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    PB SN

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    Angeles Nuñez
    Sustancias

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    PB SN

    Uploaded by

    Angeles Nuñez
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    Sustancias

    Original Title

    Pb-Sn

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    Sustancias

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    Download as pdf or txt
    11 views1 page

    PB SN

    Uploaded by

    Angeles Nuñez
    Sustancias

    Copyright:

    © All Rights Reserved
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    9.

    11 Binary Eutectic Systems • 315

    Composition (at% Sn)

    0 20 40 60 80 100

    327°C

    600
    300

    Liquid
    500
    232°C
    Temperature (°C) ␣ +L

    Temperature (°F)
    200 ␣ ␤ +L 400
    183°C
    ␤
    18.3 61.9 97.8

    300

    100 ␣ + ␤ 200

    100

    0
    0 20 40 60 80 100

    (Pb) Composition (wt% Sn) (Sn)

    Figure 9.8 The lead–tin phase diagram.


    [Adapted from Binary Alloy Phase Diagrams, 2nd edition, Vol. 3, T. B. Massalski (Editor-in-Chief),
    1990. Reprinted by permission of ASM International, Materials Park, OH.]

    In the construction of binary phase diagrams, it is important to understand that one


    or at most two phases may be in equilibrium within a phase field. This holds true for the
    phase diagrams in Figures 9.3a and 9.7. For a eutectic system, three phases (a, b, and L)
    may be in equilibrium, but only at points along the eutectic isotherm. Another general
    rule is that single-phase regions are always separated from each other by a two-phase
    Tutorial Video:
    region that consists of the two single phases that it separates. For example, the a + b
    Reading a Phase
    field is situated between the a and b single-phase regions in Figure 9.7.
    Diagram
    Another common eutectic system is that for lead and tin; the phase diagram
    How do I Read
    (Figure 9.8) has a general shape similar to that for copper–silver. For the lead–tin
    a Phase Diagram?
    system, the solid-solution phases are also designated by a and b; in this case, a rep-
    resents a solid solution of tin in lead; for b, tin is the solvent and lead is the solute.
    The eutectic invariant point is located at 61.9 wt% Sn and 183C (361F). Of course,
    maximum solid solubility compositions as well as component melting temperatures
    are different for the copper–silver and lead–tin systems, as may be observed by com-
    paring their phase diagrams.
    On occasion, low-melting-temperature alloys are prepared having near-eutectic com-
    positions. A familiar example is 60–40 solder, which contains 60 wt% Sn and 40 wt% Pb.
    Figure 9.8 indicates that an alloy of this composition is completely molten at about 185C
    (365F), which makes this material especially attractive as a low-temperature solder be-
    cause it is easily melted.

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