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    Physics96 Quiz

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    Physics96 Quiz

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    physics96 Quiz

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    Physics96 Quiz

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    Practice Quiz |Physical Science:96|Class :12th

    12 PHYSICAL SCIENCES P2
    Questions and Answers (EC/SEPTEMBER 2022)

    QUESTION 5 (Start on a new page.)

    The reaction between sodium thiosulphate (Na2S2O3) and EXCESS hydrochloric


    acid (HCℓ) is used to investigate the effect of concentration and temperature on the
    rate of reaction.

    The balanced equation for this reaction is:

    Na2S2O3 (aq) + 2 HCℓ → 2 NaCℓ (aq) + S (s) + SO2 (g) + H2O (ℓ)

    An Erlenmeyer flask is placed on a white paper marked with a light cross on it. The
    time taken for the visibility of the cross (X) to disappear is measured. See the
    diagram below.

    Na2S2O3 solution
    with HCℓ

    White paper

    NOTE: The same volume of Na2S2O3 solution was used for all three
    reactions.

    The table below shows the reaction conditions.

    Exp Concentration Concentration Temperature Volume of


    of Na2S2O3 of HCℓ (°C) HCℓ
    (mol·dm-3) (cm3)

    1 0,05 2 25 25

    2 0,05 1 25 25

    3 0,05 2 40 25

    5.1 Define the term reaction rate. (2)

    5.2 Write down the name of the independent variable for the comparison of
    experiment 1 and 2. (1)

    5.3 How will the amount of sulphur (S) formed in experiment 1 compare to the
    amount of sulphur (S) produced in experiment 2 at the completion of the
    reaction?

    Choose from HIGHER THAN, LOWER THAN or EQUAL TO.

    Give a reason for the answer. (2)

    Copyright reserved Please turn over


    2
    (EC/SEPTEMBER 2022) PHYSICAL SCIENCES P2 13

    5.4 Experiments 1 and 3 are now compared.

    The Maxwell-Boltzmann energy distribution curves for Experiments 1 and 3


    are shown below.

    Number of particles
    T1

    T2

    Kinetic energy Ea

    5.4.1 Which experiment 1 or 3 is represented by curve T2? (1)

    5.4.2 Explain the answer to QUESTION 5.4.1 by referring to the collision


    theory. (3)

    5.4.3 Sketch the curve of T2 ONLY in the answer book and indicate the
    effect that a catalyst would have on Ea.

    Indicate the new activation energy as X on the graph. (2)

    5.5 0,7118 g of Na2S2O3 reacted completely with HCℓ in experiment 1 in 34 s.

    Calculate the rate at which HCℓ reacted in experiment 1 in mol·s-1. (5)

    The volume of HCℓ used in experiment 1 is now doubled. All other reaction
    conditions remain the same.

    5.6 How would the reaction rate be affected by the change in volume?

    Choose from INCREASES, DECREASES or REMAIN THE SAME. (1)


    [17]

    Copyright reserved Please turn over


    ANSWERS
    8 PHYSICAL SCIENCES
    Practice Quiz |Physical Science:96
    3 P2/FISIESE WETENSKAPPE V2 (EC/SEPTEMBER 2022)

    QUESTION/VRAAG 5

    5.1 Marking criteria/ Nasienkriteria


    If any of the underlined key words/phrases in the correct context are
    omitted: - 1 mark per word/phrase.
    Indien enige van die sleutelwoorde/frases in die korrekte konteks
    weggelaat word: - 1 punt per woord/frase

    ANY ONE
    • Change in concentration ✓of reactant / product per (unit) time.✓

    • Change in amount/number of moles/volume/mass of products or


    reactants per (unit) time.

    • Amount/number of moles/volume/mass of products formed/reactants


    used reactants per (unit) time.

    ENIGE EEN
    • Verandering in konsentrasie van reaktanse/produkte per (eenheid)
    tyd

    • Verandering in hoeveelheid/getal mol/volume/massa van reaktanse of


    produkte per (eenheid) tyd.

    • Hoeveelheid/getal mol/volume/massa van produkte gevorm/


    reaktanse gebruik per (eenheid) tyd

    OR/OF

    The rate of change in concentration / amount of moles / number of moles /


    volume / mass. (2 or 0).

    Die tempo van verandering in konsentrasie / hoeveelheid mol / getal


    mol/volume/massa (2 of 0) (2)

    5.2 Concentration / Konsentrasie (of/van HCℓ) ✓ (1)

    5.3 Equal to / Gelyk aan ✓

    The same amount of (the limiting reagent), Na2S2O3, is used. ✓


    Dieselfde hoeveelheid (van beperkde reagens) Na2S2O3 was gebruik. (2)

    5.4.1 Experiment 3 / Eksperiment 3 ✓ (1)

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    4
    (EC/SEPTEMBER 2022) PHYSICAL SCIENCES P2/FISIESE WETENSKAPPE V2 9

    5.4.2 For T2
    • Higher temperature increases kinetic energy of particles ✓
    • Greater number of particles have sufficient energy. ✓
    • More effective collision per unit time ✓

    Vir T2
    • Hoër temperatuur verhoog die kinetiese energie van die deeltjies
    • Groter aantal deeltjies het genoeg energie
    • Meer effektiewe botsings per eenheidstyd

    OR/OF

    For T1
    • Lower temperature decreases kinetic energy of particles
    • Fewer particles have sufficient energy.
    • Less effective collision per unit time

    Vir T1

    • Laer temperatuur verlaag die kinetiese energie van die deeltjies


    • Minder aantal deeltjies het genoeg energie
    • Minder effektiewe botsings per eenheidstyd (3)
    Number of particles/

    5.4.3 Marking criteria/Nasienkriteria


    • X < Ea
    Aantal deeltjies

    ✓✓

    X Ea
    Kinetic energy / Kinetiese energie (2)

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    5
    10 PHYSICAL SCIENCES P2/FISIESE WETENSKAPPE V2 (EC/SEPTEMBER 2022)

    5.5 Marking criteria

    • Formula n = m/M
    • Substitution into n = m/M
    • Using ratio HCℓ: Na2S2O3 2 : 1
    • Substitution into rate equation
    • Final answer

    Nasienkriteria

    • Formule n = m/M
    • Vervanging in n = m/M
    • Gebruik van verhouding HCℓ: Na2S2O3 2 : 1
    • Vervanging in tempo vergelyking
    • Finale antwoord

    m
    n= ✓
    M

    0,7118
    n= ✓
    158

    n (Na2S2O3) = 4,505 x 10-3 mol

    n (HCℓ) = 2 (4,505 x 10-3) ✓

    n (HCℓ) = 9,01 x 10-3 mol

    Δn Accept / Aanvaar
    rate/ tempo = -
    Δt
    Δn
    0 - 9,01 x 10-3 rate/ tempo =
    rate/ tempo = - ✓ Δt
    34
    - 9,01 x 10-3
    rate/ tempo = 2,65 x 10-4 (mol·s-1) ✓ rate/tempo = 34
    ✓

    rate / tempo = - 2,65 x 10-4


    (mol·s-1) ✓ (5)

    5.6 REMAINS THE SAME / BLY DIESELFDE ✓ (1)


    [17]

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