational analysis of alkanes. It includes exercises to name alkanes using IUPAC nomenclature, draw structures of specific alkanes, and identify the highest and lowest energy conformations of various alkanes by analyzing molecular structure and bond rotations.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    21 views8 pages

    Chap 7

    Uploaded by

    h2300021
    The document discusses naming conventions, drawing structures, and conformational analysis of alkanes. It includes exercises to name alkanes using IUPAC nomenclature, draw structures of specific alkanes, and identify the highest and lowest energy conformations of various alkanes by analyzing molecular structure and bond rotations.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 8

    Chương 7: Alkan – hydrocarbon no

    Bài 1. Gọi tên hợp chất sau theo danh pháp IUPAC

    Bài 2. Gọi tên hợp chất sau theo danh pháp IUPAC
    Bài 3. Vẽ cấu trúc cho các alkan có tên sau
    (a) 3-Isopropyl-2,4-dimethylpentan (b) 4-Ethyl-2-methylhexan
    (c) 1,1,2,2-Tetramethylcyclopropan

    Bài 4. Vẽ tất cả các đồng phân của alkan có công thức phân tử C7H16.

    Bài 5. Vẽ các cấu trạng của etan CH3-CH3? Xác định cấu trạng bền nhất?

    Bài 6. Vẽ các cấu trạng của etan CH3-CH3? Xác định cấu trạng bền nhất?
    Nội dung 2: Cơ chế phản ứng thế gốc tự do: Xác định được sản phẩm chính – sản phẩm
    phụ
    Bài 1. Predict the major product obtained upon radical bromination of 2,2,4-trimethylpentane:

    Bài 2. Predict the major product obtained upon radical bromination of each of the following
    compounds:

    Bài 3. A synthesis of the antibiotic natural product γ-indomycinone involved the halogenation
    reaction shown below.5 The major product of the reaction is a monobrominated compound, and
    a significant amount of a minor, dibrominated compound is also formed. Draw both products,
    and explain why the dibrominated product is readily formed.

    Bài 4. Identify the major product(s) for each of the following reactions. If any of the reactions
    do not yield a product, indicate “no reaction.”
    Bài 5. When 2-methylpropane is treated with bromine in the presence of UV light, one product
    predominates.
    a) Identify the structure of the product.
    b) Draw the structure of the expected minor product.
    Bài 6. Predict the products that are obtained when methylenecyclohexane is treated with NBS
    and
    irradiated with UV light:

    Bài 7. Predict the products when each of the following compounds is treated with NBS and
    irradiated with UV light:

    Bài 8. When 2-methyl-2-butene is treated with NBS and irradiated with UV light, five different
    monobromination products are obtained, one of which is a racemic mixture ofvenantiomers.
    Draw all five monobromination products and identify the product that isvobtained as a racemic
    mixture.

    Bài 9. Identify all products expected for each of the following reactions. Take stereochemistry
    into account and draw expected stereoisomer(s), if any:

    Nội dung 3: Cho các alkan, xác định cấu trạng bền

    Bài 1. Draw a Newman projection of the following compound, as viewed from the angle
    indicated:
    Đáp án

    Bài 2. In each case below, draw a Newman projection as viewed from the angle indicated:

    Bài 3. Consider the following compound:


    a) Rotating only the C3C4 bond, identify the lowest energy conformation.
    b) Rotating only the C3C4 bond, identify the highest energy conformation.

    Bài 4. In each case below, identify the highest and lowest energy conformations. In cases where
    two or three conformations are degenerate, draw only one as your answer.

    Bài 5. Compare the three staggered conformations of ethylene glycol. The anti conformation of
    ethylene glycol is not the lowest energy conformation. The other two staggered conformations
    are actually lower in energy than the anti conformation. Suggest an explanation.

    Bài 6. What are the relative energy levels of the three staggered conformations of 2,3-
    dimethylbutane when looking down the C2C3 bond?

    Bài 7. Rank the following conformations in order of increasing energy:

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