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    Haloalkane and Haloarenes DPP 3

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    Dharmvir Tanty

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    © All Rights Reserved
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    Haloalkane and Haloarenes DPP 3

    Uploaded by

    Dharmvir Tanty
    42 views2 pages

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    Haloalkane and Haloarenes Dpp 3

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    42 views2 pages

    Haloalkane and Haloarenes DPP 3

    Uploaded by

    Dharmvir Tanty

    Copyright:

    © All Rights Reserved
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    1

    GYANA VIKASH ACADEMY


    Haloalkanes and Haloarenes DPP-03

    1. The decreasing nucleophilicity among the 6. Arrange the following compound in decreasing
    nucleophiles order of reactivity in SN2 reaction
    CH3 C–O – (a) CH3 – C – CH 2 – Br
    (a) || ||
    O O
    (b) CH3O– (b) CH3CH2–CH2–CH2Br
    (c) CN– CH3 – CH–CH 2 – Br
    O (c) |
    CH3
    (d) H3C S O–
    (d) CH3 – CH–CH 2 – CH3
    O |
    (1) (c), (b), (a), (d) (2) (b), (c), (a), (d) Br
    (3) (d), (c), (b), (a) (4) (a), (b), (c), (d) (1) b>c>d>a (2) a>b>c>d
    (3) b>c>a>d (4) c>a>b>d
    2. CH3Br + Nu–   CH3 –Nu + Br–
    The decreasing order of the rate of above reaction 7. Arrange the following compounds in decreasing
    with nucleophile (Nu–) is order of reactivity in SN1 reaction
    [Nu = (A) PhO–, (B) AcO–, (C) HO–, (D) CH3O–] Cl

    (1) D>C>A>B (2) D>C>B>A


    (2) A>B>C>D (4) B>D>C>A (a) Ph – CH2 – Cl (b)

    3. Which of the following has the highest Cl


    nucleophilicity? CH 3
    (1) F– (2) OH– |
    (3) CH3– (4) NH2– (c) (d) CH3 –C– CH 2 –Cl
    |
    CH 3
    4. Which of the following undergoes nucleophilic (1) a>c>b>d (2) c>d>b>a
    substitution by SN1 mechanism at fastest rate (3) a>b>c>d (4) b>a>c>d
    CH3 –CH–Cl
    | 8. Which of the following is the correct order of
    (1) CH3–CH2–Cl (2) CH3 decreasing SN2 reactivity?
    (3) (4) (1) RCH2X > R3CX > R2CHX
    CH2–Cl Cl
    (2) RCH2X > R2CHX > R3CX
    (3) R3CX > R2CHX > RCH2X
    5. Tertiary alkyl halides are practically inert to (4) R2CHX > R3CX > RCH2X (X = halogen)
    substitution by SN2 mechanism because of
    (1) Steric hindrance 9. Intermediate in SN2 reaction is
    (2) Inductive effect (1) Carbocation
    (3) Instability (2) Carbanion
    (4) Insolubility (3) Penta-valent c-atom
    (4) None of these
    2

    10. Which of the following would favour SN2 reaction? 14. Order of rate of reaction with AgNO3 or rate of SN1:
    (1) H2O (2) Ethanol Cl Cl Cl
    (3) THF (4) Benzene

    11. Rearrangement can occur in


    (1) SN1 (2) S N2 (I) (II) (III)
    (3) Both SN1 & SN2 (4) None of these (1) I > III > II (2) II > III > I
    (3) I > II > III (4) III > I > II
    12. Which of the following conditions favour SN2
    mechanism?
    15. Which of the following is least reactive towards SN1?
    (1) Strong nucleophile
    I
    (2) Weak conc. of nucleophile I
    (3) 3o alkyl halide
    (4) Polar protic solvent
    (1) (2)
    13. The decreasing order of rate of SN2 reaction is:
    (i) CH3  Cl
    (ii) I I
    CH3  C  CH 2  Cl
    ||
    O
    (iii) CH3  CH  CH 2  Cl (3) (4)
    |
    CH3
    (iv) CH3  CH 2  C1
    (1) (IV) > (III) > (II) > (I)
    (2) (II) > (III) > (I) > (IV)
    (3) (II) > (I) > (IV) > (III)
    (4) None

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