Chapter 16
Chapter 16
Chapter 16
16.1 Introduction
Earlier chapters discussed various coatings and their methods of curing. This chapter deals
with the unique problems coating inspectors need to understand. Each cure type has unique
inspection concerns inspectors need to understand to know what to look for and how and
when to test the coating. If the cure type is not on the product data sheet, inspectors should
contact the coating manufacturers’ technical service department.
cured coatings. There are a few single-package materials in this group, such as alkyds and
moisture cures, however most polymerization-cured coatings come in two or more contain-
ers that cannot be mixed until just prior to use. These two facts are also the leading cause of
failure for polymerization-cured coatings.
16.4.1.1 Alkyds
Alkyds absorb oxygen from the surrounding atmosphere and uses the 02 molecule to react
with the alkyd molecule in a process called oxidation.
• Delamination from previous coat – caused from exceeding the overcoat widow, coat-
ing on a dirty surface, or applying over amine blush (,)
• Chalking – caused by UV (sunlight) exposure or other radiation
Figure 16.6 Amine Blush Figure 16.7 Amine blush in removal process
temperatures during cure at least every 4 hours. Some situations may require using a data
logger to track temperatures every few minutes during the cure cycle. Only count the hours
of cure when the surface is at the curing temperature. For most epoxy paints this tempera-
ture is above 4.5C (40F).
Because epoxies and epoxy blends work well on a broad range of applications, inspectors
need to know the exact surface preparation required for each project. When white metal is
specified, the inspector must ensure the requirement is met. Specification requirements vary
widely; sometimes a lower level of cleaning is required, or sometimes the specification
requires epoxy to be applied over damp, oil contaminated surfaces, or underwater.
All epoxy coatings can be applied too thinly, and many can be applied too thickly without
sagging. Inspectors must ensure the applicator uses a WFT gauge and follows the DFT read-
ing standard specified, as well as check DFT in hard to reach areas.
When using epoxies, each case is different, so the inspector’s most difficult task is ensuring
the specified epoxy is used and applied following all the required steps and conditions for
the material and the project.
different batches of material, or from using two or more application techniques in adjoining
areas. Changes in appearances are also seen if the DFT is uneven across the surface.
Blushing. This can be caused by moisture on the surface during the cure.
Failure to cure. This can happen if thinner added during application contains any moisture.
Please note that bulk thinners purchased at low cost may contain some level of water.
16.4.2.7 Siloxanes
These can come as single-package or two-component materials and are normally blended
with other resins such as acrylic, epoxy or polyurethane.
16.6 Details
The specification called for:
• Abrasive blast in accordance with NACE 3/SSPC SP10 Near White Blasting Cleaning
• Application of a water-borne acrylic primer at 75 to 125 µm (3 to 5 mils)
• Application of a water-borne acrylic intermediate coat at 100 to 150 µm (4 to 6 mils)
• Application of a water-borne acrylic finish coat at 50 to 75 µm (2 to 3 mils)
No inspection requirements were included in the specification except the statement that the
coating manufacturers recommends procedures be followed and that the contractor follow
industry standard inspection procedures.
Application and cure times between coats and final cure were the same for all three products
and were listed on their data sheets as:
Ambient
Condition Material Surface Humidity
Temperature
A note on the data sheets stated: “Dry Film Thickness 50-75 µm (2.0-3.0 mils); do not
exceed 75 µm (3.0 mils) in a single coat.”
Ambient temperature was 36°C (97°F) at 12 noon, still clear and sunny, RH 12%.
Ambient temperature was 43°C (110°F) at 4 p.m., clear and sunny.
Checked DFT of primer on roof and sides, took 25 or 30 readings on roof and another 10 or
15 on the sides, average was 100 µm (4 mils).
Primer on roof still a little soft, but not sticky. Gave approval to apply intermediate coat
based on the fact the primer had been on for two days and must be cured by now. Told
painters to wear booties so they would not get the primer dirty. They used the blast hoses to
blow down the roof before spraying on the next coat.
3 p.m. — Blasting on sides completed with all areas blown down, looks like a good near
white blast, only a very few spots of paint visible on the surface, really clean looking.
3:30 p.m. — Intermediate coat being applied to roof and portion of the sides. Primer being
applied to bare steel portion of the sides and the ladder.
5 p.m. — One of the painters had to come down off the roof since he burned his hand when
he touched the steel with his bare hand. It did not seem bad enough to send him to the hos-
pital so we had him soak it in cold water. I guess I should check that temperature up there,
but access is limited.
6 p.m. — today’s painting completed, looks good!
16.8.1 Questions
Your team represents the coating manufacturer. Answer the following questions:
1. List three things the inspector did wrong or neglected to do that should been have done.
2. List three things the owner’s specification writer could have done to improve the specifi-
cation.
3. What could the application contractor have done to improve the quality of the job?
4. Why does your team think the coating was still soft to the touch on most of the tank and
hard on the north-facing wall of the tank? What do you think can be done to fix it?
Study Guide
1. What are the two categories of curing and their definitions?
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6. When using a solvent-borne inorganic zinc, what would be one common reasons for a
failure to cure?
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