J Matpr 2021 04 599
J Matpr 2021 04 599
J Matpr 2021 04 599
a r t i c l e i n f o a b s t r a c t
Article history: This study is confined to polymerization and the base chemical used is sodium hydroxide 14 molarity and
Received 17 April 2021 sodium silicate. High Performance Geopolymer Concrete (HPGC) was developed from Alkaline Activator
Accepted 23 April 2021 Solutions (AAS) under combination 60% Ground Granulated Blast Furnace Slag (GGBS) and 40% Fly ash
Available online xxxx
(FA) as binder materials produced high compressive strength of 76 N/mm2. Another mixing was made
with the same proportion of binder material and filler materials M sand was replaced by Copper Slag
Keywords: (CS). According to the test results the substitution of 50% copper slag with M sand produced at high com-
Fly ash
pressive strength of 80 N/mm2. Geopolymer Concrete was used for the casting of Wide Gauge Prestressed
GGBS
M sand
Concrete (PSC) sleepers as per Indian Railway standard specifications. And Pre-tensioning wires of stan-
Copper slag dard High Tensile Strength wire (HTS) were used with a pre-tensioning force of 50kN. Needed
Geopolymer concrete Compaction was carried out using table vibrators and steam curing was adopted based on the standard
Pre-tensioning pre-stressed production process of Indian Railways. Under power testing process the hardened concrete sleepers were
Railway sleepers. tested in the laboratory by stimulating the real load transfer condensing the field called Rail Seat Centre
Bottom (RSCB), Moment of Resistance (MR) and Moment of Failure (MF). As per the standard static flex-
ural test procedure, the number of sleeper on each side of the sleeper for a load up to 230 kN (MR) and
370 kN (MF) was determined. The result of the tests reveals that the Geopolymer concrete sleeper has a
high efficiency load and a high ultimate load.
Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the 12th National Confer-
ence on Recent Advancements in Biomedical Engineering.
1. Introduction for improving infrastructure viz [11,12]. Bridges across the river fly
over in cities bridges for transport facility, business malls exten-
In the Asian continent, Indian Railways is the largest network sion of city limits, consequently laying new roads, construction
and hence the consumption of concrete sleepers reaches to approx- of new houses for dwelling, new buildings for commercial purpose
imately 350 million [1,2]. In the ensuing years the demand for con- and above all constructing small, medium and large scale indus-
crete sleeper will so for the reason that consumption by private tries, construction of new buildings due to bifurcation of new dis-
corporate consumption up to 700 million sleepers [3,4]. The vital trict and construction of new medical and engineering colleges
need of concrete sleepers for Indian Railways is abundantly more [13,14].
comparing to the use of conventional Teak wood sleepers which For all construction of buildings concrete usage is a must and it
have now become obsolete and of a limited use [5,6]. A quality is cement widely used with sand. Concrete and cement with sand
wise concrete sleeper is found outstanding. Based on the growing are vital building material across the world, with the current con-
need under demand for concrete sleepers across India and global sumption of 1 m3 per person per year [15,16].
level, the study evaluates not only the quantity of demand but also Based on the need of concrete for construction, there are many
the surging scarcity of sand for manufacturing concrete sleepers concrete producing industries across India. In course of production
[7,8]. Here bellow the Indian Railway scenario highlighting the of Ordinary Portland Cement (OPC), one of the industrial wastes is
huge need for sleeper, preferably concrete sleepers [9,10]. CO2 and it constitutes 5% to 7% global anthropogenic emission
Further, based on globalization and modernization and creation [15,17]. While there is a threat and warning by scientist across
of smart cities, there has been a radical change across the country the world on global warming and climate changes an effect of
green gas development [17,18]. And concrete is found to be a seri-
E-mail address: ashok4094@gmail.com ous contributor to emission of green gas. In addition the cement
https://doi.org/10.1016/j.matpr.2021.04.599
2214-7853/Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the 12th National Conference on Recent Advancements in Biomedical Engineering.
Please cite this article as: Dr.S. Imran Khan, Mechanical performance of geopolymer pre-stressed railway sleepers, Materials Today: Proceedings, https://
doi.org/10.1016/j.matpr.2021.04.599
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
industries have been found the next largest producer of green- The following material were chosen and included for the purpose
house gases [19,20]. of maintaining the strength and durability of the best combination
Though there is a need for development of our country and also of 60% GGBS, 40% Fly ash, as binder materials and 40% as copper
industrial development in cement and concrete sector, there slag and 60% M sand composites as filler materials.
should not be any depletion of natural resources and environmen- Table 2 shows that strength limitations of various copper slag
tal hazard [21–30]. It is also observed that more number of mate- replacement ratios for M sand.
rials that are used for building construction are identified and
clustered under non-renewable resources. Meanwhile, towards
development of construction of buildings at urban and rural areas 3. Materials used in this research study
a very huge quantity of sand is required [5,31–39]. While there is a
huge demand for sand in the manufacturing process of concrete, 3.1. Cement
sand is not easily available across the country and there is a little
quantity of sand available everywhere and consequently there is As per specification of IS1269:1987, 53s Grade Ordinary Port-
an urgent need to find out alternate materials for natural aggre- land Cement (OPC) was used.
gates. Facing this critical situation it is found necessary that a
means of replacing river sand in concrete are recycled aggregate, 3.2. Fly ash
quarry dust, M sand and other industrial by product and they are
copper slag, steel slag etc [6,40–48]. In the recent days builders Class F fly ash was obtained from Hi-Tech Fly Ash (India) Tuti-
used industrial waste as building materials, an alternate to the corin for this study. As per specification of IS 3812 (Part 1); 2003
use of other natural resources for building. This alternate process and IS 3812 (Part 2); 2003the Fly ash classified in quality assurance
of using building materials is tested to be comparatively suitable was generated.
to construct building quite strong and that could stand sustainable
[28,49–56]. Besides improving quality of construction this alter-
nate process is found to be one of the sources to conserve environ- 3.3. Ground granulate blast furnace slag (GGBS)
ment from pollution. It is researched and found the quality of
strong buildings is possible when Fly ash is used. The Fly Ash is a The prime material GGBS was obtained, from JSW Cement,
waste that is procured in powder form coal burning residue in fur- (Name of place should be included) with all requirements of BS:
nace and locomotives. Another product that is added as waste 6699 with density 2.88 and the specific area 364 g/m2.
material is Blast furnace slag (GGBS) that is produced as a by-
product of iron and steel in the blast furnace while producing a vit-
3.4. Copper slog
reous granular product. It is then dried and crushed into a fine dust
[57–66]. One more waste product that is added is Copper slag and
For the purpose of test copper slog was procured from Hi-Tech
it is the byproduct of copper smelting and refining. It is submitted
Fly Ash (India) Private Ltd, Tuticorin. Samples for test were sup-
by National Council for cement and building materials, New Delhi,
plied with specification IS383;2016 and with density 3090, fine-
that Utilization of copper slag as performance improver in ordinary
ness module 2.9(Zone II) with density 2.32 g/cc.
Portland cement. The National council made an absolute research
and declared that sustainable development, by ensuring a harmo-
nious balance between the needs of people and the earth’s 3.5. Coarse andFine aggregate
resources, by mitigating green gas emissions, the conservation of
natural resources and the conversion of industrial waste into con- Locally available blue granite crushed stone aggregates up to
struction materials. Another material of combination is Geopoly- 20 mm and 10 mm in size was this study used, and characteriza-
mer that is compared to a new binder which found be a tion tests were conducted in accordance with SI 2386 (14).
ecological and cost-effective binding material, as it is produced
from industrial by product such as Fly ash and blast furnace gran-
ulated slag (GGBS) by substituting 100% cement into concrete. And 3.6. Alkaline liquids
It is practically analysed and reviewed that Geopolymer concrete is
a building construction material that can neither be ignored nor The following chemicals sodium hydroxide and sodium silicate
avoided. constitute alkaline solution. This solution should be used for prepa-
ration by mixing at least 24 h before test and use. The following
chemicals sodium hydroxide (14 molarity) and sodium silicate
2. Experimental programme maintaining the ratio of sodium silicate to sodium hydroxide to 2
were used for the study of polymerization.
Following the standard specifications of Indian Railway test
samples of pre stressed concrete (PSC) railway sleepers were
3.7. Super plasticizer
designed. Based on the specifications, 6 numbers of specimens
were prepared and of the test specimens, 3 were control concrete
A large-scale water-reducing super plasticizer (Ceraplast – 300)
and 3 were geopolymer concrete specimen. Here is the cross-
was added to the mix in order to improve the handling of fresh
section of railway sleeper each end is 154 mm in width at the
concrete.
top, 270 mm in width at the bottom and 235 mm in depth. The
length of specimens is 2750 mm. The exact cross-section details
of test specimens are illustrated in Fig. 9. The High Tensile Strength 3.8. High Tensile strength wire (HTS)
(HTS) strand 3 ply 3 mm with 18 no’s of strand each shall be ten-
sioned to the force of 27 kN. With regard to model, the conven- The sample wires were procured that comply with 3 mm 3-
tional concrete sample mixing model was designed in accordance layer designation in IS 6006 1983 for uncoated stress-free strands
with IS 10262-2009 using grade M60 concrete, whereas no code for prestressed concrete for the above testswith0.2% proof load
provision exists for the design of the geopolymer concrete mixture. 33000 N and Breaking load 39,000 N.
2
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
4. Methodology of preparation of geopolymer concrete sary. The liquid component of the mixture was subsequently added
to dry materials and continued for another four minutes.
4.1. Preparation of alkaline solutions
4.4. Casting and curing
The prime need in the process of preparation is alkali liquid and
for the purpose A mixture of sodium hydroxide solution and The samples were cast by compacting them properly and pour-
sodium silicate solution was used. The next process in this research ing them into three layers after mixing is complete. Concrete sam-
work was by mixing 14 molarity of sodium hydroxide the com- ples were placed in the steam curing chamber and maintained at
pressive strength of geopolymer concrete was investigated. The 70 degree centegradefor 24 hours.
molecular weight of Sodium Hydroxide is 40. To form one-litre
solution and to produce 14-molar solution, 560 g of sodium
5. Mechanical properties of geopolymer concrete
hydroxide flakes were weighed and dissolved in water. The volu-
metric flask has a capacity of 1 L and sodium hydroxide flakes were
Based on the findings of the test results, a high compressive
added to the water to prepare a 1-litre solution. This solution was
force of 80.33 N/mm2 was delivered by the combination of 60%
prepared during the 24 h preceding the casting.
GGBS and 40% fly ash and the substitution of 50% copper slag by
M sand. Following this, high-strength geopolymer concrete (HSGC)
4.2. Mixing proportion was produced by the above mixing combination. Table 2 sets out
the mechanical properties of Geopolymer concrete. Table 3 and
The density of Geopolymer Concrete is assumed to be 2400 kg/ Table 4 give further details.
m3 since no provisions of the Geopolymer Concrete Mixture Design
Code exist. According to the density of the concrete the rest of the 6. Information about pre stressed railway concrete sleeper
calculations were carried out. The overall volume of the concrete specimen
was filled with fine (M sand) and coarse aggregate was 80%, The
proportion of weight of the alkalinity to fly ash and GGBS ratio In order to determine the dimensions, details and mixing pro-
was kept at 0.30. The ratio of sodium silicate to sodium hydroxide portions of the concrete design an investigation was conducted
to be maintained to 2. The Super Plasticizer weighed 2% of the according to Indian Railway Standard specifications. The rail
weight of GGBS and fly ash by 86 liters for moderate Appetent tem- cross-member was designed for an axle load of 22.5 Ton. The rail
perature and 103 liters per cubic meter high appetent temperature. seat load designed for the rail sleeper is 15 Ton and the specified
In the process of preparation of Geopolymer concrete, the conven- cracking load for the rail sleeper is 230kN at the bottom of the rail
tional method for the production of standard concrete was seat and 60 kN for center top location. In total, six number of slee-
adopted. Table 1 and Fig. 1 show the combined classification chart per samples were cast and section details for each sample are illus-
for course aggregates, sand and copper slog. trated in Fig. 2.The HTS 3-ply strand 3 mm 18 not each strand must
be a tensile strength of 27 kN. The concrete is M60 grade concrete.
Table 4
Mechanical characteristics of traditional concrete.
S.No. Cube ID Average Compressive Strength (N/mm2) Average Flexural Strength (N/mm2) Average Split Tensile Strength (N/mm2)
1 CC 65.13 6.1 5.28
4
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
Fig. 5. Safety guard plate fitted with barrel, wedges and sleeper ready for casting. Fig. 8. Precast sleeper specimens.
5
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
6.3. Test procedure the moment of failure (MF) on each side. The final failure was not
expected to occur until 370kN applied. In order to determine the
For facilitating the marking of cracks samples of pre-stressed ultimate failure load this method adopted. Figs. 11–13 show the
ties were whitewashed. On a 50-ton capacity loading frame testing different tests on concrete sleeper. Table 5 illustrated comparison
was conducted. Before the process of resting the sleeper on the of test result of conventional pre-stressed rail sleeper and geopoly-
reaction blocks, the sleeper was centered using a plumb line so that mer pre-stressed concrete rail sleepers.
it is exactly below the center of the loading head. 280 mm was
labeled from the center of the loading point on both sides and on 7. Discussion
both rail seats. The support was manufactured half-round with a
diameter of 38 mm and was welded to MS plates with a thickness As per technical specifications that are used in the rail system.
of 25 mm. Additional 6 mm rubber cushions were placed between Three samples of prefabricated pre-stressed concrete sleeper were
the supports and the sleeper. The supports were located inward
280 mm from the center of the loading points, as Illustrated in
Fig. 9. The load applied to the center line of the rail seat through
the pressure distribution of the MS plate with a plate size
145 25 mm and a 6 mm rubber plate was placed between the
sleeper and the loading head. The bottom of one rail seat was
tested at the same time to ensure that the other end was not held
up. Initially, two point loads were applied to the both rail seats,
loaded at a rate of 30–40 kN per minute until the specified load
of 60 kN, which was held at this level for three minutes for crack
observation. Under this process, a crack is defined as a crack that
is barely visible to the naked eye and that is at least 15 mm long
from the tension edge of the sleeper. However, if the crack occurs
at a load lower than the specified load, its value must be recorded.
When two load points are applied to the sleeper, the load is spread
toward the center and upper surface of the sleeper. The above
mode of test device is called Sleeper Center Top (SCT).
In Fig. 10, the arrangement was explained as follow. The brack- Fig. 11. Static bending test on pre-Tensioned pre-cast conventional concrete
ets were placed outwards 280 mm from the center point of loading sleeper.
on each side and the single point load was applied to the left side of
the rail seat and also the sleeper design and the Moment of Resi-
dence. With regard to power load the load was applied at the rate
of 30 to 40 kN per minutes and the load was progressively
increased from the overly specified load of 230 kN. Further, it
was held for three minutes to observe cracks if occurred. This lay-
out test procedure was referred to as the Rail Seat Centre Bottom
(RSCB), which measures the Moment Resistance (MR) of the slee-
per. A similar procedure was applied to the other side of the rail
seat. The above procedure was repeated up to 370kN to determine
Fig. 12. Static bending test on pre-tensioners precast Geopolymer concrete sleeper.
Fig. 10. Test arrangement of rail seat centre bottom. Fig. 13. Ultimate failure of re-tensioned precast Geopolymer concrete sleeper.
6
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
Table 5
Comparison of test result of conventional pre-stressed rail sleeper and geopolymer pre-stressed concrete rail sleeper.
Sleepers ID Cube Strength in N/mm2 Sleeper Centre Top (SCT) Rail Centre Bottom Rail Centre Bottom
Load Applied in kN (RSCB) Load at First (RSCB) Load at Failure
Crack in kN in kN
Top Bottom I II I II
PSC 1 72.27 75 – 256 261 380 385
PSC 2 70.62 74 265 271 385 390
PSC 3 67.38 68 266 270 377 380
PGFGC 1 77.33 76 267 277 380 387
PGFGC 2 78.67 74 281 265 390 395
PGFGC 3 75.56 75 268 269 395 392
Fig. 14. Flexural behavior of conventional concrete sleeper. Fig. 17. Flexural behavior of Geopolymer concrete sleeper.
7
Dr.S. Imran Khan Materials Today: Proceedings xxx (xxxx) xxx
1. The ratio between span and total depth is about 0.4 and the The authors declare that they have no known competing finan-
failure of the specimen beam/ties is primarily controlled by cial interests or personal relationships that could have appeared
the shear strength of sample. to influence the work reported in this paper.
2. While testing made with an identical strength of conven-
tional concrete and geopolymer concrete, the performance Acknowledgements
of the sleepers under the first cracking load and the ultimate
load are practically identical. The authors also would like to acknowledge Dr. S. Nagan and Dr.
3. In the process of investigating the initial cracking load and Brindha D., Department of Civil Engineering, Thiagarajar College of
ultimate cracking load in control concrete and geopolymer Engineering, Madurai, Tamilnadu. India for their assistance in con-
sample, the geopolymer has the higher initial and ultimate ducting some of the tests in this study.
loading related to the control concrete sample.
4. In course of testing the convention concrete specimen and
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