Gas Oil EN590 MSDS

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SAFETY DATA SHEET

Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING


1.1 Product identifier
Product Name Gas Oils (petroleum), light vacuum
Product Description V3012-GASOIL EN590-Gas Oils (petroleum), light vacuum
Trade Name GASOIL EN590
Product code GASEN590, V3012
CAS No. 64741-58-8
EC No. 265-059-9
REACH Registration No. -

1.2 Relevant identified uses of the substance or mixture


and uses advised against
Identified Use(s) No. Exposure Scenario Page:
1 Distribution of Gas oils (petroleum), light vacuum 11
2 Formulation and (re)packing of Gas oils (petroleum), light 14
vacuum
3 Use as a fuel - Industrial 17
4 Use as a fuel - Professional 20
5 Use as a fuel - Consumer 23

Uses Advised Against Anything other than the above.

1.3 Details of the supplier of the safety data sheet


Company Identification Vitol SA
Place des Bergues 3
P.O. Box 2056
1211 Geneva 1
Switzerland

Telephone +31 10 498 7200


Fax +31 10 452 9545
E-Mail (competent person)

1.4 Emergency telephone number


Emergency Phone No. +44 (0) 1235 239 670, 24/7
Languages spoken All official European languages.

SECTION 2: HAZARDS IDENTIFICATION


2.1 Classification of the substance or mixture

2.1.1 Regulation (EC) No. 1272/2008 (CLP) Flam. Liq. 3; H226


Asp. Tox. 1; H304
Skin Irrit. 2; H315
Acute Tox. 4; H332
Carc. 2; H351
STOT RE 2; H373 (Thymus, Liver, Bone marrow)
Aquatic Chronic 2; H411

2.2 Label elements According to Regulation (EC) No. 1272/2008 (CLP)


Product Description V3012-GASOIL EN590-Gas Oils (petroleum), light vacuum

Hazard Pictogram(s)

Signal Word(s) Danger

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Hazard Statement(s) H226: Flammable liquid and vapour.


H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.
H373: May cause damage to organs through prolonged or repeated exposure:
Thymus, Liver, Bone marrow
H411: Toxic to aquatic life with long lasting effects.

Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P260: Do not breathe fume.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P331: Do NOT induce vomiting.
P273: Avoid release to the environment.

2.3 Other hazards May form explosive mixture with air. The vapour is heavier than air; beware of
pits and confined spaces. May cause irritation to eyes and air passages.
Product may release Hydrogen Sulphide: A specific assessment of inhalation
risks from the presence of hydrogen sulphide in tank headspaces, confined
spaces, product residue, tank waste and waste water, and unintentional
releases should be made to help determine controls appropriate to local
circumstances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.1 Substances
SUBSTANCE CAS No. EC No. %W/W
Gas oils (petroleum), light vacuum 64741-58-8 265-059-9 100

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures


Self-protection of the first aider Eliminate sources of ignition. If it is suspected that fumes are still present, the
responder should wear an appropriate mask or self-contained breathing
apparatus. Drench contaminated clothing with water before removing to avoid
risk of sparks from static electricity. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Avoid all contact. Do not ingest. If
swallowed then seek immediate medical assistance.
H2S Warning: Hydrogen sulphide (H2S) can accumulate in the headspace of storage tanks
and reach potentially hazardous concentrations.
If there is any suspicion of inhalation: A self contained breathing apparatus
should be worn. Remove to fresh air immediately.
Inhalation IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in
a position comfortable for breathing. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband. Call a POISON CENTER/doctor
if you feel unwell.
Skin Contact IF ON SKIN (or hair): Remove contaminated clothing immediately and wash
affected skin with plenty of water or soap and water. If irritation (redness, rash,
blistering) develops, get medical attention.
Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get
medical advice/attention.
Ingestion IF SWALLOWED: Do not induce vomiting because of risk of aspiration into the

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

lungs. If vomiting occurs spontaneously, keep head below hips to prevent


aspiration into the lungs. If unconscious, place in recovery position and get
medical attention immediately. Do not give anything by mouth to an unconscious
person. Get medical attention immediately. Do not wait for symptoms to appear.
4.2 Most important symptoms and effects, both acute Inhalation: Irritation of the respiratory tract.
and delayed Skin Contact: Causes skin irritation.
Ingestion: Aspiration into the lungs may cause chemical pneumonitis, which can
be fatal. Ingestion may cause irritation of the gastrointestinal tract. Nausea,
Vomiting and Diarrhoea.
4.3 Indication of any immediate medical attention and Treat symptomatically.
special treatment needed
Notes to a physician: IF INHALED: If unconscious, place in recovery position and get medical
attention immediately. Administer oxygen if available and artificial respiration if
necessary.
IF SWALLOWED: Do not induce vomiting because of risk of aspiration into the
lungs. If aspiration is suspected obtain immediate medical attention. If vomiting
occurs spontaneously, keep head below hips to prevent aspiration into the
lungs.

SECTION 5: FIREFIGHTING MEASURES


5.1 Extinguishing media
Suitable Extinguishing media Extinguish with sand or dry chemical. Foam, Carbon dioxide, Water fog or dry
powder
Unsuitable extinguishing media Do not use water jet. Direct water jet may spread the fire.
5.2 Special hazards arising from the substance or Flammable liquid and vapour. Will float and can be reignited on surface water.
mixture Decomposes in a fire giving off toxic fumes: A mixture of solid and liquid
particulates and gases including unidentified organic and inorganic compounds.
May form explosive mixture with air. Prevent liquid entering sewers, basements
and any watercourses. Vapours are heavier than air and may travel
considerable distances to a source of ignition and flashback. If sulphur
compounds are present in appreciable amounts, combustion products may
include also H2S and SOx (sulfur oxides) or sulfuric acid
5.3 Advice for fire-fighters Fight fire with normal precautions from a reasonable distance. Fire fighters
should wear complete protective clothing including self-contained breathing
apparatus. Keep containers cool by spraying with water if exposed to fire. Avoid
release to the environment. Dike fire control water for later disposal.

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and Caution - spillages may be slippery. Ensure operatives are trained to minimise
emergency procedures exposures. Ensure suitable personal protection during removal of spillages.
Eliminate sources of ignition. Shut off leaks if without risk. Keep away from heat,
hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid
all contact with substance. Ensure adequate ventilation. Do not breathe vapour.
Do not ingest. If swallowed then seek immediate medical assistance. All official
European languages. Do not use sparking tools. Use non-sparking ventilation
systems, approved explosion-proof equipment, and intrinsically safe electrical
systems.
H2S Warning: Product may release Hydrogen Sulphide. Exposure controls - These controls
may include: Segregation of areas, Access only to authorised persons, Permit to
work systems, Confined space working procedures, Area H2S alarms, Personal
H2S alarms, Personal escape sets, H2S awareness training. Please see section
8 for appropriate personal protection equipment
Small spillages: Wear flame-resistant antistatic protective clothing.
Large spillages: Evacuate the area and keep personnel upwind. Drench contaminated clothing
with water before removing to avoid risk of sparks from static electricity. Avoid
all contact. Wear chemical protection suit and breathing apparatus. See Also
Section: 8.
6.2 Environmental precautions Avoid release to the environment. Do not allow to enter drains, sewers or
watercourses. Spillages or uncontrolled discharges into watercourses must be
alerted to the Environment Agency or other appropriate regulatory body. If

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SAFETY DATA SHEET
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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

necessary: Dike area to contain the spill and prevent releases to sewers, drains,
or other waterways.
6.3 Methods and material for containment and cleaning Provided it is safe to do so, isolate the source of the leak. Use non-sparking
up equipment when picking up flammable spill. The vapour is heavier than air;
beware of pits and confined spaces. Ensure that the equipment is adequately
grounded. Allow small spillages to evaporate provided there is adequate
ventilation. Wear flame-resistant antistatic protective clothing. Wear chemical
protection suit and breathing apparatus.
Spillages onto land: In case of soil contamination, remove contaminated soil and treat in accordance
with local regulations. Adsorb spillages onto sand, earth or any suitable
adsorbent material. Transfer to a lidded container for disposal or recovery.
Dispose of this material and its container as hazardous waste.
Small spillages: Allow small spillages to evaporate provided there is adequate
ventilation. Wear flame-resistant antistatic protective clothing.
Large spillages: Cover spillage with foam to reduce evaporation. Do not use
water jet.
Spillages on water or at sea: Collect as much as possible in clean container for reuse or disposal.
Small spillages: Contain product with floating barriers or other equipment.
Collect spilled product by absorbing with specific floating absorbents.
Large spillages: Open waters should be contained with floating barriers or
other mechanical means and recovered, only if this is strictly necessary and if
fire/explosion risks can be adequately prevented. Otherwise control the
spreading of the spillage, and let the substance evaporate naturally.
6.4 Reference to other sections See Section: 8,13

SECTION 7: HANDLING AND STORAGE


7.1 Precautions for safe handling Keep away from sources of ignition - No smoking. Use only outdoors or in a
well-ventilated area. Prevent vapour build up by providing adequate ventilation
during and after use. May form explosive mixtures with air. Take action to
prevent static discharges. Use non-sparking tools. All parts of the plant and
equipment should be electrically bonded together and connected to earth.
Electrical continuity should be checked at regular intervals. Antistatic clothing
and footwear should be used. The vapour is heavier than air; beware of pits and
confined spaces. Avoid all contact with substance. Do not ingest. If swallowed
then seek immediate medical assistance. Do not breathe vapour. See Section:
8. Keep good industrial hygiene. Wash hands thoroughly after handling.
Contaminated clothing should be thoroughly cleaned.
H2S Warning: Product may release Hydrogen Sulphide: A specific assessment of inhalation
risks from the presence of hydrogen sulphide in tank headspaces, confined
spaces, product residue, tank waste and waste water, and unintentional
releases should be made to help determine controls appropriate to local
circumstances. These controls may include: Segregation of areas, Access only
to authorised persons, Permit to work systems, Confined space working
procedures, Area H2S alarms, Personal H2S alarms, Personal escape sets,
H2S awareness training.
7.2 Conditions for safe storage, including any Light hydrocarbon vapours can build up in the headspace of containers. These
incompatibilities can cause flammability / explosion hazards. Bund storage facilities to prevent
soil and water pollution in the event of spillage. Keep only in original packaging.
Keep containers properly sealed when not in use. Protect from sunlight.
Containers of this material may be hazardous when empty since they retain
product residue. Empty container may contain product residue which may result
in flammable or explosive vapours inside the container.
Storage temperature Stable at ambient temperatures.
Storage measures Suitable containers: Stainless steel, Mild steel
Do not store in: Synthetic materials
Incompatible materials Keep away from oxidising agents.
7.3 Specific end use(s) See Section: 1.2 and/or Exposure Scenario.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

8.1.1 Occupational Exposure Limits No Occupational Exposure Limit assigned. Users are advised to consider
national Occupational Exposure Limits or other equivalent values.

8.1.2 Biological limit value Not established.

8.1.3 PNECs and DNELs PNEC: Not established. Gas Oils (petroleum), light vacuum is a hydrocarbon
UVCB. The hydrocarbon block method is used in PETRORISK to calculate the
environmental toxicity (HC5) of each group of components in the substance.
These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this
product.
Gasoline Derived No Effect Level Oral Inhalation Dermal
Worker - Long Term - Systemic effects - 68.3 mg/m³ 2.9 mg/kg bw/day
Worker - Acute - Systemic effects - 4300 mg/m³ -
Consumer - Long Term - Systemic effects 1.3 mg/kg bw/day 20 mg/m³ 1.3 mg/kg bw/day
Consumer - Acute - Systemic effects - 2600 mg/m³ -

8.2 Exposure controls


8.2.1 Appropriate engineering controls Provide adequate ventilation, including appropriate local extraction if dusts,
fumes or vapours are likely to be evolved. Store in a cool/low-temperature, well-
ventilated (dry) place away from heat and ignition sources. Guarantee that the
eye flushing systems and safety showers are located close to the working place.

8.2.2 Individual protection measures, such as personal Protective clothing should be selected specifically for the working place,
protective equipment (PPE) depending on concentration and quantity of the hazardous substances handled.
The resistance of the protective clothing to chemicals should be ascertained with
the respective supplier.
Fuels are typically used, transferred and transported in closed systems. If
exposure is likely (i.e. during sampling) the following advice may be appropriate.
Keep good industrial hygiene. Always wash hands before smoking, eating and
drinking. Do not eat, drink or smoke at the work place.
Refer to annexes for exposure scenarios detailing use specific exposure
controls

Eye/ face protection Use eye protection according to EN 166, designed to protect against liquid
splashes.

Skin protection Hand protection: Wear impervious gloves (EN374). Gloves should be changed
regularly to avoid permeation problems. Breakthrough time of the glove material:
refer to the information provided by the gloves’ producer.
Recommended: Nitrile rubber.

Body protection: Wear anti-static clothing and shoes.


small scale: Wear suitable coveralls to prevent exposure to the skin.
large scale: Chemical protection suit.

Respiratory protection When the product is heated /In case of inadequate ventilation wear respiratory
protection. The use of a high efficiency filter (EN143) is recommended. Filter
type A1

Closed system(s): Not normally required.

Thermal hazards Not applicable.

8.2.3 Environmental Exposure Controls Avoid release to the environment.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical

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properties
Appearance Liquid. May be coloured.
Odour Diesel Odour
Odour threshold Not established.
pH Not established.
Melting point/freezing point - 40 °C - + 6 °C
Initial boiling point and boiling range 141 – 462 °C @ 101 kPa
Flash point > 55 °C @ 101 kPa
Evaporation rate Not established.
Flammability (solid, gas) Not applicable - Liquid
Upper/lower flammability or explosive limits Not established.
Vapour pressure 0.5 kPa @ 20°C
Vapour density Not established.
Relative density 0.90 – 0.92 g/cm³ @ 15 °C
Solubility(ies) Immiscible with water.
Partition coefficient: n-octanol/water Not established.
Auto-ignition temperature > 225 °C @ 101 kPa
Decomposition Temperature Not established.
Viscosity > 1.5 mm²/s @ 40 °C
Explosive properties Not explosive. (Vapour may create explosive atmosphere.)
Oxidising properties Not oxidising.

9.2 Other information None known.

SECTION 10: STABILITY AND REACTIVITY


10.1 Reactivity Stable under normal conditions. Reacts with - Strong oxidising agents
10.2 Chemical stability Stable under normal conditions. Hazardous polymerisation will not occur.
Product may release Hydrogen Sulphide.
10.3 Possibility of hazardous reactions Flammable liquid and vapour. May form explosive mixture with air. Vapours are
heavier than air and may travel considerable distances to a source of ignition
and flashback. Product may release Hydrogen Sulphide.
10.4 Conditions to avoid Elevated temperature. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Keep away from direct sunlight.
10.5 Incompatible materials Keep away from oxidising agents. Strong Acids and Alkalis.
10.6 Hazardous decomposition product(s) A mixture of solid and liquid particulates and gases including unidentified
organic and inorganic compounds. Decomposes in a fire giving off toxic fumes:
COx, H2S, SOx,

SECTION 11: TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects All test data taken from existing ECHA registrations for the substances
mentioned.
Acute toxicity - Ingestion Based upon the available data, the classification criteria are not met.
LD50 > 5000 mg/kg bw/day (rat) (OECD 401)
Acute toxicity - Inhalation Acute Tox. 4; Harmful if inhaled.
LC50 Vapour 4.11 mg/l Air (rat) (OECD 403)
Acute toxicity - Skin Contact Based upon the available data, the classification criteria are not met.
LD50 > 2000 mg/kg bw/day (rabbit) (OECD 434)
Skin corrosion/irritation Skin Irrit. 2; Causes skin irritation.
Irritating to skin. (rabbit) (OECD 404)
Serious eye damage/irritation Based upon the available data, the classification criteria are not met.
Not irritating to eyes (rabbit) (OECD 405)
Respiratory or skin sensitization Based upon the available data, the classification criteria are not met.
Sensitisation (guinea pig) - Negative (OECD 406)
Germ cell mutagenicity Based upon the available data, the classification criteria are not met.
In vitro: Negative (OECD 476)
In vivo: Negative (mouse) (OECD 474)
Carcinogenicity Carc. 2; Suspected of causing cancer.
ECHA Registration Endpoint summary: According to EU CLP Classification (EC
no. 1272/2008), VGO/Hydrocracked/Distillate fuels are classified for this
endpoint.

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Reproductive toxicity Based upon the available data, the classification criteria are not met.
STOT - single exposure Based upon the available data, the classification criteria are not met.
STOT - repeated exposure STOT RE 2; May cause damage to organs through prolonged or repeated
exposure: Thymus, Liver, Bone marrow
Oral: No data
Chronic - Systemic effects NOAEC 1710 mg/m³
No adverse effect observed (rat)
Inhalation:
Acute - Local effects NOAEC 880 mg/m³
Adverse effects observed (rat) (OECD 413)
Acute - Local effects NOAEL 30 mg/kg bw/day
Dermal:
Adverse effects observed (rat) (OECD 411)
Aspiration hazard Asp. Tox. 1; May be fatal if swallowed and enters airways.
Viscosity: > 1.5 mm²/s @ 40 °C
11.2 Other information None.

SECTION 12: ECOLOGICAL INFORMATION


12.1 Toxicity Aquatic Chronic 2; Toxic to aquatic life with long lasting effects.
Short Term (acute): LL50 (Fish) (96hr) 21 mg/l (OCED 203)
Long Term (Chronic): The aquatic toxicity was estimated using the PETROTOX computer model.
Estimated: NOEL (Fish) 0.083 mg/l
Estimated: NOEL (Invertebrates) 0.2 mg/l
12.2 Persistence and degradability Readily biodegradable. (OECD 301F)
12.3 Bioaccumulative potential Substance is complex UVCB. Indirect exposure and resulting risk estimates
predicted by PETRORISK are likely to be overestimated.
12.4 Mobility in soil The product is predicted to have low mobility in soil. Immiscible with water.
12.5 Results of PBT and vPvB assessment Substance is complex UVCB. This substance does not contain PBT constituents
included in the SVHC candidate list at concentrations above 0.1%.
12.6 Other adverse effects None known.

SECTION 13: DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods Dispose of this material and its container as hazardous waste. Do not empty into
drains, dispose of this material and its container at hazardous or special waste
collection point. Disposal should be in accordance with local, state or national
legislation. Containers of this material may be hazardous when empty since they
retain product residue. Containers must not be punctured or destroyed by
burning, even when empty. Allocation of a waste code number, according to the
European Waste Catalogue, should be carried out in agreement with the
regional waste disposal company. Waste code: 13 07 01

SECTION 14: TRANSPORT INFORMATION


ADR/RID IMDG/ADN
14.1 UN number UN 1202 UN 1202
14.2 Proper Shipping Name GAS OIL with flash-point as specified in EN GAS OIL with flash-point as specified in EN
590:2013 + A1:2017 590:2013 + A1:2017
14.3 Transport hazard class(es) 3 3 (N2, F)
14.4 Packing group III III
14.5 Environmental hazards MILIEUGEVAARLIJK / ENVIRONMENTALLY HAZARDOUS/ UMWELTGEFÄHREND
/DANGEREUX POUR/ L’ENVIRONNEMENT
14.6 Special precautions for user See Section: 2
14.7 Transport in bulk according to Annex This product is being carried under the scope of MARPOL Annex 1. Special Precautions: Refer
II of MARPOL 73/78 and the IBC Code to Chapter 7 'Handling and Storage' for special precautions which a user needs to be aware of,
or needs to comply with, in connection with transport.
14.8 Additional Information
Special provisions : 640L EmS: F-E, S-E, F-A, S-F
ADR HIN: 30 Limited Quantity: 5L
Tunnel Code: 3 (D/E)
Limited Quantity: 5L

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

SECTION 15: REGULATORY INFORMATION


15.1 Safety, health and environmental
regulations/legislation specific for the substance or
mixture
15.1.1 EU regulations
Seveso Upper Tier: 25000 tonnes
Lower Tier: 2500 tonnes
15.1.2 National regulations
Germany Wassergefährdungsklasse (Germany). WGK number: 3
15.2 Chemical Safety Assessment A REACH chemical safety assessment (CSA) has been carried out. Refer to
annexes for exposure scenarios detailing use specific exposure controls.

SECTION 16: OTHER INFORMATION


Sections indicated with the following have been revised
Header and Section 1.3

Updated version and date. New SDS Regulation 2015/830 format, all sections have been updated to include new information. Please review SDS
with care.

References:
Existing ECHA registration(s) for Gas Oils (petroleum), light vacuum (CAS No. 64741-58-8) and Chemical Safety Report.

This Safety Data Sheet was prepared in accordance with EC Regulation (EC) 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830.

LEGEND
LTEL Long Term Exposure Limit
STEL Short Term Exposure Limit
DNEL Derived No Effect Level
PNEC Predicted No Effect Concentration
PBT PBT: Persistent, Bioaccumulative and Toxic
vPvB very Persistent and very Bioaccumulative
OECD Organisation for Economic Cooperation and Development
ES Exposure Scenario
NOAEC no observed adverse effect concentration
NOAEL No Observed Adverse Effect Level

Training advice: Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether
a higher level of protection is required.

Disclaimers
Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users
to satisfy themselves of the suitability of the product for their own particular purpose. Vitol SA gives no warranty as to the fitness of the product for
any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by
law. Vitol SA accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved),
resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed.

Annex to the extended Safety Data Sheet (eSDS)


See below -

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Gas oils (petroleum), light vacuum


CAS Number 64741-58-8
EC Number 265-059-9

Summary of Parameters

Physical Parameters

Vapour pressure (Pa) 400 @ 40 °C

Partition Coefficient (log KOW) Individual components vary between 2.00 and 21.41
Individual components vary between 1.6E+03 mg L-1 and 3.2E-
Aqueous solubility (mg L-1)
19 mg L-1
Molecular weight Not applicable

Biodegradability Readily biodegradable.

Human health Parameter (DNELs)

Inhalation (mg/m³) 4300


Short term
Dermal (mg/kg bw/day) Not applicable
Worker
Inhalation (mg/m³) 68
Long Term
Dermal (mg/kg bw/day) 2.9

Inhalation (mg/m³) 20

Consumer Dermal (mg/kg bw/day) 1.3

Oral (mg/kg-1 bw/day-1) Not applicable

Environmental Parameter (PNECs)

Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

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ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Table of Contents

Number Title Page:


Exposure Scenario 1 Distribution of Gas oils (petroleum), light vacuum 11
Exposure Scenario 2 Formulation and (re)packing of Gas oils (petroleum), light vacuum 14
Exposure Scenario 3 Use as a fuel - Industrial 17
Exposure Scenario 4 Use as a fuel - Professional 20
Exposure Scenario 5 Use as a fuel - Consumer 23

Contributing Scenarios

Workers
PROC1 Use in closed process, no likelihood of exposure
PROC2 Use in closed, continuous process with occasional controlled exposure
Use in closed, continuous process with occasional controlled exposure.
PROC2 (Storage)
Bulk product storage.
PROC3 Use in closed, continuous process with occasional exposure
Use in closed, continuous process with occasional exposure.
PROC3 (Sampling)
Sample collection
Use in closed, continuous process with occasional exposure.
PROC3 (Fuel additive)
Use as a fuel additive
PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises
Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant
PROC5
contact).
Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant
PROC5 (Vapour)
contact). Substance in vapour phase.
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC8a (Manual)
Manual transfer/pouring from containers
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC8a (Maintenance)
Clean down and maintenance of vessels and containers.
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC8b (Bulk)
Bulk transfer in a closed system
PROC8b (Bulk closed Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
loading) Bulk closed loading and unloading (e.g. road/rail car bottom loading, marine vessel/barge loading)
PROC8b (Bulk open Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
loading) Bulk open loading (e.g. road/rail car top loading)
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC8b (Drum)
Drum or batch transfers.
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC8b (Refueling)
Refueling vehicles, light aircraft or marine craft
PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC15 Use as laboratory reagent.
PROC16 Using material as fuel sources, limited exposure to unburned product to be expected.
Environment
ERC1 Manufacture of substance
ERC2 Formulation of preparations
ERC3 Formulation in materials
ERC4 Industrial use of processing aids in processes and products, not becoming part of articles
ERC5 Industrial use resulting in inclusion into or onto a matrix
ERC6a Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b Industrial use of reactive processing aids
ERC6c Industrial use of monomers for manufacture of thermoplastics
ERC6d Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers
ERC7 Industrial use of substances in closed systems
ERC9a Wide dispersive indoor use of substances in closed systems
ERC9b Wide dispersive outdoor use of substances in closed systems
Consumer
PC13 Fuels
(Automotive refueling)
(Garden equipment refueling)
(Garden equipment use)

Page: 10 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Exposure Scenario 1 – Distribution of Gas oils (petroleum), light vacuum


1.0 Contributing Scenarios
Sector of uses SU SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
PROC1
PROC2
PROC2 (Storage)
PROC3
PROC3 (Sampling)
PROC4
Process category [PROC]
PROC8a (Maintenance)
PROC8b (Bulk)
PROC8b (Bulk closed loading)
PROC8b (Bulk open loading)
PROC9
PROC15
Chemical product category [PC] Not applicable
Article Categories [AC] Not applicable
ERC1
ERC2
ERC3
ERC4
ERC5
Environmental release categories [ERC]
ERC6a
ERC6b
ERC6c
ERC6d
ERC7
Specific Environmental Release Categories
ESVOC SpERC 1.1b v.1
SPERC

2.0 Operational conditions and risk management measures


2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid With potential for aerosol generation
Concentration of substance in product Covers concentrations up to 100%
Human factors not influenced by risk management
Potential exposure area Not defined
Frequency and duration of use
Exposure duration per day Covers daily exposures up to 8 hours (unless stated differently).
Frequency of use (days per year) 300
Other operational conditions affecting worker exposure
Location of use (Indoor/Outdoor) Not defined
Characteristics of the surroundings Not defined
Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene
is implemented. Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand
contact with substance likely. Clean up contamination/spills as soon as they occur. Wash off any skin contamination immediately. Provide basic
employee training to prevent/minimise exposures and to report any skin problems that may develop.
Technical conditions of use
PROC1, PROC2, PROC2 (Storage), PROC3, Handle substance within a closed system.
PROC8b (Bulk)
Organisational measures
Drain down and flush system prior to equipment break-in or maintenance. (Inhalation -
PROC8a (Maintenance)
efficiency of at least 80 %)
Risk management measures related to human health
Respiratory protection No special measures are required.
PROC4, PROC8b (Bulk),
PROC8b (Bulk closed loading), Wear suitable gloves tested to EN374. (Efficiency of at
PROC8b (Bulk open loading), least 80 %)
Hand and/or Skin protection PROC9
Wear chemically resistant gloves (tested to EN374) in
PROC8a (Maintenance) combination with 'basic' employee training. (Efficiency of
at least 90 %)
Eye Protection No special measures are required.
Other operational conditions affecting worker exposure
Wear suitable gloves tested to EN374.
Ensure material transfers are under containment or extract ventilation.

Page: 11 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Clear transfer lines prior to de-coupling.


Clear spills immediately.
Transfer via enclosed lines.
Avoid dip sampling. (PROC3 (Sampling))
Retain drain downs in sealed storage pending disposal or for subsequent recycle. Apply vessel entry procedures including use of forced supplied air.
Wear suitable coveralls to prevent exposure to the skin. (PROC8a (Maintenance))
Fill containers/cans at dedicated fill points supplied with local extract ventilation. (PROC9)
Handle in a fume cupboard. (PROC15)
2.2 Control of environmental exposure
Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tons/year): 9.6E+05
Fraction of Regional tonnage used locally: tons/year 2.0E-03
Annual site tonnage (tons/year): 1.9E+03
Average daily use (kg/day) 1.9E+04
Environment factors not influenced by risk management
Flow rate of receiving surface water (m³/d): Not defined (default = 18,000)
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Operational conditions
Emission days (days/year): 100
Release fraction to air from process (initial release prior to RMM): 1.0E-04
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-07
Release fraction to soil from process (initial release prior to RMM): 1.0E-05
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of (%): 90
Treat onsite wastewater (prior to receiving water discharge) to provide the
0
required removal efficiency of (%):
Treat soil emission to provide a typical removal efficiency of (%): Not defined
Common practices vary across sites thus conservative process release estimates used. If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Organisational measures to prevent/limit release from site
Prevent discharge of undissolved substance to or recover from onsite wastewater. Do not apply industrial sludge to natural soils. Sludge should be
incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Size of municipal sewage system/treatment plant (m³/d) 2000
Degradation effectiveness (%) 88.2
Conditions and measures related to external treatment of waste for disposal
This substance is consumed during use and no waste of the substance is generated.
Substance release quantities after risk management measures
Maximum allowable site tonnage (MSafe) based on release following total
9.6E+04
wastewater treatment removal (kg/d):

3. Exposure estimation and reference to its source


3.1 Human exposure prediction
Exposure assessment (method/calculation model) ECETOC TRA

Inhalation Dermal Combined


Process category inhalation Risk dermal Risk Risk
[PROC] exposure characterisation exposure characterisation characterisation
(mg/m³) ratio (RCR) (mg/kg bw/day) ratio (RCR) ratio (RCR)
PROC1 0.01 0.00 0.34 0.12 0.12
PROC2 1.0 0.01 1.37 0.47 0.49
PROC2
1.0 0.01 1.37 0.47 0.49
(Storage)
PROC3 3.0 0.04 0.34 0.12 0.16
PROC3
3.0 0.04 0.34 0.12 0.16
(Sampling)
PROC4 5.0 0.07 1.37 0.47 0.55
PROC8a
2.0 0.03 1.37 0.47 0.50
(Maintenance)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Bulk)
PROC8b
(Bulk closed 5.0 0.07 1.37 0.47 0.55
loading)

Page: 12 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

PROC8b
5.0 0.07 1.37 0.47 0.55
(Bulk open loading)
PROC9 5.0 0.07 1.37 0.47 0.55
PROC15 5.0 0.07 0.34 0.12 0.19

3.2 Environmental exposure prediction


Exposure assessment (method/calculation model) The Hydrocarbon Block Method has been used to calculate
environmental exposure with the Petrorisk model.
Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

Environmental marine freshwater marine


STP freshwater Soil
exposure water sediment sediment
Predicted
Environmental 1.2E-04
1.2E-05 mg/l 1.2E-06 mg/l 0.1 0.8 0.021
Exposure mg/l
(PEC)
Risk
characterisation 1.5E-03 5.1E-03 5.1E-04 2.8E-05 8.6E-03 6.3E-04
ratio (RCR)

Human exposure prediction:

Risk characterisation ratio


Route of Exposure Exposure (μg/kg-1 day-1)
(RCR)
Oral 21 0.016
Inhalation 0.027 4.8E-06

4.0 Evaluation guidance to downstream user


Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels.
For scaling see Available hazard data do not support the need for a DNEL to be established for other health effects.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
Worker ECETOC TRA
Exposure assessment
instrument/tool/method The Hydrocarbon Block Method has been used to calculate environmental
Environment
exposure with the Petrorisk model.

Page: 13 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Exposure Scenario 2 – Formulation and (re)packing of Gas oils (petroleum), light vacuum
1.0 Contributing Scenarios
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
Sector of uses SU
SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys)
PROC1
PROC2
PROC2 (Storage)
PROC3
PROC3 (Sampling)
PROC4
PROC5
Process category [PROC]
PROC5 (Vapour)
PROC8a (Manual)
PROC8a (Maintenance)
PROC8b (Drum)
PROC8b (Bulk)
PROC9
PROC14
Chemical product category [PC] Not applicable
Article Categories [AC] Not applicable
Environmental release categories [ERC] ERC2
Specific Environmental Release Categories
ESVOC SpERC 2.2.v1
SPERC

2.0 Operational conditions and risk management measures


2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid With potential for aerosol generation
Concentration of substance in product Covers concentrations up to 100%
Human factors not influenced by risk management
Potential exposure area Not defined
Frequency and duration of use
Exposure duration per day Covers daily exposures up to 8 hours (unless stated differently).
Frequency of use (days per year) 300
Other operational conditions affecting worker exposure
PROC3 Outdoor
Area of use
All other PROC’s Not defined (default = Indoor)
Characteristics of the surroundings Not defined
General measures applicable to all activities
Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene
is implemented. Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand
contact with substance likely. Clean up contamination/spills as soon as they occur. Wash off any skin contamination immediately. Provide basic
employee training to prevent/minimise exposures and to report any skin problems that may develop.
Technical conditions of use
PROC1, PROC2, PROC2 (Storage), PROC3, Handle substance within a closed system.
PROC8b (Bulk)
PROC5 (Vapour) Provide extract ventilation to points where emissions occur. (Efficiency of at least 90 %)
Organisational measures
PROC8a (Manual) Use drum pumps. (Efficiency of at least 80 %)
Drain down and flush system prior to equipment break-in or maintenance. Retain drain
PROC8a (Maintenance) downs in sealed storage pending disposal or for subsequent recycle. Clear spills
immediately. (Efficiency of at least 80 %)
Risk management measures related to human health
Respiratory protection No special measures are required.
PROC4, PROC8b (Bulk), Wear suitable gloves tested to EN374. (Efficiency of at
PROC8b (Drum), PROC9,
least 80 %)
PROC14
Hand and/or Skin protection Wear chemically resistant gloves (tested to EN374) in
PROC5, PROC8a (Manual)) combination with 'basic' employee training. (Efficiency of
at least 90 %)
Eye Protection No special measures are required.
Other operational conditions affecting worker exposure
Wear suitable gloves tested to EN374.
Ensure material transfers are under containment or extract ventilation.
Clear transfer lines prior to de-coupling.
Clear spills immediately.

Page: 14 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Transfer via enclosed lines.


Avoid dip sampling. (PROC3 (Sampling))
Retain drain downs in sealed storage pending disposal or for subsequent recycle. Apply vessel entry procedures including use of forced supplied air.
Wear suitable coveralls to prevent exposure to the skin. (PROC8a (Maintenance))
Fill containers/cans at dedicated fill points supplied with local extract ventilation. (PROC9)
Handle in a fume cupboard. (PROC15)
2.2 Control of environmental exposure
Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tons/year): 6.1E+05
Fraction of Regional tonnage used locally: (tons/year) 4.9E-02
Annual site tonnage (tons/year): 3.0E+04
Average daily use (kg/day): 1.0E+05
Environment factors not influenced by risk management
Flow rate of receiving surface water (m³/d): Not defined (default = 18,000)
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Operational conditions
Emission days (days/year): 300
Release fraction to air from process (initial release prior to RMM): 2.5E-03
Release fraction to wastewater from process (initial release prior to RMM): 2.9E-03
Release fraction to soil from process (initial release prior to RMM): 1.0E-04
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of (%): 0
Treat onsite wastewater (prior to receiving water discharge) to provide the
87.0
required removal efficiency of (%):
Treat soil emission to provide a typical removal efficiency of (%): 0
Common practices vary across sites thus conservative process release estimates used. If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Size of municipal sewage system/treatment plant (m³/d) 2000
Degradation effectiveness (%) 88.2
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.
Substance release quantities after risk management measures
Maximum allowable site tonnage (MSafe) based on release following total
1.1E+05
wastewater treatment removal (kg/d):

3. Exposure estimation and reference to its source


3.1 Human exposure prediction
Exposure assessment (method/calculation model) ECETOC TRA

Inhalation Dermal Combined


Process category inhalation Risk dermal Risk Risk
[PROC] exposure characterisation exposure characterisation characterisation
(mg/m³) ratio (RCR) (mg/kg bw/day) ratio (RCR) ratio (RCR)
PROC1 0.01 0.00 0.03 0.01 0.01
PROC2 1.0 0.01 1.37 0.47 0.49
PROC2
1.0 0.01 1.37 0.47 0.49
(Storage)
PROC3 3.0 0.04 0.34 0.12 0.16
PROC3
3.0 0.04 0.34 0.12
(Sampling)
PROC4 5.0 0.07 1.37 0.47 0.55
PROC5 5.0 0.07 1.37 0.47 0.55
PROC5
2.5 0.36 0.07 0.02 0.38
(Vapour)
PROC8a
2.0 0.03 1.37 0.47 0.50
(Manual)
PROC8a
2.0 0.03 1.37 0.47 0.50
(Maintenance)
PROC8b 5.0 0.07 1.37 0.47 0.55

Page: 15 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

(Bulk)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Drum)
PROC9 5.0 0.07 1.37 0.47 0.55
PROC14 5.0 0.07 0.69 0.24 0.31
PROC15 5.0 0.07 0.34 0.12 0.19

3.2 Environmental exposure prediction


Exposure assessment (method/calculation model) The Hydrocarbon Block Method has been used to calculate
environmental exposure with the Petrorisk model.
Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

Environmental marine freshwater marine


STP freshwater Soil
exposure water sediment sediment
Predicted
Environmental 1.8E-02 1.8E-04 0.11 mg/kg 0.058 mg/kg
1.8E-03 mg/L 1.4 mg/kg ww
Exposure mg/L mg/L ww ww
(PEC)
Risk
characterisation 0.23 0.78 0.078 4.4E-03 0.91 0.091
ratio (RCR)

Human exposure prediction:

Risk characterisation ratio


Route of Exposure Exposure (μg/kg-1 day-1)
(RCR)
Oral 44 0.034
Inhalation 16 0.003

4.0 Evaluation guidance to downstream user


Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels.
For scaling see Available hazard data do not support the need for a DNEL to be established for other health effects.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
Worker ECETOC TRA
Exposure assessment
instrument/tool/method The Hydrocarbon Block Method has been used to calculate environmental
Environment
exposure with the Petrorisk model.

Page: 16 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Exposure Scenario 3 – Use as a fuel - Industrial


1.0 Contributing Scenarios
Sector of uses SU SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
PROC1
PROC2
PROC2 (Storage)
PROC3 (Fuel additive)
Process category [PROC]
PROC8a (Maintenance)
PROC8b (Bulk)
PROC8b (Drum)
PROC16
Chemical product category [PC] Not applicable
Article Categories [AC] Not applicable
Environmental release categories [ERC] ERC7
Specific Environmental Release Categories
ESVOC SpERC 7.12a v.1
SPERC

2.0 Operational conditions and risk management measures


2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid With potential for aerosol generation
Concentration of substance in product Covers concentrations up to 100%
Human factors not influenced by risk management
Potential exposure area Not defined
Frequency and duration of use
Exposure duration per day Covers daily exposures up to 8 hours (unless stated differently).
Frequency of use (days per year) 300
Other operational conditions affecting worker exposure
PROC3 Outdoor
Area of use
All other PROC’s Not defined (default = Indoor)
Characteristics of the surroundings Not defined
General measures applicable to all activities
Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene
is implemented. Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand
contact with substance likely. Clean up contamination/spills as soon as they occur. Wash off any skin contamination immediately. Provide basic
employee training to prevent/minimise exposures and to report any skin problems that may develop.
Technical conditions of use
PROC2 (Storage) Handle substance within a closed system.
Organisational measures
Drain down and flush system prior to equipment break-in or maintenance. Retain drain
PROC8a (Maintenance) downs in sealed storage pending disposal or for subsequent recycle. Clear spills
immediately. (Efficiency of at least 80 %)
Risk management measures related to human health
Respiratory protection No special measures are required.
PROC8b (Bulk), PROC8b Wear suitable gloves tested to EN374. (Efficiency of at
(Drum) least 80 %)
Hand and/or Skin protection Wear chemically resistant gloves (tested to EN374) in
PROC8a (Maintenance) combination with 'basic' employee training. (Efficiency of
at least 90 %)
Eye Protection No special measures are required.
Other operational conditions affecting worker exposure
Retain drain downs in sealed storage pending disposal or for subsequent recycle. Wear suitable coveralls to prevent exposure to the skin.
2.2 Control of environmental exposure
Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tons/year): 5.0E+05
Fraction of Regional tonnage used locally: (tons/year) 1
Annual site tonnage (tons/year): 5.0E+05
Average daily use (kg/day): 1.7E+06
Environment factors not influenced by risk management
Flow rate of receiving surface water (m³/d): Not defined (default = 18,000)
Local freshwater dilution factor: 10

Page: 17 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Local marine water dilution factor: 100


Operational conditions
Emission days (days/year): 300
Release fraction to air from process (initial release prior to RMM): 5.0E-03
Release fraction to wastewater from process (initial release prior to RMM): 1.8E-07
Release fraction to soil from process (initial release prior to RMM): 0
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of (%): 95.0
Treat onsite wastewater (prior to receiving water discharge) to provide the
87.0
required removal efficiency of (%):
Treat soil emission to provide a typical removal efficiency of (%): 0
Common practices vary across sites thus conservative process release estimates used. If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Size of municipal sewage system/treatment plant (m³/d) 2000
Degradation effectiveness (%) 88.2
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.
Substance release quantities after risk management measures
Maximum allowable site tonnage (MSafe) based on release following total
1.8E+06
wastewater treatment removal (kg/d):

3. Exposure estimation and reference to its source


3.1 Human exposure prediction
Exposure assessment (method/calculation model) ECETOC TRA

Inhalation Dermal Combined


Process category inhalation Risk dermal Risk Risk
[PROC] exposure characterisation exposure characterisation characterisation
(mg/m³) ratio (RCR) (mg/kg bw/day) ratio (RCR) ratio (RCR)
PROC1 1.0 0.01 1.37 0.47 0.49
PROC2 1.0 0.01 1.37 0.47 0.49
PROC2
1.0 0.01 0.14 0.05 0.06
(Storage)
PROC3 1.0 0.01 0.34 0.12 0.13
PROC8a
1.0 0.01 1.37 0.47 0.49
(Maintenance)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Bulk)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Drum)
PROC16 1.0 0.1 0.03 0.01 0.02

3.2 Environmental exposure prediction


Exposure assessment (method/calculation model) The Hydrocarbon Block Method has been used to calculate
environmental exposure with the Petrorisk model.
Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

Environmental marine freshwater marine


STP freshwater Soil
exposure water sediment sediment
Predicted
Environmental 1.8E-02 1.8E-04 0.11 mg/kg 0.058 mg/kg
1.8E-03 mg/L 1.4 mg/kg ww
Exposure mg/L mg/L ww ww
(PEC)
Risk
characterisation 0.23 0.78 0.078 7.3E-03 0.91 0.091
ratio (RCR)

Human exposure prediction:

Risk characterisation ratio


Route of Exposure Exposure (μg/kg-1 day-1)
(RCR)

Page: 18 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Oral 72.6 5.6E-02


Inhalation 27 4.7E-03

4.0 Evaluation guidance to downstream user


Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels.
For scaling see Available hazard data do not support the need for a DNEL to be established for other health effects.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
Worker ECETOC TRA
Exposure assessment
instrument/tool/method The Hydrocarbon Block Method has been used to calculate environmental
Environment
exposure with the Petrorisk model.

Page: 19 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Exposure Scenario 4 – Use as a fuel - Professional


1.0 Contributing Scenarios
Sector of uses SU SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
PROC1
PROC2
PROC2 (Storage)
PROC3
PROC8a (Maintenance)
Process category [PROC]
PROC8a (Cleaning)
PROC8b (Bulk)
PROC8b (Drum)
PROC8b (Refueling)
PROC16
Chemical product category [PC] Not applicable
Article Categories [AC] Not applicable
ERC9a
Environmental release categories [ERC]
ERC9b
Specific Environmental Release Categories
ESVOC SpERC 9.12b v.1
SPERC

2.0 Operational conditions and risk management measures


2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid With potential for aerosol generation
Concentration of substance in product Covers concentrations up to 100%
Human factors not influenced by risk management
Potential exposure area Not defined
Frequency and duration of use
Exposure duration per day Covers daily exposures up to 8 hours (unless stated differently).
Frequency of use (days per year) 300
Other operational conditions affecting worker exposure
PROC16 Outdoor
Area of use
All other PROC’s Not defined (default = Indoor)
Characteristics of the surroundings Not defined
General measures applicable to all activities
Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard of occupational hygiene
is implemented. Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand
contact with substance likely. Clean up contamination/spills as soon as they occur. Wash off any skin contamination immediately. Provide basic
employee training to prevent/minimise exposures and to report any skin problems that may develop.
Technical conditions of use
PROC2 (Storage) Handle substance within a closed system.
If operational measures are not practicable, Provide a good standard of general ventilation
PROC16
(not less than 3 to 5 air changes per hour). (Efficiency of at least 30 %)
Organisational measures
PROC8a (Maintenance) Drain down and flush system prior to equipment break-in or maintenance.
PROC8b (Drum) Use drum pumps. (Efficiency of at least 80 %)
Risk management measures related to human health
Respiratory protection No special measures are required.
PROC8b (Bulk), PROC8b Wear suitable gloves tested to EN374. (Efficiency of at
(Drum), PROC8b (Refueling) least 80 %)
Hand and/or Skin protection Wear chemically resistant gloves (tested to EN374) in
PROC8a (Maintenance) combination with 'basic' employee training. (Efficiency of
at least 90 %)
Eye Protection No special measures are required.
Other operational conditions affecting worker exposure
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
Wear suitable coveralls to prevent exposure to the skin.
Avoid spillage when withdrawing pump.
Transfer via enclosed lines.
Avoid dip sampling.
2.2 Control of environmental exposure
Amounts used
Fraction of EU tonnage used in region: 0.1

Page: 20 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Regional use tonnage (tons/year): 3.4E+04


Fraction of Regional tonnage used locally: (tons/year) 5.0E-04
Annual site tonnage (tons/year): 17
Average daily use (kg/day): 47
Environment factors not influenced by risk management
Flow rate of receiving surface water (m³/d): Not defined (default = 18,000)
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Operational conditions
Emission days (days/year): 365
Release fraction to air from process (initial release prior to RMM): 1.0E-04
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-05
Release fraction to soil from process (initial release prior to RMM): 5.0E-05
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Treat air emission to provide a typical removal efficiency of (%): Not applicable
Treat onsite wastewater (prior to receiving water discharge) to provide the
0
required removal efficiency of (%):
Treat soil emission to provide a typical removal efficiency of (%): 0
Common practices vary across sites thus conservative process release estimates used. If discharging to domestic sewage treatment plant, no onsite
wastewater treatment required.
Organisational measures to prevent/limit release from site
Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Size of municipal sewage system/treatment plant (m³/d) 2000
Degradation effectiveness (%) 88.2
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.
Substance release quantities after risk management measures
Maximum allowable site tonnage (MSafe) based on release following total
2.9E+-03
wastewater treatment removal (kg/d):

3. Exposure estimation and reference to its source


3.1 Human exposure prediction
Exposure assessment (method/calculation model) ECETOC TRA

Inhalation Dermal Combined


Process category inhalation Risk dermal Risk Risk
[PROC] exposure characterisation exposure characterisation characterisation
(mg/m³) ratio (RCR) (mg/kg bw/day) ratio (RCR) ratio (RCR)
PROC1 1.0 0.01 1.37 0.47 0.49
PROC2 1.0 0.01 1.37 0.47 0.49
PROC2
0.01 0.00 0.34 0.12 0.12
(Storage)
PROC3 1.0 0.01 0.34 0.12 0.13
PROC8a
1.0 0.01 1.37 0.47 0.49
(Maintenance)
PROC8a
5.0 0.07 1.37 0.47 0.55
(Cleaning)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Bulk)
PROC8b
1.0 0.01 1.37 0.47 0.49
(Drum)
PROC8b
5.0 0.07 1.37 0.47 0.55
(Refueling)
PROC16 14.0 0.20 0.34 0.12 0.32

3.2 Environmental exposure prediction


Exposure assessment (method/calculation model) The Hydrocarbon Block Method has been used to calculate
environmental exposure with the Petrorisk model.

Page: 21 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

Environmental marine freshwater marine


STP freshwater Soil
exposure water sediment sediment
Predicted
Environmental 2.9E-05 2.9E-07 0.1 mg/kg 0.02 mg/kg
8.4E-06 mg/L 0.79 mg/kg ww
Exposure mg/L mg/L ww ww
(PEC)
Risk
characterisation 3.7E-04 4.2E-03 1.2E-04 8.0E-04 4.2E-03 1.8E-04
ratio (RCR)

Human exposure prediction:

Risk characterisation ratio


Route of Exposure Exposure (μg/kg-1 day-1)
(RCR)
Oral 21 0.016
Inhalation 0.023 4.0E-06

4.0 Evaluation guidance to downstream user


Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels.
For scaling see Available hazard data do not support the need for a DNEL to be established for other health effects.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
Worker ECETOC TRA
Exposure assessment
instrument/tool/method The Hydrocarbon Block Method has been used to calculate environmental
Environment
exposure with the Petrorisk model.

Page: 22 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Exposure Scenario 5 – Use as a fuel - Consumer


1.0 Contributing Scenarios
Sector of uses SU SU21 Consumer uses: Private households (= general public = consumers)
Process category [PROC] Not applicable
PC13
PC13 (Automotive refueling)
Chemical product category [PC]
PC13 (Garden equipment refueling)
PC13 (Garden equipment use)
Article Categories [AC] Not applicable
ERC9a
Environmental release categories [ERC]
ERC9b
Specific Environmental Release Categories
ESVOC SpERC 9.12c.v1
SPERC

2.0 Operational conditions and risk management measures


2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid
Concentration of substance in product Covers concentrations up to 100%
Human factors not influenced by risk management
210 cm²
Automotive refueling
(Palm of one hand)
Potential exposure area (Skin Contact) PC13
420 cm²
Garden equipment refueling
(Palm of both hands)
Frequency and duration of use
Automotive refueling 0.05
Exposure duration (hours/Event) PC13 Garden equipment use 2.00
Garden equipment refueling 0.03
52
Automotive refueling (Covers frequency up to:
weekly use)
Frequency of use (days per year) PC13
26
Garden equipment use;
(Covers frequency up to: once
Garden equipment refueling
in two weeks.)
Automotive refueling 37500
Amounts used (g/Event) PC13 Garden equipment use;
750
Garden equipment refueling
Other operational conditions affecting worker exposure
Area of use Not defined
Automotive refueling;
100 m³
Characteristics of the surroundings PC13 Garden equipment use
Garden equipment refueling 34 m³
Risk Management Measures
Respiratory protection No specific measures identified.
Hand and/or Skin protection No specific measures identified.
Eye Protection No specific measures identified.
2.2 Control of environmental exposure
Amounts used
Fraction of EU tonnage used in region: 0.1
Regional use tonnage (tons/year): 7.7E+04
Fraction of Regional tonnage used locally: (tons/year) 5.0E-04
Annual site tonnage (tons/year): 38
Average daily use (kg/day): 105
Environment factors not influenced by risk management
Flow rate of receiving surface water (m³/d): Not defined (default = 18,000)
Local freshwater dilution factor: 10
Local marine water dilution factor: 100
Operational conditions
Emission days (days/year): 365
Release fraction to air from process (initial release prior to RMM): 1.0E-04
Release fraction to wastewater from process (initial release prior to RMM): 1.0E-05
Release fraction to soil from process (initial release prior to RMM): 1.0E-05
Conditions and measures related to municipal sewage treatment plant

Page: 23 of 24
SAFETY DATA SHEET
Revision: 4th June 2019 Version: 4.2

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 2015/830 GASOIL EN590 V3012a

Size of municipal sewage system/treatment plant (m³/d) 2000


Degradation effectiveness (%) 88.2
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations.
Substance release quantities after risk management measures
Maximum allowable site tonnage (MSafe) based on release following total 6.5E+03
wastewater treatment removal (kg/d):

3. Exposure estimation and reference to its source


3.1 Human exposure prediction
Exposure assessment (method/calculation model) ECETOC TRA (benzene content)
Yearly Use (Chronic)

Inhalation Dermal Combined


Chemical product inhalation Risk dermal Risk Risk
category [PC] exposure characterisation exposure characterisation characterisation
(mg/m³) ratio (RCR) (mg/kg bw/day) ratio (RCR) ratio (RCR)
PC13
(Automotive 1.10 0.02 0.50 0.39 0.40
refueling)
PC13
(Garden equipment 0.51 0.01 0.00 0.00 0.01
use)
PC13
(Garden equipment 0.06 0.00 0.49 0.38 0.38
refueling)

3.2 Environmental exposure prediction


Exposure assessment (method/calculation model) The Hydrocarbon Block Method has been used to calculate
environmental exposure with the Petrorisk model.
Gas oils (petroleum), light vacuum is a hydrocarbon UVCB. The hydrocarbon block method is used in PETRORISK to calculate the environmental
toxicity (HC5) of each group of components in the substance. These are used to estimate the environmental risk for the substance. Therefore
individual environmental compartments PNECs are not available for this product.

Environmental marine freshwater marine


STP freshwater Soil
exposure water sediment sediment
Predicted
Environmental 6.5E-05 6.4E-07 0.1 mg/kg 0.02 mg/kg
6.4E-06 mg/L 0.8 mg/kg ww
Exposure mg/L mg/L ww ww
(PEC)
Risk
characterisation 8.3E-04 0.002 2.8E-04 1.7E-03 6.0E-03 3.6E-04
ratio (RCR)

Human exposure prediction:

Risk characterisation ratio


Route of Exposure Exposure (μg/kg-1 day-1)
(RCR)
Oral 21 1.6E-02
Inhalation 0.023 4.0E-06

4.0 Evaluation guidance to downstream user


Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels.
For scaling see Available hazard data do not support the need for a DNEL to be established for other health effects.
Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-
for-industries-libraries.html).
Consumer ECETOC TRA
Exposure assessment
instrument/tool/method The Hydrocarbon Block Method has been used to calculate environmental
Environment
exposure with the Petrorisk model.

Page: 24 of 24

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