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    Thermodynamics DTS - JEE Adv 1

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    Thermodynamics DTS - JEE Adv 1

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    Diwanshu Gupta
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    Thermodynamics DTS- JEE Adv 1

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    15 views2 pages

    Thermodynamics DTS - JEE Adv 1

    Uploaded by

    Diwanshu Gupta

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    © All Rights Reserved
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    of 2

    Date Planned : __ / __ / __ Daily Tutorial Sheet-1 Expected Duration : 90 Min

    Actual Date of Attempt : __ / __ / __ JEE Advanced (Archive) Exact Duration :_________

    1. First law of thermodynamics is not adequate in predicting the direction of a process. (1982)

    2. C p  C V for an ideal gas is ……. (1984)

    3. The total energy of one mole of an ideal monotomic gas at 27C is ……. cal. (1984)

    4. Heat capacity of a diatomic gas is higher than that of mono atomic gas. (1985)

    5. A system is said to be …….if it can neither exchange matter nor energy with the surroundings. (1993)

    6. Enthalpy is an ………….. property. (1997)

    7. When Fe(s) is dissolved in aqueous hydrochloric acid in a closed vessel, the work done is ………. (1997)

    8. A sample of argon gas at 1 atm pressure and 27°C expands reversibly and adiabatically from 1.25 dm 3 to

    2.50 dm 3 . Calculate the enthalpy change in this process. C v.m. for argon is 12.48 JK 1 mol 1. (2000)

    9. Assertion : The heat absorbed during the isothermal expansion of an ideal gas against vacuum is zero.
    Reason : The volume occupied by the molecules of an ideal gas is zero. (2000)
    (A) Statement-I is True, Statement-II is True and Statement-II is a correct explanation for
    Statement-I
    (B) Statement-I is True, Statement-II is True and Statement-II is NOT a correct explanation for
    Statement-I
    (C) Statement-I is True, Statement-II is False
    (D) Statement-I is False, Statement-II is True
    1
    10. Show that the reaction CO (g)  O 2 (g)  CO 2 (g ) at 300 K, is spontaneous and exothermic, when the
    2

    standard entropy change is  0.094 kJ mol 1 K 1. The standard Gibbs free energies of formation for CO2

    and CO are  394.4 and 137.2 kJ mol 1, respectively. (2000)

    11. When 1-pentyne (A) is treated with 4 N alcoholic KOH at 175°C, it is converted slowly into an
    equilibrium mixture of 1.3% 1-pentyne (A), 95.2% 2-pentyne (B) and 3.5% of 1, 2-pentadiene (C). The
    equilibrium was maintained at 175°C. Calculate G for the following equilibria : (2001)

     A
    B  G1  ?

     C
    B  G2  ?

    From the calculated value of G1 and G2 indicate the order of stability of (A), (B) and (C). Write a
    reasonable reaction mechanism showing all intermediates leading to (A), (B) and (C).

    12. One mole of a non-ideal gas undergoes a change of state (2.0 atm, 3.0 L, 95 K)  (4.0 atm, 5.0 L, 245 K)
    with a change in internal energy, U  30.0 L atm. The change in enthalpy (H) of the process in L atm
    is: (2002)
    (A) 40.0 (B) 42.3
    (C) 44.0 (D) not defined, because pressure is not constant

    VMC | Thermodynamics 66 DTS-1 | JEE Advanced (Archive)


    13. Two moles of a perfect gas undergo the following processes : (2002)
    (a) a reversible isobaric expansion from (1.0 atm, 20.0 L) to (1.0 atm, 40.0 L)
    (b) a reversible isochoric change of state from (1.0 atm, 40.0 L) to (0.5 atm, 40.0 L)
    (c) a reversible isothermal compression from (0.5 atm 40.0 L) to (1.0 atm, 20.0 L)
    (i) Sketch with labels each of the processes on the same p  V diagram.
    (ii) Calculate the total work (W) and the total heat change (Q) involved in the above
    processes.
    (iii) What will be the values of U, H and S for the overall process?

    14. C v value of He is always 3R/2 but C v value of H2 is 3R/2 at low temperature and 5R/2 at moderate

    temperature and more than 5R/2 at higher temperature. Explain in two or three lines. (2003)

    15. The enthalpy of vapourization of a liquid is 30 kJ mol 1 and entropy of vapourization is 75 J mol 1 K 1.

    The boiling point of the liquid at 1 atm is : (2004)


    (A) 250 K (B) 400 K (C) 450 K (D) 600 K

    VMC | Thermodynamics 67 DTS-1 | JEE Advanced (Archive)

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