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ETWffiIST
F'aculty of Science
Department of Chemical & F'orensic Sciences
CHEM 101 TEST 2-20t912020
Course Code: CHEN{ lOI

Course or Module Title: General Cherr-ristrv I

Date: Thursdav 17th December 2020

Time: 6:15 pm-S:00 pm

Surname : irst Name:

ID: Group: (
Duration: 1.0 hr 45 mins Total Marks: 100
The following items are provided:

. One Test Paper (10 printed pages in total inclusive of cover Page and the Periodic table of
Elements)

Answer all questions.

The paper consists of 10 multiple choice questions & 6 structured questions.

Section B
 SECTIOI.I A: Multiple choice. Choose the best answer and indicate it in the table belorv.
Each question is worth 2 points for a total of 20 points

z 4
1
/ / 6

q QT
7 8
,v
) 10

v 9/ K w ,il +/ 6
1'Astrongelectrolyteisonethat-completelyinsoltttion.
A- reacts
B. decomposes
C. disappears
D. ionizes
Which of the following pairs does not show an acid and its conjugate base?
A. HNO3 and NOr-
B. H2SO4 and HSO*-
C. H,SO4 and SOo2-
D. HSOI- and SOo2-
3. Consider the ion H2PO4- which can act as a lase and as an acid. In wirich of the following
reactions is the ion serving as a base?
(i) Hro+(aq) + H2Po4- (aq) ;=- HrPoo(ag) + H2o(l)
(ii) H3O+(aq) + HPO42- (aq) ;=: HrPOo- (aQ) + HrOlt;
(iii) H3Po4(aq) + HPo42- (uq) .- 2 H2Poo- (ao)
A. (i) only
B. (i) and (ii)
C. (i) and (iii)
D. (ii) and (iii)
E. (i), (ii) and (iii)

Page 2 of 10
:1. Which one of the following compounds is insoluble in water?

A. NarCO.
B. ZnS
c. K,so4
D. Fe(NO.),
E. AgNO,
5. Consider the n-iolecular reaction equation:
naClr(aQ) + 2AgNO3(aQ) 2AgCl(s) + BaNOr(ac)
-;
The net ionic equation contairrs which of the following species?
A. Ag+(aq)
B. Ba2*(aq)
C. NOr-(at)
D. AgCi(aq)
6. The net ionic equation for the reaction between aqueous solutions of HF and KOH is

A" HF+KOH --- + H,O+K+ +F-

B. HF+OH- --- + H,O+F-
c. HF l- K+ + OH- -----+ H?O + KF
D. H+ + OH- ---- + H.O
E. H++F- +K++OH ------- H.OrK+-F
7. Oxidation is the and reduction is the
A. gain of oxygen, Ioss of electrons
B. loss of oxygen, gain of electrot-rs "{
C. loss of electrons, gain of electrons
D. gain of oxygen, loss of mass I
!\. rr ".. ,. , a-,'i, ,1*
:r
E. gain of electrons, Ioss of electrons ;.
11 i r':

Which of the follo.,r,ir-rg is an oxidation-reduction reaction?

A. Cu(s) + 2AgNo3(aQ) ----+ 2Ag(s) + Cu(No3)2(aq)
B. HCI(aq) * NaOH(aq) -----+ H2o(l) * NaCl(aq)
C. AgNoj(aq) + HCl(aQ) AgCi(s) + HNor(ao)
--1
D. Ba(CrHrOr)2(aO) * NarSO*(a9) -----+ BaSOa(s) * 2NaCrHrOr(at)
E. H2Co3(aq) +Ca(No3)2(at) ---+ 2HNo3(au) * CaCo3(s)

Page 3 of l0
9. In which equilibriurn is the forward reaction favoured by decreasing the external pressure?

A. 2NH3(g) ,- Nr(s) +: H2(c)

B. 2NO(g) + O2G) .- 2NO2(s)
C. 2CO(g) + O2(S) .- ZCO2(S)
D. 2So2(g)+o2(s) . -2so3(s)
10. Silver carbonate would be most soh-ible itt
A. a solution of NarCO, -_-:
B. pure HrO
C. a solution of AgNO,
D. a soiution olAgCl
E. a solution of KrCO.

Page 4 of 10
 'i":;,

SECTION B: Structured questiohs. Answer all questions in the spaces provided

(80 Points)

B1. State whether each of the following statements is true (p or false (F)
tat Organic acids generallr fall in rhe catesor'r ol *7a{ ucids. ; .-
(b) A weak acicl readily transfers H* ions.-' --"
(c) A concentrated solution rvill ahlals contain stro
(d) All ionic compounds a electrolytes.&1 t
(e) "Spectator ions" ap in the total ionic equation tor a react l but not in the net ionic
. '--(-
eouatlon. i /
t
^^q ,

-l
(g) When the reaction A + B,4=_. C 'D is at eqr-rilibriun-r the sum. of the concentrations of A
and B rnust equal the
f n ol the conccrtr'ations ol C and D. --j1..
(h) ln a polyatomic lon,r{ire surn ol'oriJ.Lti,'ln rrumbers of the arorns'eqLrals to rhe clFde of
the ion
--[iLL'
(i) In tire reaction N{g + 2HCl ---- \{eCi, * H,, Mg is reduced.
C) PbCOj is less soluble in ptrle water than in a solution of NaCl. Tuu
B2. E
(a) Consider the chemical species shou n in column 1 of the table belorv. What is the conju- t6l
gate acid of each species? What is the coniugate base of each species? Ansrver by filling
in the table

HsNz* HoF\!

(b) Using solubility guidelines, hether the each of the following compounds is so1- t6l
uble or insoluble in water:

t\{" ,.\,
iv. ZnSO, H*k \e ,

v. Sr(OH)r'lnso\'b\e
vi. MgS 'S\'"'rb\e

Page 5 of 10
 lcr
). jtr
jL)
....11
{ l'( \i
tir,
,,'\

(c) Write balanced net ionic equations for the reactions that occur between the following i8l
aqueorffi6iiiiiiiris. Iiientify the spectaror ion or ions in each case.
i. Cr2(SOa):(aq) and lNHo)rCO3(aO)
c,rt roi=l* trru.*1- ro, oJ-> cilco}re,+,(H
ui,tl: Lqil
-
'lkoi.*l- - *'-
l*Craba^at -2c.e(Dr)31s1 ,*,_>J%L(%)s<
Balancednetionicequffi: r' /;^Y. qU%+ Wi"+t-.
Soectator ions:
ii. Fe(NO3)z(aq) and KOH(aq)
Ie ( rloi) 16^a; + 2 kC Ht"+ HD3.arLi + Te(ott), .r,
->2K
I-el'"*r ffir2t\o/cca v 7y/r*at{c^tl" .1> q@Y3r*a a i^e
iuulG, iiCtt^"1 ;
xe@H) r rsr
,'2
pOHr
Balanced net ionic equati
-) €) n
Spectatol ions: r' /
83. State the oxidation number of in the reactions shown in colr,rmn 1 of the
table below for both the reactant side and the product side. Decide based on the changes in
oxidation number whether indicated atom has been reduced or oxidized.

reaction

c]- _) Clz
Mn2+ -----+ Mno^L

H, H+
atom

CI

Mn
H
Oxidation Numbe;r.df

atom on

J)
+?
OJ
,ru"r{uo"
-tv /
Oxidation Number ol

atom on pl'oduct side

O \./
oYlr
r,!,f "a"M
reduced or

oxidized/
or,h4ot

oy;d;Ld
?
I \.**'1
-+ ot;d'z-tct
NOr- -----+ NO N -h( /FS o{ "j
';
F€4.r€ry\ tCdu {? r'''

64. Please, balance the following half re/ions (Show a1l the steps distinctly to get full credit) @
(a) BrOr- ---+ BrO, acidic
Yry-_f
/^\ t,ir :", , i
tsl

vB'
o-.i ?
e-+ -^/'' +t\rV .E\
"'' /-{ -{ )

t
tL
Page 6 of 10
 B'C; k.0, {ll, c)
?+\u -l
t.
!i
-> 0?
---\ )
t 'P
PJ ,

nl '-f
a. 4
1
:

tl h
.-r I'J I vrf
g. I
\,r
I */

/r/
(b) CrOr- ---+ CrOo- basic medium t?l
t/l
,/
l-\aD + C,, Oi C. D; t aaV {
\.I
-)
llt.'1 i -\-.. .r f',

\-;_ -\ I

0t\+ AO" -rffi; \ il,"

@
(a) The equilibrium constant for the reaction 2NO(g) + Br2(S) 2NIOBT(g) is Kc : 1.3 x t3l
=----.
1o-z at 1000K I
i. At this temperature does the equilibrium favor reactants or produ.tr? t ' '
t/#l',tu*
'

ar,

Page 7 of 10

ry
 ii. Calculate K, for the reacrion 2NOBr(g) ,- 2NO(g) + Br2(g)
1a. =LBl o:*tF*f
Lro r"
iii. Calculate K, for the reaction NOBr(g) ,- NO(g) + j Brr(S)

K. = lflD)18::f
,!
ll I

L c -,-- -.1
frto 6r r./" \ i :-
,l
(b)
t3l
i. What is tne uanfithe reaction coefficient, Q, at thestart of a certain reacrion when

,,:':Y m:re act i

Er co ern cie nt, e, chan gea,s th e ro rw ard re ac ri o n
proceeds?

]t vql.ss r.r
so that Q: K,
l-- I
Lr\- t
,

L \ --
r-

(c) ofi and products are given for each following t6l
SVStemS.Calcu]ateth",.@ferminelhedirectio. (left or right) in
wnrcn eacn system wlll proceed to reach equllrbrrum.
i, zNH3(s) N2(e) + 3 H2(S)
-+ : r ooM' rHzl : l ooM
Wffii#tNzl
-\ t\,7 (c=ta - ":^l: -
DoJ3--tr,-oYtl la + ar ' \"-S
*fo-rolo
/ U. -J, i {tl
k1-- fn*V-- eE
ii. 2SO3(g) i- 2SO2(S)+Or1g;
K,:0.230; [SO3] : 0.00 M, [SO2] : 1.00 M, [oz] : l'00 M
'J,/"-
Lc = f-Sc, l'f c, ] Vc -- 6 ,azo /t(}
Ug .{o Ig
Vc --o l'grt
L*c = Lt ,

ri t '. -!

f Page 8 of 10

lb
 li
\"
'. 1

86.
(a) Please suggest four (4) ways in which the ntration of hydrazine, NrHo, could be
E
increased in an equilibriLrm described by t4l
llowin_e equation:
N2(s) + zHr(.g) NrH4(g) :95kJ
-+
'{t
z. Addi^. G cq|q
3. ( rrcresi.lrv\

(b) It was found rhar oniy 0.00 r 92 g of Agcl can dissolve in 1.0 L of wa Please, tll
calculate the soh_rbilrtr, prociLrct constant , Krp, of AgCl.

h,9 r
.no\es =
C[ #_^, .til
(oa. r.s8p* le+'? :- 0'0ola3 L'se
'f'{g
-=l*3 . l+udJ t+3'JJ12'
[rr = fo-o* ';'al";
O .OC@r3j(6,"..rs
= L.f t l " )t'15q
e.ra<
" .-\et
MSa'rh=
vi*-e
: D.comig

D.oo
=

(c) Please show thar the molar solubility, s, of Bar\ h be expressed in terms of Kr, as t6l

(rvBr) i (axn) t 6 x o; - / K,r \'/'

(*il5.tu+) '- \ 108/
{*.w*1+ Qx3r.q?3?t) +

*lf .ftr t ul"q++s) t n1 'aqse

= tDl. q a341 ,l*.\
lqglq'i o rn"i$
n5\arrc-!

.",:\4" *
G0l

\4J4 ."'oles
W\'"{

naAr-tb

o 1'" qcaaa Page 9 of 10

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