(Conceptual Queatlo , chemistrt

Build Up Your Understanding

~..c~- •
~
.. ,··.

'4,.,,,. f rrnula weight of H2SO ls 98 -n.. • If a ls the degree of dls~atlon of weak dibaslc
,~·"11e o 4 • • ne Weight
: / ~;-the acid in 400ml of 0.1 M solution ls:- .
~ organic acid and y ls the hydrogen Ion
concentration, what ls the lnitl~ ~ncentrati~~ '?1 1
✓ (l) z,45 g (2) 3.92 g (3) 4.90 g (4) 9.8 g acid:· ,, f\ -· .;,t-'-r.,J ,,. ,, ...k ,.
Y1\.- - l,~ ,,__,,.,.,,,.
() ,. '' "· , •• , .. e;..

y' ;ir:aliiY of 2M sulphuric acid ls·-

N (2) 4N (3) N/2. . (4) N/
4
1
(1) a(~J- M '' ,r, J :; ' , (2) .y(a)"'1.M ·1, J ., -- • i ~

f pH ,. 3.31, then find out (H•J (Approxy) .

t \) 3.39 X 10·
3
4
(2) 5 X 10◄
(3) ~ M
2
(4) None of them

~3) 3.0 x 10· (4) None

The degree of dissociation of acetic acid is given by
5
If [OH-J == 5.0 x 10· M then pH Will be :~ the expression a. 0.1 xC-1 (where C • concentration
.Vf (l) 5 - log 5 (2) 9 + log 5 of the acid) What is the pH of the solution :-
(3) log 5 - 5 (4) log 5 - 9 (1) 1 (2) 2 (3) 3 (4) 4

1/
Basicity of Hl03 and Hl02 are respectivily :·
(1) 1 and 2 (2) 2 and 3
y Ostwald's dilution law is not applicable for strong
electrolytes because:- •
(3) 3 and 2 (4) 2 and I (1) Strong electrolytes are completely ionised
(2) Strong electrolytes are volatile •
Find out pH of solution havin~ 2 x ,lP-3 moles of
1/ oH- ion's in 2 litre solution :· • (3)
(4)
Strong
Strong
electrolytes
electrolytes
are unstable
often contain metal ions
(1) pH =3 • (2) pH • 3 + log2
(3) pH =3 - log2 (4) pH • 11 3/' The degree of ionisation of a compound depends
... •upon:
1,/ PH of tomato juice is 4.4. Then concentration of (1) Size of the solute molecules
✓ H3O• will be :-
(2) Nature of the solute molecules
(1) 39 X 104 (2) 3.9 X }Q-5 (3) Nature of the container taken
(3) 3.9 X }0-4 · (4) 3.9 X 105 (4) The amount of current passed
8. 8 g NaO~ is dissolved in one litre of solution, the y( Find out K. for 10-2 M HCN acid, having pOH
1/ molarity of the solution is:- • • is 10 :-
(1) 0.2 M (2) 0.4 M (3) 0.02 M ·(4) 0.8 M (1) K. • lo-4 (2) K0 • 10-2
(3) Ka =- 10-5 (4) None of them
9./ The amount of acetic acid present in 100 ml of
\/ O. lM s9lution is :- ' ~ Which of the following will occur if a 1.0 M solution
(1) 0.30 g (2) 3.0 g (3) 0.60 g (4) None rJ' of a weak acid is diluted to 0.01 M at constant
temperature:- ' '
~ The number of milli equivalents of acid in 100 ml (1) Percentage ionisation will increase
of 0.5N HCl solution is:- , , . (2) (H+) will decrease to 0.0lM
(1) 50 (2) 100 1 (3) 25 . (4) 200 (3) K. will increase ·,
(4) pH will decrease by 2 units
~ If the molar concentration, of Pbl 2 is
1.5 x 1Q-3 mol L-1, the concentration of iodide ions j;/ ~he pH of 0.15 M •solution of HOCl
in g ion L-1 is:- -~ c./
I (1)-3.0 X 10-3 (2) 6.0 X 10-~
(K • 9.6 X 10""} is:-
•
(1) 4._42 • (2) 2. 92 (3) 3.42 (4) None
Il
,I
(3) 0.3 X }0-3 .(4) 0.6 X 1~
~ The extent of ionisation _increases (weak
I. ." ... electrolytes}
(1) With the increase in concentration of solute

, I~ O~der of dissociation of 0.1 N CH,COOH is ;-

(Dissociation constant • 1 x to-a)
(2) On decreasing the temp. of solution

I
;
(1) io-s (2) 1<>-4 (3) i~ . (4) 10-2
(3) On addition of excess of water to the solution
(4) On stirring the solution vigorously
l
173
 Pre-Medical
/ The ~on ion effect Is shown~~
~.:: ;~,H: • 4 x 10-'0, then the pH of 31
✓ folloWinQ sets of solutions :· ~
(1) 4 ar HCN (aq) ls:- (l) Saeli + Ba(N0J2
•2 (2) 4.1 (2) NaCl + liQ
(3) 0.47 (4) 5.0
(3) NH40H + NH4O (4) None
The mol ·ty f • ·' • •
be an °
nitrous acid at which its pH ~
/ Basic strength of NH,OH in presence of •
comes 2.(K. • 4.5 x 10--1) ·-
(1) 0.3333 (2) 0.4444 g (1) Increases tft.Q
3 0 (2) RemainS unchanged •
( ) •6666 (4) 0.2222
(3) Decreases
st
Correct atement' for HCN w;ak acid at 25°C (4) Some times increases or sometimes deer'
temperature.:-
41/'f
Which of the following is a true statement .
. K1 x!OH·J ~ (1) The ionisation constant and iqnic pr~
(2) a= K • water are same. of
w
(2) Water is a strong electrolyte.
(3) The val~e ~f i~nic product ~f ~ter_ isles.,~
(3) (1) & (2) both (4) ~ = Ca~ that of its 1omsahon constant. •
\
(4) At 298K, the number of H• ions in 'a ~
ii!f~~-';:;;J water is 6.023 x 1016• e of
'tJ4. Ionic product of water will increase, if :- •
34 / If it is known that H25 is a weak acid and it is~
(1) Dissociation the pressure
(2) Add H· '
J into 2H• and 5-2 • Then in this solution Ha is~
so, pH becomes less, then what will hawen ..
(3) Add OH·
(1) Decrease in 5·2 ion concentration •
(4) Increase the temperature
(2) Concentration of 5·2 is not affected
For water at 25° C, 2 x 10-7 moles per litre is (3) Increase in s-2 ion concentration
(4) It is not possible, to add Ha in ~lution
the correct answer for which one of the followoing
(1) IH•] + [OH·] (2) [H•] 2
- I 1·

::I~~~:
.......... , _ , . . , , , , - ~

If :: ~::~ is given by :-
ilie &_patino ~ter ~ - : . ~ ~ : : : : · : aciwc ~h
(1) NaHS04 (2) HCOONa
14
7 -·)~ (1) (155x.14o·xl41014)·1 (2) 1 X 10· (3) NaHl03 (4) None of them
// 3,( Which is a basic salt :-
~ (1) PbS
,I

,,/ (3) - - - (4) None of these (2) PbCO,

18
• (3) PbSO4 (4) 2PbC03 Pb(0J\ .
Ionic product of water is equal ~o :-
(1) Dissociation constant of water x [H 20]
¢' The ·process of neutralisation invariably results ~
\. . the production of :-
(2) Dissociation constant of water x [H+] (1) H• ions
(3) Product of [H20] and [H+] (2) OH- ions
(4) Product of IOH-] 2 and (H•] J
(3) Both H• and OH- ions
(4) Molecules of water
Addition of H• and OH· ion's concentration at 90oC
(1) 10·14 (2) 10·{2 JH- Which of the following is an acid salt :-
(1) Na2S (2) N'¾S03
(3) 2 X 10-6 (4) 2 X 10·7
. (3) NaHS03 (4) Na2~ 4 .. I
At 90oC, pure water has (H30•) =1Q-o· molL- what
7 1

is the value of Kw at 90°C:• I

~ The ~ed salt among the foll~wing is :-
(1) lo-6 (2) 10-12 (1) fH(OH)COO~a (2) NaKS04
(3) lo-61 (4) 10-13.4
j. At 373 K, temp. the pH of pure H20 can be:-
(1) < 7 (2) > 7 (3) • 7 (4) = 0
CH(OH)C0ONa
(3) CaC~. (4) AU .'

174
 p
. . I .

.J (OH-I in the tJ IS
Hydroxyl Ion ,oncentratton •__ -,,1 as (where "•the •
sodium acetate tan be e><P1co<>H and C is
dissodatlon constant of cH:tate):- . . •
,dC,
t,.t'IV
the pH of O.lM_N aCl·~·so lution
• ' • • concentration of sodhJITI ac H·J _ c.1<,. .Jt<.
(1) (OH·) - (CK_. K)l/2 (2) [O t •
f LS :- 7
~~
(2) > 7 - (3) 7 . (4) 0.1 •
•.
I

1/2 I< K.,

twill be the pH of 1. 0 Mammonium formate CK.) (4) [OH-) • C. •· ••
JI wh3tiotl, If K_•l x 10-4 add J<. •lx 10-1:- (3) [OH-) • ( K
1 s0lll 5 • (2) 7 .5 (3) 8.0 (4) 9 o •
7. (l) 6. , •

ft
ich salt will not undergo hydrolysis·:- 52/ Consider :-
:7 (a) FeCl in water - Basic
t<CI (2) Na,S04 (3) NaQ (4) All A idic
(b) NH Cl in water - Acidic
(c) ~nium acetate in water .. c
~ f.ia,drourn efficiency of cationic hydrolysis will be
• (d) N~CO in water - Basic
~ shOWfl by :-
(l) Al~3 (2) Ga+3 (3) Tt•t (4) Tl+3 , Which is/;re not correctly rnatchelyd:-
' (1) b and d (2) b on
~
'

(3) a and c (4 ) d only

ucoo- + H2O ~ HCOOH + OH- is related:- oes hydrolysis
derg
~
~
,~ fl
Which of the following salts un
(ll h = Jf( (2) h =
in water:- • H cooNa
C 3 of (1) and (2)
(2) Both
ft( ~ "'4
(1) Na [){) (4)
VV (4) I\= $c (3) NaNO3
(3) h ==
54/ A salt 'X' is dissolved in water of pH • 7. The
sodium acetate
. pH of aqueous solution of
,y5 The
·
. . •:. 7 . resulting solution becomes alkaline in nature. The
~

(1) 7 (2) Very low salt is made up of:-

(4) <7 • (1) A strong acid and strong base
(3) > 7
(2) A strong acid and weak base
{~/ If p~ for CN- at 25oC is 4.7. The pH of 0.5M (3) A weak acid and weak base
?'/ aqueous NaCN solution is :- • (4) A weak acid and strong base
/ (1) 12 (2) 10 (3) 11.5 (4) 11 rt:
~ K for cyano acetic acid is 3.5 x Hr''. Then the
4U The highest pH value is of :- ';,,,,' d;gree of hydrolysis of 0.05 M. sodium cyano
7 (1) 0.1 M NaCl acetate solution will have the following value :-
(2) 0.1 M NH4Cl (1) 4.559 X 10"° (2) 5.559 X 10-6 J--
(3) 0.1 M CH3COONa (3) 6.559 x 10-0 (4) 7.559 x lo-6
(4) 0.1 M CH 3COONH4
N
~ pH of KzS solution is:-
/, (1) 7 (2) Less than 7
.
o/ • •
Degree of Hydrolysis of 100 solution of KCN is
(3) More than 7 (4) 0 9
(Given Ka = 1.4 x 10- )
~ For anionic hydrolysis, pH is given by:- (1) 2.7 x l<r' (2) 2.7 x 10-
2

l 1 1 1 (3) 2.7 x lQ-4 (4) 2.7 x 10-S

l t
1
I I
(1) pH ;: - pf<w - - p~ - - loge
2 2 2
~uTv,- ~~~,-- .~~...~---...~..... - " ' • - , . . , . . " " ' t · ~... t'-"
.1 1 1 · - - ~~ . , < > ! - ~ fflQ~ -«Jn1 l
!
1 (2) pH = 2 pi<_. + 2 pK, - 2 pK,,
% The_ solubdity product of sparingly soluble univalent
. 1 1 1 \ salt 1s defmed as the product of ionic concentra tion
(3) pH =
2
pf<w +
2
.pK11 + 2 loge . in a:-
~ (4) None of above . • : : • (1) 1 M solution .
(2) Concentration solution

f A weak acid react with strong base, ionisation

constant of weak add is lo-4. Find out equilibrium
constant for this reaction· :-
{1) 10-10 (2) 1010 (3) 10-9
• .,
(4) 10
9
(3) Very dilute solution '
(4) Saturated solutto'n '

175
~ ~ ~ ~ ~, ~ ~-t -tt" 111 ~ CA'd (,J rL~ z.. :. s tMtl°: --o
Pre-Medical (
w. In bility product of A.. ~-
61/ 1be so1u
' : • ' ; ""2"a la
/ ' th sohmiltty of salts MzX, QV1 arxl Pl., ~. then, / e,cpressi_:1'i~J x (S-, (2)
1e) relation between their K,, will be :·
( K.,(Mz>Q > K (QY
\ > K (Plz)
. (ll K,, .. 1J\53+P 1s-,2 (4) .. ~
(2) K (M V\ • IP 11 • 1D7)
(3) J<.., • 111
~
., r~ • K., (QY1) < K., ,a-~ L/ . •,,
If the solubility of PbBr2 1S •
(3) KIP(Mz>Q > KIP (QY ) • K., (PZJ S g lllolo.-. .,
(4) K.,(Ma>Q • K (QY2) • K
ya· sidertnQ 100% ionisation Its 50~ , -
IP 2
(Pli) .. . • ~on •• --""'I
IP is••
• '.
!hod~dexpression of solubility product of mercurous 2 452 3 3
. , (1). 25 • .(. ) : . ( ) 4$3 • • : 14) ,._
1 1 e is :-
If the solubility of lithium sodium ~
(1) (2 Hg•]2 x 2 [J-)2 (2) [Hg++]2 x I 2112 6 • alurnlnate u,Na3(Alf)2 is 'S: molt·•. Its~ ~
I

(3) [ Hg:• I x 11-12

• • ~
(4) [Hg2•)2 x 0-12 roduct is equal to :-
ri) 5s • (2) 12 S3
At 25°C, the K value of AgO ~ 1.8 x 1Cr10• If 4
1D-5:· moles of Ag'! are ackl~ to solution then K,p will
be , . I- (3) 1853 ( ) 291~ sa.••

One litre of saturate d soIl!tion of Ca

evaporated to dryness, when 7.0 g of ..~a,
10
(1) 1.8 X 10-15 (2) 1.8 X 10- left. The solubility product for Caca l ~is-.. L11
J4t> (3) 1.8 X 10-5 (4) 18 X l0+lO
rW, At 25oC, required 110lume of water, to dissolve lg.
(1) 4.9 x 10-3 x
(2) 4.9 10-S.
BaSO4 (K.., = 1.1 x10-10)willbe(Molecularweight
(3) 4.9 x lo-9 14) 4.~ X I0-1
--~~~~~~~~~~-- .,., ,·• ...
of BaSO = 233) :· 1fnQtf!M~,
4 ~~~l"~'~'
.,~·'' ~~ ~' ••
\, .... :. :.,t •
(1) 820 L... (2) 1 L. ,
, At 30°c, In which of th~ _one litre soht+i-
(3) 205 L. (4) 430 L. , solubility of
. 6( Concentration of Ag• ions in saturated solution of ~ will be maximum :- bility product
I I
A~2CO3.(solu ~s:1:-
7· Ag2Cr04 at 20°C is 1.5 x lo-4 mol L-1. At 20°C, a~~ (1) 0.05 M Na2~93 (2) Pure water ~
the solubility product of Ag Cr0 is :- ~ (3) 0.05 M AgNO3
2 4 _\}.. (4) 0.05 M ~
(1) 3.3750 X 10-12 (2) 1.6875 X 10-10 ~
(3) 1.68 x 10-12 7~~-~ Solubility of AgBr WIil be mm1m
. . .
(4) 1.6875 x 10-11 /
um in :·
4Jr (1) Pure water (2) 0.1 M CaBr
. 6.lJ. How many grams of CaC.0 will disoolve in distilled '
4
/ - water to make one litre saturated solution? solubility
(3) 0.1 M NaBr (4) 0.l M AgNo1
product of CaC O is 2.5 x lo-9 mol2 L-2 and its 73': In which •
of the following, the solution of AgSQi
molecular weight2 is4 128. , / will be unsaturated :-
(1) 0.0064 g (2) 0.0128 g . .
' (1) [Ag•] [SCN-J = K,p (2) [Ag+) x[SCN"j <~
(3) 0.0032 g (4) 0.0640 g (3) [Ag+) x [SCN-J > Ksp (4) [Ag•] [SCN·p <~

~ If the concentration of CrO 2• ion in a saturated

4
solution of silver chromate will be 2 x 10-4 M,
Correct order of solubility product is :·
(1) CaCr04 > SrCr04 > BaCr0
solubility product oft, silver duomate will be - •
(1) 4 X 10· 8
(2) 8 X 10·12
f (2) BaCrO4 > SrCrO4 > CaCrO
(3) CaCrO4 > BaCrO4 > SrCrO . ,
4
4

4
(3) 32 X 10·12 (4) 6 X 10·12 (4) SrCr04 > BaCr04 > CaCr0
4
If the solubility of AgCl (formula mass= 143) in water
at 25°C is 1.43 x1o-4 g/100 ml of solution then
J5. If 's' and 'S' are respectively solubility and ~ I
product of a sparingly soluble binary e ~
the value of K.., will be :- then:- ., N
(1) 1 x 10- 5
(2) 2 x 10- 5 (1) s=s (2) s = S2
(3) 1 X 10-18 (4) 2 X 10-18 1 • I
(3) s = 5112 (4) s = 2 s J
-j If the salts M,X, QY2 and Pl;. have the same
~- solubilities, their Ksp values are related as • (S < 1)
-;/, The solubi\ity product of CuS , Ag~ and HgSall
(1) Ksp (M2'<) = Ksp (QY2) < Ksp (PZJ ••
(2) Ksp (M2'{} > Ksp (QY2) = Ksp (PZJ . 10-37 , 10-44 and 10-54 respectively. The sokOIY.
(3) Ksp (M2'{} = Ksp (QYJ > ~ (PZ:J of these sulphides will be in the order • •
(4) Ksp ~ > Ksp (QY2) > Ksp (PZJ (1) HgS > Ag.fa > CuS (2) Ag~S >~gS >
(~) CuS > Ag25 ~ HgS (4) Ag,fi .> >
. . .. '
'
I.•.._ I ·~- ;
176
 The solubility product of
7 expression :-:-
(1) Ksp = (As3+J x 1s-21
As2S3 is given by the

(3) ~ = !Asa+p 1s-212

1

1:. , ( ' If the solubility of PbBr is 'S

2 ' g molecules per litre
,7.'· considering 100% ionisation
.
its_ solubillty Pt'oduci
is:-
(1) 2S3 (2) .4S2 (3) 4S3 (4) 2S4 '
61f. If the solubility of lithium
7 • alum sodium hexeafluoro
inate Li3NaiAlF_J2 is' •s: mol 1
L- : Its S(?ltibility
product is equal to :- •
' •
(1) 8
S (2) 12 S3.
(3) 18S3 (4) 2916 S8 •
-..,,/ One litre of saturate
7 · evaporated to dryness, dwso lution of C~~O is
hen 7.0 g of residue3 is
left. The solubility product fo
r C ~ O3 is:-
(1) 4. 9 X lQ-3 (2) 4. 9 X lQ-S
(3) 4. 9 X 1Q-9 ( 4) 4. 9 X 1Q-7 .

II:~ -_ -

,. At 30°C, In which of th
'I e one litre solution, the
~ solubility of Ag_ CO .(solubility
~..\ will be maximum
2 3 product = 8 x10-1~
:-
\c}J,&\ (1) 0.05 M Na C0
, (3) 0.05 M AgN 2 3 (2) Pure water
03 (4) 0.05 M NH
3
•
Solu~ility 9f _AgBr will be min I

imum in ·=-
(1) Pure water •(2) O.1 M CaBr
(3) 0.1 ~ NaBr (4) 0.1 M AgN_Os
2

...
In •rh of t}le follo • th
 H) • 1 ,< 10- • 0 1•
~rourn concentration of ~ 1n water ~:a~ Soltbillty product of Mg(O 2 ~ t,egit1 frort1 • / --·
pH, predptation of Mg(OH), ~
If tl1'

1/ lfl 0. 10-3 M
Mat 298 K, Its maximum concentration
W15 o.O11 M NaCl will be:-
(2) o.4 x 1o-4 M •
&/f,j /
M Mg1• solution :-
(1) 9 (2) 5 <3 )
3 • (4) 7

Ill fe(Ot-01
•
15

~ (1) 4 ,< 10-2 M (4) 4 x 1()-4 M 1):1' In the qualltalM! anaJysls of groUP '
'\t.. not precipitated because :- ·gher
(3) 4 ,<
(M.. ts a monovalent metal ion) has a K of , ._, ., (1) The K,. for Fe(OHl1 Is h•---■ (OtfilSpeeded
ff- ,•r-if'°icr,. 298 K. The maidmJm concentrafun ·
'
(2) To predj:itate Fe(OH)2, only SITJCIII
(3) Fe(OH) is a weak electrFo~e fe(OH>2 is +2 •
J; 1-::.;on t),at couJd be a t t a i n e d ~ f u l 2 111
solid at 298 K is :- (4) The oxidation state of e
~iS/
. . M z.n+2 and 0.01 M2 _
,_ of
4
6 >< lo-3 M (2) 2.89 x 10-2 M •
89✓ A solution, containing O.O! H 5 gas. Toe s-
J 3
(1) 2· 8 )( lo-3 M (4) 7.0 x 10-3 M / Cu2• is saturated by passing
2
f ZnS and
~
21
~ (3) • concentration is 8.1 x 10- M,1~ r~~Jy.
ij ich of the fo!lowing has maximum solubility (K I' CuS are 3.0 x 10-22 and S.O x . the solution:-
9/ ~ue is given m brackets) :- "' ~ · Which of the following will occur an
1I 1 (2) PbS04 (1.3 X 1()-3)
h~
J-tgS (1.6 X 10-54)
znS (7. 0 X 1 Q-26) (4) AgQ (1. 7 X 1Q-10)
''/ (1) ZnS will precipitate
(2) CuS will precipitate
(3) Both ZnS and CuS will pre~p~ta~
. •
solution
111
~a,cirnum soluble is :- (Ksp is given) (4) Both 2n 2 • and. Cu2
• will rernalll e
8f 1) cuS (8.5 x 10- )
36
(2) CdS (3.6 x 10-28)
h, 2
znS (1.2 X 10- 8) (4) MnS (1.4 X 10-•0) 9()/Consider (i) Zn(OH), (ii) Cr{OH)• (ii~):~~~
7
1
(iv) Al(OH) which hydroxide is preetP
3
.i' Jo which of_ the following, the solubibty of AgCI NH OH containing NH4CI :-.. .
4
(1) i, ii (2) ~•, -~v ... iv
,will be maximum :-
rw
f (1) 0.1 M AgNO3 (2) Water . ( ) Only iv
3
(4) 1, 11, Ill and
(3) 0.1 M NaCl (4) 0.1 M KCl • ;91:.,.-- What wiD hapP<!l1 If the pH of the solution of 0.001
to pH = 9

r
11ie solubility product of three sparingly soluble salts
are given below :
. Formula Solubility product
t,-<, M Mg(NO:,), solution is adjusted
(K
(1)spMg
(OH) g 9 10-
• x
2 = place
ppt will take
1
2)

No
1 PQ 4.0 x 10-20 (2) ppt will not take place
2 PQ2 3.2 x 10-14 (3) Solution will be saturated
3 PQ3 2. 7 x 10-35 (4) None of these
The correct order of decreasing molar solublity is:- ~ The solubility product constant Ksp of Mg(OH)2
(1) 1, 2, 3 (2) 2, 1, 3 (3) 3, 2, 1 (4) 2, 3, 1 is 9.0 xl0-12. Ha solution is 0.010 M with respect
to Mg2• ion, what is the maximum hydroxide ion
A,,- K value is more for :- concentration which could be present without
~'?\ (1) CuS (2) NiS (3) PbS (4) CdS causing the precipitation of Mg(OH)2 :-
7
..

~w 23 (1) 1.5 X 10·1 M (2) 3.0 X 10- M

84r The K"' value for Gd(OH) is 2.8 x 10- , the pH at
3 (3) 1.5 x 10· M 5 (4) 3.0 X 10· M
5

/ which Gd(OH)3 begins to precipitate is:-

(1) 6.08 (2) 5.08 (3) 8.47 (4) 4.08 ~ When HCl gas is passed through a saturated soution
~ If the solubility product of AgBr03 and As,f,O4 are of common salt, pure NaQ is precipitated because:-
!
1 5.5 x 1o,; and 2 x 1o,; respectively, the relationship (1) The impurities dissolve in HCI
(2) HCl is slightly soluble in water •
between the solubilities of these can be correctly
represented as:· ·• (3) The ionic product (Na•] x (ct] exceeds the
(1) sAgBrO, > sAg,SO, solubility product of NaCl
(2) sAgBrO, - sAg,SO, (4) The solubility product of NaO is lowered by
(3) sA 1 CI- from aq. HCl
gBr03 < sAg2S04. . ' ...... 6 M
t ✓ (4) Can't predict l J.W" .All'"'"'"'"-'., A solution is a mixture of 0.06 M KQ and 0.0

~ 0.5 M HCI solution. has ions· Hg", Cd", s;..♦;

• I Kl. AgNO, solution is being added drop by drop tiD t
Fe++, Cu••. To pass the H.S gas in this solution, IAgCl starts4 precipitating (K,. AgCl - lx Ht·•• and
~ Agl ~
16

~ which are precipitated out :- • :. ;' 10n at this stage will be nearly equal to ·-of-Iodide
x l0- ). The concentration •
~ (1) Cd••, Fe••, Sr' (2) Cd4 , Hg+', a,••· (1) 4.0 x 1()- M 5
(2) 2.4 x 10-; M ,••_:_
I (3) Hg+•, a.,••, Fe•• (4) Cu- , Sr-", Fe 1 4
• (3) 2.0 x 104 M (41 4 x lo-8 M
177
 Pre-Medical
Why only As3+ gets precipitated as As,?3 and not is When any substance YIs~ ,
Zn2+ as ZnS when H S is passed through an acidic• 1 n/. pH of water 7p.H becomes 13. Subst ance~
2
solution containing Asl+ and 2n2• :- ✓-- in water then .i . 1s,
(1) Enough As3+ are present in acidic medium salt of :· , id and strong base
(2) Zinc salt does not ionise in acidic medium (1) Stro~Qa~~ and weak base
(3) Solubility product of As S is less than that of (2) Wea ·d and weak base
2 3
ZnS (3) Stroakng a~d• and strong base
(4) Solubihty product changes in presence of an acid (4) We act
~~ H is shown by aqueous solution of
H2S is passed through a solution of cations in HCI y,3· Minimum P Cl (2) 0.1 M Ba(NQ :•
medium to precipitate cation of :- (1) 0.l
(3) 0.1
MM :ci2 (4) 0.1 MBa(OH)Ja
(1) II-A group of cation analysis 2 2

(2) II - B group of cation analysis

t o4'. Given :· H SO ~) 0.1 M N3iSO
(3) IV group of cation analysis / (a) 0.005 M 2 ' (d) 0.01 M HQ •
(4) Both II - A and 11-B gps. (c) 10-2 M NaOH ,, .
Choose the correct code having same pH :-
y To have more sulphide ion concentration, H2S
should be passed through :-
(1) a, c, _d (2) b, d (3) a, d (4) a, c

(1) 1 N HCl solution 1r Wh tis H• ion concentration of 5 x 10-a MHa<:O

. a. n having a 1ooL d' • t·aon:- a
(2) 0.1 M HCI solution ro 1ssoc1a
soIut10 (2) 10-2
(3) A neutral solution such as water • (1) lo-3 •
(4) An arnmonical solution ( ) 10-1
3 (4) 5 X 10-2
0~ The solubility product of hydroxides of Mg•2, Zn•2, 1 ofi. A metal hydroxide of molecular formula M(OH)
7· and fe• 3 decreases as ✓- is 50% ionised. Its 0.0025M solution will have th;
Ksp Mg(OH) > Ksp Zn(OH) > Ksp Fe(OH)3 The
2 2 pH:-
order of precipitation of hydroxides is:- (1) 12 (2) 2 • (3) 4 (4) 11.7
(1) Fe(OH)3, Zn(OH)2, Mg(OH)2
(2) Mg(OH)2 , Zn(OH)2 , Fe(OH)3 •
107. In the following solutions, the cone. of different
(3) Zn(OH) 2, Fe(OH)3, Mg(OH)2
7- • acids are given, which mixture of the acid has
(4) Zn(OH)21 Mg(OH)21 Fe(OH)3 highest pH :-
, M M M
(1) l0 H2SO4 ,
20 HNO3 , l0 HCIO4
M M M
Two monobasic weak acids have the same (2) H2SO4 , l0 HNO3 ,
concentration of H• ions. What is the relationship 20 20 HC1O4
between dissociation constant and dilution:- M M M
(3) H2SO4 , l0 HNO3 , HCIO4
20 40
1 • M M M
(3) [Ka 1V1 ] 2=Ka2V2 (4)
20 H2SO4 , HNO S
3 , HCIO4 S
~ - What is the molar concentration of chloride ion in ~ !f 1~0 mL of pH = 3 and 400 mL of pH • 3
the solution obtained by mixing 300 ml of 3.0M 1s mixed, what will be the pH of the mixture
NaCl and 200 mL of 4.0 M solution of BaCl :- (1) 3.2 (2) 3.0 (3) 3.5
2 (4) 2.8
(1) 5.0 M (2) 1.8 M
(3) 1.6 M (4) None of these 9>9. 1~ M liCI is diluted to 100 timeS. Its pH Is~ I
f!e!.· The pH of a 0.1 M ~ormic acid 0.1% dissociated JlO· (1) 6.q (2) 8.Q • (3) 6.95 (4) 9.5
j
1
'

is equal to 4. What will be the pH of another weak pH of 0.00lM acetic acid would be :-
monobasic acid (same concentration) which is 1% (1) 2 (2) > 3 . (3) 7 . (4) 14 •
dissociated . \
!)'i. At 9oac, the pH of 0.001M KOH sdullon wll
(1) 2 (2) 3 •(3) 1 .• (4) 4 be . ·. . ...

178
.. -(1) 3 •• : (2) 11 r (3) i
 p}'I of solution ls Increased fr , chernisf,Y
rt~ be ._ orn 3 to 6. Its
0
concentratio n Will
~ The PH of a 0.02 M ammonia solution which ~
J}' tf• :ec1uced to half • •• .,,...,
5% ionised will be •-
(1) poubled {1) 2 (2) 11.· (3) 5 (4) 7
(2) ~educed by 1000 times
(3) '""creased by 1000 times
(4) "'
salution_ has pOH equal to 13 at 298 K
~ For ,Po H~4, pH value is :-
,ti A non will be:- . • The (1) 1. (2) 0.586 (3) 0.856 (4) None
If 1:UHighly acidic . • (2) Highly basic
J.24. An aqueous solution of HCI is 1o-9 M HCI. The
( ) ~,oderately basic (4) Unpred·
(3 1•l tctable •
pH of the solution should be:-
'fhe pH of the solution containing 10 rnL f {1) 9 (2) Between 6 and 7
H so ulod a 0. lM (4) Unpredictable
1 ,.,,,aoH and 10(2)ml1 of 0.05M
1i
r ( 2 4 \VO be -- (3) 7 ••
(1) iero 3) >7 (4) 7
J.25.!. H~ is 'a dibasic acid which dissociates completely
,an..ich of the following statements a re ('ts) correct -=- in water. Which one of the following is the molarity
vv l • f
(a) The pH o 1.0 x 10-s M solution of HCI . 8 of an aqueous solution of this acid which has a.
pH of 1 :-
(b) The conjug~te base of H 2PQ-4 is HPO ;~ • (1) 0.1 (2) 0.05 (3) 0.2 (4) 0.5
(c) Autoprotolys1s constant of water increase: •.
temperature. 1
with J2'6. How many moles of HCIsolution
must be removed from
to change its pH
(d) When a solution of a weak mono. ti •. 1 litre of aqueous HCI
· t d • pro c aad
is t1tra e agamst a strong base t h If from 2 to 3 :- .
neutralization point pH = 1/2 pKa' a a (3) 0.00_9_ (4) 0.01
(1) a (2) a, b (3) a, b, d (4) b, c
(1) 1 (2) 0.02
..
~ - 8 g NaOH and 4.9 g H 2S04 are present in one
,. In a solution of pH = 5, more a~id is added in litre of the solution. What is its pH
11
7 order to reduce the tpH. = 2. The increase . (1) 1 (2) 13 . (3) 12 (4) 2
. m
hydrogen 10n concen ration is:- •,
. (2) 1000 times • ~ - Calculate pH of a solution whose 100 mL contains·
(1) 100 times
(4) 5 times 0.2 g NaOH dissolved in it :-
(3) 3 times (2) 11.699
(1) 10.699
tv-'
The hydrogen ion concentration in a given· solution
is 6 x 10-4 M. Its pH will be :-
• (3) 12.699 (4) 13.699

. (4) 2. . J.29. One

litre solution contains 1M HOC) [I\,= 1o-s]
(1) 6 (2) 3.22 (3) 4
'
and I
1 M NaOH. What is the pH of the
U~The pOH of beer is 10.0. The hydrogen ion solution :-
/ concentration will be :- - (1) 8 (2) 11 (3) 5 (4) 2
Kw Kw ~ What is the quantity of NaOH present in 250 cc o{
(a) 10-10 (b) 10-10 (~) 10-s (d) 1Q-4 • the solution, so that it gives a pH= 13 :-
(3) a, b, c (4) None (1) 10-13 g (2) 10-1 g (3) 1.0 g (4) 4.0 g
(1) a, d (2) b, c

lY!· An aqueous solution whose pH = 0 is :- !J1· 0.001 mol of the strong electrolyte M(OH) 2
has
*A (1)(3) Basic
Neutral •
. (2) Acidic
(4) Amphoteric
been dissolved to make a 20 mL of its saturated
solution. Its pH will be : - [1', = 1 x lQ-14)
(1) 13 (2) 3.3 (3) 11 (4) 9.8
1
l~The pH of the solution produced when an aqueous
1 solution of strong acid pH 5 is mixed with equal J,62. Choose the wrong statement :-.
volume of an aqueous solution of strong acid of (1) For a neutral solution : (H+) = [OH-]= ~
pH 3 is :-
(1) 3.3 (2) 3.5 (3) 4.5 (4) 4.0 (2) For an acidic solution : (H+) > ~ and

Following five solution of KOH were prepare as-

F'~t ➔ 0.1 moles in 1 L
[OH-J < Fw
Second ➔ 0.2 moles in 2 L (3) For a basic solution : (H•] •< ~ and
Third ➔ 0.3 moles in 3 L • . '
Fourth ➔ 0.4 moles in 4 L (OH-J > ~ .·
Fifth ➔ 0.5 moles in 5 L (4) For a neutral solution at· all temperatures :
The pH of resultant solution ls :- ·' [H•J • [OH-J • 10-7 M
{1) 2 · , • (2) 1 (3) 13 - • • (4) 7

179
 Pre-Medical
f HCN ls 5 x 10-10 at 25oC. For tnal n~
~ !'3 • The pH of 0.1 M solution of the following salt! . Ka or pH of 9 the \Olume of SM ~ Solt~
increases in order :- ,• ~ ~;:: ~be add ~to 10m lof2 MH CN ~
(1) NaCl < NH 0 < NaCN < HCI
4
(2) NaCN < NH Cl < NaCl is- (2) 7.95 mL
< HCI (1) 4 ml
(3) HCl < NaCl :: NaCN < NH Cl (4) 9.3 ml
(4) HCl < NH Cl < NaCl < (3) 2 ml
4 NaCN 6
ff ri g action of a mixture of CH3COOH
X
4• ~H,
~ioN a is rnax1mum when the ratio of::
9'. In a buffer solution the ratio of concentration ?f.
NH4CI and N}-f OH is 1 : 1 when it changes m
to acid is equal to -
(1) 1.0 (2) 100.0 (3) 10.0 • (4) 0.1
4
2 : 1 what wiR be the value of pH of buffer :- 14'5 Te pm . k colour of phenolphthalein in allrsh.._
h • "lQlllle
(1) Increase ' (2) Decrease ✓- - medi um is due to - •. :
~ (3),No effect (4) N.O.T. (l) Negative ion (2) Positive ion
( ) oH- ions , (4) Neutral form
~ To a' 50 mL of 0.05M formic acid how 3
much
volume of 0.l0M sodium formate must be added 1 &6 Which indicator works in the pH range 8 -
9.8
to get a buffer solution of pH= 4.0? (pK. of the :;;-· (1) Phenolphthalein : (2) Methyl orange
acid is 3.8) (3) Methyl red (4) Litmus
(1) 50 ml (2) 4 mL (3) 39.6 mL (4) 100
ml..
5%6~ In the volumetric estimation of HQ, if we make 1
use of phenolphthalein as an indicator, which base
✓-
4,;f',. A basic - buff er will obey the
• pOH • pl\ = 1 only under condition:-
equation

. (1) [Conjugate acid) : [base] = 1 : 10

is unsuitable for the titration :-
(1) NaOH (2) [Conjugate. acid] = [base]
(2) RbOH - (3) [Conjugate acid) :- [base] = 10 : 1 •
(3) KOH .(4) NH4 OH .. (4) N.O.T
~ In 'a mixture of weak acid and its salt, the ratio JAB· for weak acid strong base titration, the indicator
7....:., of concentration of acid to salt is increased
ten- used is :-
fold. The pH of the solution :-
(1) Potassium di-chromate
(1) Decreases by one (2)Increasesbyone-tenth (2) Methyl orange
(3) Increases by one (4) Increases ten-fold (3) Litmus
~ - pK,, for NH OH at certain temperature is 4. (4) Phenolphthalein .
4
The pH of basic buffer containing equimolar 74. ,
~ ~- From the fallowing in which titration methyl orang
concentration of NH OH and NH Cl will be:- e
(1) 7.74 4 4 ';/Vv-is a best indicator :-
(2) 4.74 (3) 2.37 (4) '9.26 (1) CH3COOH + NaOH (2) H2C20 4 + NaOH
tf;;;f..What is the suitable indicator for ti~ration of NaOH
(3) HCl + NaOH (4)Q i3(X)()H+NH40H
7~ · and oxalic acid:- ,· ~ - The total number of different kind of buffer
(1) Methyl orange s
(2) Methyl red obtained during the titration of H PO with NaOH
(3) Phenolphthalein (4) Starch solution are :-
3 4

~ 4<>. Phenolphthalein does not act as an indicator for c. (1) 3 (2) 1 , (3) 2 •
~ the titration between :-
(1) KOH and H 2SO4
% (4) 0
The H• ion concentration in 0.001- M acetic acid
'\ is 1. 34 X 1Q-4 g ion L-1. The H+ ion"~oncentration
(2) NaOH and CH3COOH of 0.164 g of CH C°'ON~ Js-added to a litre of I

II
3
(3) Oxalic acid and KMnO4 0.001 M CH COOH wiQ ~e· :- • • • -..
3
(4) Ba(OH)2 and HCI / (1) 9 x 10-6 • '- -(2) 18 x lo-6
(3) 4.5 X 10-6 ', (4) 5 X 1~ _
~ - Which c~n act as buffer :-
~ - (1) NH 0}i +) NaOH ¢. A certain acidic buffe; ~olution contains eq~al J
4
(2) HCOO!°t + CH3COO,Na , co~~entrat~on of x- and HX. The I\ for_~- ~
(3) 40 mL l):1 M NaGN + 20 mL of 0.1 M HCI . 10 .. The
..
pH of the buffer is :- . · •... _.,,
(4) None· o6JJ:iem . ' • (~).4 . _ (2) 7 (3) 10 . ' ~ lJ~
yh. (1)The buffer solution play an importa:it ~le in·:·, ~When 1.0 mL of dll. HO acid 1s•acllW t-:i toO
Incre asing the pH value • •• ' • ml of a buff • solution of pH 4.0. ~~
(2) Decreasing the pH value •
. solution · ·· .
• •
• •
4, -
(3) Keeping the pH con :,t -. (1) Becomesii • (2Ji& J!QI ~~

(4) Solution will be neu .,. I, - ~ Bec ona 2 1 ~ 5ea s~

 ' • Chemi•try
1h' pt-I of blood is malntalned by CO
,ii- "'° t,ody and chemical constt I 1111d H,co J'S· 0,05 Mammonium hydroxkl• solution Is dlsSolved
7 ;;.is p1t.momenon Is called :• luents of blood~ M ammonium chlortd• 10lutlon, Whal
In 0.001
(U eoUoldal -~~. (2) Buffer • wlll be the OH· ton concentration of this 90lut1on
~) Acidity ance (4) Salt baacltlon : l\(NH.OH) • 1.8 x 10 1
,..,
(1) 3.0 >< 10-s (2) 9.0 >< 10~
phCnolphthak!in is not a good indi 4

1f· (ll N<1OH against oxalic acid cator for titrating

(3) 9.0 )( 10·3 • (4) 3.0 )( 10
(2) {'loOH against HQ , ~- When 0.02 moles of NaOH are added to a litre
(3) NaOH against H:lSO4 , of buffer solution, Its pH changes from 5. 75 to
(4) ferrous sulphate against KMno 5.80. What ls Its buffer capacity :· • --
4
(1) 0.4 (2) 0.05 (3) - 0.05 (4) 2.5
rJ \lJhich of the follo\,~ng solution d •
17 . t,uffcr :-
1 s oes not act as ~- Calculate the pH of a buffer prepared by ~l~lng
(1) H,P04 + NaH2PO4 , , • 300 cc of 0.3 MNHs and 500 cc of 0.5 MNH40.
(2) NaHCO, + H2C03 I\ for NH3 • 1.8 x 10.s :·
(3) NH,Cl + HCl (1) 8.1187 • (2) 9.8117
(4) CH3COOH + CH 3 COONa : • (3) 8.8117 (4) None of these

. so ml ~f 2N acetic acid mixed with 10 mL of ~ - What amount of sodium propanoate should

151
/ tN so~1un1 acetate solution will hav be added to one litre of an aqueous
approxnnate pH of (K_ • 10-s) :- r, e an solution containing 0.02 mole of propanoic acid
(4) 7 (Ka • 1.34 x 10-5 at 25°C) to obtain a buffer
(1) 4 (2) 5 (3) 6 ,1
solution of pH 4. 75 :-
,,. On addition of NaOH to CH3COOH solution, 60% (1)' 4.s2 x 10-2 M (2) 3.52 x 10-2 M
(3) 2.52 x 10"2 M (4) 1.52 X 10··2 M
of the acid is neutralised. If pK.i of CH3COOH
is 4. 7 then the pH of the resulting solution is :- 1?, What will be trye pH of the solution, if 0.01 moles
(1) More than 4. 7 but less than 5.0 . of HCI is dissolved in a buffer solution containing
(2) Less than 4. 7 but more than 4.0 • 0.02 mol~ of propanoic acid (K. • 1.34 x 10---"')
(3) More than 5.0 and 0.0152 moles of salt, at 25°C : •
' • i • I
(4) Remains unchanged [log(0.173) • -0. 76)
' I
(1) 3.11 (2) 4.11 (3) 5.11 (4) 6.11
1r, 500 ml of O. 2 M acetic acid are added
to 500 ml of 0.30 M sodium acetate ~ - Calculate the pH of a buffer solution prepared by
solution. If the dissociation constant of acetic acid dissolving 30g of NazCO3 in 500 ml of an aqueous
x
is 1.5 10-s then pH of the resulting solution solution containing 150 ml of 1M HCI. Ka for
is :-
(1) 5.0 . 9.0
(2) (3) 3.0
I
. (4) 4.0 HCO3- - 5.63 x 10 11 [ log G!~) ~ -0. 05]
(1) 8.197 (2) 9.197
1,0, Half of the formic acid solutio~ is neutralised on (3) 10.1Q7 (4) 11.197
addition ·of a KOH solution' to ( it. If
K (HCOOH) = 2 x 10-4 then pH of the solution ~Calculate the "ratio of pH of a solution containing
1
is : Oog 2 = 0.3010) ' 1 mole of CH3COONa + 1 mole of HCI per litre
(1) 3.6990 (2) 10.3010 (3) 3.85 (4) 4.3010 and of other solution containing 1 mole
l ,
CH COONa + lmole of acetic acid per litre :-
1~ A solution contains 0.2M NH 40H and 0.2M 3
(1) 1: 1 (2) 2: 1 (3) 1: 2 (4) 2: 3
NH Cl. If 1.0 ml of 0.001 M H~I is added_ to • ,.
4
it. What will be the [OH·] of the resulting ~olution , M .
"'b • 2 X 10-s) ·-
(K . • ' ' I , ,,! -~
l :!JY. When 20 ml of 20 NaOH are added to 10 ml
10
(1) 2 X 10-5 (2) 5 X 10- t • I •
'
t • ;

(3) 2 x 10-3 (4) None ,of these , . ;· : : , I' • • C' .

• •

• ,. I • • ,
of
M HO, the resulting solution wlll:·
l ~✓ ~ ··
1
• 1 • I •• • K,• • 1 iwill be
1
10 • •,' • .. •

,c.. Hunderson
I

equation . pH .- P • ,~- . (1) Tum blue btrnus red : ~

• -.

applicable to 'an acidic buffer when :-

• I '

. ,,.. (2) Turn phenolphthaleln. solution

1 ..
' (1) [Add) - [Conjugate base) · · • ; .; •• :{ •
(3) Turn ~ ~ red
•M ' •

. _on;.~ red or. ~ litmus

(2) [Acid] x 1O • [Conjugate base] . _ /;.•
.. n• ., . (4) WlD ~ve no effec;t .
(3) [Acid) - (Conjugate base] x 10 • ' ' .. ;
(4) None of these h /"'• • .' ~ ,\
 Pre-Medical
171 • 10 ml of a solution oontai +
ns 0.1 M NH40+ 0.01 I Jugated base of (CHJ2 NH2 ls :•
/ M NH.OH. Which addition would not chang e the y,1. The con (2) (CHJ~•
pH of solution :- (1) CH3NH2 (4) (CHJ2NH
(l) Adding 1 ml water (3) (CH}iN
(2) Adding 5 ml of 0.1 M NH Cl
4 -.I.. h. h equilibrium can be described as lewis ~
(3) Adding 5 ml of 0.1 M NH OH 1}.f4' • W ic
(4) Adding 10 ml of 0.1 M NH Cl
4
., base reac tion but not Bronsted acid
, base reacu~
..,,,:.
4
(1) H20 + CH3COOH ~ H30• + CH3CO(}
N
)'12. 10 acetic acid was titrated with N NaOH. When•
10 (2) 2NH3 + H2SO4 ~ 2NH; + ~·
25%, 50% and 75% of titration is over then the
pH of the solution will be :- [I<_ • 1Q-!:•] ( ) NH + CH3COOH ~ NH; + CH3COQ-
3 3
(1) 5 + log 1/3. 5, 5 + log 3
(4) Cu+2 + 4NH3 ~ [Cu(NHJ412•
(2) 5 + log 3, 4, 5 + log 1/3
(3) 5 - log 1/3, 5, 5 - log 3
(4) 5 - log 1/3, 4, 5 + log 1/3
13. Conjugate base of hydrazoic acid is :-
(1) HNj (2) N; (3) N3- (4) N2

,84. NH gas dissolves in water to give NH 4OH, in this

173. The conjugated acid of 0-2 ion's is :- 3
./ (1) 0 2+ ,~-- reaction, water acts as :-
(2) H• (3) H3 O• (4) OH-
(1) An acid (2) A base
/
)14. Ionization constant of AOH and BOH base are (3) A salt (4) A conjugate base
Kb and Kb2 • Their relation is pKb < pK~ . 18'~- Conjugate acid
1 1 of Zn(OH)2 'is :-
Conjugate of following base, does not show y (1) Zn(OH)• (2) Zn(OHJ· (3) Zn2• (4) None
maximum pH: ,,.
(l)AOH (2) BOH ,186.- When ammonia is added to water it decreases the
(3) Both of them (4) NOT •./. • concentration of which of the following ion
; (1) OH· (2) H 30• · (3) NH•4 • (4) None
17 5. Select the species which can function as - Lewis
v
base, bronsted acid and bronsted base:- 187. The strongest acid among the following is -
V (1) CIOiOH) (2) C1O2(OH)
(b) NH; (c) N-3
(3) SO(OH)2 (4) SO2(OH)2
Correct code is :- , I

(1) Only a (2) a, b (3) a, C (4) b, c 188. Which of the following is not a Bronsted acid:-
/ -.. (1) CH3NH4• ,. , (2) CH3Coo-
J76. Which ion does not show acid behaviour :-

r
(3) H 2O (4) HSQ4-
3
(1) [A1(H20)6 (2) [Fe(H 20)l ~ \~ ~89. Which of the following example behave~ a Lewis
(3) HPO4 - 2 1cid BF3 , SnC1 , . SnC1 :- , •
(4) CIO; 2 4
~ ............\
(1) Stanus chloride , stanic chloride
1177. An example of Lewis acid is:- (2) BF3 ,. Stanus chloride
v (1) CaO (2) CH3NH2 ,
(3) Only BF3 i
1
(3) SO (4) None of these ···-.. (4) BF , stanus chlori de, stanic chloride
3 , 3
J t ' I

~ 90. In the reaction

ps. In the reaction NH3 ~ H20 ~ NH + + OH-water -~
4
~

HNOa + H20 ~ H Q• + NO - the c~njug-ate

behaves as :- . 3 ·1 3
(1) Acid (2) Base
base of HN0 3
is :· . . . . . . . •. .; .
(3) Neutral (4) Both acid
(l) H20 • , .
2) H 0~
_J.ri. Which ·acts as 1.ew1s i:;.; 1n the
Bel, + :PHa ➔ Ca8 +-
(1) PH
(3) eoit 1 & 2,
. Which
Sneli +
a-
(1)

12
 • Is - - than AJ3+ :- .
' ~511'0°9 Lewis add (2) St · Chemi1fty
(3) • ea lewis base (1) ~ Is a.:- .
Bronsted bases i th (2) eak conjugate base
/ 'fb' twO PO4~ __,,. n e teactlon S!rong conjugate base ·
1r· r.c,O; + ~ 1-fPot + c O 2- . (3) Weak conjugate acid

I ) t{Cp4• and P04 •

2
• are ~.1 ~ , (4) Strong conjugate add • .
(1 t{l'()t and C20t 1_'1P. 206
(2) p0 )- and Cp •
2
• ;;;/ ✓ • Which of the following 1sstrongest conjugate base
(3) t{C:0; and HP0t • (l) ao.- 4
(2) HCO; (3) F- (4) HSQ •
(4) 207 Wh w. r-. .
/ ~ compound HCI behaves as __ . .,, • baselch of the following species can act as Lewis
P· ,,,e ~ H• - in the reaction :- .
~ t-1C1 + HF ~
(1) Strong acid
Cl + F2
(2) Str
'
.,
{1) Cu2• (2) Ala
3 ·
(3) NH
3
(4) BF
3

(3) Weak acid (4) W~~g~ 3os. A compound having the formula NH2CH2COOH
se may behave :-
9'•Which of the following is not a leWi b (1) Only as an acid
2
I, • (1) NH3 (2) 0 • (3) H O . s (~1:·
2
· (2) Only as a base
J ·ch of the followin • (3) Both as an acid and base
st
197, Wh•so -2 (2) H O• g lS(3b)ron ed LoWry acid:- (4) Neither acid nor base
" (1) 4 3 OH- (4) Ct • /
3P9. (1) is acid according to :-
BF3lewis
ll~ The conjugated base for bicarbonate ion Is·-
'I y(1) CO/" (2) HCO • . • (2) Arrhenius
~ (3) CO2 . •• (4) H2cd3 (3) Bronsted and Lowery • • •- •--·. • •
/ (4) Madam Curie
191 9. Conjugated base of OH- is :-
(1) H20 (2) H30• (3) H• (4) 02- 1. 3J 0. ~ich of the following can act both as Bronsted
~ HCl does not behave as acid in :- acid and Bronsted base :-
(1) Na2C03 (2) ()2- ·
.; (1) NH3 (2) Cfi5OH (3) H2O
(3) C032 (4) NH3 •
~{. Which of the following is a base according to Lowry- 2·1 { The strongest conjugate base Is :· •
Bronsted concept :- v
(1) 1- (2) H30+ (3) HCI (4) NH/ (1) NOj (2) er .
202. In which of the fallowing reactions NH3 acts as (3) so~-
" acid '

(1) NH3 + H~l ➔ NH4Cl ~ 2. Aluminium chloride is :- • .

(2) NH3 + H+ ➔ NH/ l (1) Bronsted Lowry acid (2) Arrhenius acid
(3) Lewis acid (4) Lewis base
(3) NH3 + Na ➔ NaNH2+ H2 . . .
2 /
213. Water is a :- .
(4) NH3 cannot act as acid
✓ (1) Protogenic solvent . (2) Protophillc solvent
29'- According to Bronsted concept, the acids in the (3) Amphiprotic solvent (4) Aprotic solvent
following reaction NH3 + !""f20 ~ NH4++ OH· I

• I
214. Ammonium ion is :- ,
I are :-
(2) H20 and OH· v- (1) A conjugate acid
1 (1) NH 3 and NH 4•
(4) NH3 and OH· • (2) A conjugate base .
(3) H20 and NH4•
(3) Neither an acid nor a basic
~ Consider the following reactions :- (4) Both an acid and a base
,,.

1 r~ Co:- + Hp .== ttco; +ott· 215. Species which do not act both as Bronsted a~d
'-' and base ls :- • ·
{ii) CO2 + H20 ~ H2C03
. (1) (HSOJ-1 . . . (2) NaaCO~ . , .
("·).NH • Ha__,).· NH OH •. . (3) NH3 . : ' .(4). OH-.1. . •. - I . • •
lll 3+ 2 ~; .• +l
(iv) HCI + H O ~ Ct + H30 ,·. .
2 ~ ves that water e Which
; Which of the pairs of ~ons pro ; . . ·. ' •·- & Bronsted add & bronsted baa:-
'
0~ of the followlng ls strong lA4s ~

Is amphoteric in 4 ;· (ii) and (Ill) • • ,

(2) (') and (W) :__ .
•• • (1) NH3 (2) PHs- ~ (3) (4)Bla
.
· °'•
i (1) (i) and tu) • • • I
. . . . . . . . . &. ••• - - • • - ... • ...... •

4 I.
_. ---

(3) (iii) and (iv) . . •

 Pr:-·M.d;cal
t , ' •-~~... r Which of th
·, r: :-'(,
V' base & I I~ ."- -
e 10. _.., uag pair Is Lewis add
& l..ewls /

• 11) BF ~ of thae Is also 2 J g~ For the reaction NHc + 5-1..

,

3 lewis base at NH _~ ~
(J) CH • 3 .,, and 5-1 are a group of: · · ,·
3
• (2)
0
s1a, . 2e t (1) Adds
~
, ,, ' 0C1is(4) None of these , (2) Bas~
:>- ~18. Which of the f U (3) Acid-base pair
tbe.e . (4) None of
(1) Arrh O
OWlng Is not a correct statement
ex ~n~us lheory of acids-bases 2 20. Ac cording to Lewis concept add & bas
e
1 is capable of v (1) HO·, H•
p aimng the acidic or basic nat
ure of the (2) Ag♦ .Q'" ~ '-
substances
(2) Arrhenius in the solvents oth (3) Bf 3,NH3 4
er than water• ( ) None of ~
of Al a theory does not explain
acidic nature
3
(3) The aque •
ous 1
although 1·t d so utlon of Na2CO is alkaline
(4) A oes not contain OH3· ions
queous sol t'
u ton of CO is acidic althoug
•
h it
does not contain H• ion2s
• I

, EXERCISE-I (Conceptual Questions)

1 1 4 3
25 .. ·26'' 27 · . 28
1 1 1 3
Ans. 3 3 4 1
40 • 41 ' '42 · 11-,43
2 4. 4 3 2 1 1 4
55 56 57 .
4 2 4
Ans. 4 1 3
.70 7l 72
3 3 4 3 4 1 4 2
,ss •. 86 ,87
3 2 1
Ans. 2 4 3 100 101 102
2 3 4 4 1 2 1 4 2
An s. 4 3 115 116 117
2 3 2 4 3 1 4 4 2 2
il3 0 •131' 132
3 1 4 4
Ans. 145 .146 147' ·t4 8 I
4 1 4 3 3 3 3 3 1 1 1 3 4
158 159 160 161 162
163
1 1 1 1 2 2
-173 174 175 176 177
3 3 4 1 1 178
4
88-:. ft184~ \J85·· t18 187· 188

184
I Kp<~ 4U. Which one of the following informati on 1can be
obtained on the basis of Le Chatelier principle?
1
1 K =- (2014) (a) Dissociat ion constant of a weak acid
P K' (b) Entropy change in a reaction
p
• ~

:Jm K2 Mn0 4 as per the (c) Equilibri um constant of a chemical reaction

(d) Shift in equilibriu m position on changing value
1104- + Mn02 + 40H- of a constrain t · . (1992)
1npletion by ren1oving

so2
cm Ionic Equilibrium in Solution' '
41. Aqueous solution of which of the following
KOH (2013) compoun ds is the best conducto r of electric current?
. (a) Hydroch loric acid, HCI
10n

ss than zero. (b) A1nmonia, NH

3
(c) Fructose, C H 0 .I
lVOured at 6 12 6
,
(d) Acetic acid, C2H 0 (2015)
;11 pressure 4 2
42. Aqueous solution of acetic acid contains
lperature (a) CH3 Coo- and H+ •
., pressure
(b) CH3 Coo-, H 3 0+ and CH COOH
3
nperatur e. (2011) (c) CH3 Coo-, H 0+ and H+ ..
3
(d) CH3COOH, CH3Coo- and H~ • (1991)
+ 2H2 0(l)' 1 •
(Ifil Acids, Bases an~ Salts
I •

1ich of the follo,ving . _. .

43. Amongst the given options which of the following
.C.
. . . • molecule s/ion acts as a Lewis aci~? . ' {ii)
 52 MbG- NEET-AIPMT Chapterwise Topicwise Solutions

47• Which of these is least likely to act as a Lewis base?

(a) BF3 (b) PF3 (c) CO (d) F (2013)
@I) lonizatiOn of Acids and Bases .
59. For a weak acid HA, the percentage of..,.·-.a,.L,.g
48. Which is the strongest acid in the following? is nearly I96 at equilibrium. If the concenthtt_ ..
(a) HCIO4 (b) H2SO3 1
acid is 0.1 mol L- , then t~e correct optio~
{c) H2SO4 (d) HCIO3 (2013) K at the same temperature 1s
49. Which one of the following molecular hydrides acts (aa) 1 x 10-4 (b) 1 X 10-6
as a Lewis acid? (c) 1 x 10-s (d) 1 x 10-3
(a) NH3 (b) H2O •• (ManipurNEEr
(c) B2H6 (d) CH4 • (2010) 60. The pKb of dimethylamine and pK, of~~ 6
50. Which of the following molecules acts as a Lewis are 3.27' and 4.77 respectively at T(K). The
acid? option for the pH of dimethylammoniwn ~
(a) (CH3) 20 (b) (CH3) 3P solution is (A
(c) (CH3) 3N (d) (CH3) 3B (2009) (a) 6.25 . (b) 8.50 ~
51. Which one of the following statements is not true? . (c) 5.50 (d) 7.75 . (202, 6
(a) Among halide ions, iodide is the most powerful 61. Find out the solubility of Ni(OH?2 in 0.I_ M Nao~
, reducing agent. Given that the ionic product ofN1(OH) 2 1s 2 x IO"IS
(b) Fluorine is the only halogen that does not show (a) 2 x 10-13 M (b) 2 x 10-8 M •
•a variable oxidation state. • 8
(c) 1 x 10- ! M
1 (d) 1 x 10 M .(2020J
(c) HOCI is a stronger acid than HOBr. 1
(d) HF is a stronger acid than HCI. (2003) 62. The pH of 0.01 M NaOH(aq) solution will be
(a) 7.01 (b) 2 (c) 12 (d) 9
52. Which one of the following compounds is not a
. (Odisha NEET 201~
. protonic acid?
(a) B(OH)3 (b) PO(OH)3 .. 63. Following solutions. were prepared by ~
(c) SO(OH)2 . (d) SOi(OH)2 (2003) different volumes of NaOH and HCI of differeq 1
concentrations :
53. In HS-, r, R - NHv NH3 order of proton accepting
tendency will be A. 60mL MHCI +40mL MNaOH
1
10 10
(a) r>NH3 >R-NH2 >HS- ' M
!

M ,
(b) NH 3 > R - NH2 > HS- > Y-
(c) R- NH2 > NH3 >HS-> Y- ••t
a -
B. S~mL-HCl +45mL -NaOH
10
M
10
M
7

(d) HS-> R-NH2 > NH3 > Y- (2001) C. 75mL-HCl +25mL -NaOH
5 5
54. Conjugate acid of NH; is M M
(a) NH4OH (b) NH; , . D. l00mL-HCI +l00mL -NaOH
10 10
(c) NH2 1 (d) NH3 (2000) i
pH of which one of them will be equal to 1?
55. Which compound is electron deficient? (a) B (b) A (c) D (d) C (2011)
(a) BeC12 (b) BC13 '
64. ~e percentage of pyr~dine (C5H5N) that forms
(c) CC14 (d) PC15 (2000)
pyridinium ion (C5H5NH) in a 0.10 M aqueo11
56. The strongest conjugate base is pyridine solution (Kb for C5H5N = 1.7 x 10-9) is ..
J
(a) so;- (b) ci- (a) 0.0060% (b) 0.01396
(c) NO3 (d) CH3COO- (1999) (c) 0.77% (d) 1.6% (NEET-11201~
57. Which of the following is not a Lewis acid? 65. What is the pH of the resulting solution when
(a) SiF4 (b) C2H4 equal volumes of 0.1 M NaOH and 0.01 M HO are
(c) BF3 (d) FeC13 (1996) mixed? .. ,ft
58. Repeated use ofwhich one of the following fertilizers (a) 2.0 (b) 7.0 , 'II'
would increase the acidity of the soil? (c) 1.04 (d) 12.65 (2015)
(a) Ammonium sulphate 66. Which of the following salts will give highest pH Ill
(b) Superphosphate of lime water?
(c) Urea (a) KCl (b) NaCl
(d) Potassium nitrate (1998) (c) Na2CO3 (d) CuSO4 ••
 53

~&ccUJ'll
u}ation of lacti~
'd • • l
acid (HC H o ), a
ds 3 s 3 .
(a) 1.0 x 10-8 M . (b) 1.0 >< lo-'~
1, r- obasic ac1 m tissues ea to pain and a feeling (c) 1.0525 x 10-7 M (d) 9.52S x 10- M (2006)
6
fl1:tigue, In a 0.10 M aqueous solution, lactic acid is 77. At 25°C, the dissociation constant of a base. BOH,
of dissociated. The value of dissociation constant, is 1.0 x 10- 12• The concentration of hydroxyl ions in
3.170, this acid will be . . 0.01 M aqueous solution of the base would b~
5
i_, 14 >< 10- • (b) 1.4 x 10-4 ..
(a) 1.0 x 10-s mol 1-1 (b) 1.0 x 1~ mol L-
1
(a) ·7 x 10_. (d) 2.8 x 10-4 • (c) 2.0 x ~o-6 m~l 1- 1 (d) I.Ox 10-7 mol L- (2005)
3
(c) • , (Karnataka NEET 2013) 78. Which has highest pH?
100°c the ¾ of water is 55 times its value at (a) CH 3COOK (b) N¾CO3
(c) NH4Cl (d) NaNO3 . (2002)
68· Atoe What will be the pH of neutral solution?
25 • 5
55::: 1.74) 79. Ionisation constant of CH3COOH is 1.7 x 10-
(~~g 7.oo (b) 7.87 (c) 5.13 (d) 6.13 and concentration of H+ ions is 3.4 x 10..... Then find
( (Karnatak a NEET 2013) out initial concentration of CH3COOH molecules.
(a) 3.4 x 10-4· (b) 3.4 x 10-3 •
uirnolar solutions of the following substances (d) 6.8 x 10-3 (2001)
(c) 6.8 x 10-4
69, Eq prepared separately. Which one of these will
were • 80. Correct relation between dissociation constants of a
the highest pH value?
record . dibasic acid is
(a) BaCl2 (b) A1Cl3 :
(c) LiCl (d) BeC12 (2012) (a) . Ka1 =Kai
What is [H+] in mol/L of a solution that is 0.20 M 1
(d) Ka1 =K
- (2000)
70, . CH COONa and 0.10 M in CH3COOH? Oi
1n 3 -5)
(Ka
for CH3COOH = 1.8 x 10 81. Which stateme~t is wrong about pH and H+? . ,
-5
(a) 3.5 x 10-4 (b) 1.1 x 10-6 (a) pH of neutral water is not zero.
(c) 1.8 x 10-5 (d) 9.0 x 10 (2010) (b) Adding 1 N solution of CH3COOH and 1 N.
The ionization constant of ammoniu m hydroxide solution ofNaOH, pH will be seven.
71
' is 1.77 x 10-5 at 298 K. Hydrolysis c~nstant of (c) [H+] of dilute and hot H2SO4 is more than
ammonium chloride is concentrated and cold H 2SO4 • {6)
13
(a) 6.50 x 10-12 (b) 5.65 x 10- (d) Mixing solution ofCH3COOH and -
(c) 5.65 x 10-12
10 (2000)
(d) 5.65 x 10- (2009) HCl, pH will be less than 7.
What is the [OH-] in the final solution prepared by 82. The concentration of [H+] and concentra tion of
72.
mixing 20.0 ml of 0.050 M HCl with 30.0 ml of [OH-] of a 0.1 aqueous solution of 2% ionised weak
14
0.10 M Ba(OH) 2? acid is [ionic product of water= 1 x 10- ]
12
(a) 0.40 M (b) 0.0050 M , (a) 2 x 10-3 Mand 5 x 10- M
(c) 0.12 M (d) 0.10 M (2009) (b) 1 x 10-3 Mand 3 x 10- 11 M
73, Equal volumes of three acid solutions of pH 3, 4 (c) 0.02 x 10-3 Mand 5 x 10- 11 M
and 5 are mixed in a vessel. What will be the H+ ion (d) 3 x 10-2 Mand 4 x 10- 13 M (1999)
concentration in the mixture?
3
{ft) 83. The hydride ion H- is stronger base than its hydroxide
3
(a) 3.7 x 10- M (b) 1.11 x 10- M - ion OH-. Which of the following reaction will occur
4
(c) 1.ll x 10- M (d) 3.7 x 10-4 M (2008) if sodium hydride (NaH) is dissolved in water?
5
74. A weak acid, HA, has a Ka of 1.00 x 10- • If 0.100 (a) H- + H 2O ➔ no reaction
mol of this acid is dissolved in one litre of water, (b) Hcaq) + H 20 ➔ H 20
the percentage of acid dissociated at equilibrium is (c) Hcaq) + H 2O(l) ➔ OH-+ H 2
closest to (d) None of these. ' . (1997)
14
(a) 1.00% (b) 99.9% 84. The ionic product of water at 25°C is 10- . Its ionic
(c) 0.100% (d) 99.0% (2007) product at 90°C will be,
75. Calculate the pOH of a solution at 25°C that contains (a) 1 X 10-14 (b) 1 x 10-16
1 x_ 10- 10 M ofhydron ium ions, i.e. H3O+. (c) 1 X 10-20 (d) 1 X 10-12 (1996)
(a) 4.000 (b) 9.000 85. If a is dissociation constant, then the total number
(c) 1.000 • (d) 7.000 (2007) of moles for the reaction, 2HI ➔ H 2 + 12 will be
76, The hydrogen ion concentration of a 10-8 M HCI (a) 1 (b) 1 - a
14
• aqueous solution at 298 K (~ = 10- ) is •. ·cc) 2 (d) 2 -a (1996)
 56 EET-AIPMT Chapterwise T0picwise s I
tl\.-b& N . . aIJtlori.
.~
1 hide ion
(a) presence Of HCl decreases r the sup lubility of M 2S salt 1s 3.s )( lo-1
120. solub'l'ty
, So 11
product.
6
. . . . .
concentration ul hides is more
(b) solubility product of group _11 : P . (a) 1.7 x 10- (b) 1.7 )( 10-11
(d) 1.7 )( l0-12 Eq
(c) 1.7 x 10-ts
than that of group IV sulphide ulphide ion
(c) presence ~f HCl increases the s Iii 121. The solubili2ty ofl 0~4 saturlated
fl oride is
s01uti0it ..
3Hj
concentrationss . - x mo es Per Ut ·•
• are u
product •
1s · lta
re. By;
(d) sulphides of group IV cations (2005)
(a) 22 x 10-11 (b) 14 )( 10-4 2N
unstable in HCl. . hie salt AX 2
d f
117. The solubility pro uct a sparingly
O . 1
soL)uis . .·2 (c) 2 x 10- (d) 32 x 10-ti
is 3 2 x 10-11. Its solubility (m moles/-4
0 122 The solubility product of Cus, A&is 4.
44 equ
(a) 5.6 X 10-<I (b) 3.l ;;~
(2004) •10-31, 10- and 10-~ respecth•e!y. 'Jhe:4
l 5.
(c) 2 x 10-4 (d) 4 x
2soc is these sulphides are 1n the order 1
••

(a) HgS > Ag2S > CuS (b) CuS::, >. By1
• •product of . .Agl at in ro- N
118. The solubility
4
1.0 x 10-16 mol2 L-2. The solub~1ty of A~1 mo) L-1) (c) Ag2S > CuS > HgS (d) Ag 5::, ~~
2
solution of KI at 2soc is approxunately (m
(a) 1.0 X 10-16
(b) 1.0 X 10-12
(C) 1.0 X 10-10,
G 123. The solubility of AgCI Will be lllininu.1111 ia ~
(a) 0.01 M CaCI2 (b) Pure \\rater
(c) 0.001 M AgNO3 (d) 0.0H,1 Na(l
(d) 1.0 x 10-s , · -4
(2003) 124
•Which one of the followmg is most SO!Ublei ( Equ
119.Solubility of MX2 type electrolytes is 0.5 x 10 (a) 1Bi2S3 (Ksp == 1 x 10-70) .
molnit., then find out K,p of electrol~~:· Ag
(b) 2S (K,p = 6 x 10-51 ) K"
(a) 5 x 10-12 (b) 25 x 10
(c) 1 x 10-u (d) 5 x 10-13 (c) CµS (Ksp == 8 X 10-37) 6.
(2002)
(d) MnS (Ksp == 7 X 10- 16) 1

t
'
I. (a) ANSWER KEY
2. (a) 3.
II. (d)
(a) 4. (d) 5. (c) 7.
12. (c) 13. (a) 14. (a) 15. (b)
6. (c) 7. (c) 8.
21. (d) 22. (a) 16. (d) (c) 9. (d)
23. (a) 24. (a) 25. 17. (a) 18.
31. (a) 32. (d) (b) 26. (c) (c) 19. (d)
33. (a) 34. (a) 35. '
27. (a) 28. I

41. (a) 42. (d) 36. (a) 29.

(b) 43. (a) 44. (d) 45. (c) 37. (c) 38. (a)
SI. (d) 52. (c) (b) 39. (d)
(a) 53. (c) 54. (d) 55. 46. (b) 47. (a) 48. K1:
61. • (a)
(d) 64. (b) 65. (b)
62. (c) 63. 56. (d), (a) 49. (c) •
71. (d) • 72. 57. '(b) 58.
(d) 73. (d) 74. (a) (d) 66. (c) (a) 59. (c)
81. (b) 75. (a) 76. 67. (b) 68. K:::
82. (a) 83. (c) 84. (d) (c) (d) 69. (a)
91. (a) 92. 85. (c) 86. 77. (d) 78.
(a) 93. (d) 94. (d) (b) (b) 79. (d)
IOI. (b) 102. (b) 95. (b) 87. (c) 88. 8.
103. (d) 96. (a) (a) 89. (a)
111.(b) 104. (b) 97. . (b) 98.
112. (d) 113. (b) 105. (c) (d) 99. (b)
121. (d) 114. (b) 106. (a) Kl:
122. (b) 115. (c) I 107. (c) . 108. (b) 109. (d)
123. (a) 116. (a)
124. (d) 117. (c) 118. (b} 119. (d) liC?
I ,
1(2 I
CNI
1. (a)_: Vapour pressure is directly related totem era
Greater IS the temperature, gteater Will be the va our p lure.
So to keep it constant, tCJnperature should be coP Ptessure,
2. (a) : 30 ~ 20 . . . nstant
Initial cone. 1 2~ 0 3~ ..