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Molykote br2 Plus GB 2018

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0% found this document useful (0 votes)
31 views18 pages

Molykote br2 Plus GB 2018

Uploaded by

Akmal Udin30
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 18

SAFETY DATA SHEET

SPECIALTY ELECTRONIC MATERIALS UK


LIMITED
Safety Data Sheet according to Reg. (EU) No 2015/830
Product name: MOLYKOTE™ BR2 Plus High Performance Revision Date: 18.10.2018
Grease Version: 2.0
Date of last issue: 13.11.2017
Print Date: 21.02.2020
SPECIALTY ELECTRONIC MATERIALS UK LIMITED encourages and expects you to read and
understand the entire (M)SDS, as there is important information throughout the document. We expect
you to follow the precautions identified in this document unless your use conditions would necessitate
other appropriate methods or actions.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1 Product identifier
Product name: MOLYKOTE™ BR2 Plus High Performance Grease

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Lubricants and lubricant additives

1.3 Details of the supplier of the safety data sheet


COMPANY IDENTIFICATION
SPECIALTY ELECTRONIC MATERIALS UK
LIMITED
STATION ROAD, BIRCH VALE, HIGH PEAK
DERBYSHIRE
England
SK22 1BR
UNITED KINGDOM

Customer Information Number: 800-3876-6838


SDSQuestion-EU@dupont.com

1.4 EMERGENCY TELEPHONE NUMBER


24-Hour Emergency Contact: +(44)-870-8200418
Local Emergency Contact: +(44)-870-8200418

SECTION 2: HAZARDS IDENTIFICATION


2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008:


Serious eye damage - Category 1 - H318
Chronic aquatic toxicity - Category 3 - H412
For the full text of the H-Statements mentioned in this Section, see Section 16.

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 18


company of Dow
Product name: MOLYKOTE™ BR2 Plus High Performance Grease Revision Date: 18.10.2018
Version: 2.0

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008:

Hazard pictograms

Signal word: DANGER

Hazard statements
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P305 + P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
+ P338 + if present and easy to do. Continue rinsing. Immediately call a POISON
P310 CENTER/doctor.
P501 Dispose of contents/ container to an approved waste disposal plant.

Contains Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts

2.3 Other hazards


No data available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Molybdenum disulfide grease


3.2 Mixtures

This product is a mixture.

CASRN / REACH Classification:


EC-No. / Registration Concentration Component REGULATION (EC) No
Index-No. Number 1272/2008

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Product name: MOLYKOTE™ BR2 Plus High Performance Grease Revision Date: 18.10.2018
Version: 2.0

CASRN _ >= 38.0 - <= 46.0 % Distillates Asp. Tox. - 1 - H304


64742-52-5 (petroleum),
EC-No. hydrotreated heavy
265-155-0 naphthenic; Baseoil
Index-No. -unspecified
649-465-00-7
CASRN 01-2119493628-22 >= 3.0 - <= 4.0 % Phosphorodithioic Skin Irrit. - 2 - H315
68457-79-4 acid, mixed O,O- Eye Dam. - 1 - H318
EC-No. bis(iso-Bu and Aquatic Chronic - 2 - H411
270-608-0 pentyl) esters, zinc
Index-No. salts

Substances with a workplace exposure limit
CASRN 01-2119486977-12 >= 0.9 - <= 1.3 % Graphite Not classified
7782-42-5
EC-No.
231-955-3
Index-No.

CASRN _ >= 0.69 - <= 1.08 % Molybdenum Not classified
1317-33-5 disulfide
EC-No.
215-263-9
Index-No.

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES


4.1 Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin contact: Wash off with plenty of water. Suitable emergency safety shower facility should be
available in work area.

Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove
contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.

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Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.

4.2 Most important symptoms and effects, both acute and delayed: Aside from the information
found under Description of first aid measures (above) and Indication of immediate medical attention
and special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician: Chemical eye burns may require extended irrigation. Obtain prompt
consultation, preferably from an ophthalmologist. No specific antidote. Treatment of exposure should
be directed at the control of symptoms and the clinical condition of the patient.

SECTION 5: FIREFIGHTING MEASURES


5.1 Extinguishing media
Suitable extinguishing media: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry
chemical

Unsuitable extinguishing media: None known.

5.2 Special hazards arising from the substance or mixture


Hazardous combustion products: Carbon oxides Metal oxides Oxides of phosphorus Sulphur
oxides

Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health.

5.3 Advice for firefighters


Fire Fighting Procedures: Collect contaminated fire extinguishing water separately. This must not be
discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of
in accordance with local regulations. Contain fire water run-off if possible. Fire water run-off, if not
contained, may cause environmental damage.
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Use water spray to cool unopened containers. Remove undamaged containers from fire
area if it is safe to do so. Evacuate area.

Special protective equipment for firefighters: In the event of fire, wear self-contained breathing
apparatus. Use personal protective equipment.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures: Use personal
protective equipment. Follow safe handling advice and personal protective equipment
recommendations.

6.2 Environmental precautions: Do not release the product to the aquatic environment above
defined regulatory levels Prevent further leakage or spillage if safe to do so. Retain and dispose of

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contaminated wash water. Local authorities should be advised if significant spillages cannot be
contained.

6.3 Methods and materials for containment and cleaning up: Soak up with inert absorbent
material. Local or national regulations may apply to releases and disposal of this material, as well as
those materials and items employed in the cleanup of releases. You will need to determine which
regulations are applicable. For large spills, provide dyking or other appropriate containment to keep
material from spreading. If dyked material can be pumped, Clean up remaining materials from spill
with suitable absorbent. Sections 13 and 15 of this SDS provide information regarding certain local or
national requirements.

6.4 Reference to other sections:


See sections: 7, 8, 11, 12 and 13.

SECTION 7: HANDLING AND STORAGE


7.1 Precautions for safe handling: Do not get on skin or clothing. Do not swallow. Do not get in
eyes. Keep container tightly closed. Take care to prevent spills, waste and minimize release to the
environment. Handle in accordance with good industrial hygiene and safety practice.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.

7.2 Conditions for safe storage, including any incompatibilities: Keep in properly labelled
containers. Keep tightly closed. Store in accordance with the particular national regulations.

Do not store with the following product types: Strong oxidizing agents.

7.3 Specific end use(s): See the technical data sheet on this product for further information.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value/Notation
Distillates (petroleum), ACGIH TWA Inhalable 5 mg/m3
hydrotreated heavy fraction
naphthenic; Baseoil -
unspecified
Graphite ACGIH TWA Respirable 2 mg/m3
fraction
GB EH40 TWA inhalable dust 10 mg/m3
GB EH40 TWA Respirable 4 mg/m3
dust
Molybdenum disulfide ACGIH TWA Inhalable 10 mg/m3 ,
fraction Molybdenum
ACGIH TWA Respirable 3 mg/m3 , Molybdenum
fraction

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GB EH40 TWA 10 mg/m3 ,


Molybdenum
GB EH40 STEL 20 mg/m3 ,
Molybdenum

Derived No Effect Level


Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts
Workers
Acute systemic effects Acute local effects Long-term systemic Long-term local effects
effects
Dermal Inhalation Dermal Inhalation Dermal Inhalation Dermal Inhalation
n.a. n.a. n.a. n.a. 11.87 8.13 n.a. n.a.
mg/kg mg/m3
bw/day

Consumers
Acute systemic effects Acute local effects Long-term systemic effects Long-term local
effects
Dermal Inhalation Oral Dermal Inhalation Dermal Inhalation Oral Dermal Inhalation
n.a. n.a. n.a. n.a. n.a. 5.93 2.06 0.24 n.a. n.a.
mg/kg mg/m3 mg/kg
bw/day bw/day

Graphite
Workers
Acute systemic effects Acute local effects Long-term systemic Long-term local effects
effects
Dermal Inhalation Dermal Inhalation Dermal Inhalation Dermal Inhalation
n.a. n.a. n.a. n.a. n.a. n.a. n.a. 1.2 mg/m3

Consumers
Acute systemic effects Acute local effects Long-term systemic effects Long-term local
effects
Dermal Inhalation Oral Dermal Inhalation Dermal Inhalation Oral Dermal Inhalation
n.a. n.a. n.a. n.a. n.a. n.a. n.a. 813 n.a. 0.3
mg/kg mg/m3
bw/day

Predicted No Effect Concentration


Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified
Compartment PNEC
Oral (Secondary Poisoning) 9.33 mg/kg food

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


Compartment PNEC
Fresh water 4 µg/l
Marine water 4.6 µg/l
Intermittent use/release 45 µg/l

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Sewage treatment plant 100 mg/l


Oral (Secondary Poisoning) 10.67 mg/kg food
Soil 0.002 mg/kg dry weight
(d.w.)
Marine sediment 0.002 mg/kg dry weight
(d.w.)
Fresh water sediment 0.024 mg/kg dry weight
(d.w.)

8.2 Exposure controls


Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures


Eye/face protection: Use chemical goggles. Chemical goggles should be consistent with EN
166 or equivalent.
Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374:
Protective gloves against chemicals and micro-organisms. Examples of preferred
glove barrier materials include: Chlorinated polyethylene. Neoprene.
Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Viton. Examples of acceptable glove barrier
materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or
"vinyl"). When prolonged or frequently repeated contact may occur, a glove with a
protection class of 4 or higher (breakthrough time greater than 120 minutes according
to EN 374) is recommended. When only brief contact is expected, a glove with a
protection class of 1 or higher (breakthrough time greater than 10 minutes according
to EN 374) is recommended. Glove thickness alone is not a good indicator of the
level of protection a glove provides against a chemical substance as this level of
protection is also highly dependent on the specific composition of the material that the
glove is fabricated from. The thickness of the glove must, depending on model and
type of material, generally be more than 0.35 mm to offer sufficient protection for
prolonged and frequent contact with the substance. As an exception to this general
rule it is known that multilayer laminate gloves may offer prolonged protection at
thicknesses less than 0.35 mm. Other glove materials with a thickness of less than
0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE:
The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but
not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to
glove materials, as well as the instructions/specifications provided by the glove
supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit

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requirements or guidelines, wear respiratory protection when adverse effects, such as


respiratory irritation or discomfort have been experienced, or where indicated by your risk
assessment process. For most conditions, no respiratory protection should be needed;
however, if handling at elevated temperatures without sufficient ventilation, use an approved
air-purifying respirator.
Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A
(boiling point >65 ºC)

Environmental exposure controls


See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to
prevent excessive environmental exposure during use and waste disposal.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
Appearance
Physical state Grease
Color black
Odor slight
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point closed cup > 200 °C
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 0.89
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.

9.2 Other information

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Molecular weight No data available


Particle size No data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

SECTION 10: STABILITY AND REACTIVITY


10.1 Reactivity: Not classified as a reactivity hazard.

10.2 Chemical stability: Stable under normal conditions.

10.3 Possibility of hazardous reactions: Can react with strong oxidizing agents.

10.4 Conditions to avoid: None known.

10.5 Incompatible materials: Oxidizing agents

10.6 Hazardous decomposition products


No hazardous decomposition products are known.

SECTION 11: TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

11.1 Information on toxicological effects


Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury.
As product: Single dose oral LD50 has not been determined.

Acute dermal toxicity


Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.

Acute inhalation toxicity


At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated
material may cause respiratory irritation.
As product: The LC50 has not been determined.

Skin corrosion/irritation
Brief contact may cause slight skin irritation with local redness.
Prolonged contact may cause moderate skin irritation with local redness.
May cause drying and flaking of the skin.

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Serious eye damage/eye irritation


May cause severe irritation with corneal injury which may result in permanent impairment of vision,
even blindness. Chemical burns may occur.

Sensitization
For skin sensitization:
Contains component(s) which did not cause allergic skin sensitization in guinea pigs.

For respiratory sensitization:


No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)


Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Contains component(s) which have been reported to cause effects on the following organs in animals:
Liver

Carcinogenicity
Contains component(s) which did not cause cancer in laboratory animals.

Teratogenicity
Contains component(s) which, in laboratory animals, have been toxic to the fetus only at doses toxic to
the mother.

Reproductive toxicity
Contains component(s) which did not interfere with reproduction in animal studies.

Mutagenicity
Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in
others. Contains component(s) which were negative in animal genetic toxicity studies.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

COMPONENTS INFLUENCING TOXICOLOGY:

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


Acute oral toxicity
LD50, Rat, > 5,000 mg/kg OECD Test Guideline 401

Acute dermal toxicity


LD50, Rabbit, > 5,000 mg/kg OECD Test Guideline 402

Acute inhalation toxicity


LC50, Rat, 4 Hour, dust/mist, > 5.53 mg/l OECD Test Guideline 403

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


Acute oral toxicity
LD50, Rat, male, 3,600 mg/kg

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Acute dermal toxicity


LD50, Rabbit, male and female, > 20,000 mg/kg

Acute inhalation toxicity


The LC50 has not been determined.

Graphite
Acute oral toxicity
LD50, Rat, > 2,000 mg/kg OECD Test Guideline 401 No deaths occurred at this
concentration.

Acute dermal toxicity


The dermal LD50 has not been determined.

Acute inhalation toxicity


LC50, Rat, 4 Hour, dust/mist, > 2 mg/l OECD Test Guideline 403 No deaths occurred at this
concentration.

Molybdenum disulfide
Acute oral toxicity
LD50, Rat, > 2,000 mg/kg No deaths occurred at this concentration.

Acute dermal toxicity


LD50, Rat, male and female, > 2,000 mg/kg No deaths occurred at this concentration.

Acute inhalation toxicity


LC50, Rat, 4 Hour, dust/mist, > 2.82 mg/l No deaths occurred at this concentration.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

12.1 Toxicity

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


Acute toxicity to fish
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50
greater than 100 mg/L in most sensitive species).
LL50, Pimephales promelas (fathead minnow), 96 Hour, > 100 mg/l, OECD Test Guideline
203

Acute toxicity to aquatic invertebrates


EL50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l

Acute toxicity to algae/aquatic plants


EL50, Pseudokirchneriella subcapitata (green algae), 72 Hour, > 100 mg/l, OECD Test
Guideline 201

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NOELR, Pseudokirchneriella subcapitata (green algae), 72 Hour, 100 mg/l, OECD Test
Guideline 201

Toxicity to bacteria
NOEC, 10 min, >= 1.93 mg/l

Chronic toxicity to aquatic invertebrates


NOELR, Daphnia magna (Water flea), 21 d, 10 mg/l

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


Acute toxicity to fish
Material is toxic to aquatic organisms (LC50/EC50/IC50 between 1 and 10 mg/L in the most
sensitive species).
Based on data from similar materials
LL50, Cyprinodon variegatus (sheepshead minnow), semi-static test, 96 Hour, 4.5 mg/l, OECD
Test Guideline 203

Acute toxicity to aquatic invertebrates


Based on data from similar materials
EL50, Daphnia magna (Water flea), static test, 48 Hour, 23 mg/l, OECD Test Guideline 202

Acute toxicity to algae/aquatic plants


Based on data from similar materials
EL50, Desmodesmus subspicatus (green algae), 72 Hour, 24 mg/l, OECD Test Guideline 201

Toxicity to bacteria
Based on data from similar materials
EC50, 3 Hour, > 1,000 mg/l, OECD Test Guideline 209

Chronic toxicity to aquatic invertebrates


Based on data from similar materials
NOEC, Daphnia magna (Water flea), 21 d, 0.4 mg/l

Graphite
Acute toxicity to fish
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50
greater than 100 mg/L in most sensitive species).
LC50, Danio rerio (zebra fish), 96 Hour, > 100 mg/l, OECD Test Guideline 203

Acute toxicity to aquatic invertebrates


EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l, OECD Test Guideline 202

Acute toxicity to algae/aquatic plants


EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, > 100 mg/l, OECD Test
Guideline 201

Toxicity to bacteria
EC50, 3 Hour, > 1,012.5 mg/l, OECD Test Guideline 209

Molybdenum disulfide
Acute toxicity to fish

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Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50


greater than 100 mg/L in most sensitive species).
For similar material(s):
LC50, Fish, 96 Hour, > 100 mg/l

Acute toxicity to aquatic invertebrates


Based on data from similar materials
EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l

Acute toxicity to algae/aquatic plants


Based on data from similar materials
ErC50, algae, 72 Hour, Growth rate, > 100 mg/l

Toxicity to bacteria
EC50, 30 Hour, Respiration rates., > 100 mg/l

Chronic toxicity to fish


Based on data from similar materials
NOEC, Fish, 34 d, > 10 mg/l

Chronic toxicity to aquatic invertebrates


Based on data from similar materials
NOEC, Daphnia magna, 21 d, > 10 mg/l

12.2 Persistence and degradability

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 31 %
Exposure time: 28 d
Method: OECD Test Guideline 301F

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
Based on data from similar materials 10-day Window: Fail
Biodegradation: 1.5 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

Graphite
Biodegradability: Biodegradation is not applicable.

Molybdenum disulfide
Biodegradability: Biodegradability is not applicable to inorganic substances.

12.3 Bioaccumulative potential

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified

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Bioaccumulation: No relevant data found.

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


Bioaccumulation: For similar material(s): Bioconcentration potential is low (BCF < 100 or
Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.69 OECD Test Guideline 107

Graphite
Bioaccumulation: No relevant data found.

Molybdenum disulfide
Bioaccumulation: Partitioning from water to n-octanol is not applicable.

12.4 Mobility in soil

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


No relevant data found.

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


No specific, relevant data available for assessment.

Graphite
No relevant data found.

Molybdenum disulfide
No relevant data found.

12.5 Results of PBT and vPvB assessment

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This
substance is not considered to be very persistent and very bioaccumulating (vPvB).

Graphite
This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This
substance is not considered to be very persistent and very bioaccumulating (vPvB).

Molybdenum disulfide
This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

12.6 Other adverse effects

Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil -unspecified


This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts


This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

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Graphite
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Molybdenum disulfide
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

SECTION 13: DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Do not dump into any sewers, on the ground, or into any body of water. This product, when being
disposed of in its unused and uncontaminated state should be treated as a hazardous waste
according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national
and provincial laws and any municipal or local by-laws governing hazardous waste. For used,
contaminated and residual materials additional evaluations may be required.

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code
will depend on the use that is made of this material. Contact the authorized waste disposal services.

SECTION 14: TRANSPORT INFORMATION

Classification for ROAD and Rail transport (ADR/RID):


14.1 UN number Not applicable
14.2 UN proper shipping name Not regulated for transport
14.3 Transport hazard class(es) Not applicable
14.4 Packing group Not applicable
14.5 Environmental hazards Not considered environmentally hazardous based on
available data.
14.6 Special precautions for user No data available.

Classification for SEA transport (IMO-IMDG):


14.1 UN number Not applicable
14.2 UN proper shipping name Not regulated for transport
14.3 Transport hazard class(es) Not applicable
14.4 Packing group Not applicable
14.5 Environmental hazards Not considered as marine pollutant based on available data.
14.6 Special precautions for user No data available.
14.7 Transport in bulk according
to Annex I or II of MARPOL
Consult IMO regulations before transporting ocean bulk
73/78 and the IBC or IGC
Code

Classification for AIR transport (IATA/ICAO):

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Product name: MOLYKOTE™ BR2 Plus High Performance Grease Revision Date: 18.10.2018
Version: 2.0

14.1 UN number Not applicable


14.2 UN proper shipping name Not regulated for transport
14.3 Transport hazard class(es) Not applicable
14.4 Packing group Not applicable
14.5 Environmental hazards Not applicable
14.6 Special precautions for user No data available.

This information is not intended to convey all specific regulatory or operational


requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

SECTION 15: REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture

REACh Regulation (EC) No 1907/2006


This product contains only components that have been either pre-registered, registered, are exempt
from registration, are regarded as registered or are not subject to registration according to Regulation
(EC) No. 1907/2006 (REACH)., Polymers are exempted from registration under REACH. All relevant
starting materials and additives have been either pre-registered, registered, or are exempt from
registration to Regulation (EC) No. 1907/2006 (REACH).,The aforementioned indications of the
REACH registration status are provided in good faith and believed to be accurate as of the effective
date shown above. However, no warranty, express or implied, is given. It is the buyer´s/user´s
responsibility to ensure thathis/her understanding of the regulatory status of this product is correct.

Restrictions on the manufacture, placing on the market and use:


The following substance/s contained in this product is/are subject through Annex XVII of REACH
regulation to restrictions on the manufacture, placing on the market and use when present in certain
dangerous substances, mixtures and articles. Users of this product have to comply with the restrictions
placed upon it by the aforementioned provision.
CAS-No.: 64742-52-5 Name: Distillates (petroleum), hydrotreated heavy naphthenic;
Baseoil -unspecified
Restriction status: listed in REACH Annex XVII
Restricted uses: See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control
of major-accident hazards involving dangerous substances.
Listed in Regulation: Not applicable

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Product name: MOLYKOTE™ BR2 Plus High Performance Grease Revision Date: 18.10.2018
Version: 2.0

15.2 Chemical safety assessment


Not applicable

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Classification and procedure used to derive the classification for mixtures according to
Regulation (EC) No 1272/2008
Eye Dam. - 1 - H318 - Calculation method
Aquatic Chronic - 3 - H412 - Calculation method

Revision
Identification Number: 1512986 / A670 / Issue Date: 18.10.2018 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
GB EH40 UK. EH40 WEL - Workplace Exposure Limits
STEL Short-term exposure limit (15-minute reference period)
TWA 8-hour, time-weighted average
Aquatic Chronic Chronic aquatic toxicity
Asp. Tox. Aspiration hazard
Eye Dam. Serious eye damage
Skin Irrit. Skin irritation

Full text of other abbreviations


ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods
by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the
Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation;
Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration
associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good
Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil

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Product name: MOLYKOTE™ BR2 Plus High Performance Grease Revision Date: 18.10.2018
Version: 2.0

Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG -


International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal
Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the
Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed
(Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No
Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization
for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the
International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition
Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan
Chemical Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very
Bioaccumulative

Information Source and References


This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

SPECIALTY ELECTRONIC MATERIALS UK LIMITED urges each customer or recipient of this


(M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become
aware of and understand the data contained in this (M)SDS and any hazards associated with the
product. The information herein is provided in good faith and believed to be accurate as of the
effective date shown above. However, no warranty, express or implied, is given. Regulatory
requirements are subject to change and may differ between various locations. It is the buyer's/user's
responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The
information presented here pertains only to the product as shipped. Since conditions for use of the
product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
conditions necessary for the safe use of this product. Due to the proliferation of sources for
information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for
(M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from
another source or if you are not sure that the (M)SDS you have is current, please contact us for the
most current version.

GB

Page 18 of 18

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