Berger Zinc Chromate Red Oxide Msds - T&T - 9259

BERGER PAINTS TRINIDAD LIMITED
P.O.BOX 546, 11 CONCESSIONS ROAD, SEA LOTS
PORT OF SPAIN, TRINIDAD W.I
PH# (868) 623-2231/5 FAX# (868) 627-2468/ 623-1682
1 – Product Identification
Product Name: Zinc Chromate Red Oxide

Product Description: Alkyd Based
Product Code: 3700
2 – Hazards Identification
HMIS Rating: Health = 1 Flammability = 2 Reactivity = 0
2.1 Skin Contact

Frequent or prolonged contact may irritate and cause dermatitis
Low order of toxicity
Skin contact may aggravate an existing dermatitis condition
2.2 Eye Contact

Slightly irritating but not injurious to eye tissue.
2.3 Inhalation
High vapour/aerosol concentrations (attainable at elevated temperatures well above ambient) are irritating to the eyes
and the respiratory tract and may cause headaches, dizziness, anaes central nervous system effect, including death.
thesia, drowsiness, unconsciousness and other
3 - Composition
Component CAS# Concerntration%

Alkyd Resin 29
Soybean Oil 61790-12-3 38
Phtalic Anhydride 85-44-9 19
Pentaerythritol 115-77-5 7
White Spirit 64742-88-7 25
Stoddard Solvent 8052-41-3 15

(White Spirits)
Pigment 55
Red Oxide 1309-37-1
Talc 14807-96-6
Zinc Chromate 37300-23-5
Calcium Carbonate 1317-65-3
4 – First Aid Measures
4.1 Skin Contact

Flush immediately with large amounts of water, use soap if available. If irritation persists seek medical attention.
Remove contaminated clothing and shoes and launder before reuse.
Material Safety Data Sheet
Zinc Chromate Red Oxide
4.2 Eye Contact

Flush eyes immediately with large quantities of water for 15 minutes and seek medical attention.
4.3 Inhalation
Move victim to a ventilated area immediately. If coughing, difficulty in breathing or any other respiratory symptoms
develop seek medical attention at once.
4.4 Ingestion
If ingested, do not induce vomiting. Seek medical attention immediately. Aspiration of material into the lungs can cause
chemical pneumonitis which can be fatal.
5 – Fire Fighting Measures
5.1 Stability
Stable product, will not autoignite under normal conditions.
Autoignition temperature of the white spirits is 504°F. Flammable limits: LEL=0.7; UEL=5.5 @ 77°F
5.2 Fire Fighting

Use water spray to cool fire exposed surfaces and to protect personnel. Isolate “fuel” supply from fire.
Use foam, dry chemical or water spray to extinguish fire. Avoid spraying water directly into storage containers due to
danger of boilover.
5.3 Advice to Fire Fighters

Incomplete combustion can yield carbon monoxide and toxic vapours. Wear self-contained breathing apparatus and
protective suit.
6 – Accidental Release Measures
6.1 Land Spill

Remove all sources of ignition. Ventilate area. Absorb spill with an absorbent material such as sawdust, to eliminate
focus of possible ignition, and place material into a closed container. Wear protective equipment during clean up. If
large spillage occurs, dike the area to prevent this material from entering water systems or sewers. Warn authorities
and residents of affected zones of fire and explosion danger. Prevent Contamination of soil, vegetation and subterranean
water.
6.2 Water Spill

Remove all sources of ignition. Warn occupants and shipping in surrounding and downwind areas of fir and explosion
hazard and request all to stay clear.
Remove from surface with suitable absorbents. If allowed by local and environmental authorities, sinking and/or
suitable dispersants may be used in non-confined waters.
Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.
7 – Handling and Storage
7.1 Storage Temperature

Ambient
7.2 Storage and Transport Pressure (mmHg)

Atmospheric
7.3 Storage and Handling

Keep container closed. Handle and open containers with care. Store in a cool, well ventilated place. Do not handle or
store near open flame, heat or other sources of ignition. Protect material from direct sunlight.
Avoid prolonged or repeated inhalation of heated vapours or spray mists. Avoid prolonged or repeated skin contact.
Excessive exposure to vapours or spray mists can result in headache, dizziness, uncoordination, nausea and loss of
consciousness.
8 – Exposure Controls/Personal Protection
Date of Issue: Sep 2015 Revision No: 1 Page 2 of 4

8.1 Exposure Controls
Use only with adequate ventilation. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment.
8.2 Personal Protection

Respiratory Protection: A canister type respirator must be worn to prevent inhalation of vapours and spray mists when
the TLV or PEL is exceeded
Ventilation: General ventilation is required during normal use. Local ventilation may be required during certain
operations to keep exposure levels of vapours and mists below the limits.
Protective Gloves/Clothing: Chemical resistant nitrile, neoprene or rubber gloves required. Wear protective clothing to
prevent skin contact.
Eye Protection: Where contact is likely, wear safety glasses with side shields
9 – Physical and Chemical Properties
Physical State Opaque Suspension

Colour Red
Specific Gravity 1.4 – 1.5 Kg/L
Solidification Point N/A
Boiling Point (Range) 157 - 201°C (315 – 394°F)
Freezing Point -76°C (-105°F)
Flash Point 43°C (109°F)
Ignition Temperature 260°C (500°F)
Water Solubility Negligible
Viscosity 70 – 75 KU (500 – 700cps)
Odour Organic Dissolvent
10 – Stability and Reactivity
10.1 Stability
Stable
10.2 Reactivity
No data available
10.3 Hazardous Polymerization

Will not occur
10.4 Incompatibility
Avoid contact with strong oxidizing agents
10.5 Hazardous Decomposition Products

Incomplete combustion can yield carbon monoxide and toxic vapours
11 – Toxicological Information
Acute Toxicity – Not Listed

Chronic Toxicity – Not Available
12 – Ecological Information
Ecotoxicity Data – Not Available
13 – Disposal Considerations
Date of Issue: Sep 2015 Revision No: 1 Page 3 of 4 Use non-leaking containers, seal tight and label properly. Dispose
of in accordance with applicable local, county, state and federal regulations.
14 – Transportation Information
14.1 Land Transport (ADR/RID)

ADR/RID Class: Flammable liquid
Danger Code (Kemler): 30
UN number: 1866
Packaging Group: lll
Hazard label: 3
14.2 Maritime Transport (IMDG)

IMDG class: 3
UN Number 1866
Hazard Label: 3
Packaging Label: lll
EMS number: F-E, S-E
Maritime Pollutant: No
14.3 Air Transport (ICAO-TI and IATA-DGR)

ICAO-TI/IATA-DGR: 3
UN Number: 1866
Hazard Label: 3
Packaging Group: lll
Proper Shipping Name: Alkyd-Based Enamel Paint
15 – Regulatory Information EU Regulations
15.1 Risk Phrases

R10 Flammable
R66 Repeated exposure may cause skin dryness and cracking
R67 Vapours may cause drowsiness and dizziness
15.2 Safety Phrases

S61 Avoid release to the environment. Refer to special instructions/Safety Data Sheet
16 – Other Information
S1/2 Keep locked up and out of reach of children.
S27/28 Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty
of water.
S29/35 Do not empty into drains. This material and its container must be disposed of in a safe way.
The information in this MSDS is given in good faith and to the best of our knowledge. It may not be valid for such material used in
Date of Issue: Sep 2015 Revision No: 1 Page 4 of 4
combinations with any other materials or in any process. No representation, warranty or guarantee is made due to its accuracy,

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BERGER PAINTS TRINIDAD LIMITED

P.O.BOX 546, 11 CONCESSIONS ROAD, SEA LOTS

PORT OF SPAIN, TRINIDAD W.I

PH# (868) 623-2231/5 FAX# (868) 627-2468/ 623-1682

Product Name: Zinc Chromate Red Oxide

HMIS Rating: Health = 1 Flammability = 2 Reactivity = 0

2.1 Skin Contact

2.2 Eye Contact

Component CAS# Concerntration%

Stoddard Solvent 8052-41-3 15

4 – First Aid Measures

4.1 Skin Contact

4.2 Eye Contact

5 – Fire Fighting Measures

5.2 Fire Fighting

5.3 Advice to Fire Fighters

6 – Accidental Release Measures

6.1 Land Spill

6.2 Water Spill

7 – Handling and Storage

7.1 Storage Temperature

7.2 Storage and Transport Pressure (mmHg)

7.3 Storage and Handling

8 – Exposure Controls/Personal Protection

Date of Issue: Sep 2015 Revision No: 1 Page 2 of 4

8.2 Personal Protection

9 – Physical and Chemical Properties

Physical State Opaque Suspension

10 – Stability and Reactivity

10.3 Hazardous Polymerization

10.5 Hazardous Decomposition Products

Acute Toxicity – Not Listed

Ecotoxicity Data – Not Available

14.1 Land Transport (ADR/RID)

14.2 Maritime Transport (IMDG)

14.3 Air Transport (ICAO-TI and IATA-DGR)

15 – Regulatory Information EU Regulations

15.1 Risk Phrases

15.2 Safety Phrases

S1/2 Keep locked up and out of reach of children.

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