Safety Data Sheet

24-hour emergency- (INFOTRAC #1-800-535-5053) Submit Copy to the

Office of Safety (STOP 9031, 701-777-3341)

Section 1.IDENTIFICATION

Product Name: Sulfur

Product Use: Rubber compounding and various industrial applications

Synonyms: 104 RUBBERMAKERS, 338 SUPERFINE RM, 340 VERY FINE

GRIND RUBBERMAKERS

Other Designations:
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Section 2.HAZARD(S) IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Skin irritation (Category 2), H315

2.2 GHS Label elements

Signal word : Warning

Hazard statement

H315 : Causes skin irritation.

2.3 Precautionary Statement(s)

P210 Keep away from heat/sparks/open flames/hot

surfaces. No smoking.

P240 Ground/bond container and receiving

equipment.

P241 Use explosion-proof electrical/ ventilating/

lighting equipment.

P264 Wash skin thoroughly after handling.

P280 Wear protective gloves/ eye protection/ face

protection.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P332 + P313. If skin irritation occurs: Get medical advice/

attention.
 P362 Take off contaminated clothing and wash
before reuse.

P370 + P378 In case of fire: Use dry sand, dry chemical or

alcohol-resistant foam to extinguish.

P402 Store in a dry place.

P403 Store in a well-ventilated place.

P404 Store in a closed container.

2.4. Hazards not otherwise classified (HNOC) or not covered by GHS

Combustible Dust

Section 3.COMPOSITION INFORMATION ON INGREDIENTS

3.1 Substances

Chemical Formula : S8

Molecular Weight : 32.07 g/mol

CAS-No. : 7704-34-9

EC-No. : 231-722-6

Index-No. : 016-094-00-1

3.2 Hazardous Ingredient : None

Section 4. FIRST AID MEASURES

4.1 Description of First Aid Measures

Skin: Wash skin thoroughly with mild soap and water. Wash exposed
clothing separately before reuse.

Eye: Immediately flush eyes with plenty of water for 15 minutes, while
holding upper and lower lid apart to insure rinsing of entire eye
surface and lids. Do not use boric acid to rinse with. FOR SEVERE
IRRITATION, SEEK MEDICAL ATTENTION, preferably an ophthalmologist.

Inhalation: Move victim to fresh air. Watch for signs of an allergic reaction.
Use a bronchodilator inhaler if directed by asthma patient. Keep victim
warm and quiet. If not breathing, give artificial respiration. If heart has
stopped beating, start cardiopulmonary resuscitation (CPR). SEEK
MEDICAL ATTENTION.
Ingestion: Give one tablespoon of Syrup of Ipecac to induce vomiting. If
vomiting does occur, give fluids again. If vomiting has not occurred in
twenty minutes, the same dose of Syrup of Ipecac may be repeated one
additional time. Alternatively, vomiting may be induced by touching the
back of the throat with a finger. Do not give anything by mouth to an
unconscious or convulsing person. SEEK MEDICAL ATTENTION.

Section 5. FIRE-FIGHTING MEASURES

5.1 Extinguishing Media

Suitable Extinguishing Media

Water fog, spray, alcohol-resistant foam, dry chemical, or carbon

dioxide

Unsuitable Extinguishing Media

Do not use solid streams of water, which could create sulfur dust
clouds and cause an explosion or could move burning sulfur to
adjacent areas.

5.2 Exposure and Special Hazards Arising from the Substance or

Mixture

Sulfur Oxides Prevent human exposure to smoke, fumes, or

products of combustion.

5.3 Advice for Personnel

Evacuate nonessential personnel from the fire area. If large fire,

evacuate people downwind from fire. Consider evacuation for ½
mile in all directions.

5.4 Advice for Firefighters

Firemen exposed to contaminated smoke should be immediately

relieved and checked for symptoms of exposure of toxic gases. This
should not be mistaken for heat exhaustion or smoke inhalation.
Seek medical attention immediately.

5.5 Protective Equipment

Wear full-faced, self-contained breathing apparatus and full

protective clothing.

5.6 Other Important Fire and Explosion Hazard Information

 Fire will rekindle until mass is cooled below 310°F (154°C). Cool
surrounding areas with water fog to prevent re-igniting. Sulfur dust
is HIGHLY FLAMMABLE. If suspended in air, it will ignite by friction,
static electricity, heat, sparks, or flames. Sulfur dust clouds may
explode.

Section 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions

Minor spills such as torn or ruptured containers should be repaired

or patched with tape if possible. Place spilled material in a
disposable container. Avoid getting dust in eyes.

Methods and Materials for Containment and Cleanup

Gently sweep or shovel up spilled material using a natural fiber

broom and/or aluminum shovel to prevent sparking, to avoid
creating a dust cloud. Place sweepings in an appropriate chemical
waste container for reclaiming or disposal in an approved facility.
Wash spill site after clean-up is complete.

Section 7. HANDLING AND STORAGE

Precautions for Safe Handling

All handling and conveying equipment should be properly grounded

and bonded. Be careful not to create dust. Avoid contact with skin or
eyes. Avoid any conditions that might tend to create a dust
explosion. Maintain good housekeeping practices to minimize dust
build-up and dispersion. Eliminate sources of ignition. Keep away
from heat, sparks, and flames. Use nonferrous tools, when available,
to reduce sparking. Gently sweep or shovel up spilled materials
using a natural fiber broom and/or aluminum shovel to prevent
sparking. Maintain adequate ventilation in all areas.

Conditions for Safe Storage, Including any Incompatibilities

Containers should be stored in a cool, dry, well-ventilated area. Keep

container tightly closed. Store away from flammable materials,
 sources of heat, flames, and sparks. Separate from chlorates,
nitrates, and other oxidizing agents. Exercise due caution to prevent
damage to or leakage from container.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Components with Workplace Control Parameters

Contains no substances with occupational exposure limit values.

Exposer Controls

Appropriate Engineering Controls

Handle in accordance with good industrial hygiene and safety practice.

Wash hands before breaks and at the end of workday. Maintain adequate
ventilation in all areas. No flares or flames in area. Be careful not to create
dust. Eliminate sources of ignition.

Personal Protective Equipment

Respiratory: Wear dust masks and use NIOSH/MSHA approved dust

respirator if airborne concentrations exceed exposure limits.

Eyes/Face: Wear suitable, protective safety glasses to prevent eye

irritation from dust.

Hands: Wash hands thoroughly after handling and before eating or

smoking.

Skin/Body: Wear suitable, protective clothing to prevent skin

irritation from dust. Wash skin thoroughly after handling and before
eating or smoking. Wash contaminated clothing separately before
reuse.

Environmental Exposure Controls: Follow best practice for site

management and disposal of waste. Avoid release to the
Environment.

General Industrial Hygiene Considerations

Protective equipment should be used in any situation that may

result in hazardous exposure. Maintain good housekeeping practices
to minimize dust build-up and dispersion. Eliminate sources of
 ignition. Use nonferrous tools to reduce sparking. Sweep or shovel
up spilled material using a natural fiber broom and/or aluminum
shovel to prevent sparking. Maintain adequate ventilation in all
areas.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Physical State Solid, powder form

Appearance Yellow powder

Formula S8 (Rhombic or monoclinic)

Odor Odorless, or faint odor of rotten eggs

Odor Threshold No data available

pH No data available

Boiling Point 832° F (444° C)

Melting/Freezing Point 118-120°C (244-248°F)

Flash Point 207°C (405°F) Closed Cup

Evaporation Rate No data available

Flammability May form combustible dust

concentrations in air

Flammable/Explosion Limits Upper: 6.38% (v) Lower: 0.17% (v)

Vapor Pressure 8mmHg at 246°C (475°F) 1mmHg at

183.8°C (362.8°F)

Vapor Density No data available

Purity 99.5% Min.

Auto-Ignition Temperature 240°C (464°F)

Decomposition Temperature Does not decompose

Viscosity Not applicable

Specific Gravity 2.07 @ 70° F

Solubility in Water Insoluble

Bulk Density Powder: 33-80 lbs. /ft3

SECTION 10: STABILITY AND REACTIVITY

Reactivity: No Data Available

Chemical Stability: Stable under recommended storage conditions.

Possibility of Possible Hazardous Reactions: No Data Available

Conditions to Avoid: Avoid moisture. Keep away from heat sources, sparks,
and open flames. Minimize dust generation and accumulation.

Incompatible Materials: No Data Available

Hazardous Decomposition Products: Hazardous decomposition products

formed under fire conditions.

SECTION 11: TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Inhalation, ingestion, skin contact, and eye

contact

Information on Toxicological Effects

Signs and Symptoms of: Nose or throat irritation, coughing, chest

discomfort, asthma, difficulty breathing,

Overexposure: nausea, vomiting, stinging eye irritation, skin

irritation, hives.

Exposure Limits: No exposure limits have been established

Acute Symptoms and Effects Inhalation: Prolonged inhalation may

cause irritation of respiratory tract. Breathing of dust may aggravate
asthma and other pulmonary diseases.

Eye Contact: Sulfur dust is an eye irritant.

Skin Contact: No adverse effects; however, skin irritation may be

aggravated in persons with existing skin lesions.

Ingestion: Ingested sulfur is converted to sulfides in the

gastrointestinal tract, and ingestion of 10 to 20 grams has caused
irritation of the GI tract and renal injury. Swallowing large amounts
may cause nausea and vomiting

Long-Term Effects: None known to humans

Carinogenicity

IARC: No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed human
carcinogen by IARC. No component of this product present at levels
greater than or equal to 0.1% is identified as probable, possible or
confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than

or equal to 0.1% is identified as a carcinogen or potential carcinogen
by ACGIH.

NTP: No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen by
NTP. No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.

OSHA: No component of this product present at levels greater than

or equal to 0.1% is on OSHA’s list of regulated carcinogens. No
component of this product present at levels greater than or equal to
0.1% is on OSHA’s list of regulated carcinogens.

Toxicity

LD50 Oral: >5050 mg/kg (rats) Dermal: >2020 mg/kg (rats)

LC50 Inhalation @ 90%: >5.49-mg/L air concentration (rats)

Skin Slightly irritating (rabbits)

Eye Minimal irritation in non-washed eyes (rabbit)

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SECTION 12: ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

LC50- Oncorhynchus mykiss (rainbow trout) -> 180 mg/l -96h

LC50- other fish- 866 mg/l -96h

Toxicity to Daphnia and Other Aquatic Invertebrates

EC50- Daphnia magna (Water flea) -> 5,000 mg/l -48h

Ecotoxicity No data available

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SECTION 13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Product Waste Dispose of content and/or container in accordance

with local, regional, national, and/or international regulations.

Packaging Waste Dispose of content and/or container in accordance

with local, regional, national and/or international regulations.

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SECTION 14: TRANSPORTATION INFORMATION

Solid sulfur is not regulated if transported in non-bulk packaging (less than

400kg per package) or if formed to a specific shape, such as prills,
granules, pellets, pastilles, or flakes (49 CFR 172.102, special provision
30).

US and Canadian Shipments

Bulk containers (packaging) of powdered sulfur of more than 400

kg (880 lbs.) per package

UN UN transport packagin environmen

number proper hazard g tal
shipping class(es) group hazards
name
DOT NA1350 Sulfur 9 (Misc. III No data
(Domestic) (Sulphur) Hazardou available
s
Materials)
DOT NA1350 Sulphur 4 III No data
(Internation (Sulfur) available
al)
TDG NA1350 Sulfur 4.1 III No data
available

SECTION 15: REGULATORY INFORMATION

TSCA

This product is listed on the TSCA Inventory at CAS Registry Number 7704-
34-9.
CERCLA

Comprehensive Environmental Response, Compensation, and Liability Act

(CERCLA)

• If this product is accidentally spilled, it is not subject to any special

reporting. We

Recommend that you contact state and local authorities to determine if

there are

Other local reporting requirements.

SARA TITLE III

Superfund Amendments and Reauthorization Act, Title III

• Sections 311/312: None. Section 313: None. Section 302: None.

RCRA

Resource Conservation and Recovery Act

• Not subject to reporting because sulfur is not identified as a hazardous

waste.

SECTION 16: OTHER INFORMATION

Issue Date: 06-03-2015

Revision Date: 05-27-2022

Prepared by: Harwick Standard Distribution Corporation.