ATOMIC STRUCTURE

Matching answer type questions:

1.

COLUMN – I COLUMN – II
(A) Energy of mass less particle (P)
(Q
(B) Work Function Four
)
(C) (R)
Number of lobes in a 3d orbital
(D) (S) Connected to orbital motion
other than
Energy and angular
(E) (T)
momentum
Minimum energy needed to
Mutual repulsion of atomic
(F) (U) liberate an electron from the
electrons
surface of metal
Mass times velocity times
(G) (V) Quanta
radius
The frequency distribution of
(W
(H) the radiation emitted from a
)
black body
Probability of finding an
(I) (X) Hund rule
electron in a given region
(J) Black – body radiation (Y) Temperature - dependent
2. If in Bohr’s model, for unielectronic atom following symbols are used
Radius of orbit with atomic number Z;
Potential energy of ; Kinetic energy of ;
Velocity of ; Time period of revolution.
Column-I Column-II
a) p) 1 : 8
b) q) -8 : 1
c) r) 1 : 9
d) s) 8 : 1
t) 2 : 1
3. Column-I Column-II
a) Lyman series p) Visible region
b) Humphery series q) Ultraviolet region
c) Paschen series r) Infrared region
d) Balmer series s) Far infrared region
t) Cosmic region

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4. Given in hydrogenic atom rn, Vn, E, Kn stand for radius, potential energy,
total energy and kinetic energy in nth orbit.
Column I Column II
(A (P) 1
) =?
(B (Q –2
)  ,y=? )
(C rn  E x , x = ? (R –1
) )
(D Ratio of angular momentum of (S 2
) electron in second to first orbit )
5. Match the following
Column I Column II
(A Potential energy of an electron (P) 13.6 eV
) in the 1 st
excited state of
hydrogen atom
(B Kinetic energy of an electron in (Q -13.6 eV
) the ground state of He +
)
(C Total energy of an electron in (R - 6.8 eV
) the third energy level of Li 2+
)
(D Ionization energy of hydrogen (S 54.4 eV
) atom )
6. Match the statements in column I with corresponding transition in column II
having the same value for the same property. Each item in column I has
only one correct answer in column II.
= wavelength; = energy change; = velocity

Column I Column II
(A) of H (P) 4→2 of H
(B) of He+ (Q 4→2 of He+
)
(C) of H (R 4→ 8 of Be3+
)
(D) of H (S 9→3 of Li2+
)
7. Column-I Column-II
a) If P .E = - 13.6 ev p) 21
b) I.E of electron from 2 shell of Na
nd +
q) 10
c) Number of spectral lines when electron
jumps from 7th to 3rd shell r) Total energy = - 6.8 ev
d) Number of spectral lines when electron
comes from 7th shell to 1st shell s) 411.4ev
t) All series of lines
8. Matching
Column I Column II

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 A) B2 P) Paramagnetic
B) N2 Q) diamagnetic
C) R) Mixing of s & p orbital
D) O2 S) Bond order
9. 1. Match the following.
Column – I Column – II
(A Magnetic moment of an (p principal Q.N.
) atom or ion )
(B Radial node (q Azimthal Q.N.
) )
(C Hund’s rule (r) Magnetic Q.N.
)
(D Orbital angular momentum (s) spin Q.N.
) of electron

10. Column I Column II

(A H (p Radius of 2nd orbit =
) )
(B He+ (q Energy of 4th orbit =
) )
(C Be3+ (r) Radius of 3rd orbit = 0.53 ×
) 3Å
(D Li2+ (s velocity of electron in the 1st
) ) orbit = 2.18×108 cm/sec.
11.
Column II
Column I (electronic
(characteristics
transition)
of radiation)
(A) n1  in H-atom (p Visible region
)
(B) in He+ ion (q Energy numerically equal to
Rhcz2
(C) in He+ ion (r) Called ionization energy

(D) in H-atom (s Ultraviolet region

)
12. Match the following:
Column I contains the species and the figure shows the transition.
Column II contains the energy in(ev) of the species corresponding to that
change. Match Column-I with Column-II.

Column I Column II
p
A) 54.4
)

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 q
B) 30.6
)
C) r) 122.4

D
s) 13.6
)
13. Match the following columns
Column II
Column I
(A (p Aufbau principle
) ) violated

(B (q Hund’s rule
) ) violated

(C (r) Pauli’s rule

) violated

(D (s Aufbau, Hund’s,
) ) Pauli’s rules are
followed
14. AN ELECTRON IS MAKING 4 WAVES IN AN ORBIT OF H-ATOM. THEN MATCH
THE COLUMNS I & II.
Column I Column II
(A) Momentum of the electron is (p 0.85
. X is )
(B) Distance between the preceding (q 8.48
and succeeding orbits of the )
electron revolving orbit
(C) Separation energy in eV (r) 0.497

(D) Potential energy in eV (numerical (s 1.7

value) )

15. Match Column - I with Column - II Column - I

Column I Column II
( The d orbital (p)
A which has two
) angular nodes
( The d orbital with (q)
B two nodal
) surfaces formed
cones
( The orbital (r)

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 C without angular
) node
( The orbital with (s)
D three angular
) nodes
16. Match the following
,
,

Column I Column II
(A) (p)
(B) (q) 1
(C) (r) 2

(D) (s)

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ATOMIC STRUCTURE – KEY SHEET
Matching Answers
1 A–R 2 A–Q 3 A–Q 4 A–Q 5 A–R 6 A -Q
B–U B–S B–S B–P B–S B -P
C–P C–R C–R C–R C -Q C -S
D–Q D-P D-P D-S D-P D -R
E–S
F–X
G–T
H–Y
I–W
J-V
7 A-R 8 A-PR 9 A – QS 10 A-S 11 A-QRS 12 A-R
B-S B-QRS B – PQ B-P B-S B-P
C-Q C-P C-PQRS C-Q C-PQS C-S
D-PT D-PS D – RS D-R D-P D-Q
13. A-P 14 A-R 15 A-PQ 16 A-S
B-QR B-Q B-Q B-P
C-PR C-P C-S C-P
D-QR D-S D-R D-Q

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 ATOMIC STRUCTURE – SOLUTIONS
Matching solutions
1. Conceptual
2. Conceptual
3. Conceptual
4. Conceptual
5. Conceptual
6. Conceptual
7. Conceptual
8. Conceptual
9. Conceptual
10. (a)for H, radius of 2nd orbit = 0.53 ×

(b)for He+ energy of 2nd orbit =

(c)for Be2+, radius of 4th orbit =

also, energy of 4th orbit = –13.6×

(d)For velocity of electron in 3rd orbit = 2.18 × 108 ×

11. Energy = – 13.6 eV = –21.78 × 10–19g ionisation energy is the energy
required to take an electron from ground state to infinity. In H-atom spectra
Balmer series (H2) fall in visible region but not in He + ion spectrum. Actually
in He+ ion spectra, same transition of electron from higher orbit to H 3 is in
visible region.
12.
13. Conceptual
14. Conceptual
15. Conceptual
16. Conceptual

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