ChemicalBonding - D13 Sep 2023

Yogendra sir
chapter 4 Std : Xl Sci. Date : 14/09/23

Total Marks: 40 Chemical Bonding Time: 1 hours
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [40]
1. Which of the following has maximum bond angle ?
(A) H2O (B) NH3 (C) CO2 (D) CH4
2. Which of the following is not a resonance and structure of CO2 ?
(A) O = C = O (B) +O º C – O– (C) +O – C º O+ (D) –O – C º O+
3. Which of the following has coordinate covalent bond ?
(A) H2O (B) CaCl2 (C) O3 (D) N2
4. In which hybridization the maximum bond angle in following ?
(A) sp (B) sp2 (C) sp3 (D) dsp2
5. Who proposed the valence bond theory ?
(A) Pouling (B) van der waals (C) Lewis (D) Mulliken
6. Which is the correct order number for bond length of C – O in CO, CO32– and CO2 ?
(A) CO2 < CO32– < CO (B) CO < CO32– < CO2 (C) CO < CO2 < CO32– (D) CO32– < CO2 < CO
7. Which of the following molecule/ion have not unpaired /single electron ?
(A) N2+ (B) O22– (C) O2 (D) B2
8. In which one, all the bonds are not equal ?
(A) BF4– (B) NH4+ (C) C2H4 (D) SiCl4
9. Which one has least energy in given molecular orbitals ?
(A) s2pz (B) s1s (C) s*2s (D) p2px
10. Which one is correct Lewis structure of N2 ?

gg gg gg gg gg gg
(A) :N º N: (B) : N º N : (C) : N – N : (D) : N = N :
gg gg gg gg
11. In which molecule coordinate bond is not present ?
(A) H3O+ (B) NH4+ (C) BF4– (D) CO32–
12. In which molecule the bond is form by p – p overlapping ?
(A) H2 (B) H2O (C) HCl (D) Cl2
13. AB3 molecule has trigonal pyramidal shape state no. of bonding and nonbonding electrons ?
(A) 3 and 1 (B) 2 and 2 (C) 1 and 3 (D) 0 and 4
14. In which hybridization 90° angle are more ?
(A) dsp2 (B) sp3d2 (C) dsp3 (D) sp3d
15. Which one has strong H bonding from the following ?
(A) F –– H ····· F (B) O –– H ····· Br (C) O –– H ····· S (D) O –– H ····· O
16. Which compound has incomplete octet ?
(A) BCl3 (B) NH3 (C) PCl3 (D) ICl
17. Which one is correct from the following ?
(A) H2O, sp2, linear (B) NH4+, dsp2 square planar
(C) H2O, sp3, angular (D) CH4, dsp3 tetrahedral
18. Which one of the following is paramagnetic and having 0.5 bond order ?
(A) O2– (B) N2 (C) F2 (D) H2+
Which one of the following is paramagnetic and having 0.5 bond order ?
(A) O2– (B) N2 (C) F2 (D) H2+
19. Which one is correct statement of the following ?
(A) H2+ and H2– both are equal stable (B) H2+ and H2– does not exist
(C) H2+ is more stable than H2 (D) H2+ is less stable than H2–
20. The bond length of H2 , F2 and HF is 74 pm, 144 pm and 92 pm respectively. Which one is most
stable ?
(A) F2 (B) H2 (C) HF (D) All are equal
21. State bond length of O – O and O = O in ozone.
(A) 148, 121 (B) 148, 188 (C) 121, 108 (D) 148, 148
22. State nonbonding electron on P in PCl5.
(A) 5 (B) zero (C) 3 (D) 2
23. What is the bond length in O3 molecule ?
(A) equal to O = O (B) equal to O – O
(C) between O – O and O = O (D) All of these
24. Which one has ionic and covalent bond ?
(A) KCl (B) KCN (C) O2 (D) C2H6
25. Which orbital has molecular symmetry ?
(A) p (B) p* (C) s (D) y*
26. Which molecular orbital is form by positive overlapping of
(A) (B)
(C) (D) :
27. As per MO theory last electron of N2 filled in which molecular orbital ?
(A) sMO (B) pMO (C) 2p (D) sp
28. Which statement is not correct ?
(A) s-bond is weak than p-bond (B) s-bond is strong than p-bond
(C) C – C is shorter than C = C (D) double bond is stronger them single bond.
29. What is the correct bond order for given electron configuration ? (s1s)2 (s*1s)2 (s2s)2 (s*2s)2 (s2pz)1
(A) 0.5 (B) 1 (C) 0 (D) 1.5
30. What is correct for bond order ?
no. of e_ in no. of e_ in
BMO - ABMO
(A) BO = ABMO no. (B) BO =
2
no. of e_ in no. of e_ in
ABMO - BMO
(C) BO = (D) BO = BMO – BMO
2
31. Arrange according to bond order ?
(A) NO < C2 < O2– < He+ (B) C2 < NO < He+ < O2–
(C) He+ < O2– < NO < C2 (D) He+ < O2– < C2 < NO
32. Which are has highest ONO bond angle ?

(A) NO3– (B) NO2– (C) NO2 (D) NO2+
33. Which is correct order of bond length ?
(A) O2 < O3 < O22– (B) O2 < O22– < O3 (C) O22– < O3 < O2 (D) O = O22– > O3
34. Shape of XeF4 ........
(A) linear (B) pyramidal (C) tetrahedral (D) square planar
35. Which one is correct order of dipole moment ?
(A) CH4 < NF3 < NH3 < H2O (B) NF3 < CH4 < NH3 < H2O
(C) NH3 < NF3 < CH4 < H2O (D) H2O < NH3 < NF3 < CH4
36. Which is the correct Lewis structure of N2 ?
(A) N º N (B) N º N (C) N – N (D) N = N
37. Which has strongest H-bond ?

(A) S — H ----- O (B) O — H ----- S (C) F — H ----- F (D) O — H ----- N
38. Shape of PCl3 ........
(A) Trigonal pyramidal (B) Tetrahedral (C) Pyramid (D) Square planar
39. CaO and NaCl has same crystal structure and same radius if lattice enthalpy of NaCl is U than the
lattice enthalpy of CaO is ?
U
(A) (B) U (C) 2U (D) 4U
2
40. Which orbital’s are equivalent in homonuclear molecule ?
(A) s1s and s2s (B) p2px and p2py (C) p2px and s2pz (D) s2px and s*
2pz

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Yogendra sir

chapter 4 Std : Xl Sci. Date : 14/09/23

10. Which one is correct Lewis structure of N2 ?

32. Which are has highest ONO bond angle ?

37. Which has strongest H-bond ?

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