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    Pharmaceutical Organic Chemistry - I

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    Sivakumar

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    © All Rights Reserved
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    Pharmaceutical Organic Chemistry - I

    Uploaded by

    Sivakumar
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    Pharmaceutical Organic Chemistry - I

    Uploaded by

    Sivakumar

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    Code: 13R00105

    R13

    B.Pharm I Year (R13) Supplementary Examinations December 2016


    PHARMACEUTICAL ORGANIC CHEMISTRY – I
    Time: 3 hours Max. Marks: 70
    PART – A
    (Compulsory Question)
    *****
    1 Answer the following: (10 X 02 = 20 Marks)
    (a) What do you mean by electromeric effect?
    (b) Give the structure of 5 chloro, 3 hydroxy-hexanoic acid.
    (c) Give the structure of 2, 4 dinitro benzaldehyde.
    (d) Give the structure of (E)-2-pentene.
    (e) What product is obtained by the addition of HCl to 2-hexene in presence of H2O2.
    (f) Give an example of stereospecific reduction of 1-propyne.
    (g) What is Saytzeff’s rule?
    (h) Given an example of W.
    (i) Give an example of Oppenauer oxidation.
    (j) Why are acid chlorides more reactive than carboxylic acids towards nucleophilic substitution?

    PART – B
    (Answer all five units, 5 X 10 = 50 Marks)
    UNIT - I
    2 Describe in detail Bayer’s strain theory its merits and demerits.
    OR
    3 Describe the mechanism of free radical substation reaction of methane with chlorine.
    UNIT - II
    4 Explain the thermodynamic factors controlling 1, 2 and 1, 4 addition of HBr to Butadiene.
    OR
    5 Give the mechanism of SN1 and the factors that affect this reaction.
    UNIT - III
    6 Elucidate the theory of reactivity and orientation in Electrophilic Aromatic Substitution reaction.
    OR
    7 Give two reactions each of Naphthalene, Anthracene, Phenanthrene and Naphthacene.
    UNIT - IV
    8 Explain Kolbe-Schmidt and Reimer-Tiemann reactions with mechanism and examples.
    OR
    9 Give five general reactions of alcohols.
    UNIT - V
    10 Explain the stability of the carboxylate anion and the factors affecting the stability.
    OR
    11 Give some reactions of malonic and acetoacetic esters.

    *****

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