BS en 12513-2011
BS en 12513-2011
BS en 12513-2011
National foreword
This British Standard is the UK implementation of EN 12513:2011. It
supersedes BS EN 12513:2000, which is withdrawn.
The UK participation in its preparation was entrusted to Technical
Committee ISE/111, Steel Castings and Forgings.
A list of organizations represented on this committee can be
obtained on request to its secretary.
This publication does not purport to include all the necessary
provisions of a contract. Users are responsible for its correct
application.
© BSI 2011
ISBN 978 0 580 63855 8
ICS 77.080.10
Compliance with a British Standard cannot confer immunity from
legal obligations.
This British Standard was published under the authority of the
Standards Policy and Strategy Committee on 30 April 2011.
Amendments issued since publication
Date Text affected
BS EN 12513:2011
English Version
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
© 2011 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 12513:2011: E
worldwide for CEN national Members.
BS EN 12513:2011
EN 12513:2011 (E)
Contents Page
Foreword ..............................................................................................................................................................3
Introduction .........................................................................................................................................................4
1 Scope ......................................................................................................................................................5
2 Normative references ............................................................................................................................5
3 Terms and definitions ...........................................................................................................................5
4 Designation ............................................................................................................................................6
5 Order information ..................................................................................................................................6
6 Manufacture............................................................................................................................................6
6.1 General ....................................................................................................................................................6
6.2 Heat treatment ........................................................................................................................................6
7 Requirements .........................................................................................................................................7
7.1 Chemical composition ..........................................................................................................................7
7.2 Brinell hardness .....................................................................................................................................7
7.3 Microstructure ........................................................................................................................................7
8 Sampling .................................................................................................................................................7
8.1 Frequency of sampling for chemical analysis ....................................................................................7
8.2 Number and frequency of Brinell hardness tests ..............................................................................7
9 Test methods..........................................................................................................................................8
9.1 Chemical analysis ..................................................................................................................................8
9.2 Hardness test .........................................................................................................................................8
9.3 Microstructure examination ..................................................................................................................8
10 Retests ....................................................................................................................................................9
10.1 Need for retests......................................................................................................................................9
10.2 Test validity ............................................................................................................................................9
10.3 Nonconforming test results ..................................................................................................................9
10.4 Heat treatment of samples and castings .............................................................................................9
Annex A (informative) Heat treatment of abrasion resistant cast irons ................................................... 12
Annex B (informative) Conversion between Brinell, Vickers and Rockwell C hardness ........................ 15
Annex C (informative) Relationship between relevant wall thickness and chemical composition
for nickel-chromium cast irons ......................................................................................................... 16
Annex D (informative) Typical microstructures of abrasion resistant cast irons .................................... 17
Annex E (informative) Comparison of abrasion resistant cast iron material designations
according to EN 1560 and ISO/TR 15931 .......................................................................................... 18
Annex F (informative) Significant technical changes between this European Standard and its
previous edition .................................................................................................................................. 19
Bibliography ..................................................................................................................................................... 20
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BS EN 12513:2011
EN 12513:2011 (E)
Foreword
This document (EN 12513:2011) has been prepared by Technical Committee CEN/TC 190 “Foundry
technology”, the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by August 2011, and conflicting national standards shall be withdrawn at
the latest by August 2011.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
Within its programme of work, Technical Committee CEN/TC 190 requested CEN/TC 190/WG 8 "High alloyed
cast iron" to revise EN 12513:2000.
Annex F provides information about significant technical changes between this European standard and the
previous edition.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and United Kingdom.
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EN 12513:2011 (E)
Introduction
This European Standard deals with the classification of abrasion resistant white cast irons in accordance with
their chemical composition and hardness. Such cast irons are widely used in the mining, earth moving, milling
and manufacturing industries where high resistance to abrading minerals and other abrading solids is
required.
The abrasion resistance of these cast irons depends on them having the appropriate structure and hardness
for the application. These properties are obtained by careful control of the material composition and the
processing route.
In this edition of EN 12513, the designation by symbol is based on Brinell hardness instead of Vickers
hardness, because it corresponds better with the measurement method applied in practice.
In this European Standard a new designation system by number, as established in EN 1560, is given.
NOTE This designation system by number is based on the structure and rules of EN 10027-2 and so corresponds
with the European numbering system for steel and other materials.
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EN 12513:2011 (E)
1 Scope
This European Standard defines the grades of abrasion resistant white cast irons. It specifies the grades in
terms of:
chemical composition;
hardness.
The types of abrasion resistant white cast irons covered by this standard are:
4 % Ni 2 % Cr cast irons;
9 % Cr 5 % Ni cast irons;
11 % < Cr ≤ 14 %;
14 % < Cr ≤ 18 %;
18 % < Cr ≤ 23 %;
23 % < Cr ≤ 30 %.
This European Standard does not define the abrasion resistant grades of ausferritic spheroidal graphite cast
irons which are subject of EN 1564.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
EN ISO 6506-1, Metallic materials — Brinell hardness test — Part 1: Test method (ISO 6506-1:2005)
3.1
unalloyed or low alloy abrasion-resistant cast iron
cast iron having a structure which consists of eutectic iron carbides in a predominantly pearlitic matrix
3.2
nickel-chromium abrasion-resistant cast iron
cast iron having a structure consisting of either
— simple eutectic carbides M3C type (M = Fe, Cr) in a matrix which is predominantly martensitic, referred to
as 4 % Ni 2 % Cr cast irons,
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EN 12513:2011 (E)
or
— complex eutectic carbides (M7C3 and M3C) in a matrix which is predominantly martensitic, referred to as
9 % Cr 5 % Ni cast irons.
NOTE 1 Both of these materials can contain some bainite and retained austenite.
NOTE 2 All these grades referred to in this sub-clause are free of pearlite.
3.3
high chromium abrasion resistant cast iron
cast iron containing between 11 % and 30 % Cr having a structure consisting of complex carbides in a matrix
which, in the hardened condition, is predominantly martensitic but which can also contain some austenite or
other transformation products of austenite
3.4
relevant wall thickness
wall thickness representative for the casting, defined for the determination of the size of the cast samples to
which the mechanical properties apply
4 Designation
The material shall be designated either by symbol or by number, in accordance with the designations given in
Table 1 to Table 3.
NOTE Comparison of EN 12513 grade designations to the grades from the current ISO standard for abrasion
resistant cast iron (ISO 21988) is given in Annex E.
5 Order information
The following information shall be supplied by the purchaser:
c) any special requirements which have to be agreed upon between the manufacturer and the purchaser by
the time of the acceptance of the order (see EN 1559-1 and EN 1559-3).
6 Manufacture
6.1 General
The manufacturing methods for abrasion-resistant cast irons, unless otherwise specified by the purchaser,
shall be left to the discretion of the manufacturer.
The manufacturer shall ensure that the requirements of this European Standard are met for the material grade
specified in the order.
Unless otherwise specified by the purchaser castings can be supplied in one of the following conditions:
as-cast;
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EN 12513:2011 (E)
hardened;
soft annealed.
When it is required to machine castings produced in the high chromium cast iron grades, they can be ordered
in the soft annealed condition. When the purchaser specifies delivery in the soft annealed condition any
subsequent machining or heat treatment shall be the responsibility of the purchaser.
NOTE Annex A gives guidance on the types of heat treatment which can be used to obtain the required hardness,
structure and properties.
7 Requirements
The chemical composition of the grades of abrasion-resistant cast iron shall be in accordance with Tables 1, 2
or 3. Unless otherwise specified by the purchaser, the manufacturer shall choose the appropriate chemical
composition to obtain the required properties of the casting.
NOTE Unless otherwise specified, other elements may be present, at the discretion of the manufacturer.
The Brinell hardness of the grades of abrasion-resistant cast iron shall be in accordance with Tables 1, 2 or 3.
7.3 Microstructure
Microstructure examination, if required, shall be agreed by the time of acceptance of the order. Where a
microstructure examination is agreed, the location for sampling, the methods used to examine the
microstructure, and acceptance criteria shall be subject to that agreement. The microstructure examination
shall be performed in accordance with 9.3.
8 Sampling
Samples representative of the material shall be produced at a frequency in accordance with the process
quality assurance procedures used by the manufacturer or as agreed with the purchaser.
Samples for chemical analysis shall be cast in a manner which ensures that their representative chemical
composition can be determined.
Unless otherwise specified by the purchaser by the time of acceptance of the order, the number and
frequency of Brinell hardness tests shall be in accordance with the process quality assurance procedures
used by the manufacturer.
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EN 12513:2011 (E)
In the absence of a process quality assurance procedure or any other agreement between the manufacturer
and the purchaser, a minimum of one sample shall be produced to confirm the material grade, at a frequency
to be agreed between the manufacturer and the purchaser at the time of the acceptance of the order.
9 Test methods
The methods used to determine the chemical composition of the material shall be in accordance with
validated methods. Any requirement for traceability shall be agreed between the manufacturer and the
purchaser at the time of the acceptance of the order. The chemical analysis shall be carried out on a test
sample made from the same melt as the castings the sample represents.
NOTE Optical emission spectrometry and X-ray fluorescence techniques are acceptable methods of analysis.
9.2.1 Brinell hardness test shall be carried out in accordance with EN ISO 6506-1, preferably using the
3 000 kgf load. Other hardness testing methods and corresponding hardness values can be agreed between
the manufacturer and the purchaser.
NOTE Hardness determined by one test method is not necessarily comparable to hardness determined by other test
methods. Conversions between Brinell, Vickers and Rockwell C hardness considered to be applicable to abrasion
resistant cast irons are given in Annex B, for guidance only.
9.2.2 Each Brinell hardness test shall be carried out on a casting at locations agreed by the manufacturer
and purchaser, or on a test block cast-on to the casting itself.
Unless otherwise specified by the purchaser, the dimensions and location of the cast-on block shall be left to
the discretion of the manufacturer.
NOTE A cast-on test block can be used when the size of the casting or the number of castings to be tested makes
direct testing on the castings impracticable.
9.2.3 If the test is to be carried out on a cast-on block the latter shall not be removed until after any required
heat treatment has been carried out.
9.2.4 When castings are too large or too difficult to be tested in a conventional hardness testing machine or
when there is need for on-line inspection of a large number of castings, a portable hardness testing device
may be used. When using portable hardness testing devices, its accuracy shall be validated using a calibrated
test block. The use of such devices shall be agreed upon between the manufacturer and the purchaser at the
time of the acceptance of the order.
Microstructure examination shall be performed on a sample cut from a casting, or from a separately cast, side-
by-side cast or cast-on sample. The sample shall have comparable solidification and cooling conditions as the
critical sections of the casting.
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EN 12513:2011 (E)
10 Retests
Retests are permitted to be carried out if a test result does not meet the specified requirements for the
specified grade (see 10.3).
a) a faulty mounting of the test piece or defective operation of the test machine;
In the above cases, a new test piece shall be taken from the same cast sample or from a duplicate sample
cast at the same time to replace those invalid test results.
If any test gives results which do not conform to the specified requirements, for reasons other than those
given in 10.2, the manufacturer shall have the option to conduct retests. If the manufacturer conducts retests,
two retests shall be carried out for each failed test.
If both retests give results that meet the specified requirements, the material shall be deemed to conform to
this European standard.
If one or both retests give results that fail to meet the specified requirements, the material shall be deemed not
to conform to this European standard.
Unless otherwise specified, in the case of castings in the as-cast condition with properties not in conformance
with this European Standard, a heat treatment may be carried out.
In the case of castings which have undergone a heat treatment and for which the test results are not valid or
not satisfactory, the manufacturer shall be permitted to re-heat treat the castings and the representative
samples. In this event, the samples shall receive the same number of heat treatments as the castings.
If the results of the tests carried out on the re-heat treated samples are satisfactory, then the re-heat treated
castings shall be regarded as conforming to the specified requirements of this European Standard.
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EN 12513:2011 (E)
Table 1 — Brinell hardness and chemical composition of unalloyed or low alloy abrasion resistant
cast iron
Table 2 — Brinell hardness and chemical composition of nickel-chromium abrasion resistant cast
irons
NOTE 1 For guidance on the relationship between relevant wall thickness and composition, see Tables C.1 and C.2.
NOTE 2 Both toughness and resistance to repeated impact increase as the carbon content decreases. Resistance to
abrasion increases as the carbon content increases.
NOTE 3 For castings with alloy contents at the low end of the range and supplied in the as-cast condition or in the
case of castings with greater thicknesses, it can be difficult to obtain the minimum hardness. The requirements for such
castings should be agreed between the manufacturer and the purchaser.
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EN 12513:2011 (E)
Table 3 — Chemical composition and Brinell hardness of high chromium abrasion resistant cast irons
NOTE 1 In order to reach the required minimum hardness in the as cast condition the chemical composition for each material shall be adjusted depending on the casting
dimensions and the production method. The minimum hardness values can also be met by heat treatment.
NOTE 2 The material designation by symbol is in accordance with EN 1560 with additional information in brackets regarding their chemical composition. The material
designations by numbers are in accordance with EN 1560.
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EN 12513:2011 (E)
Annex A
(informative)
Should a heat treatment be required to improve machinability, this should be agreed between the
manufacturer and the purchaser at the time of acceptance of the order.
4 % Ni 2 % Cr cast iron castings are frequently supplied and used in the as-cast condition. For certain
applications, castings can benefit from a heat treatment at 250 °C to 300 °C for 8 h to 16 h followed by air or
furnace cooling. This treatment relieves residual casting stresses.
For improved resistance to repeated impact, to help the complete breakdown of as-cast austenite, castings
can be tempered at the higher temperature of 425 °C to 475 °C.
heat treatment at 425 °C to 475 °C for 4 h to 6 h followed by air or furnace cooling; and then
9 % Cr 5 % Ni cast iron castings can be heat treated in one of two ways depending on casting complexity.
a) For simple shapes, a single heat treatment is adequate, involving heat treatment at 800 °C to 850 °C for
6 h to 12 h followed by air or furnace cooling.
b) Where maximum resistance to repeated impact is required, castings can benefit from a heat treatment at
800 °C to 850 °C for 8 h to 16 h, followed by air or furnace cooling, followed by 250 °C to 300 °C for 8 h to
16 h followed by air or furnace cooling.
NOTE Air cooling from 850 °C to 800 °C may be undesirable for heavy sections of complex design as cracking may
occur.
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EN 12513:2011 (E)
A.3.1 General
High chromium cast iron castings can be supplied in either the as-cast or heat treated condition. An
appropriately balanced combination of chemical composition and heat treatment is necessary for satisfactory
results. Typical heat treatments are hardening, tempering and soft annealing.
NOTE A high risk of cracking exists during heat treatment of large castings, particularly with large changes in section
thickness. Heating up rates less than 50 °C/h may be necessary.
A.3.2 Hardening
Hardening involves slowly heating up the casting to a defined temperature range and holding for a time
appropriate to its thickness and chemical composition, followed by rapid cooling. Only simple shaped castings
can be oil quenched without the risk of cracking, so rapid cooling is most frequently carried out by air/gas
cooling. The air/gas cooling can be carried out by fan cooling, forced gas or atomised liquid spray techniques.
It can be necessary to cool complex shaped castings in still air. In such circumstances, it is important that the
material chemical composition makes provision for sufficient hardenability.
A.3.3 Tempering
If casting hardness below 380 HBW is required (e.g. to facilitate machining) soft annealing can be carried out.)
then slowly cooling down in the furnace to about 810 °C; and
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EN 12513:2011 (E)
NOTE Instead of slowly cooling the casting through the transition temperature are, a fixed holding temperature may
be used for an appropriate time interval.
A.3.5 Annealing
Casting in as-cast condition can be annealed in order to transform any retained austenite to martensite.
If the castings require reduced internal stresses a stress relieving treatment should be made.
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EN 12513:2011 (E)
Annex B
(informative)
Table B.1 shows approximate hardness conversions between Brinell, Vickers and Rockwell C according to the
cast iron table of EN ISO 18265.
Table B.1 — Approximate conversions between Brinell, Vickers and Rockwell C hardness for abrasion
resistant cast irons
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EN 12513:2011 (E)
Annex C
(informative)
Annex C gives the relationship between relevant wall thickness and chemical composition for nickel-chromium
cast irons.
Tables C.1 and C.2 show typical chemical compositions, which ensure the formation of a white cast iron and a
pearlite-free matrix structure in castings of various thickness.
Table C.1 — Relationship between relevant wall thickness and chemical composition for
nickel-chromium abrasion resistant cast irons (4 % Ni 2 % Cr cast irons)
Table C.2 — Relationship between relevant wall thickness and chemical composition for
nickel-chromium abrasion resistant cast irons (9 % Cr 5 % Ni cast irons)
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EN 12513:2011 (E)
Annex D
(informative)
a) Hypoeutectic, consisting of eutectic carbides in a matrix of primary austenitic dendrites and eutectic
austenite.
During hardening, the austenite phase transforms to predominantly martensite containing a fine
dispersion of secondary carbides. The structure may also contain retained austenite, and other
transformation products of austenite.
b) Hypereutectic, consisting of primary carbides and eutectic carbides in an eutectic austenite matrix.
During hardening, the austenite phase transforms to predominantly martensite containing a fine
dispersion of secondary carbides. The structure may also contain retained austenite, and other
transformation products of austenite.
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EN 12513:2011 (E)
Annex E
(informative)
This informative annex compares the material designation of the standardized grades based on the ISO and
EN designation systems.
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EN 12513:2011 (E)
Annex F
(informative)
This European Standard includes the following significant technical changes compared to the previous edition:
Clause/Paragraph/Table/Figure Change
Introduction The designation by symbol is based now on Brinell hardness instead of
Vickers hardness.
2 Normative references have been modified.
3.2 and 3.3 Have been modified.
3.4 Definition for "relevant wall thickness" added.
6.1 and 6.2 Have been modified.
7.1 and 7.2 Have been modified.
7.1, Table 1 Material grade EN-GJN-HB400 (5.5601) has been added
7.1, Table 2 Material grades EN-GJN-HB500 (5.5603) and EN-GJN-HB630 (5.5606)
have been added.
7.3 Requirements for "Microstructure" added.
9.1 and 9.2 Have been modified
9.3 "Microstructure examination" added.
10 Completely revised.
Annex A Modified and sub-clauses "A.3.5 Annealing" and "A.3.6 Stress relieving"
added
Annex B Values for Brinell and Rockwell hardness in Table B.1 modified.
Annexes D, E and F Added.
Bibliography Added
NOTE The technical changes referred include the significant technical changes from the EN revised but is
not a exhaustive list of all modifications from the previous version.
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EN 12513:2011 (E)
Bibliography
[2] EN 1559-3, Founding — Technical conditions of delivery — Part 3: Additional requirements for iron
castings
[3] EN 1560, Founding — Designation system for cast iron — Material symbols and material numbers
[6] EN ISO 6507-1, Metallic materials - Vickers hardness test — Part 1: Test method (ISO 6507-1:2005)
[7] EN ISO 18265, Metallic materials — Conversion of hardness values (ISO 18265:2003)
[8] EN ISO 6508-1, Metallic materials — Rockwell hardness test — Part 1: Test method (scales A, B, C,
D, E, F, G, H, K, N, T) (ISO 6508-1:2005)
[10] ISO/TR 15931, Designation system for cast irons and pig irons
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