MADHUVAN VATIKA PUBLIC SCHOOL

Chemistry HOLIDAY HOMEWORK Roll No. :

Student Name : Class :

Question 1 2 3 4 Marks Obtained Total Marks Signature of Examiner :

Marks Obtained 100 Date : 21-05-2024

Que 1 (A) Choose The Right Answer From The Given Options.[1 Marks Each] [100]
1. 18 carat gold contains ?
(A) 18% gold (B) 4% gold (C) 75% gold (D) 60% gold
2. Cortisone is a molecular substance containing 21 atoms of carbon per molecule. The mass
percentage of carbon in cortisone is 69.98%. It's molar mass is:
(A) 176.5 (B) 252.2 (C) 287.6 (D) 360.1
3. What will be the molality of the solution made by dissolving 10g of NaOH in 100g of water?
(A) 2.5m. (B) 5m. (C) 10m. (D) 1.25m.
4. What is the mass percent of carbon in carbon dioxide?
(A) 0.034% (B) 27.27% (C) 3.4% (D) 28.7%
5. Equal volume of gases contain equal number of moles.State whether the above statement
is true or false.
(A) The statement is True.
(B) The statement is False.
(C) Neither.
(D) Equal volume of gases contain equal number of moles, only when the temperature is
increased.
6. Law of conservation of mass is also known as:
(A) Law of indestructibility. (B) Law of mass action.
(C) Law of conservation of energy. (D) None of the above.
7. The result reported in the following multiplication of significant figures,
2.5 × 1.25 = 3.125 should be:
(A) 3.125 (B) 3.1 (C) 3.12 (D) 3.10
8. % composition requires ................ of the compound :
(A) Molar mass (B) Temperature
(C) Atmospheric pressure (D) Both a and b
9. A sample of H 2 ​SO4 ​contains 3.2 kg of sulphur. The weight (in g) of hydrogen present in the
sample is:
(A) 100 (B) 200 (C) 50 (D) 150
10. What is the mass of one atom of C−12 in grams?
(A) 1.992 × 10−23 gm (B) 1.989 × 10−23 gm
(C) 1.892 × 10−23 gm (D) 1.965 × 10−23 gm
11.

[1]
 One mole of any substance contains 6.022 × 1023 atoms/ molecules. Number of molecules
of H 2 SO4 present in 100mL of 0.02M H 2 SO4 solution is ______.
(A) 12.044 × 1020 molecules. (B) 6.022 × 1023 molecules.
(C) 1 × 1023 molecules. (D) 12.044 × 1023 molecules.
12. The solution of A and B are 0.1 and 0.2 molar in a substance. If 100ML of 'A' are mixed with
25mL of B and there is no change in volume, then the final molarity of solution is:
(A) 0.15M (B) 0.18M (C) 0.12M (D) 0.30M
13. Which law was given by Antoine L. Lavoisier?
(A) Laws of multiple proportion (B) Law of conservation of mass
(C) Both A and B (D) None of the above
14. Which of the following statements illustrate the law of multiple proportions?
(A) 3.47g of BaCl2 reacts with 2.36g Na2 SO4 to give 3.88g BaSO4 and 1.95g NaCl.
(B) Hydrogen sulphide contains 5.89% hydrogen, water contains 11.1% hydrogen and sulphur
dioxide contains 50% oxygen.
(C) An element forms two oxides, XO and XO2 containing 50% and 60% oxygen respectively.
The ratio of masses of oxygen which combines with 1g of element X is 2 : 3.
(D) 20mL ammonia gives 10 volumes N2 and 30 volumes H 2 at constant temperature and
pressure.
15. How many number of molecules and atoms respectively are present in 2.8L of a diatomic
gas at STP?
(A) 6.023 × 1023 , 7.5 × 1023 (B) 6.023 × 1023 , 15 × 1022
(C) 7.5 × 1022 , 15 × 1022 (D) 15 × 1022 , 7.5 × 1023
16. Sulphuric acid reacts with sodium hydroxide as follows:
H 2 SO4 + 2NaOH → Na 2 SO4 + 2H 2O
When 1L of 0.1M sulphuric acid solution is allowed to react with 1L of 0.1M sodium
hydroxide solution, the amount of sodium sulphate formed and its molarity in the solution
obtained is:
(A) 0.1mol L–1 (B) 7.10 g
(C) 0.025mol L–1
(D) 3.55g
17. Chemical hypothesis first emerged in Classical Greece by:
(A) Einstein (B) Louis Pasteur
(C) Aristotle (D) Leuweenhock
18. Which law states that if two elements can combine to form more than one compound, the
masses of one element that combine with a fixed mass of other element, are in the ratio of
small whole numbers?
(A) Avogadro's law. (B) Law of definite composition.
(C) Law of multiple proportions. (D) Gay Lussac's law of gaseous volumes.
19. Which of the following options is not correct?
(A) 8008 = 8.008 × 103 (B) 208 = 3
(C) 5000 = 5.0 × 103
(D) 2.0034 = 4
20. Which of the following represents largest number of particles.

[2]
 (A) Atoms in mole of CH 4 (B) Atoms in 0.5 mol of SO3
(C) Atoms in 0.5 mole of CO2 (D) Atoms in 1 mol of CO.
21. An alkaloid contains 17.28% of nitrogen and its molecular mass is 162. The number of
nitrogen atoms present in one molecule of alkaloid is:
(A) 5 (B) 4 (C) 3 (D) 2
22. Which statement is linked with the idea that two identical containers filled with different
gases will contain the same number of particles?
(A) Mosely (B) Avagadro (C) Dalton (D) Mendeleev
23. An organic compound on analysis was found to contain 10.06% carbon, 0.84% hydrogen
and 89.10% chlorine. What will be the empirical formula of the substance?
(A) CH 2 Cl2 (B) CHCl3 (C) CCl4 (D) CH 3 Cl
24. What is the mass percent of carbon in carbon dioxide?
(A) 0.034% (B) 27.27% (C) 3.4% (D) 28.7%
25. A mixture of 24dm3 of hydrogen and 100dm3 of oxygen was ignited and the reaction
mixture was cooled to room temperature and pressure. What will be volume of gases
remaining of the end of the reaction?
(A) 24dm3 (B) 76dm3 (C) 88dm3 (D) 112dm3
26. The concentration of a solution or the amount of substance present in its given volume can
be expressed in which of the following ways?
(A) Mass percent or weight percent (w/ (B) Mole fraction or molarity.
w%). (C) Molality.
(D) All of the above.
27. 4.6 × 1022 atoms of an element weight 13.8g. What is the atomic mass of the element?
(A) 290u (B) 180.6u (C) 34.4u (D) 104u
28. Uncertainty Principle was given by:
(A) Heisenberg (B) Thomson (C) Rutherford (D) Bohr
29. The volume of 0.5M aqueous NaOH solution required to
neutralize 10ml of 2M aqueous HC1solution is:
(A) 20ml (B) 40ml (C) 80ml (D) 120ml
30. Which of the following statements about a compound is incorrect?
(A) A molecule of a compound has atoms of different elements.
(B) A compound cannot be separated into its constituent elements by physical methods of
separation.
(C) A compound retains the physical properties of its constituent elements.
(D) The ratio of atoms of different elements in a compound is fixed.
31. Chemistry is sometimes called as:
(A) Biological Science (B) Central Science
(C) Biochemistry (D) Both A and C
32. Which is the lightest element in the universe?
(A) Helium (B) Hydrogen (C) Nitrogen (D) Silicon
33. At same temperature and pressure, equal volumes of gases contain the same number of:
(A) Molecules (B) Electrons (C) Protons (D) Particles

[3]
34. A compound contains 69.5% oxygen, 30.5% nitrogen and its molecular weight is 92. The
formula of compound is:
(A) N2 O (B) NO2 (C) N2 O4 (D) N2 O5
35. What is the atomic mass (u) of chlorine?
(A) 34 (B) 35.5 (C) 33 (D) 35
36. The laws of chemical combination formed on the basis of:
(A) Dalton's atomic theory (B) Dalton's mass theory
(C) Both A and B (D) None of the above
37. Which of the following terms are unitless?
(A) Molality. (B) Molarity.
(C) Mole fraction. (D) Mass percent.
38. Mass can neither be created nor destroyed. This is in agreement with which law of
chemical combination?
(A) Law of definite proportion (B) Law of multiple proportion
(C) Law of conservation of mass (D) Law of conservation of momentum
39. If 1 L of O2 ​at 15o C and 750mm pressure contains N molecules, the number of molecules
in 2 L of SO2 ​under the same conditions of temperature and pressure will be:

(A)
N
(B) N (C) 2N (D) 4N
2

40. The mass of a sand and powdered mixture along with a beaker is 56g. If the mass of the
dried mixture is 20g, find the % composition of the mixture in 100g?
(weight of beaker = 20g).
(A) 20% (B) 36% (C) 55% (D) 60%
41. Branch of chemistry deals with structure of matter, the energy changes and theories, laws
and principles that explain the transfer motion of matter for one form to another is known
as:
(A) Physical chemistry (B) Inorganic chemistry
(C) Organic chemistry (D) Analytical chemistry
42. What is % composition of a substance?
(A) Sum of all the components.
(B) % composition of the sum of two components.
(C) % of the total mass of a substance.
(D) None of the above.
43. The mass of hydrogen at STP, that is present in a vessel which can hold 4 grams of oxygen
under similar conditions, is:
(A) 1gm (B) 0.5gm (C) 0.25gm (D) 0.125gm
44. The matter is neither created nor destroyed during any physical or chemical change. This
statement is of the:
(A) Law of constant proportion. (B) Law of conservation of mass.
(C) Law of reciprocal proportion. (D) Law of multiple proportion.
45. 1.020g of metallic oxide contains 0.540g of the metal. If the specific heat of the metal, M is
0.216 cal deg-1 g-1 . The molecular formula of its oxide is:
(A) MO (B) M2 O3 (C) M2 O4 (D) M2 O

[4]
46. Dalton’s atomic theory was based on:
(A) Law of chemical combination. (B) Mass theory.
(C) Periodic table. (D) None of the above.
47. Which of the following reactions is not correct according to the law of conservation of
mass.
(A) 2Mg(s) + O2 (g) → 2MgO(s)

(B) C3 H8 (g) = O2 (g) → CO 2 (g) = H2 O(g)

(C) P4 (s) = 5O2 (g) → P4 O10 (s)

(D) CH 4 (g) = 2O2 (g) → CO 2 (g) + 2H2 O(g)

48. Which law is not applicable for a nuclear reaction where large amount of energy is
released?
(A) Law of conservation of mass (B) Law of definite proportion
(C) Law of multiple proportion (D) Avagrado's law
49. What will be the ratio of Cl35 and Cl37 respectively in ordinary chlorine if the atomic weight
of chlorine is 35.5
(A) 1 : 3 (B) 3 : 1 (C) 1 : 2 (D) 2 : 1
50. The relative atomic mass of naturally occurring chlorine is not a whole number. What is the
reason for this ?
(A) Chlorine atoms can have different number of neutrons.
(B) Naturally occurring chlorine cannot be obtained pure.
(C) Chlorine is unstable.
(D) The mass of the electrons has been included.
51. A certain metal sulphide, MS2 ​, is used extensively as a high temperature lubricant. If MS2
is 40.06% by mass of sulphur, metal M has atomic mass:
(A) 160amu (B) 64amu (C) 40amu (D) 96amu
52. Isotopes have same____but different____.
(A) Atomic number, mass number. (B) Mass number, atomic number.
(C) Number of neutrons, atomic number. (D) None of these.
53. For an atom of a given element, the number of electrons equals to:
(A) The number of protons + number of neutrons.
(B) The atomic number of the element.
(C) The number of proton − number of neutrons.
(D) The mass number of the element.
54. The Bohr model of atoms:
(A) Uses Einstein's photo electric equation.
(B) Predicts continuous emission spectra for atoms.
(C) Predicts the same emission spectra for all types of atoms.
(D) Assumes that the angular momentum of electrons is quantized.
55. The first use of quantum theory to explain the structure of atom was made by:
(A) Heisenberg (B) Bohr (C) Planck (D) Einstein
56. For the electrons of oxygen atom, which of the following statements is correct?
(A) Zeff for an electron in a 2s orbital is the same as Zeff for an electron in a 2p orbital.

[5]
 (B) An electron in the 2s orbital has the same energy as an electron in the 2p orbital.
(C) Zeff for an electron in 1s orbital is the same as Zeff for an electron in a 2s orbital.
(D) The two electrons present in the 2s orbital have spin quantum numbers ms but of opposite
sign.
57. Atomic mass unit is abbreviated as __________.
(A) atm (B) ama (C) a.m.u (D) aum
58. Who suggested the distribution of electrons into different orbits of an atom?
(A) E. Goldstein (B) Ernest Rutherford
(C) Bohr and Bury (D) Dalton
59. Number of angular nodes for 4d orbital is __________.
(A) 4. (B) 3 (C) 2. (D) 1.
60. Two electrons occupying the same orbital are distinguished by:
(A) Principle quantum Number. (B) Magnetic quantum number.
(C) Azimuthal quantum number. (D) Spin quantum number.
61. Out of the following pairs of electrons, identify the pairs of electrons present in degenerate
orbitals:
(A) (a) n = 3, l = 2, ml = -2, ms = − 12
1
(b) n = 3, l = 2, ml = -1, ms = −
2

(B) (a) n = 3, l = 1, ml = 1, ms = + 2 1

1
(b) n = 3, l = 2, ml = 1, ms = +
2

(C) (a) n = 4, l = 1, ml = 1, ms = + 2 1

1
(b) n = 3, l = 2, ml = 1, ms = +
2

1
(D) (a) n = 3, l = 2, ml = +2, ms = − 2
1
(b) n = 3, l = 2, ml = +2, ms = +
2

62. The relation between atomic number (Z) and atomic mass (A) for light elements is given
by:
(A) A = Z (B) A = 2Z (C) 2A = Z (D) A = 4Z
63. Probability of finding an electron at a point within an atom is:
2 2
(A) Equal to the |ψ| at that point. (B) Proportional to the |ψ| at that point.
(C) Inversely proportional to the |ψ| at
2
(D) None of the above.
that point.
64. The mass number of X is 23 which contains 15 electrons. What is the atomic mass of X?
(A) 38 amu. (B) 23 amu.
(C) 8 amu. (D) None of above.
65. Which of the following sets of quantum numbers are correct?
n l ml
a. 1 1 +2
b. 2 1 +1
c. 3 2 -2
d. 3 4 -2

[6]
66. Orbital angular momentum depends on __________.
(A) l. (B) n and l. (C) n and m. (D) m and s.
67. What is the name for the number of protons in an atom?
(A) Atomic identity (B) tomic mass
(C) Atomic weight (D) Atomic number
68. f Aufbau rule is violated, then Ca 20 will be in:
(A) S-block (B) P-block (C) D-block (D) F-block
69. The first line in the Balmer series in the H atom will have the frequency:
(A) 3.29 × 1025 s-1 (B) 4.57 × 1024 s-1
(C) 8.22 × 1025 s-1 (D) 8.02 × 1014 s-1
70. Atomic number of Bismuth is:
(A) 84 (B) 85 (C) 83 (D) 82
71. What idea states that lower energy level orbitals will be filled with electrons before higher
energy level orbitals?
(A) Pauli's exclusion principle. (B) Octet rule.
(C) Aufbau principle. (D) Hund's rule.
72. When electron jumps from N shell to L shell, the energy is:
(A) Emitted. (B) Bsorbed.
(C) Reflected. (D) Cannot be predicted.
73. Which of the following properties of atom could be explained correctly by Thomson Model
of atom?
(A) Overall neutrality of atom. (B) Spectra of hydrogen atom.
(C) Position of electrons, protons and (D) Stability of atom.
neutrons in atom.
74. Which of the following has the same number of protons?
(A) Isobars (B) Isoelectronic
(C) Isotopes (D) Isotones
75. According to Bohr hypothesis, discrete quantity is:
(A) Momentum (B) Angular velocity
(C) Potential energy (D) Angular momentum
76. What is maximum number of orbitals that can be identified with the following quantum
number?
(A) 1 (B) 2 (C) 3 (D) 4
77. Which of the following pairs of d-orbitals have electron density along the axis?
(A) dz2 dxz (B) dxz , dyz (C) dz2 , dx2 y2 (D) dzy , dx2 y2

78. For an element (Z = 25), how many electrons are present in the "N" shell in its ground
state?
(A) 13 (B) 2 (C) 15 (D) 3
79. Chlorine exists in two isotopic forms, Cl-37 and Cl-35 but its atomic mass is 35.5. This
indicates the ratio of Cl-37 and Cl-35 is approximately:
(A) 1 : 2. (B) 1 : 1. (C) 1 : 3. (D) 3 : 1.

[7]
80. Mass number is ___________.
(A) The sum of the total number of protons and neutrons present in the nucleus of an atom.
(B) The electrons present in the outermost shell of an atom.
(C) An atom of each element having a definite combining capacity.
(D) The total number of protons present in the nucleus of an atom.
81. Pairing of electrons in the orbitals belonging to the same subshell (p, d or f) does not take
place until each orbital belonging to that subshell is singly occupied. This is called:
(A) Hund's rule of maximum multiplicity. (B) Pauli's exclusion principle.
(C) Aufbau principle. (D) None of the above.
82. Determine the number of electron in the isotope of 'H' (mass no. 2).
(A) 1 (B) 2 (C) 0 (D) 3
83. Energy of the electron in Bohr's orbit is equal to ?
(A) Potential energy only.
(B) Kinetic energy only.
(C) Sum of potential and kinetic energy.
(D) difference of kinetic and potential energy.
84. The electronic configuration of an element is 1s2 2s2 2p3 . The number of unpaired electron
in this atom are:
(A) 3 (B) 5 (C) 7 (D) 1
85. How many electrons can fit in the orbital for which:
n = 3 and l = 1?
(A) 10 (B) 14 (C) 2 (D) 6
86. Aufbau principle does not give the correct arrangement of filling up of the atomic orbitals
in:
(A) Cu and Zn (B) Co and Zn (C) Mn and Cr (D) Cu and Cr
87. Which of the following properties of atom could be explained correctly by Thomson model
of atom?
(A) Overall neutrality of atom.
(B) Spectra of hydrogen atom.
(C) Position of electrons, protons and neutrons in atom.
(D) Stability of atom.
88. The first model of an atom was given by _____________.
(A) N. Bohr (B) E. Goldstein (C) Rutherford (D) J.J. Thomson
89. Thomson's atomic model concluded that _____ is the constituent particle of all kinds of
atoms.
(A) Electron (B) Protron (C) Neutron (D) None of these
90. By knowing the number of protons in a neutral atom, one can determine:
(A) The identity of the element. (B) The number of neutrons in the atom.
(C) The number of common isotopes of (D) The atomic radius size.
the element.
91. Identify the pairs which are not of isotopes?
(A) 13
6
X,
13
6
Y. (B) 35
17
X,
37
17
Y. (C) 14
6
X,
14
7
Y. (D) 8
4
X,
8
5
Y.

[8]
 92. The pair of ions having same electronic configuration is ______.
(A) Cr3+, Fe3+ (B) Fe3+, Mn2+ + (C) Fe3+, CO3+ (D) Sc3+, Cr3+
93. The plot of orbital wave function ψ(r) as a function of distance r of the electron from the
nucleus for 2s orbital is:

(A) (B) (C) (D)

94. Which of the following is responsible to rule out the existence of definite paths or
trajectories of electrons?
(A) Pauli's exclusion principle.
(B) Heisenberg's uncertainty principle.
(C) Hund's rule of maximum multiplicity.
(D) Aufbau principle.
95. Electronic configuration of five elements I, II, III, IV, V is mentioned below.

In the above configuration element I, II, III, IV and V represent as:

(A) C, N, O, F, Ne (B) Ne, F, O, N, C
(C) C, O, N, Ne, F (D) O, C, F, Ne, V
96. Atomic number of an atom is equal to the __________.
(A) Number of protons. (B) Number of electrons.
(C) Both a and b. (D) Sum of proton and electron.
97. Thomson showed that the stream of particles in cathode ray tube is made up of small
particles which are a component of the atom and is:
(A) Neutral. (B) Negatively charged.
(C) Positively charged. (D) Both A and B.
98. The number of radial nodes for 3p orbital is ______.
(A) 3 (B) 4 (C) 2 (D) 1
99. The radius of second Bohr's orbits for hydrogen atoms is:
−34
h = 6.6262 × 10 Js, me
−31
= 9.109 × 10 kg, echange

19C
= 1.6021 × 10

˚ ˚ ˚ ˚
(A) 1.65A (B) 4.76A (C) 0.529A (D) 2.12A

100. Who was the first scientist to propose a model for the structure of an atom?
(A) J.J. Thomson (B) Dalton
(C) Ernest Rutherford (D) E. Goldstein
----- -----

[9]