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    EXP5

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    suryansu2006

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    © All Rights Reserved
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    EXP5

    Uploaded by

    suryansu2006
    19 views3 pages

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    © © All Rights Reserved

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    Copyright:

    © All Rights Reserved
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    19 views3 pages

    EXP5

    Uploaded by

    suryansu2006

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    (The reactions should be written on blank side of the record)

    REACTION OF NO-3
    1. Pb(NO3)2 + H2 SO4 → PbSO4 + 2NO3
    2.4 HNO3 + Cu → Cu (NO3)2 + 2NO2 + 2H20
    3. Pb (NO3)2 + 2H2SO4 → Pb(HSO4)2 + 2HNO3
    4. FeSO4 + NO + 5H₂O →[Fe(NO) (H₂O)5] SO4
    (brown ring)
    5. 2 FeSO4 + 2HNO2 + H2SO4 → Fe2(SO4)3 + 2NO + 2H20

    REACTION OF Pb2+
    1. Pb (NO3)2 (aq) + 2 HCl → PbCl2 (s)↓ + 2 HNO3
    2. Pb Cl2 (s) + hot water (H₂O) → PPt. dissolved
    cooling
    3. Pb Cl2 (aq) → PPt. reappears
    4. PbCl2 (aq) + K2Cr2 O4 → PbCrO4 ↓ +2 KCl
    Yellow ppt
    5. Pb Cl2 (aq) + 2KI → PbI2↓ + 2 KCl
    Yellow ppt
    Experiment -5
    QUALITATIVE ANALYSIS OF SALTS
    Aim Of The Experiment
    To identify the acid and basic radical present in a given sample of salt.
    Preliminary Test:
    Salt packet no: ___
    Colour of the salt: white
    Structure of the salt: Crystalline
    Solubility: Soluable in hot water
    I. Dry Test for Basic Radical:
    (a) Dry test tube heating :-
    Experiment Observation Inference
    A pinch of salt was taken in a a)salt decrepitates a)Pb(NO3)2 , KBr, NaCl may
    clean dry test tube and was b)Reddish brown gas that be present
    heated. turns FeSO4 solution black. b)NO2 -/NO3- may be present
    c)Brown Residue when hot c)Pb 2+ may be present
    and yellow when cold
    (b) Charcoal cavity test :-
    Experiment Observation Inference
    A pinch of salt was mixed Brown residue May be Pb2+
    with a double quantity of
    sodium carbonate and the
    mixture was heated in
    charcoal cavity in reducing
    flame.
    c)Flame test:-
    Experiment Observation Inference
    A mixture of salt with conc. Dull bluish white colour flame May be Pb2+
    HCl was introduced into
    oxidizing flame
    II. Dry Test for Acid Radical:
    (a) Dil. H2SO4 test:-
    Experiment Observation Inference
    A pinch of salt was taken in a No efferverence/ reaction 𝐶𝑂32− ,𝑆𝑂32− , 𝑁𝑂2− , 𝑆 2−
    clean dry test tube. To it 1ml takes place are absent
    of dil. H2SO4 was added

    (b) Concentrated H2SO4 test -


    Experiment Observation Inference
    A pinch of salt was taken in a Reddish brown gas that turns N𝑂3− May be present
    clean dry test tube. To it 1 ml FeSO4 solution black.
    of concentrated H2SO4 was
    added

    (c) Copper turning test:-


    Experiment Observation Inference
    A pinch of salt was taken in a Pungent brown gas evolved May be N𝑂3−
    clean dry test tube. To it few which turns moist blue litmus
    drops of conc. H2SO4 was red
    added, 1 to 2 pieces of
    copper turning was added
    and it was heated warmed.

    III. Wet Test for Acid Radical:


    (a) Confirmative test for N𝑶− 𝟑 (Brown ring test) -
    Experiment Observation Inference
    To aqueous solution of the A brown ring is formed N𝑂3− is confirmed.
    salt, few drops of conc. between the junctions of
    H2SO4 followed by freshly liquids, i.e., the acid and salt
    prepared Ferrous Sulphate solution layer
    solution was added.
    IV. Wet Test for Basic Radical:
    Experiment Observation Inference
    1 to 2 cc of salt sol. was Group 1 basic radical, Pb2+
    taken in a test tube and to it A white precipitate is formed may be present
    dil. HCl was added.
    Analysis of White Precipitate
    The precipitate was dissolved in hot water and it was divided into 3 parts.
    Part-1 Part-2 Part-3
    The solution was allowed to To it potassium Chromate To it KI solution was added.
    cool down White precipitate solution was added Yellow Yellow precipitate is
    reappears precipitate is formed formed

    Pb2+ is confirmed
    Conclusion:
    The given salt contains
    a. Acid Radical- N𝑂3−
    b. Basic Radical - Pb2+

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