TH Soldering Defects
TH Soldering Defects
TABLE OF CONTENTS
(INTRODUCTION)
1. TROUBLE-SHOOTING OUTLINE
2. NON-WETTING & POOR WETTING
3. DEWETTING
4. SOLDER BALLS FROM WAVE-SOLDERING
5. COLD SOLDER JOINTS
6. INCOMPLETE FILLETS, UNFILLED HOLES & POOR SOLDER RISE
7. EXCESS SOLDER
8. ICICLING
9. BRIDGING
10. SOLDER & COMPONENT SHORT CIRCUITS
1
INTRODUCTION
Bad solder joints that require touch-up are a complex subject. First of all, we must judge it
is caused by poor design, bad soldering technique, bad soldering materials, improper pre-
treatment or unsuitable equipment. In addition, technical and inspection standards often
lead to unnecessary touch-up, but they are not included in our discussion since the
soldering operation and quality standards required by each electronic industry are
different,
A lot of solder joints that are considered bad, in fact, are actually good. However, there are
too many widely recognized inspection standards, which wrongly emphasize the beauty of
solder joints and ignore their functions, thus resulting in a huge and unreasonable touch-
up cost in this industry. Remember that touch-up does not always improve quality.
Here, we assume that there is no problem with PCB’s design, soldering materials selected
and pre-treatment before soldering and only discuss technical problems during the
soldering process.
Special problems with soldering and suggested solutions will be discussed in this course.
While many soldering problems may recur, problems faced by each electronics company
are still not exactly the same, so there will be no so-called Standard Answer. Here we
provide years of experience for customers’ reference, but users still have to treat individual
problems appropriately.
https://www.1clicksmt.com/product/lead- https://www.1clicksmt.com/product/Ant-
free-wave-solder-Machine-e-therm-rw- i1.html Offline selective soldering
series.html Dual wave solder machine machine Ant-i1
machine RW-450
2
1. Trouble-shouting outline
When problem occurs, the first thing that must be checked is the basic conditions of the
manufacturing process. We summarize them as the following three factors.
1. 1 Bad materials
These materials include such chemicals for soldering as flux, oil, tin, cleaning materials,
and PCB cladding materials such as anti-oxidation resin, temporary or permanent solder
mask and printing ink.
1.2 Bad solder joints
This involves all solder joints’ surfaces, such as components (including surface-bonded
parts / SMT parts), PCBs and electroplated PTHs, etc. must be taken into consideration.
1.3 Improper equipment
These include improper machines, equipment and maintenance and such external factors
as temperature, conveyor belt speeds and angles, as well as the depths of immersion and
so on which are variables directly related to machine. In addition, ventilation, air pressure,
voltage and more factors must be analyzed.
Every problem is different in its own way and should not be lumped under one head.
Following is a series of standard inspection steps which can help you find out the root
cause.
Step 1: When soldering, the smallest variable should be machines, so the first thing is to
check them. In order to realize the correctness of your check, independent electronic
instruments can be used as auxiliaries such as thermometers to detect temperatures and
multi-meters to calibrate the parameters accurately. Try to find out the most suitable
working conditions from the actual operations and records. Note: in any case, do not
depend on adjusting the equipment to overcome temporary soldering problems because
such adjustments may lead to bigger problems.
Step 2: Check all the soldering materials, such as flux’s specific gravity, transparency,
color, ion content and purity of tin-lead alloy. This is a continuous work accompanied by
both regular inspection and random sampling. All these are helpful to ensure their quality.
Step 3: Poor solder joints of PCBs and components are the biggest factor causing
soldering problems. To study the soldering problem of PCB, we must first fix or isolate the
other variables which may occur, and then discuss them one by one. For example, if
soldering defects occur on pins, other variables should be locked first, and only those pins
with soldering defects can be thoroughly compared and analyzed. Through this way of
tracking, the source of problem will be clear soon.
Step 4: Check the quality of the PTHs, punching, drilling and other defects. We may use
amplifying equipment to see if the PTH surface is smooth, clean or has any other
impurities or breaks or the thickness of electroplated layer is standard or not. In the
process of tracing soldering problems, the principle and concept should be correct. In
addition, steps are very important. How to find out the problem effectively by comparison
and analysis is the biggest problem for electronic engineers.
3
2 NON-WETTING & POOR WETTING
If the solder joints are good or not depends on whether the parts to be soldered can get
well wetted, accordingly the quality of solder joint is determined by the quality of wetting.
Basically, solder can wet and weld copper pads or other metals, and the surfaces of these
metals should not be covered by oxide or other impurities (such as dust, organic
compounds, etc.). Bad wetting is often caused by the unclean surface of the parts to be
soldered.
Non-wetting and dewetting are different from each other because of their different forming
process, so they must be discussed separately. Non-wetting means that when soldering,
the solder cannot completely cover the surface of the part to be soldered and the surface
of the metal to be soldered is exposed, which is especially easy to happen on bare copper
board (Figure 2-1). The red bare copper as seen from the figure overspreads the whole
solder side, and its periphery is mainly formed by the cohesion of tin.
From another point of view, dewetting means that when soldering, tin has fully covered the
whole solder side, which means that the surface is well wetted (Figure 2-2). Now eutectic
reaction happens between the metal to be soldered and the tin-lead alloy. But, when the
surface soldered cools down, its wettability begins to decrease and tin’s cohesion begins
to increase. So, a part of liquid tin on the originally flat tin surface is pulled open because
of the unbalanced tension between them, and balls or beads are formed via solidification
in a dihedral-angle way. At this time, only a small amount of tin-lead alloy can truly achieve
the metal-metal combination with the solder side thickly. Those thin tin surfaces seem to
cover the whole bare copper surface from the viewpoint of naked eyes, but non-wetting
which cannot be seen by naked eyes is often detected under the high-energy microscope.
Section 3 will provide more detailed information about dewetting.
Cause of non-wetting
The defects mentioned in this section are the result of one or more of the following factors:
Both PCBs and components may be contaminated. Contaminants include oil, paint, wax,
grease, etc. These contaminants are collectively referred to as impurities (dirt) and can be
removed by appropriate cleaning methods.
★ Traditional vapor degreaser has successfully been widely used, but we must choose
electronic-cleaning solvents which will not harm PCBs to avoid harmful residues.
★ We may use a water-based cleaner, but must make sure that these impurities are
soluble in water.
4
★ Some external contamination is from solder mask on the PCB surface. If wrong stencil
printing program is used or printing ink is spilled when drying, it is very difficult to remove
the solder mask after drying. When such mask touches the solder side, it can only be
removed by friction or tool. This kind of mechanical force to remove the mask is widely
used, but also relatively easy to bury some tiny particles in the PCB surface. Further
explanations will be given below.
Foreign substances embedded on the surface of materials to be soldered may also affect
the wettability. On a soft metal surface, it is easy to insert hard objects into the metal
surface with a grindstone or grinder. These non-metallic materials are obviously not
soldered with tin-lead alloys and cannot be removed with flux. Brushes made from some
synthetic materials also face similar problems.
The best treatment for this case is the chemical etching of the entire surface to remove
nonmetallic impurities. These etching agents are very strong chemicals and must be
properly controlled. It is the best to ask the PCB supplier for detailed operation method.
Silicon contamination is caused by many reasons. Plastic bags use silicon as mold release
agent, so is considered to be a major contamination source. Recently, a lot of safe plastic
bags have improved this problem, but we still have to pay attention to their selection.
Another source is the coolant applied before soldering. Special attention should be paid to
the use of silicon compounds in the factory, although they are far away from the soldering
process. However, due to the infection caused by human hand, soldering process will be
covered by silicon compounds quickly.
So far, there is no way to remove silicone oil and the only way is to keep PCBs clean and
control it tightly as possible as you can.
The oxide film on the solder surface over PCBs cannot be completely removed by flux, so
is also one of the sources for poor wetting. As long as the metal surface is exposed to air,
the oxide film will form. However, proper and reasonable oxide film can be easily removed
by flux. However, PCB’s improper storage or manufacturing process and burn-in process
will cause serious oxidation, leaving the flux powerless.
5
PCBs can be sprayed or rolled with tin (pre-tin) first by strong flux, and then cleaned with
water or solvent. This means that active flux is used to remove severe oxidation film first
and then coated with tin to prevent oxidation.
Chemical solvent can be used for etching, which means that, strong-acid solution, after
appropriate dilution, is used to wipe the oxidized circuits. After appropriate cleaning, plug
in the components and solder them immediately. PCBs with the use of such solution on
their surface, if not soldered immediately, will show more serious oxidation. Soldered
PCBs should be listed for tracing.
Contaminated flux, low activity or wrong operation cannot remove the oxide film effectively,
so they should be included in the assessment.
Tin-lead alloy
★ Too short soldering time or too low preheating temperature may leave the flux not
enough time to remove the oxide film. If you can extend the soldering time and strengthen
the preheating effect, it is absolutely helpful to remove the oxide film.
Check composition of the tin-lead alloy in tin oven (see Table 2-3, 2-4 and 2-5). Establish
standard soldering flowcharts and operation instructions so that operators can follow the
rules and reduce the variables due to human error.
6
Copper Cu 0.050 Copper Cu 0.050
Iron Fe 0.020 Iron Fe 0.020
Stibium Sb 0.2-0.5 Stibium Sb 0.2-0.5
Zinc Zn 0.005 Zinc Zn 0.005
Total all others TAO 0.080 Total all others TAO 0.080
Table 2-5
3 DE-WETTING
De-wetting is similar to non-wetting (see Section 2), both of them are unacceptable defects
with regards to soldering quality. In this case, solder has already wetted surface of the
object to be soldered, but after a period of time, part of the solder can’t adhere to the
surface and accumulates in the state of liquid (Figure 2-2). Now, cohesion of the solder will
form these accumulated liquid solder into “small drops”, making the solder surface uneven.
When wetting, eutectic reaction may occur with some metals. For example, if copper, iron,
gold, silver, or other metals are soldered with tin-lead alloy, another layer of new alloy
(Intermetallic Compound Layer, please refer to the soldering principle) will appear in the
interface between metals and tin-lead alloy. The new alloy layer’s composition is different
from the original metal’s composition, also different from original tin-lead alloy’s
composition. The leveler and evener the new alloy is, the higher the soldering fastness is
and the better the wettability is.
There are a lot of reasons to cause de-wetting, mainly the soldering surface is
contaminated (oxidized) and solder cannot fully adhere for a uniform Intermetallic
compound.
PCBs’ de-wetting, excepting to the contaminated solder side of bare copper board, is
mainly from tin-plating process. The problem is not the surface of tin-plated layer, but the
interface between bare copper board and plated tin. Please see Figure 3-2 for this kind of
situation. The problem also happens with tin-plated board, because when soldering, tin’s
cohesion is responsible for pulling back evenly. If the solder side is contaminated and thus
cannot be wetted, the surface tension of the solder side will be uneven, some tin’s flow
force will be greater than its cohesion, thus tin falls off, causing uneven surface.
When de-wetting happens, re-soldering is not helpful, as most of the contaminated surface
has been buried by the tin and the flux cannot pre-clean it, so the wetting function cannot
be achieved.
The following suggestions can help solve the problem. Strip the solder off from the solder
side and even more clean the oxide film on the surface before re-soldering.
Do not damage bare copper or other materials of the PCBs if stripping off with chemical
solvent.
You may also use high-temperature air-knife to molt solder (that is, PCBs are dipped in
molten solder and taken out and then strong air knife is used to blow the solder flat), and
then flux with high activity is used for soldering.
If this problem occurs with pins, repeated solder immersion or soldering can be helpful.
7
4 SOLDER BALLS
Solder balls and solder webbing are formed in different places. Most of the solder balls
occur on the component side of PCBs (Figure 4-1), while solder webbings occur on solder
side. Because of the cohesive force of solder itself, the appearance of these solder
particles present spherical. They usually adhere to the surface of the PCBs as the flux
solidifies, and are sometimes buried on the surface of PCBs’ plastic such as solder mask
or printing ink, because these inks, when soldering, will have a softening process and are
easy to stick to the solder balls.
The reaction mechanism that pushes a solder ball out of the PCB surface is very similar to
the formation of blow holes (see Section 2 of Chapter 2), except that the time for gas to
form is different. In the case of solder ball, a large amount of gas in the hole is quickly
formed and eager to volatilize, but the molten solder on top of the hole has not yet
solidified, so the solder ball is easier to rush out from the top, but less likely to form blow
holes or empties from the bottom. On the contrary, in terms of blow holes, gas generation
in the hole is slower and less, when it wants to volatilize, the solder at top of the solder
hole has been solidified, so it can only rush out from the bottom of the molten solder, thus
forming empties. More details will be given in Section 3 of Chapter 2 in this course as to
how and from where gas is generated in the hole.
Most solder balls are formed because the un-dried flux volatilizes or the flux’s moisture
content is too high when PCBs are being soldered. When gas contacts the high-
temperature molten solder instantaneously, its volume expands, causing the outbreak of
solder, at the same time, the solder is ejected, thus forming solder ball.
In many formulations of flux, more or less water will be introduced, but this small amount of
water will not cause a solder ball. If a solder ball suddenly happens, it can be caused by
one of the followings:
Insufficient preheating of PCB which may result in undried flux on PCB surface.
Defective PTH.
Excessive dampness or moisture during soldering may result from the following reasons:
A fully-filled flux bucket (200 or 201), if exposed to rain, will collect moisture around the
opening. It will suck moisture into the bucket from the loose opening when the temperature
changes. So it is important to have a sheltered warehouse and check at all times if the
opening of the flux bucket is closed.
During foaming, air compressor will carry a large amount of water and oil into the foaming
tank, so it is necessary to install a water filter (or trap), maintain and check the air
compressor at any time.
8
Be aware of any wet parts or tools in the manufacturing process and avoid them as
possible as you can.
Working with an air knife, in addition to helping warm-up, will also prevent finger from
bringing moisture back into the foaming tank.
When solder ball occurs, the patching process is the same as the webbing’s, except that
the surface of the part is blocked by many other parts, making it more difficult to remove
the solder ball by brushing. Care must be taken to inspect the solder balls under the parts
as they are often hidden and difficult to detect (see Section 10).
Solder ball is a defect that can occur at any time in the soldering process, causing serious
damage to reliability. Prevention is the only reliable way to avoid it.
Cold solder joint is defined as the solder joint surface not being smooth which is like a
broken glass. Cold solder joint is formed by the mutual movement between parts and PCB
in the process of solder joint solidification (Fig. 5-1). This mutual movement affects the
crystallization process of tin-lead alloy and reduces the strength of the whole alloy. If cold
solder joint is serious, there may even be tiny cracks or fractures on the surface of solder
joints.
PCB has passed through the outlet of conveyer track but the solder is not dry yet.
After PCB is soldered, we can solve the problem of cold solder joints by keeping the
conveyer track stable and let tin-lead alloy get perfect crystallization in the process of the
solidification. If cold solder joint occurs, it can be repaired by touch up. If cold solder joint is
serious, we can consider a re-soldering.
The vibration of parts may affect the solidification of solder joints, resulting in uneven or
incomplete appearance of solder joints. Our quality control staff must establish a set of
appearance standards of solder joints, so that the soldering operators can have a basis for
judgment.
6 INCOMPLETE FILLETS
There are many names for incomplete fillets that circulate in the industry of electronics,
such as blow holes, pin holes, drop-outs, or empties. In the following course (Chapter 2),
we will discuss these defects separately and integrate our terms according to their different
characteristics. Therefore, incomplete fillets can be classified into Unfilled Holes or Poor
9
Solder Rise.
There is no solder coated around the single-layer board, double-layer board, multi-layer
board and solder joint for 3600. (Figure 6-1).
Solder is not wetted completely to the top of the hole wall. This occurs only on double-
layer or multiple-layer boards (PTH) (Fig. 6-2). When new PCB design is completed and is
soldered the first time, to track the problem will be very complex. If design is complete and
the production of PCBs and soldering process are very stable but these problems are
suddenly found, the followings should be checked and improved one by one. However,
before discussing the followings, the inspection of both machines and materials must be
completed first, for example, temperature, speed, flux, lead-tin alloy, etc. If the problem is
not caused by the machines and materials, inspection should be carried out according to
the followings.
Solder mask flows into the PTH or sticks to the copper pad surface (for single-layer
boards).
10
Cracks or residues exist over the PTH.
PTH is contaminated.
If these problems occur with a certain batch of parts or PCBs, you may check and
compare other batches of parts or PCBs to find out the difference, or check whether there
is a change in the manufacturing process of the upstream manufacturer.
If problems are repeated with certain parts, it may be that the original design did not
consider the heat balance problem. That is, the temperature distribution of PCB solder
joint is not balanced. From this point of view, it can be seen that the multiplayer board
needs special preheating treatment, especially heat should be transferred to the top of the
through-hole, because in the case of incomplete solder joints, the multilayer board will not
be acceptable.
As for the height of the solder level in a PTH, each factory has its own standard based on
the requirements of its products. In the case of double-layer boards, IPC specifies that
height of the solder level from top of the through-hole is allowed to reduce by 25% (based
on the thickness of PCB). But the PTH wall must be completely wetted even the height is
reduced by 25%. As to the multiple-layer boards, a lot of manufacturers require that PTH
must be filled completely.
7 Excess solder
Excess solder is defined as having too much solder around the solder joint as we are
unable to determine whether it is a standard solder joint (Fig. 7-1). Too much solder hides
the curvature of wetting between solder joint and PCB, and may cover part of the pins
where should be exposed, making it invisible to the naked eye. Excess solder doesn’t
make the solder stronger or more conductive, it just wastes solder.
Each electronics factory must have a set of instructions for its own product or soldering
process, which must specify the maximum amount of solder to be consumed per solder
joint. The surface, top and bottom of the solder joint must be well wetted in shape of a
cone with a standard curvature (solder strip).
11
If the excess solder is found, it must be removed. The most efficient method is to re-solder
the PCB, but the PCB must be allowed to sit for 4~6 hours, so that the strength of PCB’s
resin structure can restore. If soldering is performed twice too fast, it will cause heat
damage.
The occurrence of excess solder can affect the reliability of products seriously. It may
mask defects in solder and cause headaches in mechanical strength, electrical properties
or appearance. No soldering standard allows severe excess solder to occur.
8. ICICLING
The term “icicling” can describe the shape of solder joint very aptly (F ig. 8-1). The reason
for this is that when the molten solder touches the object to be soldered, it will cool down
rapidly due to a fast loss of heat and be drawn into a sharp shape like icicling before
reaching the wetting state. They often occur in wave soldering, dip soldering and touch up
processes. Places where icicling happens include solder joints, solder surfaces, pins, and
even solder-dipping equipment or tools.
8.1 Touch up
When soldering manually with a soldering iron, “small flag” may happen over solder joint
and tip of the soldering iron. This situation is due to uneven heat conduction which results
in sharp cooling of solder, meaning that soldering iron’s temperature is not enough.
The solution is not to always increase the temperature of the soldering iron. Instead, we
should use the same temperature, but an iron which can supply more heat. That means
we may use an iron with higher heat content and more stable temperature, or larger
contact area. The tip of the soldering iron should be kept clean. Proper solder stick and
correct touch-up technique are also helpful to solve the problem of icicling.
The causes of icicling with automatic soldering furnace are quite complicated. In addition
to heat conduction, other problems such as bad solder joints, design, machine and
equipment may also result in icicling. Let’s discuss them one by one.
A. Heat conduction
Uneven heat transfer may be caused by too large solder area on PCB surface or too
dense objects to be soldered due to local heat absorption. Heavier metal parts may absorb
more heat.
12
Flux with low activity may not wet parts enough.
Too large solder area on PCB surface may result in slow solidification and high fluidity of
molten solder.
The solder surface in a manual or automatic solder-feeding furnace has solder slag or
suspended matter.
Heat conduction and problems with machine and equipment can be adjusted by means of
detection. Design problems must be solved by improving the original design or overcome
by touch up. Bad solder joints must be resolved by other means (see Section 1).
9 BRIDGING
Bridging will cause PCB short circuit. The reason may not be only excess solder (Fig. 9-1).
However, the cause of short circuit is not simply the bridging. Problems may occur with the
metal wiring under the solder mask, or the parts themselves (To be mentioned in Section
10 of this chapter). A bridging is defined when a short circuit is caused due to the
connection between solder joints on PCB surface. The main cause of bridging is PCB
circuit design, soldering materials or machine and equipment.
The discharge of solder flow on solder surface of PCB is not considered (PCB design
criteria is not followed). So, it is easy to cause solder accumulation and form a bridging
when solder flows through PCB.
Molten solder flows before solder joints or other soldered wirings are dried after a PCB has
been soldered. So, solder touches adjacent solder joints or soldered wirings.
Pins are not bent regularly or are kept too close to each other.
13
There are solder, copper or other metal residues on PCBs or pins.
10.1 Short circuit occurs with wirings covered with solder mask
The main reason for this is that the PCB substrate wirings, when being tin-plated or tin-
sprayed, are plated too thickly. When tin-plated boards are soldered, some plated solder
will once again molten by 250℃ molten solder and reflow around, and mostly flow to the
bottom. When the plated solder is melting, high tension may appear with PCBs and solder
mask, leading to the flow of molten solder. This strong momentary push often puts the
solder into the adjacent metal wirings, thus causing short circuit. Following are some
solutions for your reference.
When designing PCB circuits, put the wirings as far away from each other as possible.
A. Design
The exposed wiring is too close to the top of the solder joint.
14
Metal parts or lead wires are too close to the exposed wirings.
B. Processing
If short circuit occurs in components themselves, it is very difficult to find out the cause.
Currently, only X-ray can be used to find it, but the speed is slow and cost is high, which is
not in line with economic benefits. When short circuit happens, parts are replaced or PCBs
are repaired for solution.
15